• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.302-308
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• 2005

Nitrate is one of common contaminants frequently found in the bank filtrate. Biological autotrophic denitrification into permeable reactive barrier(PRB) system to reduce nitrate concentration in bank filtrate was implanted. The objectives of research are to investigate effect of inoculation, to evaluate alternative alkalinity sources, and to determine effect of hydraulic characteristics, such as retention time, flow rate on the performance of semi-pilot PRB system. Semi-pilot scale biological PRB system was installed using elemental sulfur and limestone/oyster shell as reactive materials near Nakdong River in Kyoungnam province, Korea. Nitrate concentration in bank filtrate was reduced by indigenous microorganisms in oyster shell as welt as by inoculating microorganisms isolated from the sludge of an anaerobic digester in a wastewater treatment plant. Oyster shell as well as limestone can be used as an alkalinity source. However, oyster shell resulted in suspended solids of effluent. As the flow rate in the system increased from 66 to 132 mL/min and accordingly the residence time decreased from 15 to 7.5 hours, nitrate concentration in effluent increased and nitrate removal efficiencies decreased from 75 to 58% at the fixed thickness of 80 cm of PRB.

• Economic and Environmental Geology
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• v.45 no.1
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• pp.23-30
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• 2012

Major ions and nitrogen isotopic analyses were performed to determine the geochemical characters and to identify the source of nitrate of the shallow groundwater around agricultural field in the Youngdong area. The pH value of groundwater ranges from 60. to 8.2 (pH 7.2, mean). The average of EC, Eh and DO is 369 ${\mu}S/cm$ (70~729 ${\mu}S/cm$), 165.6 mV (29~383.2 mV), 4.3 mg/L (1.8~8.0 mg/L) respectively. The ion concentraion of groundwater was in the order of $Ca^{2+}$>$Na^{2+}$>$Mg^{2+}$>$K^{2+}$ and ${HCO_3}^-$>${NO_3}^-$>${SO_4}^{2-}$>$Cl^-$>$F^-$. Most of groundwater is Ca-$HCO_3$ type. The groundwater was affected by water-rock interaction in the shallow depth. Some groundwater is Ca-Cl or Na-$HCO_3$ (2.5%) type that was due to agricultural activities. The $NO_3$_N concetration of grondwater range from 10.2 mg/l to 26.9 mg/l, which show that this area is under nitrate pollution. ${\delta}^{15}N-NO_3$ value of the groundwater is the origins of are a combination of animal wastes and man-made fertilizers.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.471-471
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• 2011

2012년 가축분뇨 해양투기가 전면 금지됨에 따라 가축분뇨의 자원화의 필요성이 대두되고 있다. 하지만 현재 가축분뇨 발생량의 일부는 퇴비화로 농경지로 환원되고 있으며, 지역에 따라 일부 지역에서는 농경지면적 대비 가축분뇨 필요량을 초과하는 것으로 나타나, 산림지 및 조림지역으로의 가축분뇨 환원이 새로운 대안중 하나로 대두되고 있다. 특히, SCB (Slurry Composting and Biofiltration) 액비는 성분이 비교적 균질하고 저농도이며 냄새가 없어 산림유역에 시비가 가능할 것으로 판단된다. 하지만, 액비 시비량에 따라 수분 및 영양성분 수지 불균형 등을 초래하여 토양에 축적될 우려가 있고, 지하수로 침출될 가능성이 있어 이에 대한 모니터링이 필요할 것으로 판단된다. 따라서 본 연구에서는 산림유역 중 백합나무 조림지인 바이오순환림과 포플러 조림지인 유휴지에 SCB액비를 시용하였을 때 지하수에 미치는 영향을 살펴보기 위하여 매주 지하수 수질 모니터링을 실시하였다. 특히, 청색증 등을 유발시켜 지하수 오염의 지표인 질산성질소를 중심으로 지하수 수질 분석을 하였으며 질산성질소의 오염원을 판단하기 위하여 질소 동위원소비를 분석하였다. 시험림의 물리적 특성이 다른 두 산림유역에서의 SCB액비 시용에 따른 지하수 모니터링 결과는 향후 지속적인 모니터링이 이루어진다면 산림지에서 SCB액비 시용에 따른 수질영향 평가 및 모델링 기초 자료로 활용될 수 있을 것으로 판단된다.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.6
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• pp.599-608
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• 2010

