• Title/Summary/Keyword: 질산염

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The Importance of groundwater discharge for environmental assessment of Chinhae Bay (진해만 환경평가를 위한 해저지하수의 중요성)

  • Chung Chong Soo;Hong Gi Hoon;Kim Suk Hyun;Kim Young Il;Moon Duk Soo;Park Jun Kun;Choi Jun Sun;Yang Dong Beom
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.4
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    • pp.23-36
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    • 2000
  • Bottom sea waters in eight stations including from inner bay to outer bay to understand the importance of the submarine groundwater discharge for the environmental assessment of Chinhae Bay was collected in August 1999 and January 2000. Generally, /sup 222/Rn is very useful tracer to assess the submarine groundwater discharge because it is 2-4 orders of magnitude more concentrated in groundwater compared to surface water. The /sup 222/Rn activities ranged between about 33 to 182 dpm/100kg within the bay. Higher activities more than 100 dpm/100kg were found at the inner bay. The /sup 226/Ra activities, its parent, however, were little different between stations. /sup 222/Rn activities at the same station varied with season. It suggests that the major source of /sup 222/Rn is not from the bottom sediment, but from the change of submarine groundwater discharge by precipitation. The contents of Cl/sup -/ and SO/sub 4//sup 2-/ in the groundwater of Wonjeon-ri were very high as 1,312 and 369 ppm, respectively, indicating that this groundwater along the Chinhae coast was affected by seawater. Therefore, the submarine groundwater in the inner Bay may discharge to the overlying water. It indicates that these submarine groundwater discharges may play an important role as another important source of nutrients in the Chinhae Bay, because groundwater around the Chinhae Bay showed high concentration of dissolved inorganic nutrients (average , nitrate>174 μM, silicate>262 μM). Therefore, further studies are required to assess the contribution by the submarine groundwater discharge in the biogeochemical processes of the Chinhae Bay.

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EFFECT OF SUYEONG RIVER WATER ON THE WATER POLLUTION OF SUYEONG BAY (수영강의 수질오탁과 그것이 광안리 해수욕장에 미치는 영향에 대하여)

  • WON Jong-Hun;LEE Bae-Jeong;SIM Mu-Gyoung;PARK Heon-Serk
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.12 no.4
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    • pp.267-276
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    • 1979
  • This research was conducted to evaluate tile effects of polluted Suyeong River water on the water quality of Kwangan-Ri bathing beach. The quantity of pollutant loading of Suyeong River was determined in January 1979, and the directions of tidal currents and the chemical constituents of the Suyeong Bay water were observed in May 1979. The results are as follows: The quantity of total pollutant loading which was discharged into Suyeong Bay is: BOD 75.2ton/day; COD 96.9ton/day; SS 20.5ton/day; ammonia-nitrogen 12.4ton/day; nitrate-nitrogen 430kg/day; nitrite-nitrogen 85.1kg/day; phosphate-phosphorus 594kg/day and total heavy metals 3.01ton/day. Considering the tidal current, the polluted waters of Suyeong River flow off the Kwangan-Ri beach during tile ebb tides, and flow into the Kwangan Ri beach during the flood tides. Consequently, the water quality of Kangan-Ri bathing beach is not suitable for bathing.

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Effective Costal Environmental Management by Conjugation of Modeling of Bio-Purification and Total Allowable Pollutant Loads in Masan Bay (생물정화기작과 총허용오염부하량을 연계한 마산만의 효율적 해양환경 개선방안)

  • Eom, Ki-Hyuk;Kim, Gui-Young;Lee, Won-Chan;Lee, Dae-In
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.38-46
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    • 2012
  • This study carried out current status, characteristics, and problems of coastal environment management on semi-enclosed Masan Bay in Korea and suggests cost-effective and eco-friendly water quality management policy. The pollutants from terrestrial sources into the Bay have apparently environmental pollution problems, such as eutrophication, red tide, and hypoxia. The carrying capacity of the Bay is estimated by hydrodynamic model and ecosystem model, material circulation including bivalve in ecosystem is analyzed by the growth model of bivalve. The resulting reduction in the input load was found to be 50~90%, which is unrealistic. When the efficiency of water quality improvement through bivalve farming was assessed based on the autochthonous COD, 30.7% of the total COD was allochthonous COD and 69.3% was autochthonous COD. The overall autochthonous COD reduction rate by bivalve aquaculture farm was found to be about 6.7%. This study indicate that bivalve farming is about 31% less expensive than advanced treatment facilities that remove both nitrogen and phosphorous.

