• Journal of the Korean Institute of Gas
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• v.19 no.6
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• pp.99-104
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• 2015

Today the most efficient way to transport the natural gas is carried via the liquid. In order to liquefy the natural gas to be cooled to $-160^{\circ}C$ or less. Cooling method has a number of different ways. In this paper, we studied control method for the representative liquefaction process, C3MR. Natural gas liquefaction control is a tool that can maintain the quality of natural gas is a means to ensure stable operation. Analyzing the C3MR process, and select the control parameters for the control valve. We find control structure for mixed refrigerant cycle through the step response. A control result obtained through the dynamic simulation arbitrarily given a disturbance was found to maintain a steady-state results.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.686-686
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• 2009

가스하이드레이트는 수소결합을 하는 물분자의 고체상 격자(Lattice)내에 포집되어 들어가는 기체분자로 구성된 결정화합물로서 외형적인 형태는 얼음과 거의 유사하다. 천연가스 하이드레이트 기술의 최대장점으로는 액화천연가스(LNG)는 초저온인 $-162^{\circ}C$의 저장조건이 필요하지만 천연가스하이드레이트(NGH)기술은 비교적 온화한 조건인 $-15^{\circ}C$에서 천연가스를 고체상태로 저장/이용할 수 있다는 것이다. 천연가스를 $-162^{\circ}C$에서 액화시킨 LNG상태로 생산, 수송, 저장하는 경우보다 고체상태인 NGH(Natural Gas Hydrate)로 만들어서 생산, 수송, 저장할 경우 천연가스의 생산, 수송, 저장, 재가스화 등의 일련의 공정과 비교해볼 때 LNG방법보다 약 24%이상의 경비를 절감을 할 수 있다고 보고되어지고 있다. 따라서, 천연가스의 수송 및 저장기술에서의 탁월한 경제성으로 인해 선진국에서는 가스하이드레이트에 대한 활발한 연구가 진행되고 있다. 특히 일본은 5Ton/Day용량의 NGH 생산플랜트를 건설하여 시운전 중에 있다. NGH기술의 주요 활용분야는 대용량의 가스매장량을 요구하여 LNG공정기술을 적용할 수 없는 중소형가스전 또는 한계가스전에 경제적으로 적용하는 해양수송분야와 천연가스 공급망이 갖춰져 있지 못한 지역에 NGH Pellet형태로 수송/재기화하여 활용하는 내륙운송이 분야가 있다. 국내에서는 지식경제부 국책과제인 ETI(Energy Technology Innovation)사업을 시작으로 국가경쟁력 제고 차원에서 이러한 기술의 기반구촉 및 실증화 사업이 진행되고 있다. 주요 내용으로는 NGH Process Flow, Overall NGH Process concept diagram, NGH Carrier outline, NGH Land Transportation chain 등이 포함되어 있다.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.856-856
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• 2009

석유 및 천연가스를 대체하는 자원으로 석탄이 유망하다고 전망하고 있다. 미국에서는 6대 파괴력이 있는 기술로 청정석탄기술이 선정되었고, 한국에서도 15대 그린에너지 중 하나인 청정연료에 석탄전환기술이 포함되어 전략로드맵이 작성되고 있다. 국내에서 추진되고 있는 석탄기술은 석탄가스화를 기반으로 하고 있다. 석탄가스화는 고체연료인 석탄을 $1000^{\circ}C$ 이상의 고온에서 산소와 반응시켜 일산화탄소와 수소가 주성분인 합성가스로 전환하는 기술이다. 석탄을 가스화하면 석탄에 포함된 불순물을 쉽고 완벽하게 제거할 수 있으며 특히 CO2 제거를 값싸게 할 수 있어 청정화가 가능하다. 최근 고유가를 겪으면서 열량이 높은 고급탄의 확보가 어려워지면서 가격이 낮고 수급이 용이한 저급탄을 활용하는 기술의 수요가 발생되어 국내에서 기업을 중심으로 저급탄을 고효율로 가스화하는 기술 개발이 시도되고 있다. 정제된 석탄가스는 성분을 조절하여 촉매에 의해 메탄으로 전환시킬 수 있고, 이렇게 제조된 가스를 합성천연가스(SNG)라 한다. 값싼 저급탄을 사용하면 SNG를 천연가스보다 저렴하게 생산할 수 있다. 국내 기업이 SNG 제조 실증시설을 도입하고, 동시에 핵심기술인 SNG 합성반응공정을 개발하는 사업을 추진하고 있다. 석탄가스를 촉매반응에 의해 디젤 및 �F싸로 전환하는 석탄간접액화기술은 현재 남아공 Sasol사에서 상업적으로 운전되고 있는 기술이나 국내로의 기술이전이 거의 불가능하다. 철을 기반으로 하는 고유 촉매와 scale-up이 가능한 반응기가 핵심인 기술로 국내에서 세미-파일럿급 액화공정 기술개발이 진행중이다. 전세계적으로 석탄액화공장의 수요가 현재의 15만배럴/일에서 2030년 240만배럴/일로 증가한다고 예측된다. 따라서 200조원 이상의 플랜트 시장이 기대되며 국산 가스화, SNG 및 액화기술로 상당부분의 시장을 장악하고자 한다.