The effect of silica(fumed) on nitrate reduction by zero-valent iron(ZVI) was studied using batch experiment. The reduction of nitrate was tested in three different aqueous media including de-ionized water, artificial groundwater and real groundwater contaminated by nitrate. Kinetics of nitrate reduction in groundwater were faster than those in de-ionized water, and first-order rate constant($k_{obs}$) of ZVI/silica(fumed) process was about 2.5 time greater than that of ZVI process in groundwater. Amendment of Silica(fumed) also decreased ammonium presumably through adsorption on silica surface. The pHs in all processes increased due to oxidation of ZVI, but the increase was lower in groundwater due to buffering capacity of groundwater. The result also showed amount of reduced nitrate increased as initial nitrate concentration increased in groundwater. Separate adsorption isotherm experiments indicated that fumed silica itself had some degree of adsorption capacity for ammonium. The overall results indicated that silica(fumed) might be a promising material for enhancing nitrate reduction by ZVI.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.2011-2015
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• 2010

비점오염원에 의한 수질오염은 지표수 오염과 지하수 오염으로 분리될 수 있는데 보통 지하수는 지표수에 비하여 수질이 양호 하다고 여겨지만 오염된 하천 주위의 지하수 오염이 심각할 수 있다. 이러한 지하수에 의한 오염원을 산정하고 분석하기 위해 여러 가지 수문관련 공식이나, HSPF, MODFLOW, SWAT 모형 등이 사용되고 있는데 이 중, SWAT 모형은 다양한 작물 및 재배방법이 지표수 및 지하수 수질에 미치는 영향을 유역단위로 평가가 가능하여 국내 외 에서 널리 활용되고 있다. SWAT 모형은 소유역별 수문학적 반응단위인 HRU를 이용하여 유역 내 수문 및 수질을 평가하는데 소유역내 HRU의 공간적인 정보를 고려하지 않는 준 분포형 모형으로 다양한 영농방법이 지표수 및 지하수에 미치는 영향을 공간적으로 분석 하는데는 한계가 있다. 따라서 본 연구에서는 이러한 SWAT 모형의 단점을 개선하여 공간적으로 분석할 수 있는 SWAT HRU Mapping module을 개발하였고 강원도 평창군 대관령면 횡계2리 지역에 적용하여 지하수 함양량 및 대수층 유입 $NO_3$-N 부하량 및 농도를 분석하였다. 적용결과, 횡계2리 유역의 2006년 대수층 유입 $NO_3$-N 부하량 및 농도를 비교하면 일반적으로 농경지에서의 대수층 유입 $NO_3$-N 부하량이 큰 것으로 나타났고, 대부분 농경지에서 대수층으로 유입되는 $NO_3$-N의 농도가 산림에 비해서 상당히 높은 것으로 분석되었으며 2007년의 결과도 비슷한 경향이 나타났다. 본 연구의 결과에서와 같이 같은 밭이라 하더라도 재배되는 작물의 종류 및 시비량 등에 따라 대수층으로 유입되는 오염부하에는 상당한 영향이 있을 수 있으며, 또한 재배 작물과 토양 특성에 따라 $NO_3$-N이 대수층으로 유입될 것으로 판단된다. 따라서 본 연구에서 개발된 HRU Mapping Module은 유역에서의 수질 개선시기저유출을 통한 오염원의 시공간적 분석을 하는데 매우 유용하게 활용될 수 있으리라 판단된다.

• Journal of the Society of Disaster Information
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• v.16 no.3
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• pp.542-549
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• 2020

Purpose: As nitrate nitrogen produced during fermentation of liquid fertilizer is a pollution indicator of water, in this study, four research areas where liquid fertilizer was sprayed were selected, and a model was designed to estimate the concentration of nitrate nitrogen pollution. Method: Prior to shooting on site, a spectrum library was constructed by dividing the ratio of liquid fertilizer into 5 groups: 0%, 25%, 50%, 75%, and 100%. PLSR (Partial least squares regression) method was applied to hyperspectral images acquired in the study area based on the aspect of spectrum. Result: The behavior of nitrate nitrogen was confirmed by 1st and 2nd differentiation of the spectrum of the constructed liquid fertilizer. PLSR concentration estimation modeling was implemented using images from field experiments and compared with actual concentration of nitrate nitrogen. Conclusion: When comparing the PLSR concentration estimation model with the actual concentration of nitrate nitrogen, it was measured that the detection is possible in high concentration areas where the concentration of nitrate nitrogen is 70mg/kg or more.

