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Mechanism of Surface Film Formation on Graphite Negative Electrodes and Its Correlation with Electrolyte in Lithium Secondary Batteries (리튬 이차전지의 흑연 음극 표면피막 생성기구와 전해질과의 상관성)

  • Jeong, Soon-Ki
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.19-33
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    • 2010
  • The surface film, which is formed on graphite negative electrodes during the initial charging, is a key component in lithium secondary batteries. The battery reactions are strongly affected by the nature of the surface film. It is thus very important to understand the physicochemical properties of the surface film. On the other hand, the surface film formation is a very complicated interfacial phenomenon occurring at the graphite/electrolyte interface. In studies on electrode surfaces in lithium secondary batteries, in-situ experimental techniques are very important because the surface film is highly reactive and unstable in the air. In this respect electrochemical atomic force microscopy (ECAFM) is a useful tool for direct visualizing electrode/solution interfaces at which various electrochemical reactions occur under potential control. In the present review, mechanism of surface film formation and its correlation with electrolyte are summarized on the basis of in-situ ECAFM studies for understanding of the nature of the surface film on graphite negative electrodes.

154kV Main TR. Bay IED Based On IEC-61850 (IEC-61850 기반의 154kV M.Tr Bay IED 적용 사례)

  • Roh, Jae-Keun;Oh, Jae-Hoon;Kim, Byoung-Choul;Ko, Choul-Jin;Yang, Hang-Jun
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.764-765
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    • 2011
  • 전력시스템을 더 효율적으로 운용하고, 더 지능화하려는 노력은 2000년대 초 다양한 각도로 진행되어 왔다. 그리하여 중장기 국책과제인 전력IT 과제를 필두로 여러 지능화 기기들이 국 내외 유관업체를 통하여 지속적으로 성장을 하였고 현재에 이르러서는 과제의 틀이 아닌 비즈니스 모델 창출을 위하여 여러 시범 사업들이 구상되고 있는 중이다. 이는 전력IT 의 핵심 아이템이라 할 수 있는 IEC-61850 국제 표준 프로토콜 기반의 IED (Intelligent Electronic Devices) 개발과 어울려 변전소의 직접 현장 적용을 통한 엔지니어링 기술 개발에 역점을 두고 있는 상태이다. 변전소 자동화 (S/A: Substation Automation)의 영역이 점점 현실화 되어가고, 전 세계 적용 Site의 폭발적인 증가로 힘입어 이젠 선택이 아닌 필수가 되고 있고, 적용에서 끝이 아닌 다양한 엔지니어링 Tool 의 개발, 진단 시스템의 융합 등과 더불어 계속 발전해나가고 있다. 본 논문에서는 이러한 시대적 흐름을 바탕으로 당사에서 참여중인 한국전력 154kV S/A 시범사업 및 스마트그리드 실증사업을 통하여 현장 적용된 154kV Main Transformer 용 IED 솔루션의 적용 사례를 소개하고자 한다. S/A 시범사업의 경우, 한국전력 충주본부 풍동S/S에서 올해 초 설계되어 현재 현장 엔지니어링을 1차 마무리한 상태이며, 스마트 그리드 실증사업은 제주 성산S/S에서 진행 중이며 이도 마무리를 하는 단계에 이르러, 그동안 현장적용의 문제점을 논의하고, 이에 대한 대응책을 서로 공유하며 정리하고 있다. 참고로 본 논문에서는 IEC-61850 프로토콜 구현에 대한 것은 다루지 않으며, 다만 현장제어에 필요하고 또한 구현되어 있는 기능에 대한 전반적인 내용을 다루게 된다.

