• The tire
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• s.49
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• pp.9-14
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• 1973

공기를 활용하고 있는 중요상품중에 자동차타이어가 있다. 그러나 긴 타이어의 역사에 있어서도 이 공기를 완전히 지배하기까지에는 아직 이르지 못했다. 즉 타이어의 빵꾸! 라고 하는 사고가 바로 그것이다. 따라서 이 빵꾸를 없애는 일은 타이어기술자의 오랜 꿈이기도했다. 그래서 우선 맨 먼저, 생각된 상품에 튜우브레스 타이어가 있다. 튜우브레스 타이어는 튜우브에 대체되는 인너어라이너어라고 하는 고무층을 타이어내에 첩부함으로써 개발되었다. 그러나 림과의 관계로 해서 오로에는 안맞고 공기누설도 되는 등으로 해서 1950년대에 등장했으면서도 저신장, 일본에 있어서도 17년전에 국산화해서 시판되었으나 시장으로부터는 그다지 환영을 못받았다. 연이나 1965년에 이르러 튜우브레스 타이어용 인너어라이너어를 위해서만 존재하는 염소화부칠이라고 하는 고무가 앳소의 손에 의해서 개발되었다. 그 공기누설방지도는 천연고무의 7부, 일반합성고무의 5부, 또한 도로는 고속화에로 정비가 진척되고 타이어 안전성은 공기를 활용하고 있는 중요상품중에 자동차타이어가 있다. 그러나 긴 타이어의 역사에 있어서도 이 공기를 완전히 지배하기까지에는 아직 이르지 못했다. 즉 타이어의 빵꾸! 라고 하는 사고가 바로 그것이다. 따라서 이 빵꾸를 없애는 일은 타이어기술자의 오랜 꿈이기도했다. 그래서 우선 맨 먼저, 생각된 상품에 튜우브레스 타이어가 있다. 튜우브레스 타이어는 튜우브에 대체되는 인너어라이너어라고 하는 고무층을 타이어내에 첩부함으로써 개발되었다. 그러나 림과의 관계로 해서 오로에는 안맞고 공기누설도 되는 등으로 해서 1950년대에 등장했으면서도 저신장, 일본에 있어서도 17년전에 국산화해서 시판되었으나 시장으로부터는 그다지 환영을 못받았다. 연이나 1965년에 이르러 튜우브레스 타이어용 인너어라이너어를 위해서만 존재하는 염소화부칠이라고 하는 고무가 앳소의 손에 의해서 개발되었다. 그 공기누설방지도는 천연고무의 7부, 일반합성고무의 5부, 또한 도로는 고속화에로 정비가 진척되고 타이어 안전성은 점점 중시되는 시대로 진입해서 이제 또다시 튜우브레스시대의 재래를 마지하려 하고 있는 것이다. 그렇기는 해도 이 염소화부칠이라고 하는 고무의 수행하는 기능은 크다. 그저 공기누설에 강하다는 것만은 아니다. 편평라디알스틸시대를 지향하는데 있어서 부가결한 존재로 되어 가는 것 같다.

• Elastomers and Composites
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• v.44 no.1
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• pp.41-46
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• 2009

The effects of temperature and curing systems on the compression set of natural rubber (NR) at constant load were investigated. NR was compounded with various amounts of sulfur and DCP in order to obtain various crosslink densities and curing systems. Compression sets at constant load were compared with those at constant strain. Compression set at constant load was more affected by changes in crosslink density than compression set at constant strain, due to the differences of exerted strain energy density. Compression set of sulfur cured NR under constant load was increased with increasing load and temperature, but the compression set of DCP cured NR was not changed by increasing load and temperature.

• Elastomers and Composites
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• v.47 no.2
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• pp.156-161
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• 2012

Difference in recovery behaviors from the circular deformation of natural rubber (NR) composites aged in air and distilled water, respectively were investigated. Recoveries of the samples aged in air were larger than those of the samples aged in distilled water. Recovery rates of the samples reinforced with filler were faster than those of the unreinforced ones. Recovery rates of the carbon black-filled samples were faster than those of the silica-filled ones. Difference in the recovery behaviors according to the aging media can be explained by the crosslinking density changes and the annealing effect.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.144-148
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• 2011

Various types of accelerators, thiuram (TMTD), thiazole (MBTS), and sulfenamide (CBS) are added into a silica filled natural rubber (NR) compound. Their effects on vulcanization properties are also investigated. TMTD shows a fast vulcanization rate and a higer maximum torque ($T_{max}$), as well as excellent mechanical properties (hardness, 300% modulus, tensile strength, elongation). MBTS shows a moderate vulcanization rate, a lower $T_{max}$, and mechanical properties. Finally, CBS shows a slow vulcanization rate but excellent mechanical properties. The same vulcanization trend can be found in carbon black filled NR compounds.

• Elastomers and Composites
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• v.41 no.2
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• pp.88-96
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• 2006

The self-sealing rubber material for a fuel cell which has self-sealing ability, in case of fuel leakage, was studied. Cure characteristics, density, swelling, and surface morphology of foamed natural rubber were investigated with carbon black and with processing oil within the range of $10{\sim}30phr$. The rheological properties indicated that the value of $ts_2$ and the value of $Tc_{90}$ were increased with increasing a content of processing oil, while carbon black did not show a similar trend. A difference in density by foaming was decreased to one fifth scale compared to the initial value. According to the swelling test of foamed natural rubber in fuel C, isooctane and toluene, all the self-sealing action was finished in two minutes. From the SEM image for the surface of rubber compounding, a foaming by sodium bicarbonate was found to be unequal and consecutive foaming cell.

