• Economic and Environmental Geology
• /
• v.51 no.1
• /
• pp.15-26
• /
• 2018

The spatio-temporal variations of nitrate concentrations in groundwater of Jeju Island were evaluated by an analysis of time series groundwater quality data (N = 21,568) that were collected from regional groundwater monitoring (number of wells = 4,835) for up to 20 years between 1993 and 2015. The median concentration of $NO_3-N$ is 2.5 mg/L, which is slightly higher than those reported from regional surveys in other countries. Nitrate concentrations of groundwater in wells tend to significantly vary according to different water usage (of the well), administrative districts, and topographic elevations: nitrate level is higher in low-lying agricultural and residential areas than those in high mountainous areas. The Mann-Kendall trend test and Sen's slope analysis show that nitrate concentration in mid-mountainous areas tends to increase, possibly due to the expansion of agricultural areas toward highland. On the other hand, nitrate concentrations in the Specially Designated Groundwater Quality Protection Zones show the temporally decreasing trend, which implies the efficiency of groundwater management actions in Jeju. Proper measures for sustainable groundwater quality management are suggested in this study.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2020.06a
• /
• pp.282-282
• /
• 2020

본 연구는 여수시 농어촌지역에 대하여 지하수 함양특성, 개발가능량 산정 및 오염부하량 등의 조사를 통해서 체계적인 지하수자원의 보전관리(안)을 수립하기 위해 수행되었다. 연구지역은 여수시 화양면, 소라면 2개 면을 포함하는 농어촌 용수구역(여소지구)으로, 여소지구의 총면적은 130.68 ㎢이며, 이 중 임야면적은 81.57 ㎢, 경지면적은 32.98 ㎢ 이고, 경지면적은 논 15.37 ㎢, 밭 17.42 ㎢, 시설재배 0.19 ㎢로 구성되어 있다. 여소지구의 30년 강수평균은 1,454.08 mm/년이며, 지하수 함양량은 국가지하수관리 기본계획(국토교통부, 2019) 및 전라남도 지하수관리계획(전라남도, 2009) 보고서를 참고하여 평균값인 11.28%로 산정한 결과, 21,279 천㎥/년으로 분석되었다. 또한, 지하수연보(국토교통부, 2018)의 세부용도별 이용량을 활용하여 지하수 이용량을 산정한 결과, 2,638.35 천㎥/년이었으며, 강수량, 함양률 및 면적 값을 고려하여 지하수 개발가능량을 산정한 결과, 16,387.57 천㎥/년, 개발가능량 대비 이용량은 16.11%로 확인되었다. 여소지구의 질산성질소 항목은 총 181개소(경지면적 0.2 ㎢당 1점)에 대해 분석한 결과, 전체 평균값은 6.67 mg/L이었으며, 농업용수 수질기준(20 mg/L)을 초과한 관정은 8개소(6%)로 확인되었다. DRASTIC을 이용한 오염취약성 지수는 평균값이 119.57점으로 나타나 오염취약성이 낮은 것으로 분석되었다. 신고·허가된 축사 시설을 기준으로 점오염원 조사결과, 단위면적당 시설수(오염원밀도)는 3.12 개소/㎢로 조사되었으며, 인구, 가축 및 토지이용 등 인자별을 고려하여 오염부하량을 산출한 결과, 단위면적당 오염부하량은 75.30 kg/day/㎢로 확인되었다. 행정구역별로 7가지 지표를 반영하여 관심, 주의, 경계 및 심각 4단계로 기준을 설정하여 지하수관리 필요지역을 선정하였다. 수량 측면은 개발가능량 대비 이용량, 단위면적당 이용량 및 관정밀 3가지 지표를 적용하였고, 수질 측면은 질산성질소 평균, 오염취약성 지수, 오염원밀도 및 단위면적당 오염부하량 4가지 지표를 적용하여 선정하였다. 지하수관리 필요지역을 분석한 결과, 전체 18개 리 중에서 14개 리에서 수량관리 12개리에서 수질관리 필요지역이 나타났다. 수량관리 필요지역은 지하수 취수량 조정 및 관리 확충 등의 대책방안이 마련되어야 하며, 수질관리 필요지역은 주변 오염원관리 및 수질검사 강화 등의 대책방안이 필요할 것으로 판단된다.

