• Fire Science and Engineering
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• v.32 no.6
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• pp.28-33
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• 2018

To measure the full scale fire test and heat release rate of bed mattresses according to the building compartment space, a fire test was performed using the Standard test method to determine the heat release rate of mattresses and mattress sets (KS F ISO 12949: 2011). Both test locations showed similar fire growth until approximately 3 minutes after burner ignition. After 3 minutes, the heat release rate in the test room was higher than the open calorimeter. For bed mattresses (SS), the maximum heat release rate in the open calorimeter was 735 kW and the maximum heat release rate in the test room was 992 kW. For bed mattresses (Q), the heat release rate in the test room increased more rapidly than the open calorimeter. The maximum heat release rate in the open calorimeter was 1,087 kW (346 s) and the maximum heat release rate in the test room was 2,127 kW (287 s). The difference between the maximum heat release rate and the measurement time according to the test location was confirmed.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.2
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• pp.132-140
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• 2009

Recently, the interest in the development of high efficiency Diesel engine technology using alternative fuel has been on the rise and related studies are being performed. Therefore, the DME(Dimethyl Ether), an oxygen containing fuel as an alternative fuel for light oil that can be used for diesel engines since it generates very little smoke. But it is unavoidable that the modification of a fuel supply system in an engine to application of the DME fuel because of DME fuel properties. So, in this study, a DME high pressure pump for a common-rail fuel supply system has been composed and the test results of the pump have been presented. As the results of the tests, it is confirmed that DME pump inlet pressure, pump speed and common-rail pressure effects on the volumetric efficiencies of the pump. Finally, it is defined that the optimum plunger volume of a DME pump has to be extended to the minimum 150% compared to a Diesel pump plunger volume considering DME fuel properties and volumetric efficiencies characteristics at same specifications of the high pressure pump.

• Fire Science and Engineering
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• v.29 no.3
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• pp.31-36
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• 2015

This study analyzed the flame characteristics when igniting 200 ml of flammable liquids containing equal parts gasoline and another flammable liquid. These mixtures were used to fill a divided space in a simulation. The length of one side of the divided space was 2,000 mm, and the length of the combustion device was 1,000 mm. The mixture with alcohol had the highest flame propagation speed (0.7 s), while the mixture with light oil showed the lowest (1.2 s). The gasoline and acetone mixture reached peak flame in 25.5 s, at the highest speed, while the mixture with light oil reached peak flame in 163.7 s at the lowest speed. The gasoline and light oil showed the longest continuous combustion time (332.7 s), while the gasoline and paint thinner showed the shortest (121.5 s). A fire inspector who is examining the scene of a fire needs to analyze both the statements of the first eyewitness and the flame characteristics collectively.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.112-112
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• 2016

인체접촉시 니켈도금의 알러지 반응을 억제하기 위한 대체 도금기술인 비 시안계 Cu-Sn 합금도금을 개발함에 있어서, 황산구리5수화물과 황산제일주석을 금속염으로 하여 황산 및 계면활성제, 유화제 등을 포함한 각종 유기첨가제를 포함하였고 특히 은백색조의 외관 색상과 안정적인 Cu-Sn 합금전착을 위해 2종의 착화제인 EDTP($C_{14}H_{32}N_2O_4$)와 TEA(Triethanolamine)를 첨가한 비 시안계 Cu-Sn 합금 도금액을 도출하였다. Cu-Sn 합금도금 피막 조성의 균일화를 도모하기 위해서는 합금 도금액중의 Cu와 Sn 금속이온 농도를 일정하게 유지하는 것이 필요하다. 그러나 합금 도금액중 2가 주석이온($Sn^{2+}$)은 수용액중에서 4가 주석이온($Sn^{4+}$)으로 산화됨으로써 도금액 색상이 백탁이 되고 Stannic Hydroxide($Sn(OH)_4$, $SnO_2{\cdot}2H_2O$)이 생성되어 대량의 침전물이 침강하는 문제점이 발생되는 등 시간 경과에 따른 도금액의 경시 변화가 발생되었다. 상기 침전물은 연속여과에 의해 제거 가능하나 합금 도금액중 $Sn^{2+}$ 농도가 지속적으로 감소하게 된다. 이는 합금 도금액중 금속이온 비율이 변동함으로써 합금도금 피막의 조성비를 일정하게 유지하는 것이 곤란해진다. 이에 $Sn^{4+}$ 침전물 생성을 방지하기 위한 산화방지제를 개발하고 또한 산화방지제의 첨가에 따른 도금 피막 외관에 미치는 영향을 평가하여 외관 개선을 위한 광택제를 개발하고자 한다. 본 연구의 결과를 토대로 니켈도금과 동등 이상의 기능 특성을 갖는 비시안계 Cu-Sn 합금도금액을 개발하여 실용화하는 것을 목적으로 하였다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.39 no.12
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• pp.1166-1173
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• 2011

Electro-Mechanical Ignition Safety Device(EMISD) for solid rocket motor is designed and manufactured. The EMISD utilizes a true rotary solenoid for arming mechanism and an electric squib(initiator) for generating ignition energy. In order to prove the ignition capability of the EMISD, 10-cc Closed Bomb Test(CBT) is performed, which measures the pressure built by high temperature and high pressure gas generated by operating EMISD. The pressure built in the free volume of 10-cc closed bomb and the opening time of the ignition gas outlet are calculated using one dimensional gas dynamic model which is composed of the ideal gas equation and mass-energy conservation equation. Comparing the test result with model prediction, it is realized that the pressure built in the free volume of closed bomb due to the firing of EMISD, has the efficiency ratio of about 34%.