Impact of Physicochemical Properties of Root Substrates on Growth of Mother Plants and Occurence of Daughter Plants in 'Seolhyang' Strawberry Propagation through Bag Culture ('설향' 딸기 번식을 위한 자루재배시 상토의 물리·화학성이 모주 생육과 자묘 발생에 미치는 영향)

  • Choi, Jong-Myung;Park, Ji-Young;Latigui, Ahmed
    • Horticultural Science & Technology
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    • v.29 no.2
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    • pp.95-101
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    • 2011
  • The influence of physicochemical properties of root substrates on the growth of mother plants and occurrence of daughter plants in 'Seolhyang' strawberry propagation were investigated through plastic bag cultivation. Six different formulations of root substrates were coir dust + perlite (5:5, A), coir dust + perlite (6:4, B), coir dust + perlite (7:3, C), coir dust + coconut chip (7:3, D), coir dust + coconut chip (6:4, E), and peatmoss + vermiculite (5:5, v/v; F). The total porosities (TP) and container capacities (CC) of all root substrates were higher than 85% and 55%, respectively, indicating that all substrates were in the acceptable range. But the TP and CC of F substrate were 91.5% and 60%, respectively, which were the highest among the root substrates tested. In the soil chemical properties analyzed before planting and after harvesting of 'Seolhyang' strawberry mother plants, the root substrates of A, B, C, and F had higher electrical conductivity and $NO_3$-N concentrations than those of D and F. The root substrates of A, B, C, and F had heavier runner fresh and dry weights, longer runner lengths, and more daughter plant occurrence than those of D and F. The treatment F had higher tissue N content than any other treatments at 120 days after the transplanting of 'Seolhyang' strawberry and statistical differences were not observed among remained 5 substrates. The treatment of F also had the higher tissue contents of other nutrients except N analyzed at 120 days after transplanting. These results indicated that soil chemical properties rather than physical properties severely influenced the growth of runners and occurrence of daughter plants.

Analysis of Long-Term Monitoring Data From the Geum River Estuary (금강 하구의 장기 관측 자료 분석)

  • JEONG YONC HOOW;KIM YEONC TAE;CHAE YOUN ZOO;RHEE CHOONC WOON;KO KYUNC RAN;KIM SOH YOUNG;JEONG JU YOUNG;YANG JAE SAM
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.10 no.3
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    • pp.139-144
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    • 2005
  • To investigate the long-term variation of water qualities, we have daily monitored physio-chemical characteristics of surface water in the Geum River estuary from June 1996 to April 2004. We found that the water qualities were determined by three dominant factors : 1. fluvial input from Geum River ($28.3\%$), 2. chemical processes such as nitrification and phosphate addition originated from sediment resuspension and domestic sew- age input ($18.6\%$), 3. biological processes such as nutrient consumption by primary producers ($13.5\%$). The factor 1 (fluvial input) effectively affected the water quality of the estuary particularly during the normal or low river discharge. The factor 2 (chemical processes) and the factor 3 (biological processes) showed distinct seasonal differences due to their relative strengths of biological activities. The factor 3 was a governing parameter during the period of spring algal bloom in 2004. For the spring period, an empirical equation derived from the multi-regression analyses showed that the in-situ chlorophyll-a distributions in the estuarine water were successfully simulated by the phosphate concentrations and N/P ratios. Therefore we suggest that phosphate functions as a limiting factor for the primary productivity in the Geum River estuary for the dry season, especially during spring.

