• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.21-27
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• 2015

In order to meet the current emission regulations (EURO-6), it is necessary to significantly reduce $CH_4$ and $NO_X$ emissions. This study investigated the effect of a reduction in the valve overlap on the combustion and emission characteristics of a hydrogen-compressed natural gas engine under a part-load operating condition. The combustion and emission characteristics were analyzed for each fuel using the original camshaft and an altered camshaft with reduced valve overlap. The results showed that the thermal efficiency was decreased and the fuel flow was increased when using the altered camshaft. The $CO_2$ and $CH_4$ emissions were increased as a result of the reduced thermal efficiency. Under lean operating conditions, the $NO_X$ emission was decreased compared with one of the conventional camshaft. Thus, under the same fuels and operating conditions, it had a harmful influence on the emission characteristics and thermal efficiency.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.1977-1983
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• 2000

SCR(selective catalytic reduction) pilot plant for reduction of the nitrogen oxides using diesel oil as a reductant was installed at the NG(natural gas) fired combined cycle and the activity of Pt(0.3%)/Zeolite catalyst was studied in real flue gas condition according to the amount of reductant. reaction temperature and space velocity. NOx conversion gradually increased with increasing the diesel oil concentration up to C/N ratio 5.5(C/N ratio: the ratio of the number of carbon atom to the number of NOx molecules included in the flue gas). Increasing the reaction temperature. NOx conversion increased and reached a maximum conversion of 50% at $190^{\circ}C$. NOx conversion did not changed with increasing the space velocity up to 18,500/hr and then gradually decreased. These results reveal the potential for diesel oil as a reductant for de-NOx SCR process.

• Journal of Energy Engineering
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• v.24 no.4
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• pp.24-32
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• 2015

National and international regulations on the exhaust gases of diesel engines are being strengthened, and a study of the combutsion engine and the post-porcessing system are in progress as a variety of ways. There are many techniques for the removal of nitrogen oxide like HC-SCR, LNT, Urea-SCR. And the technical development on the Urea-SCR owing to high conversion efficiency and fuel economy characteristics has being processed. This study investigated the physical/chemical properties of urea according to the change of the urea content, and were analysed the characteristic of exhaust gas. According to the increase of urea content, the contests of biuret aldehyde, phosphate content was increased and the changes of emission quantity of carbon monoxide, hydrocarbons and particulate matter in the exhaust gas was very slight. The emission quantity of NOx was decreased in accordance with increasing the urea content and it was shown to be more than 80 % in the urea solution having more than 30 wt%.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.3
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• pp.275-282
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• 2010

The effect of swirl flow on NOx in a nonpremixed turbulent hydrogen jet with coaxial air was studied. The swirl vane angle was varied from $30^{\circ}$ to $90^{\circ}$. The fuel jet air velocity and coaxial air velocity were varied in an attached flame region as $u_F=85{\sim}160m/s$ and $u_A=7{\sim}14m/s$. The objective of the current study was to analyze the characteristics of nitrous oxide emission in a swirl flow and to propose a new parameter for EINOx scaling. The experimental results show that EINOx decreases with the swirl vane angle and increased with flame length. Further, EINOx scaling factors can be determined by considering the effective diameter ($d_{F,eff}$) in a far field concept. The EINOx increased in proportion to the flame residence time (${\sim}{\tau_R}^{1/2.8}$) and the global strain rate (${\sim}{S_G}^{1/2.8}$).

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.204-206
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• 2014

석탄 화력발전소에는 연소가스의 질소산화물(NOx) 저감을 위한 SCR(selective catalytic reduction)설비가 운전되고 있으며, SCR은 환원제인 암모니아($NH_3$)를 이용하여 연소가스 내에 질소산화물을 물과 질소로 분해하는 역할을 한다. 그러나, 연소가스 중의 일부 삼산화황($SO_3$)과 미반응 암모니아가 결합하여 황산암모늄염(Ammonium bisulfate; $NH_4HSO_4$)을 생성하며, 이는 후단 APH(air preheater)의 열소자에 점착된 후 분진들과 함께 성장하여 막힘을 야기한다. 막힘이 발생된 APH는 연소가스의 흐름을 방해하기 때문에 차압을 증가시키며, 이는 발전효율의 감소뿐만 아니라 급전정지를 초래한다. 이를 해결하기 위하여 $CO_2$ 드라이아이스 세정 방법을 적용하였으며, pilot-scale plant에서 실험을 수행하였다. 또한, 드라이아이스 공정변수인 분사압력과 분사시간을 제어하여 pilot-scale plant의 APH 열소자 표면에 생성되어있는 오염물질들의 제거효율을 관찰한 결과 95 %의 높은 제거효율을 보였다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.3
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• pp.611-614
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• 2008

