• Title/Summary/Keyword: 철(II)

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Alkaloids from fruits of Piper nigrum (후추(Piper nigrum) 열매의 Alkaloids)

  • Park, Il-Kwon;Lee, Hak-Ju;Lee, Sang-Gil;Shin, Sang-Chul;Park, Ji Doo;Choi, Don-Ha;Ahn, Young-Joon
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.5
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    • pp.88-95
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    • 2003
  • Five amide alkaloids were isolated from the fruits of Piper nigrum. The structures were determined as : pellitorin (I), quineensine (II), pipercide (III), retrofractamide A (IV), and piperine (V) respectively on the basis of spectrosopic data.

Preparation and Characterization of Pt-Fe/Carbon Black Nanocatalyst for Anion Exchange Membrane in Alkaline Electrolysis (음이온 교환막 수전해용 Pt-Fe/카본블랙 나노 촉매 제조 및 특성)

  • SUNGKOOK CHO;JAEYOUNG LEE;HONGKI LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.715-722
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    • 2022
  • Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.

Developing the Deep Text-to-Ontology Generator based on Neuro-Symbolic Architecture (뉴로-심볼릭 구조 기반 온톨로지 생성기 제안)

  • Hyeoung-Cheol Park;Eun-Su Yun;Min-Jeong Kim;Hui-Jae Bae;Yu-Jin Shin;Jee-Hang Lee
    • Proceedings of the Korea Information Processing Society Conference
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    • 2023.11a
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    • pp.672-674
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    • 2023
  • 본 논문은 뉴로-심볼릭 구조를 바탕으로 일반 텍스트로부터 온톨로지 생성이 가능한 심층 신경망 기반 온톨로지 추출기를 제안한다. 온톨로지 추출 단계를 (i) 온톨로지 학습 및 (ii) 온톨로지 생성의 2 단계로 상정, (i) 일반 텍스트로부터 문장 구조 및 논리적 관계를 학습하는 트랜스포머 기반 심층 생성 신경망 출력을 이용하여 (ii) 계층적으로 결합한 심볼릭 추론기로 온톨로지를 생성하는 뉴로-심볼릭 구조 온톨로지 추출기를 구현하였다. 1800 개 훈련 집합으로 학습 후 200 개 테스트 집합으로 평가한 결과, 정확도 91.9%, Precision 100%, Recall 99.1%로 비교 모델 OpenIE 의 성능에 비해서 각각 83.8%, 1.8%, 3.5% 개선된 것을 확인하였다. 정성적 품질에 있어서, 복잡한 문장 (예: 관계대명사, 접속사, 중첩 구조)에서도 비교 모델에 비해 더 정밀한 온톨로지 생성 결과를 보였다.

Application of Iron-Catalyzed Air Oxidation Process for Organics and Color Removals in Recalcitrance Flexographic Inks Wastewater (난분해성 후렉소잉크 폐수중 유기물 및 색도제거를 위한 철촉매 공기산화 공정의 적용)

  • Cho, Yong Duck;Yoon, Hyon Hee;Park, Sang Joong;Kim, Jong Sung;Lee, Sang-Wha
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.4
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    • pp.487-498
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    • 2006
  • The oxidation processes of metal catalysis were practically applied into the flexographic inks wastewater treatment to derive the most effective and economical system among all the processes of iron-salts coagulation, iron-catalyzed air oxidation, and coagulation followed by biological treatment. The iron concentration and pH were optimized as $2.8{\times}10^{-3}mol$ and 5.5~6.0, respectively, for all the oxidation processes. At the optimal reaction conditions, the removal efficiencies of $TCOD_{Mn}$ and Color were as follows for the respective process: i) 75% $TCOD_{Mn}$ and 77% Color removals for iron-salts coagulation, ii) 91% TCODMn and 90% Color removals for iron-catalyzed air oxidation, iii) 74~92% $TCOD_{Mn}$ and 81~90% Color removals for coagulation followed by biological treatment. Based on the economical and technological aspects, iron-catalyzed air oxidation was confirmed as the most effective process in the treatment of industrial wastewater.