Comparision of Cation-Anion Balance in Leaves on the Stalk Positions of Young Tobacco Plant (담배식물(植物)의 엽서별(葉序別) 이온균형(均衡) 비교(比較))

  • Lee, Yun-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.3
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    • pp.223-229
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    • 1986
  • These studies were investigated ionic balance of leaves from different stalk positions of tobacco plant (cv. NC82) grown on pots supplied with nitrate salts solution in the phytotrone. The results of studies are summerized as follows: 1. In comparision with the leaves along the stalk positions, lower position contained higher proportion of total cation and total anion including organic acid, but their concentration lessened gradually at the upper stalk. The ratio in amounts of inorganic cations and anions in leaf laminae depended on their stalk positon, being more than three times in the fifth, but becoming about 1.3 in the tenth. 2. Inorganic cations in the laminae were mostly $K^+$, $Ca^{{+}{+}}$, and $Mg^{{+}{+}}$, comprising about 80% of total with the first two regardless of their stalk positions. Among these two ions $Ca^{{+}{+}}$ tended to become higher at lower stalks, while $K^+$ was higher in younger and became lower when leaves got older and/or more number of leaves were emerged. 3. Total cations were balanced with inorganic and organic acid anions. Composition of inorganic and organic anions were different along stalk positions, ionic balance was governed by organic acid anions dominantly in older leaves, but by inorganic anions in the younger leaves. 4. The discrepancy in the balance between total cations and anions was more pronounced in the older leaves containing higher amount of cations and organic acids. It was suggested that discrepancy was due to precipitation of oxalate as Ca-salt which was not dissolved in the methylation solution of measurement employed.

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Nutrient Composition of Benthic Diatom Cultured on Plate at Four Areas in Spring (봄철 해역별 파판배양 부착규조류의 영양성분)

  • 김해영;허성범
    • Proceedings of the Korean Aquaculture Society Conference
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    • 2003.10a
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    • pp.143-144
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    • 2003
  • 봄철 해역에 따른 부착미세조류의 영양성분 변화를 알아보기 위하여 본 실험을 수행하였다. 실험은 울진, 부안, 완도, 부산 지역에서 봄철인 2~4월 동안 실시되었으며 실험간의 오차를 줄이기 위해 실험 시작일의 차이는 최대 10일 이내로 하였다. 배양을 위한 실험해역의 기초 조사로 배양지역 연안해수의 수온, 염분, pH, 총질소, 총인, Chlorophyll-a의 측정을 하였고 각 지역의 부착미세조류를 수확하여 영양분석을 하였다. 실험에 사용된 파판은 전복 종묘생산에 이용되는 규조배양용 파판과 틀을 이용하였고 실험기간은 총 8주 동안 실시하였다. 2주마다 파판을 수거한 뒤 부착된 미세조류를 부드러운 솔로 분리하여 원심 분리한 후 지방산과 아미노산의 측정을 하였다. 또 각 시료의 일정량을 Sedwick-rafter counting chamber를 이용하여 검경ㆍ계수한 후 이를 단위면적당 개체수(cells/$\textrm{cm}^2$)로 환산하여 biomass를 구하였다. 봄철 지역간의 수온의 범위는 13.9~16.6$^{\circ}C$를 보였으며 울진이 가장 높고 부안지역이 가장 낮았다. 염분은 부안지역의 염분이 평균 2$\textperthousand$ 이상 낮았으며 그 외의 지역은 큰 차이가 없었다. pH는 7.77~8.21의 범위를 보이고 있었으며 질산염 농토는 부산이 0.265mg/$\ell$로 최대값을 보였고 울진이 0.032mg/$\ell$로 제일 낮았다. 인산염 농도는 완도지역이 0.018mg/$\ell$로 최대치를 보였고 부안은 검출되지 않았다. Chlorophyll-a의 농도는 울진지역이 0.66mg/$\ell$으로 제일 낮았으며 부산이 2.69mg/$\ell$, 부안지역이 2.27mg/$\ell$ 로 높은 값을 보였다. 봄철 지역에 따른 부착미세조류의 아미노산 분석결과는 울진이 실험지역 중 제일 높은 총 아미노산과 필수아미노산의 함량을 나타냈으며 각 지역별로 울진은 4주에 20.3%, 부안은 8주째 8.1%, 완도는 8주째 4.7%, 부산은 6주째 10.4%로 서로다른 시기에 높은 아미노산의 함량을 나타냈다. 실험지역 부착미세조류의 지방산 결과를 보면 전 실험기간동안 지방산 중 대부분은 $C_{18}$이하의 포화 또는 불포화 지방산이 주를 이루고 있었으며 palmitic acid( $C_{16:0}$)와 palmitoleic acid( $C_{16:0}$)의 양이 전체 지방산 함량중 37.47~75.94%로 대부분을 차지하고 있었다. 그리고 n-3HUFA(high unsaturated fat쇼 acids)인 EPA는 부안지역이 2주째 20.85%로 전체 지역중 함량이 제일 높았고, 울진은 실험기간중 6주가 14.76%로 제일 높은 함량을 보였다. 완도는 6주에만 10.97%의 함량을 보였으며 부산지역의 시료에서는 EPA의 검출이 없었다. 봄철 각지역에 설치된 파판에서의 부착미세조류 출현량을 보면 2주째의 부착미세조류량은 부안이 8.3$\times$$10^3$ cells/$\textrm{cm}^2$로 가장 높았고 부산이 0.6$\times$$10^3$ cells/$\textrm{cm}^2$로 가장 낮았다. 울진의 경우 0.7$\times$$10^3$ cells/$\textrm{cm}^2$로 부산과 비슷하게 낮은 출현량을 보였고 완도는 2.4$\times$$10^3$ cells/$\textrm{cm}^2$였다. 4주째의 출현량은 울진지역이 471.1$\times$$10^3$ cells/$\textrm{cm}^2$로 가장 높았으며 부안, 완도, 부산 순으로 출현량이 낮았고 특히 부산은 1.2$\times$$10^3$ cells/$\textrm{cm}^2$로 가장 낮았다. 6주째의 출현량은 울진 지역이 368.6$\times$$10^3$ cells/$\textrm{cm}^2$로 가장 높았으며 부안 89.8$\times$$10^3$ cells/$\textrm{cm}^2$, 완도 25.1$\times$$10^3$ cells/$\textrm{cm}^2$, 부산 5.9$\times$$10^3$ cells/$\textrm{cm}^2$ 순이었다. 8주째의 경우에도 울진, 부안, 완도, 부산이 각각 255.8$\times$$10^3$ cells/$\textrm{cm}^2$, 157.8$\times$$10^3$ cells/$\textrm{cm}^2$, 44.3$\times$$10^3$ cells/$\textrm{cm}^2$, 1.1$\times$$10^3$ cells/$\textrm{cm}^2$로 4주, 6주의 경우와 같은 경향을 보였다.보였다.