• Journal of the Korean Institute of Gas
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• v.17 no.4
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• pp.51-57
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• 2013

The process of liquefied natural gas is less then $-160^{\circ}C$ to natural gas by cooling at atmospheric pressure. When control strategy was made, one of the most significant is analysis of process. It is important to understand the control variable change according to manipulated variable change. In this study, we experiment natural gas liquefied process using C3MR(Propane Pre-cooled Mixed Refrigerant) process by BSU(Bench Scale Unit). We analyzed the change of refrigerant temperature and natural gas temperature according to the change of refrigerant flow rate so as to search an influence flow rate according to adjust each manipulated variables. One of the manipulated variable affected a number of control variables, but were able to confirm a control variable with a large response.

• Journal of the Korean Institute of Gas
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• v.17 no.1
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• pp.67-72
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• 2013

The LNG liquefaction plant which have a higher value-added business in the LNG value chain takes about 35% of total cost. Liquefaction process is core technology of liquefaction plant. Almost all of cost which was consumed from the liquefaction plant, using for operation energy of liquefaction process. The cost can be reduced by increasing efficiency of liquefaction cycle. C3MR(propane pre-cooled, mixed refrigerant cycle) which liquefies NG using propane and MR cycle has the high efficiency, so C3MR is mostly used liquefaction process in LNG industry. In this study, process simulation and analysis were performed for C3MR process. C3MR process variables were found through this simulation and analysis, and then the process optimization was performed. It is considered that the results of process analysis, process variables and process optimization study can be utilized to develope new liquefaction process.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.6
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• pp.756-761
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• 2012

Natural gas is converted in to LNG by chilling and liquefying the gas to the temperature of $-162^{\circ}C$, when liquefied, the volume of natural gas is reduced to 1/600 of its standard volume. This gives LNG the advantage in transportation. In this study, the effects of the pressure drop of refrigerant and natural gas in the LNG heat exchanger of cryogenic cascade refrigeration cycle were investigated and then the design criteria for the pressure drop of refrigerant and natural gas of the LNG heat exchanger were proposed. The pressure drop of the cascade liquefaction cycle was investigated and simulated using HYSYS software. The simulation results showed that the pressure drop in the LNG heat exchanger is set to 50 kPa considering the increase in the compressor work and COP of cryogenic cascade liquefaction cycle.

• Plant Journal
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• v.15 no.2
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• pp.46-55
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• 2019

This paper presents a LNG Liquefaction cycle configuration using two stages of methane expansion (i.e. spliting into two stages as warm & cold to generate an additional inflection point within a cold composite curve) and a single stage of nitrogen expansion to improve the efficiency of the conventional Methane & Nitrogen Expansion Cycle. In comparison with Double Nitrogen Expansion Cycel and Methane & Nitrogen Expansion Cycle, the cycle efficiency has increased approximately from 13.92 and 13.13 to 12.08 kW/ton/day (8~15% efficiency increase). A Life Cycle Cost (LCC) analysis based on Net Present Value (NPV) also show an improvement in therms of project NPV, against a minor increment of a CAPEX.

• Journal of the Korean Institute of Gas
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• v.13 no.6
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• pp.44-48
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• 2009

In this paper, two different types of natural gas liquefaction cycle with 2 staged compression were designed and simulated to develop liquefaction process which is the core technology in the Industry of natural gas liquefaction plant. These include the cascade cycle with inter-cooler which is consisted of propane, ethylene and methane cycle. One of these is that liquid-gas heat exchanger is applied to between methane and ethylene cycles, and another is that liquid-gas heat exchanger is added to between ethylene and propane on the above process. Also, these cycles are compared with two staged cascade process using an inter-cooler. The COP of process2 is shown about 14.0% higher than that of process1, respectively. Also, the yield efficiency of LNG improved comparing with process1 with 11.5% lower specific power.

• Journal of the Korean Institute of Gas
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• v.23 no.4
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• pp.19-27
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• 2019

The consumption of liquefied natural gas (LNG) has increased annually due to the strengthening of international environmental regulations. In order to produce stable and efficient LNG, it is essential to divide the global (overall) operating condition and construct a quick and accurate monitoring system for each operation condition. In this study, multi-mode monitoring system is proposed to the LNG plant fractionation process. First, global normal operation data is divided to local (subdivide) normal operation data using global principal component analysis (PCA) and k-means clustering method. And then, the data to be analyzed were matched with the local normal mode. Finally, it is determined the state of process abnormality through the local PCA. The proposed method is applied to 45 fault case and it proved to be more than 5~10% efficient compared to the global PCA and univariate monitoring.

• Journal of the Korean Institute of Gas
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• v.5 no.3 s.15
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• pp.23-28
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• 2001

BOG(Boil Off Gas) is formed about 0.05 vol$\%$/day from LNG tanks of LNG receiving terminal. To recycle the BOG using LNG cold energy, the quantities of LNG and BOG is mixed at the ratio of 11 : 1 by mass in the recondenser of mixing drum type. However, this process is inefficient in the view of energy. It is the most necessary for improvement BOG recondensing process to reduce LNG quantities supplying to recondense system. Therefore, this study has aimed to propose heat exchanger type and suggest results through the analysis of ASPEN PLUS simulator and feasibility study.