• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.1
• /
• pp.552-558
• /
• 2011

In this paper, simulation works for a cascade refrigeration cycle using propane, ethylene and methane as a refrigerant have been performed for the liquefaction of natural gas using Peng-Robinson equation of state built-in PRO/II with PROVISION release 8.3. The natural gas feed compositions were supplied from Korea Gas Corporation and the flow rate was assumed to be 5.0 million tons per annual. Supply temperature for propane refrigerant was fixed as $-40^{\circ}C$, that for ethylene refrigerant as $-95^{\circ}C$, and that for methane refrigerant as $-155^{\circ}C$. Natural gas was finally cooled and liquefied to $-162^{\circ}C$ by Joule-Thomson expansion. Conclusively, 91.64% by mole of the natural gas liquefaction ratio was obtained through a cascade refrigeration cycle and Joule-Thomson expansion.

• Journal of Advanced Marine Engineering and Technology
• /
• v.33 no.8
• /
• pp.1123-1128
• /
• 2009

In this paper, the cycle performance characteristics of a cascade refrigeration system with internal heat exchanger using natural refrigerants is presented to offer the basic design data for the operating parameters of the system. This system considered in this study is consisted of a high temperature cycle using a carbon dioxide(R744) and low temperature cycle using refrigerants such as R290, R1270, R600a and Ethane. The main results were summarized as follows : The COP of the cascade refrigeration system of R600a with internal heat exchanger is the highest grade in low temperature cycle using refrigerants such as R290, R1270, R600a and Ethane. The COP of the cascade refrigeration system with internal heat exchanger only in high temperature cycle is the highest value among three type cycle, such as only low temperature cycle, only high temperature cycle and all the cycle.

• Journal of the Korean Institute of Gas
• /
• v.17 no.4
• /
• pp.51-57
• /
• 2013

The process of liquefied natural gas is less then $-160^{\circ}C$ to natural gas by cooling at atmospheric pressure. When control strategy was made, one of the most significant is analysis of process. It is important to understand the control variable change according to manipulated variable change. In this study, we experiment natural gas liquefied process using C3MR(Propane Pre-cooled Mixed Refrigerant) process by BSU(Bench Scale Unit). We analyzed the change of refrigerant temperature and natural gas temperature according to the change of refrigerant flow rate so as to search an influence flow rate according to adjust each manipulated variables. One of the manipulated variable affected a number of control variables, but were able to confirm a control variable with a large response.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.2
• /
• pp.1013-1019
• /
• 2011

In this paper, simulation works for a multi-stage cascade refrigeration cycle using propane, ethylene and methane as refrigerants have been performed for the liquefaction of natural gas using Peng-Robinson equation of state built-in PRO/II with PROVISION release 8.3. The natural gas feed compositions were supplied from Korea Gas Corporation and the flow rate was assumed to be 5.0 million tons per annual. Supply temperature for propane refrigerant was fixed as $-40^{\circ}C$, that for ethylene refrigerant as $-95^{\circ}C$, and that for methane refrigerant as $-155^{\circ}C$. For the multi-stage refrigeration cycle, three-stage refrigeration was assumed for propane refrigeration cycle, two-stage refrigeration for ethylene refrigeration cycle and three-stage refrigeration for methane refrigeration cycle. Natural gas was finally cooled and liquefied to $-162^{\circ}C$ by Joule-Thomson expansion. Conclusively, 91.71% by mole of the natural gas liquefaction ratio was obtained through a cascade refrigeration cycle and Joule-Thomson expansion and 0.433 kW of compression power was consumed for the liquefaction of 1.0 kg/hr of natural gas.

• Korean Chemical Engineering Research
• /
• v.51 no.6
• /
• pp.677-684
• /
• 2013

A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.26 no.3
• /
• pp.171-182
• /
• 1997

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.31 no.7
• /
• pp.32-44
• /
• 2002

1989년 프레온계 냉매의 대체 가능한 물질로서 $CO_2$재 출연하게 되었고, 그 이후 관련 연구는 점차 증가하였다. 1996년 북미 지역에서 $CO_2$의 연구는 일리노이 대학내 ACRC (Air Conditioning and Refrigeration Center)에서 최대로 시작되었다. 연구비의 90%는 산업체에 의해 지원되었고, 나머지는 미국 정부에 의해 지원되었다. 본 고는 자동차 및 가정용 에어컨 및 열펌프 시스템 및 구성부품 개선에 대한 전반적인 연구활동에 관해 기술하였다. 또한 시스템 성능 비교 결과는 열전달, 압력강하, 사이를 변환,냉매 분해에 대한 연구 지침을 제시하였고, 지속적인 연구 노력을 통하여 천연냉매를 이용하여 간접적인 지구온난화 가스 방출을 최소화하기 위한 시스템 효율을 증가시키고 빈다. $CO_2$의 고유 특징인 초임계 $CO_2$사이클, $CO_2$의 열역학 및 전달 물성치를 통한 효율 개선, 내부 열교환을 통한 사이클 성능 개선방안도 기술되었다.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
• /
• v.31 no.7
• /
• pp.53-64
• /
• 2002