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Hydrochemistry and Nitrogen and Sulfur Isotopes of Emergency-use Groundwater in Daeieon City (대전지역 민방위 비상급수용 지하수에 대한 수리화학과 질소 및 황 동위원소 연구)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.13 no.2
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    • pp.239-256
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    • 2003
  • The purpose of this study is to investigate the hydrochemical characteristics of emergency-use groundwater in the Daejeon area, and to elucidate the contamination source of $NO_3-N$ and the origin of sulfate in the groundwater. The groundwater shows weak acidic pH, the electrical conductivity ranging from 142 to $903{\;}\mu\textrm{S}/cm$, and the hydrochemical types of $Ca-HCo_3$ and $Ca-Cl(SO_4,{\;}NO_3)$. The Box-Whisker analysis and the Krigging analysis of chemical data of groundwater were made to demonstrate the concentration distribution of hydrochemical composition, and to compare the trend of hydrochemical data. The groundwater in the area of Dong-gu, Jung-gu and Daeduk-gu, where are old town, shows higher electrical conductivity, nitrate content, sulfate and $EpCO_2$ levels than groundwater in new town area of Seo-gu and Yusung-gu. ${\delta}^{15}N$ of groundwater in the area of Seo-gu and Yusung-gu ranges from +7.4 to $+9.6{\textperthousand}$, indicating that major contamination source of $NO_3-N$ is the leakage from municipal sewage pipe lines. ${\delta}^{15}N$ of groundwater in the old town area of Tong-gu, Jung-gu and Daeduk-gu shows the range between +10.2 and $+23.5{\textperthousand}$, meaning that major contamination source is leakage of septic tank. ${\delta}^{34}S$ of groundwater shows the range of $+3~13.4{\;}{\textperthousand}$. Sulfur isotope indicates the possibility of a sulfate reduction and the input of anthrophogenic source.