• Economic and Environmental Geology
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• v.41 no.4
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• pp.393-403
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• 2008

Hydrogeochemistry of groundwater was studied in order to identify the influence of cow manure, distributed to a farmland as organic fertilizer, on nitrate concentrations in shallow groundwater and its spatio-temporal variations. From monitoring wells, water levels were measured using automatic data loggers, and water samples collected and analyzed in Feb., April, June and Oct. 2007. The average electric conductivity and concentration of nitrate in the groundwater show the highest levels in April and decline in subsequent sampling times. Decreases in dissolved oxygen(DO) and nitrate concentrations from April to Oct. and corresponding increases in $HCO_3$ concentrations indicate denitrification processes by microorganisms. Spatial variation of nitrate concentration appeared to be affected by the redox conditions of groundwater controlled by geochemical reactions of Mn, Fe and DOC contents.

• Economic and Environmental Geology
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• v.51 no.1
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• pp.15-26
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• 2018

The spatio-temporal variations of nitrate concentrations in groundwater of Jeju Island were evaluated by an analysis of time series groundwater quality data (N = 21,568) that were collected from regional groundwater monitoring (number of wells = 4,835) for up to 20 years between 1993 and 2015. The median concentration of $NO_3-N$ is 2.5 mg/L, which is slightly higher than those reported from regional surveys in other countries. Nitrate concentrations of groundwater in wells tend to significantly vary according to different water usage (of the well), administrative districts, and topographic elevations: nitrate level is higher in low-lying agricultural and residential areas than those in high mountainous areas. The Mann-Kendall trend test and Sen's slope analysis show that nitrate concentration in mid-mountainous areas tends to increase, possibly due to the expansion of agricultural areas toward highland. On the other hand, nitrate concentrations in the Specially Designated Groundwater Quality Protection Zones show the temporally decreasing trend, which implies the efficiency of groundwater management actions in Jeju. Proper measures for sustainable groundwater quality management are suggested in this study.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.1B
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• pp.119-124
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• 2006

The purpose of this study was the comparison of pollutants removal and the track study of the nitrogen and phosphorus, the estimation of the nitrification and denitrification rate, and the investigation of the nitrogen mass balance between intermittently aerated membrane bioreactor(IAMBR) and intermittently aerated bioreactor(IABR), thus it verified the validity of the membrane submergence. As a result, it had no difference of organic matter removal, however, IAMBR showed better efficiency than IABR in the nutrients. Also, $NO_3{^-}$-N concentration at the anoxic state in the reactor was lower in IAMBR, and the denitrified nitrogen of IAMBR was 40.9%, that of IABR was 10.7%, thus it found out that the denitrification capability of IAMBR was higher than IABR above fourfold. Therefore, it seems resonable to conclude that the membrane helps to improve the removal of pollutants, because of the high MLSS concentration and the available method of intermittent inflow/outflow.

• Journal of Korea Water Resources Association
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• v.32 no.4
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• pp.501-510
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• 1999

Stream and groundwater qualities of small agricultural watershed in Kangwon Probince, Korea were monitored 1 to 2 years, and the relationships between stream and groundwater qualities and seasonal water quality changes analyzed. Flooded paddy fields influenced groundwater level and quality during rice culture. The differences between groundwater levels during rice culture and non-culture spans were between 0.8 and 2.91 m. Seasonal changes of total nitrogen and nitrate nitrogen concentrations of stream and groundwater were very similar and groundwater quality was thought to have a profound impact on stream quality of the research watersheds. Suspended solids and BOD maintained the first degree stream water quality throughout the monitoring period except for a few and short flooding spans. The concentrations of total phosphorus and total bacteria of both waters showed wide variations and any seasonal trends were not observed. Long-term monitoring studies on small rural watersheds were recommended to understand the pattern of both stream and groundwater quality changes with respect to land use, season and cultural practice, and to apply the results to develop effective water quality management policies for large river and domestic water supply systems.