Photochemical Degradation of Polymers (고분자 물질의 광화학적 분해)

  • Sang Chul Shim;Hong Lim
    • Journal of the Korean Chemical Society
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    • v.19 no.6
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    • pp.454-462
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    • 1975
  • The photodegradation of polystyrene and polyethylene was studied utilizing several additives to promote photooxidation. Polymer films with small amount of additives were irradiated with ultraviolet lamps in Rayonet Photochemical Reactor. The progress of photodegradation was followed by measuring the intensities of carbonyl and hydroxyl stretching bands in infrared spectra as well as the viscosity changes. It was found that the increase of carbonyl or hydroxyl peaks was proportional to the decrease of the molecular weight of polymers under study. Iron(II, III) complexes of dithiocarbamate and their analogs showed good results.

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Indirect Assessment of Obesity and Correlation between Energy Intake and Energy Expenditure of Middle School Students (중학생의 간접적 비만판정과 에너지섭취 및 소비량과의 관계)

  • Kim, Yun-Hwa;Jang, Hyun-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.2
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    • pp.291-299
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    • 1997
  • This study was accomplished to investigate the prevalence of obesity in 371 Kumi-city middle school students. The means of this study were anthropometric measurement and questionnaires about nutrient intake and energy expenditure. Anthropometric measurements were height, weight, arm circumference and skinfold thickness(biceps, triceps, subscapular, supraliac, calf). The results obtained are as follows: Energy, calcium, iron intake for boys were lower than RDA. Iron intake was low in girls. Energy intake is lower than energy expenditure and RDA for boys. Energy intake, energy expenditure and RDA for girls were balanced. The average height, weight and arm circumference of boys were respectively 160.0cm, 49.4kg, 23.1cm and those of girls were respectively 155.9cm, 48.9kg, 22.6cm. Prevalence of obesity was respectively 5%, 4%, 7%, 4%, 59%, 15%, 14%, 24% for boys and 6%, 10%, 13%, 9%, 30%, 7%, 1%, 3496 for girls by RBW, BMI, RI, OI, %Fat I, %FatII, %FatIII, triceps. Correlation between subscapular skinfold thickness and BMI, RI, OI and %FatII showed high.

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전이금속 (Ru$^{3+}$, Ni$^{2+}$, Cu$^{2+}$, Pd$^{2+}$)-Polyaza(N$_4$) 착물의 합성과 올레핀 산화반응에 대한 촉매적 활성

  • Park, Yu Cheol;Kim, Seong Su;Na, Hun Gil;Lee, Dong Cheol;Sin, Sang Hui;Byeon, Jong Cheol
    • Journal of the Korean Chemical Society
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    • v.38 no.4
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    • pp.295-301
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    • 1994
  • The Ru(Ⅲ), Ni(Ⅱ), Cu(Ⅱ), and Pd(Ⅱ) complexes of N$_4$-polydentate ligands(meso-Me$_6$-[14]-ane, rac-Me$_6$-[14]-ane, and cyclam) have been prepared and their catalytic activity and selectivity in the oxidation of olefins in the presence of oxidant such as NaOCl, H$_2$O$_2$, t-BuOOH, and PhIO studied. The oxidations of cyclohexene, 1-hexene, cyclooctene, 1-octene, and styrene as substrates have been investigated gas chromatographically. The Ru(Ⅲ)-N$_4$ complexes showed high selectivity for epoxide in the catalyzed oxidation of olefins with NaOCl. The catalytic activities of Ru(Ⅲ)-N$_4$ complexes were discussed in terms of the flexibility of N$_4$-polydentate ligands, the Ru(Ⅲ)-Cl bond interaction and the steric effect of oxidants. The oxidation of 1-octene using PhIO as oxidant was carried out to verify. The Pd(Ⅱ) complex turned out to be more active catalyst than the Ni(Ⅱ) complexes.

