• Title/Summary/Keyword: 질소산화물 무배출

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Experimental study of NOx reduction in marine diesel engines by using wet-type exhaust gas cleaning system (선박용 디젤엔진의 NOx를 저감하기 위한 습식 배기가스 처리기술 적용에 관한 실험적 연구)

  • Ryu, Younghyun;Kim, Taewoo;Kim, Jungsik;Nam, Jeonggil
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.216-221
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    • 2017
  • Diesel engines have the highest brake thermal efficiency among internal combustion engines. Therefore, they are utilized in medium and large transportation vehicles requiring large amounts of power such as heavy trucks, ships, power generation systems, etc. However, diesel engines have a disadvantage of generating large quantities of nitrogen oxides during the combustion process. Therefore, the authors tried to reduce the amount of nitrogen oxides in marine diesel engines using a wet-type exhaust gas cleaning system utilizing the undivided electrolyzed seawater method. In this method, electrolyzed seawater in injected into the harmful gas discharge from the diesel engine using real seawater. The authors investigated the reduction of NO and NOx from the pH value, available chlorine concentration, and the temperature of electrolyzed seawater. The results of this experiment indicated that when the electrolyzed seawater is acidic, the NO oxidation rate in the oxidation tower is higher than that when the electrolyzed seawater has a neutral pH. Likewise, the NO oxidation rate increased with the increase in concentration of chlorine. Further, it was confirmed that the electrolyzed seawater temperature had no effect on the NO oxidation rate. Thus, the NOx exhaust emission value produced by the diesel engine was reduced by means of electrolyzed seawater treatment.

Characteristics of Flue Gas Using Direct Combustion of VOC and Ammonia (휘발성 유기 화합물 및 암모니아 직접 연소를 통한 배기가스 특성)

  • Kim, JongSu;Choi, SeukCheun;Jeong, SooHwa;Mock, ChinSung;Kim, DooBoem
    • Clean Technology
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    • v.28 no.2
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    • pp.131-137
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    • 2022
  • The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NOX reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NOX concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NOX emission while NO2 was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.

Development of a 30 kW Hydrogen-Fueled Micromix Combustor for Research (연구용 30 kW 수소 전소 마이크로믹스 연소기 개발)

  • Seojun Ock;Minsu Kim;Suhyeon Park
    • Journal of Aerospace System Engineering
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    • v.17 no.6
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    • pp.72-81
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    • 2023
  • Hydrogen-fueled gas turbines are a promising technology that can resolve the carbon dioxide emission issue as future aviation propulsion engines and carbon-free power generations. To achieve high efficiency and stability of gas turbines using 100% hydrogen as fuel, an innovative design of combustor systems is necessary to consider the characteristics of hydrogen, which are different from those of conventional hydrocarbon fuels. Micromix is a combustor design method, which aims to terminate the reaction quickly by intense mixing of fuel and air, consequently reducing NOx and increasing the stability. In this paper, we examine the principles and design process of micromix combustors as a pure-hydrogen combustion technology, and we introduce a design of a 30 kW micromix hydrogen combustor for research.

Improvement of DeNOx efficiency of SNCR Process with Chemical Additives in Urea Soution (환원제로 우레아를 사용하는 SNCR 공정에서 첨가제 적용에 따른 탈질효율 향상 연구)

  • Yoo, Kyung Seun;Park, Sung Woo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.663-668
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    • 2017
  • Dye waste water generated in the dye industry is categorized as hazardous waste water that requires appropriate treatment. The pilot scale experimental trials were carried out using dye waste water as an effective additive for the selective non-catalytic reduction (SNCR) of NOx in combustion flue gases. The additives were waste liquor obtained from the dye industry and several purification steps were taken to make a standardized reagents. The dye waste water was shown to possess valuable SNCR qualities (at least 87% NOx reduction efficiency) considering its availability as a waste product, which has to be strictly treated, and have little effects on CO removal. The results indicated that the NO removal efficiency increased first and then decreased with increasing temperature within $750-1150^{\circ}C$. The maximum NO reduction efficiency was approximately 87% at the optimal reaction temperature. A more than 10% increase in NO reduction was achieved in the presence of 1000 ppm Na-additives (dye waste water) compared to that without additives. The Na-based additives have also a significant promoting effect on $N_2O$ reduction and within the SNCR temperature window.