• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.155-157
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• 1998

Dinitramide salts may be useful as effective solid oxidizers because of higher oxygen content than nitrate salts. 3-Nitramino-propanoate was given by base treatement in the retro-Michael reaction of N-nitro-4-azaheptanedioate, which was prepared by nitration of 4-azaheptanedioate using $HNO_3$-TFAA(trifiluoroacetic anhydride)-$Br_2$. The nitramino compound was treated wile $NO_2BF_4$ to give dinitramino compound which was subsequently reacted with bases to give dinitramide salts.

• Journal of the Korea Institute of Military Science and Technology
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• v.10 no.3
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• pp.200-207
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• 2007

Single base propellant using a nitrate ester compound NC decomposes naturally during storage time. Therefore, the research for storage life extension is necessary to single base propellant. In this research, $CaCO_3$ inorganic stabilizer had been added into single base propellants up to 0.3%, and the accelerated aging test of the propellant was started. And then, with applying the Arrhenius equation, the storage life of the test of the propellant was contrasted with that of reference propellant. As a result, the storage life of the propellant containing $CaCO_3$ inorganic stabilizer was about twice longer than the reference propellant.

• Journal of the Korean Applied Science and Technology
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• v.10 no.1
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• pp.23-29
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• 1993

Transesterification reaction between dimethyl phthalate and ethylene glycol was kinetically investigated in the presense of various metal nitrate catalysts at $170^{\circ}C$. The reaction rates measured by the amount of distilled methanol from the reaction vessel. The transesterification reaction was carried out under the first order conditions respect to the concentration of dimethyl phthalate and catalyst, respectively. The over all order was 2nd. By Arrhenius plot, the activation energy was calculated as 17.4kcal/mole and 17.2kcal/mole on the transesterification reaction with zinc nitrate and lead nitrate, respectively. Apparent rate constant, k' was appeared linear about concentration of catalyst.