Changes in Chemical and Microbiological Properties of Spring Waters in Tongyeoung Area (통영시내 약수의 화학적 및 세균학적 품질변화)

  • 최종덕;김정균
    • Journal of Food Hygiene and Safety
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    • v.15 no.4
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    • pp.328-333
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    • 2000
  • This study was carried out to changes in chemical and microbiological properties of spring waters in Tongyeoung area. In this paper, ninety spring water samples were collected from 9 station for 11 month to evaluated chemical and bacteriological water quality. Range and mean values of constituents of the samples are as followed; water temperature 5.2~25.8$^{\circ}C$, 16.3$^{\circ}C$, pH 6.0~7.2, 6.7, total residue 33.6~210 mg/1, 90.6 mg/1, turbidity 0.35~5.48, 1.45NTU, KMnO4 consumed 0.51~4.21 mg/1, 1.39 mg/1, chloride ion 6.23~42.5, 16.7 mg/l, phosphate-phosphorus ND-0.04, 0.02 mg/1, nitrite-nitrogen ND~0.02, 0.01 mg/1, nitrate-nitrogen ND~3.56, 1.42 mg/1, ammonia-nitrogen ND~0.20, 0.14 mg/1, dissolved total nitrogen ND~3.78, 1.57 mg/1, iron 0.04~0.28, 0.13ppm, zinc 0.03~0.66, 0.20ppm, mangan ND~0.01, allumium 0.14~0.58, 0.39ppm, copper ND~0.01, 0.01, lead ND~0.01, 0.01ppm, Arsenic ND~0.01, 0.01ppm, mercury ND~0.02, chrome not detected, cadmium not detetced respectively. The viable cell counts of the spring waters ranged 5.0~760/m1(means 130/m1). Range and mean value of total coliform and focal coliform MPN's of the spring waters were 0~2,400MPN/100 ml, 73MPN/100 ml and 0~540MPN/100 ml, 21MPN/100 ml. Spring water quality was usually poor with viable cell counts exceeding 130 CFU/liter and the coliform counts in spring waters of 73 MPN/liter. Composition of coliform by IMViC reaction was 33.3% E. coli, 15.6% Citrobacter freundii, 35.6% Klebsiella aerogenes and others.

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A case study of monitored natural attenuation at the petroleum hydrocarbon contaminated site: I. Site characterization (유류오염부지에서 자연저감기법 적용 사례연구: I. 부지특성 조사)

  • 윤정기;이민효;이석영;이진용;이강근
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.27-35
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    • 2003
  • The study site located in an industrial complex has a Precambrian age gneiss as a bedrock. The poorly-developed, disturbed soils in the study site have loamy-textured surface soil (1 to 2 m) and gravelly sand alluvium subsurface (2 to 6 m) on the top of weathered gneiss bedrock. The depth of the groundwater table was about 3.5 m below ground surface and increased toward down-gradient of the site. The hydraulic conductivity of transmitted zone (gravelly coarse sand) was in the range of 5.0${\times}$10$\^$-2/∼1.85${\times}$10$\^$-1/ cm/sec. The fine sand layer was in the range of 1.5${\times}$10$\^$-3/ to 7.6${\times}$10$\^$-3/ cm/sec. and the reclaimed upper soil layer was less than 10$\^$-4/ cm/sec. Toluene, ethylbenzene, and xylene (TEX) was the major contaminant in the soil and groundwater. The average depth of the soil contamination was about 1.5 m in the gravelly sand alluvium layer. At the depth interval 2.4∼4.8 m, the highest contamination in the soil is located approximately 50 to 70 m from the suspected source areas. The concentration of TEX in the groundwater was highest in the suspected source area and a lesser concentration in the center and southwest parts of the site. The TEX distribution in the groundwater is associated with their distribution in the soil. Microbial isolation showed that Pseudomonas flurescence, Burkholderia cepacia, and Acinetobactor lwoffi were the dominant aerobic bacteria in the contaminated soils. The analytical results of the groundwater indicated that the concentrations of dissolved oxygen (DO), nitrate, and sulfate in the contaminated area were significantly lower than their concentrations in the none-contaminated control area. The results also indicated that groundwater at the contaminated area is under anaerobic condition and sulfate reduction is the predominant terminal electron accepting process. The total attenuation rate was 0.0017 day$\^$-1/ and the estimated first-order degradation rate constant (λ) was 0.0008 day$\^$-1/.