• Journal of Soil and Groundwater Environment
• /
• v.8 no.3
• /
• pp.30-36
• /
• 2003

The effect of humic acid on the simultaneous removal of nitrate and phosphate was investigated in a micellar-enhanced ultrafiltration (MEUF). At the low molar ratio of cetylpyridinium chloride (CPC) to contaminants, the removal of nitrate was lower to 50％ by 100 ppm of humic acid due to the competition for binding on micelles. At the molar ratio higher than 3, however, the removal of nitrate was over 80％. Phosphate was removed over 80% at the molar ratio higher than 1. The CPC and humic acid were rejected over 99 ％ by UF membrane. The flux did not decrease by 100 ppm of humic acid but rather slightly increased since the humic acid adsorbed on the membrane made the membrane more hydrophilic. As a result, humic acid did not diminish the performance of MEUF in the simultaneous removal of nitrate and phosphate.

• Journal of the Society of Disaster Information
• /
• v.16 no.3
• /
• pp.542-549
• /
• 2020

Purpose: As nitrate nitrogen produced during fermentation of liquid fertilizer is a pollution indicator of water, in this study, four research areas where liquid fertilizer was sprayed were selected, and a model was designed to estimate the concentration of nitrate nitrogen pollution. Method: Prior to shooting on site, a spectrum library was constructed by dividing the ratio of liquid fertilizer into 5 groups: 0%, 25%, 50%, 75%, and 100%. PLSR (Partial least squares regression) method was applied to hyperspectral images acquired in the study area based on the aspect of spectrum. Result: The behavior of nitrate nitrogen was confirmed by 1st and 2nd differentiation of the spectrum of the constructed liquid fertilizer. PLSR concentration estimation modeling was implemented using images from field experiments and compared with actual concentration of nitrate nitrogen. Conclusion: When comparing the PLSR concentration estimation model with the actual concentration of nitrate nitrogen, it was measured that the detection is possible in high concentration areas where the concentration of nitrate nitrogen is 70mg/kg or more.

• Journal of Soil and Groundwater Environment
• /
• v.13 no.5
• /
• pp.57-73
• /
• 2008

Nitrate concentrations were measured up to 49 mg/L (as $NO_3$-N) and 22% of the samples exceeded drinking water standard in shallow and bedrock groundwater of the northern Nonsan area. Nitrate concentrations showed a significant difference among land use groups. To predict nitrate concentration in groundwater, multiple regression analysis was carried out using hydrogeologic parameters of soil media, topography and land use which were categorized as several groups, well depth and altitude, and field parameters of temperature, pH, DO and EC. Hydrogeologic parameters were quantified as area proportions of each category within circular buffers centering at wells. Regression was performed to all the combination of variables and the most relevant model was selected based on adjusted coefficient of determination (Adj. $R^2$). Regression using hydrogelogic parameters with varying buffer radii show highest Adj. $R^2$ at 50m and 300m for shallow and bedrock groundwater, respectively. Shallow groundwater has higher Adj. $R^2$ than bedrock groundwater indicating higher susceptibility to hydrogeologic properties of surface environment near the well. Land use and soil media was major explanatory variables for shallow and bedrock groundwater, respectively and residential area was a major variable in both shallow and bedrock groundwater. Regression involving hydrogeologic parameters and field parameters showed that EC, paddy and pH were major variables in shallow groundwater whereas DO, EC and natural area were in bedrock groundwater. Field parameters have much higher explanatory power over the hydrogeologic parameters suggesting field parameters which are routinely measured can provide important information on each well in assessment of nitrate contamination. The most relevant buffer radii can be applied to estimation of travel time of contaminants in surface environment to wells.

• Clean Technology
• /
• v.15 no.3
• /
• pp.194-201
• /
• 2009

Reductive reactivity of zero-valent iron nanoparticles was investigated for removal of nitrate-nitrogen which is considered one of the major water pollutants. To elucidate the difference in reactivity between preparation methods, iron nanoparticles were synthesized respectively from microemulsion and aqueous solution of ferric ions. Iron nanoparticles prepared from microemulsion were deposited on aluminum by electrophoretic method, and their reaction kinetics was compared to that of the same nanoparticles suspended in aqueous batch reaction. With an approximation of pseudo-first-order reaction, rate constants for suspended nanoparticles prepared from microemulsion and dilute aqueous solution were $3.49{\times}10^{-2}min^{-1}$ and $1.40{\times}10^{-2}min^{-1}$, respectively. Iron nanoparticles supported on aluminum showed ca. 30% less reaction rate in comparison with the identical nanoparticles in suspended state. However, supported nanoparticles showed the superior effectiveness in terms of nitrate-nitrogen removal per zero-valent iron input especially when excess amounts of nitrates were present. Iron nanoparticles deposited on aluminum maintained reductive reactivity for more than 3 hours, and produced nitrogen gas as a final reduction product of nitrate-nitrogen.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2000.05a
• /
• pp.90-90
• /
• 2000

