• The Journal of Engineering Geology
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• v.12 no.4
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• pp.471-484
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• 2002

Alluviums in the Keum River watershed cover an areal extent of $3,029{\;}\textrm{km}^2$ and contain about 8.1 billion tons of groundwater. However, the waters are severely polluted by nitrate, possibly due to the application of nitrogen fertilizer (>250 N kg/ha) on agricultural land. This paper aims to elucidate the pollution status and behaviors of nitrate in alluvial groundwaters in the Keum River watershed area, based on regional hydrogeochemical study. Most of the collected samples (n = 186) are polluted by nitrate (average = 42.2 mg/L, maximum = 295 mg/L). About 29% of the samples have the nitrate concentrations exceeding Korean Drinking Water Standard (44 mg/L $NO_3$). The distribution of nitrate concentrations in the study area is largely dependant on geochemical environments of alluvial aquifers. In particular, the decrease of redox potential of alluvial groundwaters showed a good correlation with the decreases of nitrate, iron, and manganese concentrations. Thus, the change of redox state in alluvial aquifers, likely reflecting their sedimentary environments, controls both the behavior and fate of nitrogen compounds and their natural attenuation (denitrification) in aquifers. A carbon-rich, silty layer within alluvium strata forms a reducing condition and possesses a buffering capacity on nitrate pollution.

• Korean Journal of Ecology and Environment
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• v.48 no.2
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• pp.95-107
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• 2015

In order to identify long-term trends of water quality parameters in Lake Kyeongpo, Mann-Kendall test, Sen's slope estimator and linear regression were applied on data, with 15 parameters from three different sites and rainfall, monitored once in every two months from March to November during 1998~2013. Seasonal variation analysis only used Mann-Kendall test and Sen's slope estimator. Analysis result showed that salinity, transparency and nutrient variables (total phosphorus, dissolved inorganic phosphorus, total nitrogen, nitrate nitrogen, ammonia nitrogen) were only parameters having statistically significant trend. In linear regression analysis, salinity (surface and bottom layer of all sites) and transparency (only at site 1), were figured out with statistically significant increasing trend, while in non-parametric statistical method, salinity and transparency in all sites (surface, middle, deep) were figured out with statistically significant increasing trend. Water quality parameters showing statistically significant decreasing trends were dissolved oxygen (surface layer of site 1 and bottom layer of sites 2 and 3), total phosphorus (sites 1 and 2), dissolved inorganic phosphorus, total nitrogen, nitrate nitrogen and ammonia nitrogen in the linear regression analysis and, dissolved oxygen (bottom layer of all sites), total phosphorus, dissolved inorganic phosphorus, total nitrogen, nitrate nitrogen and ammonia nitrogen in the non-parametric method. Seasonal trend analysis result showed that salinity, turbidity, transparency and suspended solids in spring, salinity, transparency, nitrate nitrogen and suspended solids in summer and temperature, salinity, transparency and suspended solids in fall were the variables depending on the season with increasing trends. In general, rainfall during the research period showed decreasing trend. The significant reduction trends of nutrients in Lake Kyeongpo were believed to be related to lagoon restoration and water management project run by Gangneung city and under-water wear removal, but further detailed studies are needed to know the exact causes.

• Journal of Korea Water Resources Association
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• v.32 no.4
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• pp.501-510
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• 1999

Stream and groundwater qualities of small agricultural watershed in Kangwon Probince, Korea were monitored 1 to 2 years, and the relationships between stream and groundwater qualities and seasonal water quality changes analyzed. Flooded paddy fields influenced groundwater level and quality during rice culture. The differences between groundwater levels during rice culture and non-culture spans were between 0.8 and 2.91 m. Seasonal changes of total nitrogen and nitrate nitrogen concentrations of stream and groundwater were very similar and groundwater quality was thought to have a profound impact on stream quality of the research watersheds. Suspended solids and BOD maintained the first degree stream water quality throughout the monitoring period except for a few and short flooding spans. The concentrations of total phosphorus and total bacteria of both waters showed wide variations and any seasonal trends were not observed. Long-term monitoring studies on small rural watersheds were recommended to understand the pattern of both stream and groundwater quality changes with respect to land use, season and cultural practice, and to apply the results to develop effective water quality management policies for large river and domestic water supply systems.

