• Title/Summary/Keyword: 천연냉매

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Next generation absorption technologies in USA and Japan(2) - Next generations technologies in Japan - (미국 및 일본의 차세대 홉수식 열펌프 기술(2) - 일본의 차세대 흡수식 연구동향 -)

  • 강용태
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.28 no.4
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    • pp.300-314
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    • 1999
  • 가스구동 흡수식 시스템은 인류와 환경에 여러 가지 유익을 가져다준다. 첫째, 시스템의 고효율에 따른 매력적인 경제성을 제공하고, 둘째 천연가스의 사용으로 인하여 여름철 피크 전력소요(peak electric demand)를 완화하고, 셋째 이산화탄소 ($CO_2$)의 발생을 감소시킴으로써 지구 온난화 현상을 완화한다 실제로 가스구동 흡수식 시스템으로부터의 $CO_2$발생량은 증기보일러를 사용하는 전기구동 냉동기에 비하여 85% 수준인 것으로 보고되었다(Suzuki 등). 넷째로 암모니아 및 물과 같은 환경 친화적인 냉매들을 사용함으로서 오존층을 파괴하는 Chlorofluorocarbon(CFC) 및 Hydrochlorofluorocarbon(FCFC)계 냉매들을 대체할 수 있는 이점이 있다.

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Characteristics of Cryogenic Cascade Refrigeration Cycle for Liquefaction of Natural Gas with the Pressure Drop of Heat Exchanger (LNG 열교환기의 압력강하에 따른 천연가스 액화용 초저온 캐스케이드 냉동사이클 특성)

  • Yoon, Jung-In;Choi, Kwang-Hwan;Son, Chang-Hyo;Kwag, Jin-Woo;Baek, Seung-Moon
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.6
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    • pp.756-761
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    • 2012
  • Natural gas is converted in to LNG by chilling and liquefying the gas to the temperature of $-162^{\circ}C$, when liquefied, the volume of natural gas is reduced to 1/600 of its standard volume. This gives LNG the advantage in transportation. In this study, the effects of the pressure drop of refrigerant and natural gas in the LNG heat exchanger of cryogenic cascade refrigeration cycle were investigated and then the design criteria for the pressure drop of refrigerant and natural gas of the LNG heat exchanger were proposed. The pressure drop of the cascade liquefaction cycle was investigated and simulated using HYSYS software. The simulation results showed that the pressure drop in the LNG heat exchanger is set to 50 kPa considering the increase in the compressor work and COP of cryogenic cascade liquefaction cycle.

A Study on the Price Evaluation Per 1 Ton of Liquefied Natural Gas According to the Refrigerants Supply Temperature in the Electric Refrigerator (전기식 냉동기에서 냉매의 공급온도에 따른 액화천연가스의 톤당 냉열 가격 산출에 대한 연구)

  • KIM, YONUNGWOO;PARK, ILSOO;CHO, JUNGHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.473-477
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    • 2019
  • In this paper, cold heat price contained in the 1 ton/h of LNG has been evaluated using PRO/II with PROVISION release 10.2 from Aveva company when LNG is used to liquefy several refrigerants instead of using vapor recompression refrigeration cycle. Normal butane, R134a, NH3, R22, propane and propylene refrigerants were selected for the modeling of refrigeration cycle. It was concluded that LNG cold heat price was inversely proportional to the refrigerant supply temperature, even though LNG supply flow rate is not varied according to the refrigerant supply temperature.

Advanced Dual Refrigerant Expansion Cycle for LNG Liquefaction (천연가스 액화용 이중 냉매 팽창 사이클)

  • Kim, Minki;Kim, Mungyu;Lee, Kihwan;Kim, Hyobin;Lee, Donghun;Min, Joonho;Kim, Jinmo
    • Plant Journal
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    • v.15 no.2
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    • pp.46-55
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    • 2019
  • This paper presents a LNG Liquefaction cycle configuration using two stages of methane expansion (i.e. spliting into two stages as warm & cold to generate an additional inflection point within a cold composite curve) and a single stage of nitrogen expansion to improve the efficiency of the conventional Methane & Nitrogen Expansion Cycle. In comparison with Double Nitrogen Expansion Cycel and Methane & Nitrogen Expansion Cycle, the cycle efficiency has increased approximately from 13.92 and 13.13 to 12.08 kW/ton/day (8~15% efficiency increase). A Life Cycle Cost (LCC) analysis based on Net Present Value (NPV) also show an improvement in therms of project NPV, against a minor increment of a CAPEX.

Case Studies for Optimizing Energy Efficiency of Propane Cycle Pressure Levels on C3-MR Process (C3-MR 공정의 프로판 사이클 압력 레벨에 따른 에너지효율 최적화를 위한 사례연구)

  • Lee, In-Kyu;Tak, Kyung-Jae;Lim, Won-Sub;Moon, Il;Kim, Hak-Sung;Choi, Kwang-Ho
    • Journal of the Korean Institute of Gas
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    • v.15 no.6
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    • pp.38-43
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    • 2011
  • Natural gas liquefaction process runs under cryogenic condition, and it spends large amount of energy. Minimizing energy consumption of natural gas liquefaction process is an important issue because of its physical characteristics. Among many kinds of natural gas liquefaction processes, C3-MR(Propane Pre-cooled Mixed Refrigerant) process uses two kind of refrigerants. One is the propane as the pure refrigerant(PR) and the other is the mixed refrigerant(MR). In this study, to find the optimal compressing level, propane cycle is simulated on different pressure level. The case study result shows relationship between energy consumption and pressure level. As a result, the conclusion is that at a higher pressure level, process consumes lower energy. At 5 pressure-levels, energy consumption is 23.7% lower than 3 pressure-levels.