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An Experimental Study on Structural Behaviour of Asymmetric H Beam Slim floor under Load Condition in Fire (내화 피복된 비대칭 H형강을 적용한 슬림플로어 보의 재하가열조건 화재거동에 관한 실험적 연구)

  • Kim, Hyung-Jun;Kim, Hyung-Jun;Min, Byung-Youl;Lee, Jae-Sung;Park, Soo-Yong
    • Fire Science and Engineering
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    • v.25 no.1
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    • pp.63-71
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    • 2011
  • When it comes to slim floor using asymmetric H-beam, it was designed that the steel member is embedded in concrete with relatively low thermal conductivity so as to minimize the deterioration of rigidity of steel member in fire. But given the bottom flange of asymmetric H-beam is directly exposed to the fire, the measure of applying the fireproof coating to improve the fire rate performance of slim floor beam was sought. The test was aimed at comparing the fireproof performance by adjusting the load ratio of 0.4 and 0.3, and The test was carried out to identify the 3-hour fire performance by reinforcing the beam as well as applying the fireproof coat, In the wake of comparing the specimen depending on variation of load ratio, lowering load ratio by 0.1 resulted in difference of 12 minutes and deflection was 39 mm. It was able to improve 12 minutes by reinforcing the beam and up to 102.4 mm in deflection.

Architecture Modeling for Kiosk-based Public Services through Web (키오스크 기반 웹 민원처리시스템 구축을 위한 아키텍쳐 모델링)

  • 안임상;정기원
    • The Journal of Society for e-Business Studies
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    • v.9 no.1
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    • pp.285-301
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    • 2004
  • Public service provision through internet is one of major parts for e-government implementation. It is essential to link the internal administrative network with internet to provide the services through internet and to support kiosks through internet, which should result in critical issues for security. A relay server, as a front server for the public service processing system and a web server, a control server for kiosks, are placed between the public service processing system and kiosks to solve those security issues. It is the way to solve security issues through protecting direct communication between the public service processing system and a web server and authenticating a relay server and a web server through authentication process. In the implementation of the system this paper provide a design for an architecture model of the public service processing system through internet, which are aiming to develop high level of the quality system effectively, to reduce the risk of initial stage of development, and to reduce the incurring cost due to reworks.

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The Design and Implementation of Restructuring Tool with Logical Analysis of Object-Oriented Architecture and Design Information Recovery (설계 정보 복구와 객체 지향 구조의 논리적 분석을 통한 재구성 툴 설계 및 구현)

  • Kim, Haeng-Gon;Choe, Ha-Jeong;Byeon, Sang-Yong;Jeong, Yeon-Gi
    • The Transactions of the Korea Information Processing Society
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    • v.3 no.7
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    • pp.1739-1752
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    • 1996
  • Software reengineering involves improving the software maintenance process and improving existing systems by applying new technologies and software tools. Software reengineering can help us understand existing systems and discover software components that are common across systems. In the paper, we discuss the program analysis and environment to assist reengineering. Program analysis takesan existing program as input and generates information about structured part and object-oriented part. It is used to restructure the information by extracting code through reengineering methodology. These restructuring informations with object-oriented archilccture are mapping prolog form to query by using direct reation and summary relation.

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Performance Analysis of DMF Acquisition System in Frequency-Selective Rayleigh Fading Channel (주파수 선택적 레일리 페이딩 채널에서의 DMF 초기동기 장치의 성능분석)

  • 김성철;이연우;조춘근;박형근;차균현
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.7B
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    • pp.1351-1360
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    • 1999
  • In frequency selective channels, conventional PN code acquisition schemes are not ideal candidates. This is because they are primarily designed for the AWGN channel. In this paper, a direct-sequence spread-spectrum(DSSS) PN code acquisition system based on digital matched filtering (DMF) with automatic threshold control(ATC) algorithm is presented and analyzed with regards to probability of detection and probability of false alarm. These two important probabilities, the probability of detection ($P_D$) and the probability of false alarm ($P_{FA}$) are derived and analyzed in considering Doppler shift, sampling rate, mean acquisition time, and PN chip rate in frequency selective Rayleigh fading channel when using serial-search method as detection technique. From computer simulation results of a DMF acquisition system model, it is shown that the performance of the acquisition system using ATC algorithm is better than that of constant threshold system.