• Journal of Adhesion and Interface
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• v.8 no.2
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• pp.15-21
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• 2007

To prepare a natural rubber-based pressure-sensitive adhesive (PSA) for protection film of opto- functionalized sheet, natural rubber (NR) was blended with a DCPD type tackifier and three types of aliphatic hydrocarbon resins, respectively. Also, to supply low cohesion strength of NR, in the fixed ratio of tackifier, synthetic rubber, styrene-isoprene-styrene (SIS) block copolymer was blended with NR as a function of SIS contents. PSA performance of prepared PSAs was evaluated using probe tack and peel strength. Probe tack of NR/tackifier blends was increased with increasing tackifier contents, and showed maximum peak. In addition, probe tack of NR/tackifier blends slightly increased with increasing softening point of aliphatic hydrocarbon resins. Their peel strength increased up to 50 wt% of tackifier contents, but in the over contents of tackifier, they showed stick-slip failure mode. Finally, probe tack of NR/SIS/tackifier blends showed the maximum values at 20~40 wt% of tackifier contents, but at 20 wt% of tackifier contents, they showed fibrillation. For this reason, peel strength showed maximum values at 40 wt% of tackifier contents.

• Elastomers and Composites
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• v.34 no.2
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• pp.147-155
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• 1999

Waxes compounded into rubber migrate to the surface and form a protection film on the rubber surface. In general, antiozonants were used with wax to protect ozonation of rubber. Influence of wax barrier formed on the surface of a rubber vulcanizate on migration of antiozonants was studied using natural rubber (NR) vulcanizates containing various type waxes. IPPD (N-isopropyl-N'-phenyl-p-phenylenediamine), HPPD (N-l,3-dimethylbutyl-N'-phenyl-p-phenylenediamine), SBPPD (N,N'-di(sec-butyl)-p-phenylenediamine), and DMPPD (N,N'-di(1,4-dimethylpentyl)-p-phenylenediamine) were employed as antiozonants. Migration experiments were performed at constant temperatures of 60 and $80^{\circ}C$ for 10, 20, 30 days using a convection oven. The migration rates of the antiozonants in the vulcanizate without wax are faster than those in the vulcanizates containing waxes. The antiozonants migrate slower in the vulcanizate containing wax with a high molecular weight distribution than in the vulcanizate with a low one. The migration rates of DMPPD and SBPPD are faster than those of HPPD and IPPD.

• Elastomers and Composites
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• v.12 no.1
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• pp.43-46
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• 1977

브롬화 부틸고무는 새로운 연속적(連續的)인 방법(方法)에 의해 제품(製品)의 질(質)이 균일(均一)하고 안정(安定)한 제품(製品)을 얻을 수 있는 바 이것은 소위(所謂) 상품명(商品名)으로 Folysar Bromobutyl X2라 한다. 이 고무는 일반(一般) 부틸고무와는 달리 여러가지 장점(長點)을 지니고 있다. 다시 말하면 일반(一般) 부틸고무에 비(比)해 첫째 가황속도(加黃速度)가 빠르며, 둘째 천연(天然)고무 또는 SBR과 같은 불포화(不飽化) 고무들과 혼합사용(混合使用)이 가능(可能)하며, 셋째 이러한 고무들과의 혼합사용시(混合使用時) 접착력(接着力)도 우수(優秀)하며 마지막으로 글로로프렌이나 EPDM과도 혼합(混合)이 가능(可能)하기 때문에 여러가지 용도(用途)로 사용(使用)할 수 있다. 이러한 점(點)을 참작(參酌)하여 브롬화 부틸고무의 이용도(利用度)는 (1) 타이어중, tubeless 타이어의 inner liner, white side wall, sidewall coverstrip 그러고 라디얼 타이어에 이용(利用)될 수 있고, (2) 내열성(耐熱性)이 요구(要求)되는 고속용(高速用) 또는 heavy-duty 타이어의 튜우브, 자동차(自動車) 부품(部品) 예(例)컨대 mount등(等)에 이용(利用)할 수 있을 뿐만 아니라 행크 라인닝, 고무 호오스, 콘베어 고무벨트, 의료용 병마개, 접착제등(等)에 광범위(廣範圍)하게 이용(利用)할 수 있다.

• Polymer(Korea)
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• v.36 no.2
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• pp.235-244
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• 2012

A thiazole type accelerator MBT (2-mercapto benzothiazole) was added into silica filled natural rubber (NR) compound with various concentrations (0, 1, 2, 3, 4 phr). The effects of MBT on the cure rate, mechanical property, degree of rubber-filler interaction (${\alpha}_F$), crosslinking density, and viscoelastic property ($tan{\delta}$) were investigated. As accelerator concentration increased, the $t_{s2}$ and $t_{90}$ decreased and the crosslinking density and modulus at 300% elongation increased. The tensile strength and elongation increased up to 3 phr and no further increased at 4 phr. The $tan{\delta}$ value measured at room temperature was higher than that of the $70^{\circ}C$. The ${\alpha}_F$ value was not affected by the addition of MBT. The mechanisms for the vulcanization rate were reviewed.

• The tire
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• s.20
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• pp.31-51
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• 1969