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Effect of Ferrous Ion on the Formation of Exotoxin A from Pseudomonas sp. PY002 and Cloning of it's Gene (Pseudomonas sp. PY002에서 Exotoxin A의 생성에 미치는 철 이온의 영향과 Exotoxin A 유전자의 클로닝)

  • Choi, Sun-Ah;Kim, Ho-Sang;Choi, Ji-Young;Kang, Jeong-Suk;Kim, Chun-Sung;Kim, Duck-Lae;Kim, Young-Ju;Yeo, Myeong-Gu;Park, Yeol
    • Korean Journal of Microbiology
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    • v.35 no.1
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    • pp.7-12
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    • 1999
  • By SDS-polyacrylamide gel elcctrophoresis (SDS-PAGE) and immunoblot analysis that a protein with 66,000 daltons in size was recognized by P. aeruginosa anti-exotoxin A from P. sp. PY002. The yields of exotoxin A in P. sp. PY002 culture were influenced by the concentration of iron in the culture media. Increasing of the exotoxin A production and siderophore production was made slight increasing in the MKB medium. On the other hand, to clone the gene encoding the exoloxin A genomic library of P. sp. PY002 was constructed in pBluescript SK(+). From this library a exotoxin A homologous gene was isolated by immunological hybridization method using P. aemginosa anti-exoloxin A as a probe. Two putative clones were isolated and designated pETA23 and pETA42. Thc restriction analysis ol pETA42 demonstrated that thc 1760 bp insert contained one NcoI, PvuII, SstI, Kpnl and EcoRI site and three SmaI and HaeD sites.

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Ecological Analysis and Environmental Evaluation of Aquatic Insects in Agricultural Ecosystem (농업생태계 내 수서곤충류의 생태분석 및 환경평가)

  • Kim, Jong-Gill;Choi, Young-Cheol;Choi, Ji-Young;Sim, Ha-Sik;Park, Hae-Chul;Kim, Won-Tae;Park, Byung-Do;Lee, Jong-Eun;Kang, Ki-Kyung;Lee, Duck-Bae
    • Korean journal of applied entomology
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    • v.46 no.3
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    • pp.335-341
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    • 2007
  • The main habitats of diving beetles in agricultural ecosystems were identified as ponds, irrigation channels, and reservoirs, where the water system is maintained throughout the year. Four species, Cybister japonicus, Cybister brevis, Hyphydrus japonicus and Noterus angustulus, were selected as biological indicators which can be used to evaluate the healthiness of the agricultural ecosystem. The species number of 4 indicator species, the species number of diving beetle species, and the diversity index were used as factors for environmental evaluation. The evaluation was classified into grades $I{\sim}IV$. The non-fertilizer and non-pesticide agricultural practicing area and the sustainable agricultural practicing area were evaluated as grades $I{\sim}II$, and the general agricultural area to be relatively fine with a grade II. However, the analysis indicated the agricultural areas near a residential area and an industrial complex to be poor with a grade of IV, suggesting that immediate improvement in the agricultural environment is needed.

A Study on the Treatment of Petroleum-Contaminated Soils Using Hydrogen Peroxide (석유로 오염된 토양의 과수를 이용한 처리에 관한 연구)

  • 최진호;김재호;공성호
    • Journal of Korea Soil Environment Society
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    • v.2 no.3
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    • pp.49-57
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    • 1997
  • Naturally-occurring iron minerals, goethite and magnetite, were used to catalyze hydrogen peroxide and initiate Fenton-like oxidation of silica sand contaminated with diesel, kerosene in batch systems. Reaction conditions were investigated by varying H$_2$0$_2$concentration(0%, 1%, 15%), initial contaminant concentration(0.2, 0.5, 1.0g diesel and kerosene/kg soil), and iron minerals(1, 5wt% magnetite or goethite). Contaminant degradations in silica sand-iron mineral-$H_2O$$_2$ systems were identified by determining total petroleum hydrocarbon(TPH) concentration. In case of silica sand contaminated with diesel(1g contaminan/kg soil with 5wt% magnetite) addition of 0%, 1%, 15% of $H_2O$$_2$showed 0%, 25%, and 60% of TPH reduction in 8 days, respectively When the mineral contents were varied from 1 to 5wt%, removal of contaminants increased by 16% for magnetite and 13.1% for goethite. The results from system contaminated by kerosene were similar to those of the diesel. Reaction of magnetite system was more aggressive than that of goethite system due to dissolution of iron and presence of iron(II) and iron(III); however, dissolved iron precipitated on the surface of iron mineral and seemed to cause reducing electron transfer activity on the surface and quenching $H_2$$O_2$. The system used goethite has better treatment efficiency due to less $H_2$$O_2$ consumption. Results of this study showed possible application of catalyzed $H_2$$O_2$ system to petroleum contaminated site without addition of iron source since natural soils generally contain iron minerals such as magnetite and goethite.

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