• KSBB Journal
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• v.24 no.3
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• pp.291-295
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• 2009

This study performed verification experiment for the removal of total nitrogen in sewage from a Town M village sewage treatment plant using YPNR processes. The total nitrogen discharged after the denitrification process was maintained at a level of 8-15 mg/L, which results in the total nitrogen removal efficiency above 68% on average. The total nitrogen components in discharged water consisted of 16% of ammonia nitrogen, 6% of nitrite nitrogen, and 77% of nitrate nitrogen, which reaches a 95% nitrification efficiency. Hence, the YPNR advanced treatment process used in this study can be successfully applied to sewage treatment.

• Journal of the Korean Society of Groundwater Environment
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• v.2 no.2
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• pp.85-92
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• 1995

This study was conducted to find out the relationship between microflora in groundwater and its physico-chemical environmental factors at the 59 sites, where distributed at 3 cities and 18 counties in Jeonranam-Do, Korea. The average values of environmental factors were as followings; pH 6.9, temperature 20.1 $^{\circ}C$, dissolved oxygen 6.5 mg/1, the depth of wells 80.1 m, and nitrate 10.7 mg/1. The average value of microbial population size; Heterotrophic bacteria-NA (HPC-NA) and heterotrophic bacteria-YEPD (HPC-YEPD) were 1.4${\times}$10$^3$CFU/ml and 0.59${\times}$10$^3$ CFU/ml respectively HPC-YEPD numbers were 42.1% of HPC-YEPD. Coliform bacteria were detected at 16 sites, and its average numbers were 6.7 CFU/ml. General fungi were detected at 14 sites, and its had average numbers were 3.9 CFU/ml. The correlation coefficient was calculated value as relation index between the microbial population sizes and environmental factors in groundwater. In case of HPC-NA, the correlation coefficient value with dissolved oxygen was 0.087 But it showed negative correlation coefficient with other factors. In case of HPC-YEPD, the correlation coefficient value with pH, temperature and nitrate were 0.0957, 0.0019 and 0.0151 respectively. It was concluded that the population size of HPC-NA were influenced by the order of temperature, dissolved oxygen, pH and the depth of wells and that HPC-YEPD were influenced by the order of pH, dissolved oxygen, nitrate, the depth of wells and temperature.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.8
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• pp.649-654
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• 2009

Respirometric analysis of domestic sewage by measuring oxygen uptake rate(OUR) was carried out for the experimental assessment of the organic and biomass fractions. The data of the organic and biomass fractions in sewage is essential for the activated sludge model to optimize the biological treatment plant. As a result of this study, the fractions of readily biodegradable substrate($S_S$), slowly biodegradable substrate($X_S$), inert soluble substrate($S_I$), inert particular substrate($X_I$) and heterotrophic biomass($X_{HAB}$) were about 26.6%, 41.5%, 8.5%, 14.7% and 8.7% on the basis of chemical oxygen demand($COD_{Cr}$), respectively. And the fractions of nitrogen were also studied. The fractions of soluble nitrate nitrogen($S_{NO}$), soluble ammonia nitrogen($S_{NH}$), soluble nonbiodegradable organic nitrogen($S_{NI}$), soluble biodegradable organic nitrogen($S_{ND}$) and slowly biodegradable organic nitrogen($X_{ND}$) were about 3.7%, 64.9%, 4.7%, 9.4% and 17.4%, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.2
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• pp.155-160
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• 2008