Urea-SCR system has been known so far as one of effective after treatments for the reduction of NOx. In order to achieve better performance in SCR system, optimal geometric conditions for a urea injection system should be achieved. This research focused to visualize spray characteristics of urea injected SCR system in a heavy duty diesel engine. The experiment was conducted by varying injection pressures and flow rates of urea. The flow visualization was made by photographing techniques of CCD camera.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1994.11a
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• pp.97-100
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• 1994

산화구리가 담지된 알루미나 흡수제/촉매를 이용하여 유황산화물과 질소산화물의 제거반응 특성을 고정층 반응기를 이용하여 고찰하였다. 반응온도가 증가할 수록 $350^{\circ}C$까지 탈질 효율이 증가하였으며 그 이상의 온도에서는 암모니아의 산화에 의하여 탈질효율이 감소하였다. 암모니아의 $NO_{x}$ 선택성은 $SO_{x}$ 가 존재하지 않는 경우에 $NH_3/NO_{x}$mole 비 1.0 까지 유지되었으나 $SO_{x}$ 가 존재하면 선택성은 매우 감소하였다. 동시제거 반응의 경우 $400^{\circ}C$ 이상에서 효과적이었으며 $350^{\circ}C$ 이하에서는 암모늄 염의 생성으로 인하여 탈질효율의 감소가 반응시간이 증가함에 따라서 감소하였다.

• Plant Journal
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• v.18 no.3
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• pp.52-61
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• 2022

This study tested the effect of de-NOx Facility operating condition on Nox emisiion in a 125 MW wood pellet power plant in Yeongdong Eco Power Plant Unit 1, which is in operation. As SNCR urea flow rate increased, NOx emission gradually decreased, but ammonia slip after SCR increased. The boiler under test has a structure that is unfavorable to SNCR operation due to the high internal temperature, and the optimum location of the nozzle will be required. SCR dilution air temperature change did not affect the amount of NOx generated. Increasing SCR ammonia flow reduced the NOx emission at SCR outlet and also increased the NOx removal efficiency. However, the ammonia flow rate of 111 kg/h, which does not exceed the ammonia slip its own reference limit, is estimated to be the maximum operating standard. The increase in SCR mixer pressure reduced NOx emission and the removal efficiency was also measured to be the most effective variable to inhibit NOx production.

• Journal of Energy Engineering
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• v.20 no.3
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• pp.191-199
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• 2011

The char burn-out and NOx emissions from sub-bituminous coal were investigated in drop tube furnace under $O_2/N_2$ and $O_2/CO_2$ environments with different $O_2$ concentrations of 12, 21 and 31%. Results show that the char burn-out rate is faster as $O_2$ concentration increases higher and char burn-out rate under $O_2/CO_2$ decreases due to the lower oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. NO concentration increases with increasing $O_2$ concentration, but declines at $O_2$ concentration of 31%. Meanwhile, NO emission indexes decreases monotonically with increasing $O_2$ concentration, which indicates that more NO reduction occurs with higher $O_2$ concentration probably due to greater HCN formation. For all conditions of $O_2$ concentration, the NO concentration under $O_2/N_2$ maintains higher than those of $O_2/CO_2$ due to presence of thermal NO.

• Journal of the Korean Institute of Gas
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• v.19 no.4
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• pp.22-28
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• 2015

In order to keep the competitiveness of LPG fuel for transportation fuel, the difference in fuel consumption with gasoline and cost for an aftertreatment system should be reduced with continuous development of technology for LPG engine. In the present study, spray-guided type direct injection combustion system, whose configuration is composed of direct injector in the vicinity of spark plug, was employed to realize stable lean combustion. A certain level of nitrogen oxides($NO_x$) emits due to a locally rich mixture regions in the stratified mixture. With the application of EGR system for the reduction of $NO_x$, 15% of $NO_x$ reduction was achieved whereas fuel consumption and hydrocarbon emission increased. By the application of EGR, the combustion speed reduced especially appeared at initial flame development period and peak heat release rates and increasing rates for heat release rate decreased as EGR rate increased due to the dilution effect of intake air.