• Journal of the Korean Ceramic Society
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• v.41 no.4
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• pp.297-301
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• 2004

Nano-sized mullite (3Al$_2$O$_3$$.$2SiO$_2$) colloids were prepared by use of the spray combustion method. For combustion reaction, Al(NO$_3$)$_3$$.$9$H_2O$, and CH$_{6}$N$_4$O were used as an oxidizer and a fuel respectively, and then colloidal silica was also added as 2SiO$_2$source for mullite. The temperature of the reaction chamber was kept at 80$0^{\circ}C$ to initiate the ignition of droplets of the mixed precursors. For preventing droplet coagulation, the droplet number concentration was reduced using the metal screen filter, and the residence time of aerosol was kept at 2.5 seconds for laminar flow. The synthesized colloidal particles had an uniform spherical shape with 130 nanometer size and the crystalline phase showed the mullite with stoichiometry in the observations of XRD and TEM.

• Fire Science and Engineering
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• v.25 no.3
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• pp.57-62
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• 2011

The combustion characteristic was evaluated for Pinus densiflora, used as a building material in Hanok, which were treated with two different flame retardant method. The specimen was brushed with flame retardant liquid two or three times and then let the specimen dehydrated during 24 h for spreaded treating. And the other specimen was soaked in the liquid for 72 h. The test methods were inflammability test using meker burner and heat release rate test using cone calorimeter. As a result for the tests, flame retardant treated specimens met the requirements of the inflammability and the spreaded treated method was more efficient than immersed method. The spreaded treated specimen had lower combustive properties than immersed specimen in TTI (time to ignition), PHRR (peak heat release rate), MLR (mass loss rate) and THR (total heat release).

• Fire Science and Engineering
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• v.24 no.3
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• pp.72-77
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• 2010

Honeycomb core structure with its excellent stiffness and strength is being utilized in many fields such as interior building material. Because it is inexpensive and renewable, honeycomb paper production is economically and environmentally helpful. However, the paper needs to be fireproofed because it is vulnerable to fire. In this study, we have undergone the performance evaluation process of the honeycomb paper which is widely used as interior material of a fire door and packing material. Four kinds of honeycomb (a honeycomb made of flame-resistant paper; a honeycomb attached with conventional flame-resistant film made in the laboratory; honeycomb impregnated with flame retardant; a honeycomb attached with flame-resistant film after impregnating fire retardant) were used in the study to compare the fire retardant performance. As a result, the honeycomb with impregnated flame retardant showed the highest performance. The flame-resistant film was effective in delaying the igniting time but had a negative effect on the rate of heat and smoke production.

• Clean Technology
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• v.13 no.1 s.36
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• pp.79-84
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• 2007

Separation of ethylene from ethane and propylene from propane have been conducted using facilitated olefin transport membrane with SPEEK-Ag (Ag substituted sulfonated poly(ether ether ketone)). SPEEK was prepared by the sulfonation of PEEK using cone. $H_2SO_4$ and the reaction time affected the degree of sulfonation (DS) of the resulting SPEEK. SPEEK-Ag composite membrane was formed by soaking SPEEK in the polyester support into the Ag salt solution. With increasing the concentration of SPEEK in MeOH, the thickness of SPEEK on the polyester increased. The selectivity and the flux of SPEEK-Ag membrane for the separation of ethylene/ethane and propylene/propane were changed by the thickness of SPEEK layer on the top of polyester support. The anion of silver salt also affects the membrane performance.

• Journal of Soil and Groundwater Environment
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• v.12 no.2
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• pp.27-36
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• 2007

A recent study showed that MTBE can be degraded by Fenton's Reagent (FR). The treatment of MTBE with FR, however, has a definite limitation of extremely low pH requirement (optimum pH $3{\sim}4$) that makes the process impracticable under neutral pH condition on which the ferrous ion precipitate forming salt with hydroxyl anion, which result in the diminishment of the Fenton reaction and incompatible with biological treatment. Consequently, this process using only FR is not suitable for in-situ remediation of MTBE. In order to overcome this limitation, modified Fenton process using NTA, oxalate, and acetate as chelating reagents was introduced into this study. Modified Fenton reaction, available at near neutral pH, has been researched for the purpose of obtaining high performance of oxidation efficiency with stabilized ferrous or ferric ion by chelating agent. In the MTBE degradation experiment with modified Fenton reaction, it was observed that this reaction was influenced by some factors such as concentrations of ferric ion, hydrogen peroxide, and each chelating agent and pH. Six potential chelators including oxalate, succinate, acetate, citrate, NTA, and EDTA were tested to identify an appropriate chelator. Among them, oxalate, acetate, and NTA were selected based on their remediation efficiency and biodegradability of each chelator. Using NTA, the best result was obtained, showing more than 99.9% of MTBE degradation after 30 min at pH 7; the initial concentration of hydrogen peroxide, NTA, and ferric ion were 1470 mM, 6 mM, and 2 mM, respectively. Under the same experimental condition, the removal of MTBE using oxalate and acetate were 91.3% and 75.8%, respectively. Optimum concentration of iron ion were 3 mM using oxalate which showed the greatest removal efficiency. In case of acetate, $[MTBE]_0$ decreased gradually when concentration of iron ion increased above 5 mM. In this research, it was showed that modified Fenton reaction is proper for in-situ remediation of MTBE with great efficiency and the application of chelatimg agents, such as NTA, was able to make the ferric ion stable even at near neutral pH. In consequence, the outcomes of this study clearly showed that the modified Fenton process successfully coped with the limitation of the low pH requirement. Furthermore, the introduction of low molecular weight organic acids makes the process more available since these compounds have distinguishable biodegradability and it may be able to use natural iron mineral as catalyst for in situ remediation, so as to produce hydroxyl radical without the additional injection of ferric ion.