$CO_2$ 20세기 초 천연 냉매 $CO_2$는 광범위하게 사용되었지만 프레온계 냉매의 출현으로 1940년경부터 $CO_2$냉매는 사용이 제한되었다. 그러나 반 세기 동안 사라졌던 $CO_2$냉매는 1980년 후반에 노르웨이 과학 기술대학 (NTNU)과 북구 최대 민간연구소 (SINTEF)의 Lorentzen 교수에 의해 $CO_2$천연 냉매 사용을 재고하게 되었다. 프레온계 냉매의 환경적 논쟁이 쟁점이 되면서 천연 냉매 사용을 재고하게 되었다. 특히 비가연성과 비유독성으로 인한 $CO_2$냉매가 주목을 받고 있다. 초월임계 사이클레서의 고압 제어에 대한 새로운 개념은 Lorentzen 교수와 동료 연구원에 의해서 특허로 제안되었다. 이에 대한 상업적 권리를 Norsk Hydro사는 1990년에 얻었고,1990년대 초반에 NTNU/SINTEF의 공동 연구개발 프로그램을 통해 기술 경쟁력과 실현 가능성이 검증되었다. 현재 연구소에서는 최초로 초월임계 $CO_2$사이클을 이용한 상업용 온수 열펌프 시스템, 2003년 시작할 연료전지 전기 자동차에 대한 연구를 수행하고 있다. NTNU/SINTEF에서 개발된 $CO_2$기술은 Hydro-SINTEF 공동 벤처 기업인 Shecco기술회사를 통해 제조업자에게 허가된다. 본 고에서는 NTNU/SINTEF에서 수행하였거나 수 중인 과제들을 중심으로 유럽의 $CO_2$시스템의 결과와 주요 개발 범위를 정리하였으며, 특히 작동유체로서의 $CO_2$냉매의 특징을 간단히 설명하고, 온 수 열 펌프, 자동차용 공조기 및 열 펌프, 상업 냉동기 등이 기술되었다. 그 외 압축기 위주의 요소기술 개발에 관한 내용도 기술되었고, 차세대 기술 경향과 전망에 대해서도 제시되었다. 제시되었다.성균 350$\times$$10^4$ CFU균, 방선균 434$\times$$10^4$ CFU균, 진균 676$\times$$10^4$ CFU균으로 진균의 개체수가 비교적 높게 나타났으며, 비산불지역에서는 호기성균 328$\times$$10^4$ CFU균, 방선균 319$\times$$10^4$ CFU균, 진균 461$\times$$10^4$ CFU균으로 진균의 개체수가 높게 나타났다. 토양미생물은 호기성균, 방선균, 진균 모두 비산불지역 보다 산불지역에서 많이 나타났다. 본 조사지역에서 호기성균은 활엽수림보다 침엽수림에서 많게 나타났으며, 방선균과 진균은 침엽수림보다 활엽수림에서 많이 나타났다.효과와 이를 이용한 자기냉동의 방법 그리고 최근에 이루어진 새로운 진전에 대해 소개하고 공기조화 및 냉동분야에의 적용 가능성을 전망해 보고자 한다.및 도입 등 선주들에게 다양한 선박건조자금을 제공하여 내수기반 확충에도 노력해야 할 것 이다.있었다., 인삼이 성장될 때 부분적인 영양상태의 불충분이나 기후 등에 따른 영향을 받을 수 있기 때문에 앞으로 이에 대한 많은 연구가 이루어져야할 것으로 판단된다.태에도 불구하고 [-wh]의미의 겹의문사는 병렬적 관계의 합성어가 아니라 내부구조를 지니지 않은 단순한 단어(minimal $X^{0}$ elements)로 가정한다. 즉, [+wh] 의미의 겹의문사는 동일한 구성요 소를 지닌 병렬적 합성어([$[W1]_{XO-}$ $[W1]_{XO}$ ]$_{XO}$)로 그리고 [-wh] 의미의 겹의문사는 중복된 발은을 지닌 한 단어로 ([W]$_{XO}$ )

• Journal of the Korean Institute of Gas
• /
• v.19 no.6
• /
• pp.99-104
• /
• 2015

Today the most efficient way to transport the natural gas is carried via the liquid. In order to liquefy the natural gas to be cooled to $-160^{\circ}C$ or less. Cooling method has a number of different ways. In this paper, we studied control method for the representative liquefaction process, C3MR. Natural gas liquefaction control is a tool that can maintain the quality of natural gas is a means to ensure stable operation. Analyzing the C3MR process, and select the control parameters for the control valve. We find control structure for mixed refrigerant cycle through the step response. A control result obtained through the dynamic simulation arbitrarily given a disturbance was found to maintain a steady-state results.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.5
• /
• pp.3327-3335
• /
• 2014

In this study, comparison works have been performed for single-stage and multi-stage refrigeration cycle using propane as a refrigerant in order to cool down the natural gas stream. A comparative analysis has been performed for a single, two, three and four stage refrigeration cycle using propane as a refrigerant for cooling the natural gas stream. For the simulation, natural gas feedstock properties supplied by KOGAS were utilized and Peng-Robinson equation of state model was used. As the number of compression stages increase, the condenser heat duty is decreased. The refrigeration heat duty for a four-stage refrigeration cycle is decreased by 20.36% compared to that for a single-stage refrigeration cycle. Moreover, the total refrigerant circulation rate for a four-stage refrigeration system is was reduced by 14.53% compared to the single stage refrigeration cycle. The total compression power for a four-stage compression was reduced by 41.61% compared to the single stage compression.