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.10
• /
• pp.578-582
• /
• 2015

It was investigated whether the removal of nitrogen ions included livestock wastewater were increased by increasing the reaction time of livestock wastewater and microbubbles with catalyst. For this study, the nitrogen reduction system using microbubbles with catalyst was used. The two reactors were consecutively arranged, and the second reactor (Step 2) was located to next the first reactor (Step 1). Each reactor was reacted for 2 hours and air or oxygen as oxidant was fed into the reactor during operation before microbubble device. When oxygen was used, ammonia nitrogen was removed each 18.3% and 52.8% during 2 (only step 1) and 4 (step 1 and step 2) hours reactions. This value was higher than that of when air was fed. When oxygen was used, the longer the reaction time, the ammonia nitrogen removal was higher. The longer the reaction time, the higher the nitrite and nitrate was also removed such as ammonia nitrogen. Also this system was examined whether organic matter removal is effective. The total chemical oxygen demand (TCOD) removal was higher than the soluble chemical oxygen demand (SCOD). Some materials among causing substances COD were difficult to decompose biologically. Therefore, it means that it will be easy to operate the biological processes following step and reduce the concentration of organic contaminants in effluent.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.3
• /
• pp.302-308
• /
• 2005

Nitrate is one of common contaminants frequently found in the bank filtrate. Biological autotrophic denitrification into permeable reactive barrier(PRB) system to reduce nitrate concentration in bank filtrate was implanted. The objectives of research are to investigate effect of inoculation, to evaluate alternative alkalinity sources, and to determine effect of hydraulic characteristics, such as retention time, flow rate on the performance of semi-pilot PRB system. Semi-pilot scale biological PRB system was installed using elemental sulfur and limestone/oyster shell as reactive materials near Nakdong River in Kyoungnam province, Korea. Nitrate concentration in bank filtrate was reduced by indigenous microorganisms in oyster shell as welt as by inoculating microorganisms isolated from the sludge of an anaerobic digester in a wastewater treatment plant. Oyster shell as well as limestone can be used as an alkalinity source. However, oyster shell resulted in suspended solids of effluent. As the flow rate in the system increased from 66 to 132 mL/min and accordingly the residence time decreased from 15 to 7.5 hours, nitrate concentration in effluent increased and nitrate removal efficiencies decreased from 75 to 58% at the fixed thickness of 80 cm of PRB.

• Economic and Environmental Geology
• /
• v.45 no.1
• /
• pp.23-30
• /
• 2012

Major ions and nitrogen isotopic analyses were performed to determine the geochemical characters and to identify the source of nitrate of the shallow groundwater around agricultural field in the Youngdong area. The pH value of groundwater ranges from 60. to 8.2 (pH 7.2, mean). The average of EC, Eh and DO is 369 ${\mu}S/cm$ (70~729 ${\mu}S/cm$), 165.6 mV (29~383.2 mV), 4.3 mg/L (1.8~8.0 mg/L) respectively. The ion concentraion of groundwater was in the order of $Ca^{2+}$>$Na^{2+}$>$Mg^{2+}$>$K^{2+}$ and ${HCO_3}^-$>${NO_3}^-$>${SO_4}^{2-}$>$Cl^-$>$F^-$. Most of groundwater is Ca-$HCO_3$ type. The groundwater was affected by water-rock interaction in the shallow depth. Some groundwater is Ca-Cl or Na-$HCO_3$ (2.5%) type that was due to agricultural activities. The $NO_3$_N concetration of grondwater range from 10.2 mg/l to 26.9 mg/l, which show that this area is under nitrate pollution. ${\delta}^{15}N-NO_3$ value of the groundwater is the origins of are a combination of animal wastes and man-made fertilizers.