Comparative Study on the Properties Estimation of the Constituents of the Natural Gas and Refrigerant Mixtures Between GERG-2004 Model and Peng-Robinson Equation of State (GERG-2004 모델식과 Peng-Robinson 상태방정식을 이용한 천연가스 및 냉매 구성성분들의 물성 비교연구)

  • Kim, Mi-Jin;Rho, Jae-Hyun;Kim, Dong-Sun;Cho, Jung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.2
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    • pp.906-918
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    • 2012
  • In this study, we compared with results simulated by EOS(Equation of State) using Peng-Robinson model and GERG-2004 model for estimating vapor pressure, latent heat of vaporation, liquid density, and binary isotherm vapor-liquid equilibrium on pure components composing natural gases. We obtained the simulated results that while EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model for estimating liquid density, but rather it is less accurate for estimating binary isotherm vapor-liquid equilibrium. On the other hand, the use of Costald model in EOS using Peng-Robinson model for increasing more accuracy to calculate liquid density is almost same as EOS using GERG-2004 model within the error of 1 % compared with experimental data. Also, we confirmed that on the estimation of binary isotherm vapor-liquid equilibrium, EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model, but they are almost same.

Study on Simulation and Optimization of C3MR Liquefaction Cycle (천연가스 액화공정의 C3MR 냉동사이클의 공정모사와 최적화에 관한 연구)

  • Park, Chang Won;Cha, Kyu Sang;Lee, Sang Gyu;Lee, Chel Gu;Choi, Keun Hyung
    • Journal of the Korean Institute of Gas
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    • v.17 no.1
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    • pp.67-72
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    • 2013
  • The LNG liquefaction plant which have a higher value-added business in the LNG value chain takes about 35% of total cost. Liquefaction process is core technology of liquefaction plant. Almost all of cost which was consumed from the liquefaction plant, using for operation energy of liquefaction process. The cost can be reduced by increasing efficiency of liquefaction cycle. C3MR(propane pre-cooled, mixed refrigerant cycle) which liquefies NG using propane and MR cycle has the high efficiency, so C3MR is mostly used liquefaction process in LNG industry. In this study, process simulation and analysis were performed for C3MR process. C3MR process variables were found through this simulation and analysis, and then the process optimization was performed. It is considered that the results of process analysis, process variables and process optimization study can be utilized to develope new liquefaction process.

Design and Analysis of Hydrogen Production and Liquefaction Process by Using Liquefied Natural Gas (액화천연가스(LNG)를 사용한 수소 생산 및 액화 공정 개발)

  • Noh, Wonjun;Park, Sihwan;Lee, Inkyu
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.200-208
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    • 2021
  • Compare to the gaseous hydrogen, liquid hydrogen has various advantages: easy to transport, high energy density, and low risk of explosion. However, the hydrogen liquefaction process is highly energy intensive because it requires lots of energy for refrigeration. On the other hand, the cold energy of the liquefied natural gas (LNG) is wasted during the regasification. It means there are opportunities to improve the energy efficiency of the hydrogen liquefaction process by recovering wasted LNG cold energy. In addition, hydrogen production by natural gas reforming is one of the most economical ways, thus LNG can be used as a raw material for hydrogen production. In this study, a novel hydrogen production and liquefaction process is proposed by using LNG as a raw material as well as a cold source. To develop this process, the hydrogen liquefaction process using hydrocarbon mixed refrigerant and the helium-neon refrigerant is selected as a base case design. The proposed design is developed by applying LNG as a cold source for the hydrogen precooling. The performance of the proposed process is analyzed in terms of energy consumption and exergy efficiency, and it is compared with the base case design. As the result, the proposed design shows 17.9% of energy reduction and 11.2% of exergy efficiency improvement compare to the base case design.

Thermodynamic Analysis on Hybrid Turbo Expander - Heat Pump System for Natural Gas Pressure Regulation (히트펌프를 적용한 터보팽창기 천연가스 정압기지의 열역학적 분석)

  • Sung, Taehong;Kim, Kyoung Hoon;Han, Sangjo;Kim, Kyung Chun
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.13-20
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    • 2014
  • In natural gas distribution system, gas pressure is regulated correspond to requirement using throttle valve which is releasing huge pressure energy as useless form. The waste pressure can be recovered by using turbo machinery devices such as a turbo expander. In this process, excessive temperature drop occurs due to Joule-Thompson effect during the expansion process. Installing natural gas boiler before or after the turbo expander prevents temperature drop. Fuel cell or gas engine hybrid system further improve the efficiency, but 1~2% of total transporting natural gas is used for operating the hybrid system. In this study, a heat pump system is proposed as a preheating device which can be operated without using transporting natural gas. Thermodynamic analysis on evaporating and condensing temperatures and refrigerants is conducted. Results show that R717 is proper refrigerant for the hybrid system with high COP and low turbine work within the defined operating conditions. In domestic usage in Korea, the heat pump system has more economic feasibility owing to natural gas being imported with a high price of LNG form.