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Influence Evaluation of Fiber on the Bond Behavior of GFRP Bars Embedded in Fiber Reinforced Concrete (섬유보강 콘크리트에 묻힌 GFRP 보강근의 부착거동에 대한 섬유영향 평가)

  • Kang, Ji-Eun;Kim, Byoung-Ill;Park, Ji-Sun;Lee, Jung-Yoon
    • Journal of the Korea Concrete Institute
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    • v.24 no.1
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    • pp.79-86
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    • 2012
  • Though steel reinforcing bars are the most widely used tensile reinforcement, corrosion problems are encountered due to the exposure to aggressive environments. As an alternative material to steel, the fiber reinforced polymers have been used as reinforcement in concrete structures. However, bond strength of FRP rebar is relatively low compared to steel rebar. It has been reported that fibers in matrix can resist crack growth, propagation and finally result in an increase of toughness. In this study, high-strength concrete reinforced with structural fibers was produced to enhance interfacial bond behavior between FRP rebar and concrete matrix. The interfacial bond-behaviors were investigated from a direct pullout test. The test variables were surface conditions of GFRP bars and fiber types. Total of 54 pullout specimens with three different types of bars were cast for bond strength tests. The bond strength-slip responses and resistance of the bond failure were evaluated. The test results showed that the bond strength and toughness increased according to the increased fiber volume.

A Dynamic Approach to Extract the Original Semantics and Structure of VM-based Obfuscated Binary Executables (가상 머신 기반으로 난독화된 실행파일의 구조 및 원본의미 추출 동적 방법)

  • Lee, Sungho;Han, Taisook
    • Journal of KIISE
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    • v.41 no.10
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    • pp.859-869
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    • 2014
  • In recent years, the obfuscation techniques are commonly exploited to protect malwares, so obfuscated malwares have become a big threat. Especially, it is extremely hard to analyze virtualization-obfuscated malwares based on unusual virtual machines, because the original program is hidden by the virtual machine as well as its semantics is mixed with the semantics of the virtual machine. To confront this threat, we suggest a framework to analyze virtualization-obfuscated programs based on the dynamic analysis. First, we extract the dynamic execution trace of the virtualization-obfuscated executables. Second, we analyze the traces by translating machine instruction sequences into the intermediate representation and extract the virtual machine architecture by constructing dynamic context flow graphs. Finally, we extract abstract semantics of the original program using the extracted virtual machine architecture. In this paper, we propose a method to extract the information of the original program from a virtualization-obfuscated program by some commercial obfuscation tools. We expect that our tool can be used to understand virtualization-obfuscated programs and integrate other program analysis techniques so that it can be applied to analysis of the semantics of original programs using the abstract semantics.

Characteristics of Non-thermal Plasma Generation by Duty Ratio and Frequency of Pulse Voltage (펄스고전압의 시비율과 주파수에 따른 비열플라즈마 발생특성)

  • Park, Seung-Lok;Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.5
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    • pp.146-150
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    • 2004
  • The effects on non-thermal plasma generation by duty Ratio and frequency of pulse voltage were investigated experimentally. For these, a new type of non-thermal plasma generator with mesh electrode was manufactured and it was possible to generate the surface and silent discharge simultaneously by new type of non-thermal plasma generator. Duty ratio and frequency were selected as main parameters to control the movement of electron which is mainly related to the non-thermal plasma generation. The characteristics of non-thermal plasma generation were investigated indirectly by measuring the I-V curve and quantity of ozone generation. The most effective condition of duty ratio and frequency to generate the non-thermal plasma was identified by experiments with manufactured non-thermal plasma generator.

Correction of Missing Feature Points for 3D Modeling from 2D object images (2차원 객체 영상의 3차원 모델링을 위한 손실 특징점 보정)

  • Koh, Sung-shik
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.12
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    • pp.2844-2851
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    • 2015
  • How to recover from the multiple 2D images into 3D object has been widely studied in the field of computer vision. In order to improve the accuracy of the recovered 3D shape, it is more important that noise must be minimized and the number of image frames must be guaranteed. However, potential noise is implied when tracking feature points. And the number of image frames which is consisted of an observation matrix usually decrease because of tracking failure, occlusions, or low image resolution, and so on. Therefore, it is obviously essential that the number of image frames must be secured by recovering the missing feature points under noise. Thus, we propose the analytic approach which can control directly the error distance and orientation of missing feature point by the geometrical properties under noise distribution. The superiority of proposed method is demonstrated through experimental results for synthetic and real object.