In this study, the nitrate removal efficiency was examined under a variety of operating conditions, such as different doses of the reducing agent, different electrode types, different HRTs(hydraulic retention times), and different current densities, using the multistep electrochemical process. The nitrate removal efficiency increased and the input energy decreased when the reducing agent was used, and almost no difference was found between the electrode types in terms of their nitrate removal efficiency and current efficiency. So that the Zn reducing agent could be recovered, though, the B-type electrode was chosen(step 1: Pt-Zn; step 2: Pt-Zn; step 3: Pt-Zn; step 4: Pt-Zn). HRT experiments were carried out on constant electric current density unrelated HRTs and various electric current density related HRTs: the constant amount of electric current per unit volume. As a result, HRT and the electric current density caused concentration polarization and the lack of an applied current. That is to say,the lower the HRT, the greater the decrease in concentration polarization and in the amount of applied current per unit volume. Therefore, optimal conditions were found through the experiments that were conducted on HRT and electric current density. When a spacer was installed in the process, the nitrate removal efficiency and energy efficiency increased even more because the diffusion likewise increased.

• Journal of Soil and Groundwater Environment
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• v.14 no.6
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• pp.73-77
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• 2009

Two different aquifers with different characteristics developed in the study area - a lower and upper aquifer zone. Nitrate contamination of the lower aquifer zone was likely due to infiltration of nitrate-contaminated groundwater of the upper aquier zone through abandoned groundwater wells. In order to evaluate the feasibility of a preliminary packer designed to prevent nitrate migration through abandoned groundwater wells NO3-N concentrations of the upper and lower part of preliminary packer installed at four sampling sites were measured. Nitrate concentrations of the and lower part of Yechun sinwolri were 10.3 mg/L and 5.0 mg/L, respectively. Yechun eosinri, Yechun jeowooriis, and Andong hoegokri were $NO_3$-N concentrations in the upper (11.3, 11.0, and 14.6 mg/L) and lower (8.8, 1.6, and 8.0 mg/L), respectively. $NO_3$-N contents of all groundwater samples in the lower part after the preliminary packer installation showed 22~85% lower than those of the upper part.

• Journal of Korea Water Resources Association
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• v.40 no.6 s.179
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• pp.469-483
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• 2007

Nitrate and chloride are the most common contaminants in groundwater and their concentrations increase easily due to fertilizer consumption and urbanization. The number of time series data for groundwater quality at a single site was not sufficient to analyze trends on Jeju Island. Therefore rectangle grids were drawn for the whole island and single grid was determined to be $500m{\times}500m$ after considering similar stream density, homogeneous hydraulic coefficients, geologic features of volcanic rock and low topographic slopes. All data within each lattice were collected and arranged in time series order and analyzed using Sen's method. 10.6 % of the total lattices for chloride and 22.4% for nitrate showed upward trends from the early 1990's to the early 2000's. Especially, upward trends for nitrate concentration are distinct in the low mid-mountainous areas of western and southern watersheds. Many septic tanks and much domestic waste from the urbanization of the low mid-mountainous area have produced this upward trend. Additionally, the agricultural region has dramatically increased since the 1990's and this has led to an increase of fertilizer consumption and, as a result, nitrate concentration. Therefore, the target of any management plan for groundwater quality on Jeiu Island needs to be focused on careful land use decisions in the mid-mountainous areas which are near Halla Mountain.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.1
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• pp.53-60
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• 2005

Ferrous cement hydrates made from hydrating Portland cement doped with Fe (II) were reported to reductively dechlorinate chlorinated organics and to reduce Cr (VI) to Cr (III). In this study, kinetics of nitrate removal by ferrous cement hydrates were investigated. Nitrate removal kinetics were characterized by experimental variables such as cement hydration, amount of cement addition, Fe (II) dose, pH, and byproducts. As a result, hydrated cement showed better performances than non-hydrated cement due to the formation of LDH (layered double hydroxide). Doping of Fe (II) into the cement was found to improve removal efficiency at high pHs by association with Fe (II) sorbed on cement hydrates as a reactive reductant. Reduction of nitrate produced ammonium as a major product, which accounted for 63.5% of the final products, and nitrite (0.15%) as a minor product. These results indicate that the developed media are effective as sorbent/reducing agents in the nitrate removal and the reaction mechanisms of nitrate removal are sorption and reduction.