• Title/Summary/Keyword: 지화학 분석

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Geochemical Evaluation and Characterization of the Shale Gas Resources (셰일 가스 자원의 지화학적 평가 및 특성화)

  • Lee, Young-Joo
    • Economic and Environmental Geology
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    • v.46 no.4
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    • pp.359-373
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    • 2013
  • Shale is considered as a source rock for conventional oil and gas exploration and development because shale is fine-grained detrital sedimentary rock which can preserve the organic matter better. Shale has a good sealing capacity for the petroleum trap due to its low permeability. Commercial recoveries of gas from shale in the North America based on the development of technologies of horizontal drilling and hydraulic fracturing reveal that shale also function as a effective reservoir rock. Geochemical techniques to evaluate generation potential of the hydrocarbons from organic matter in the source rocks can be applied for the exploration of the shale gas resources. To evaluate shale gas resources, it is important to understand various geochemical processes and shale characteristics controlling generation, storage and estimation of shale gas reserves. In this paper, the generation mechanism of the oil and gas from organic matter is reviewed, and geochemical techniques which can be applied for the evaluation and characterization of shale gas are introduced.

A Study on the Usage of Industry & Technology Joumals (산업기술분야 학술지 이용에 관한 연구)

  • Kim, Suk-Young;Hwang, Hye-Kyong
    • Journal of Information Management
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    • v.31 no.4
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    • pp.13-49
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    • 2000
  • This paper describes the results of journals usage analysis conducted at the Korea Institute of Industry & Technology Information. The study covers the photocopy usage of journals during the past 5 years from 1995 through 1999. Analysis showed that 19% of journal collection met 93% of total demands. The Analysis also provided on journal use patterns. The most frequently used subject field of journals was Chemistry and Chemical Engineering. A relationship was found between rankings of journal as measured by the photocopy data and SCI journal citation ranking, however, no relationship was found between photocopy rankings of journal and rankings of journal impact factors.

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Characteristics of Groundwater Pollution and Contaminant Attenuation at Waste Disposal Sites (폐기물 매립지 주변의 지하수 오염과 오염물질의 지연 특성)

  • 오석영;전효택
    • Journal of the Korean Society of Groundwater Environment
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    • v.3 no.1
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    • pp.37-49
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    • 1996
  • The objectives of this study are to investigate the groundwater and surface water contamination, to interpret the attenuation mechanism of contaminant transport, and to find the appropriate contamination indicator. at the two big landfill sites : Nanjido Landfill and Hwasung Landfill. Leachate from the Nanjido, th, Hwasung and the Kimpo waste disposal sites is characterized by high temperature (31.7-40.1$^{\circ}C$), high electric conductivity (14,650-32,800 ${\mu}$S/cm), somewhat higher pH(7.58-8.45) and low Eh (-119.4-20.4 mV), and is enriched in both major (Na$^{+}$, K$^{+}$, Ca$^{2+}$, Mg$^{2+}$, HC $O_3$$^{-}$, Cl$^{-}$) and minor (Mn, Sr$^{2+}$, Ba$^{2+}$, Li$^{+}$, F$^{-}$, Br$^{-}$) ions. Municipal solid waste leachate and industrial waste leachate are effectively discriminated by the content of S $O_4$$^{2-}$, Fe, and heavy metals. The attenuation mechanism of each component was assessed using the chemical analysis. Cl-normalizing process, WATEQ4F simulation, and preceding flownet analysis. Based on the calculation of Contamination Factor, K, Na, Ca, Mg, B, Zn, HC $O_3$, Cl, F, Br and TOC are effective contamination indicators in the Nanjido landfill site, and K, Na, Ca, Mg, B, S $O_4$, HC $O_3$, Cl, F, Br and TOC in the Habsburg landfill site Particularly, TOC is the best contamination indicator in landfill sites influenced by sea water.

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Geochemical baseline mapping for geochemical hazard assessment (지구화학적 재해 평가를 위한 지화학도 작성 및 기준치 설정)

  • 신성천;염승준;황상기
    • The Journal of Engineering Geology
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    • v.10 no.2
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    • pp.215-233
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    • 2000
  • The national geochemical baseline mapping project has been conducted since 1996 to establish a quantitative assessment system for geochemical hazards in natural environments. The geochemical image maps have been edited for thirty-six elements(i.e., 10 major oxides and 26 trace elements) in light sediments, finer fraction than 150 $\mu$m, collected from first- to second-order streams(totally 11,000) over five provinces in the western half(ca. 45,000 km$^2$) of Korea. Natural background values of the elements were given for different geological environments. Based on the statistics, geochemical baselines were newly obtained for a quantitative hazard assessment on toxicity of heavy metals and deficiency of essential nutrients. Some chosen examples of geochemical hazards are presented based on new geochemical image maps and related baseline data.

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Study of the Improvement of Hazardous Chemical Management for Chemical Accident Prevention (화학사고 예방을 위한 유해화학물질 관리 개선 연구)

  • Lee, Deok-Jae;Lee, Tae-Hyung;Shin, Chang-Hyun
    • Fire Science and Engineering
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    • v.31 no.1
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    • pp.74-80
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    • 2017
  • Chemicals are convenient for humans but the damage caused by hazardous chemicals can be widespread if they are not managed properly. The Chemical Substance Management Act strengthened the management of hazardous chemicals and the management of handling facilities. On the other hand, an analysis of chemical accidents occurring in the past 4 years showed that chemical accidents occurring at the handling facilities are increasing, and additional preventive measures are needed. In this study, to prevent chemical accidents of hazardous chemicals, the causes and problems of accidents were analyzed through the case study of chemical accidents and measures for improvement are proposed.

The Characteristics of Organic Matter in the Quaternary Sediments from ODP Leg 127 Site 794A, East Sea (동해 ODP Leg 127 Site 794A에서 채취한 제4기 퇴적물의 유기지화학적 특성 연구)

  • Lee Sang Il;Lee Young-Joo;Kim Ji Hoon;Oh Jae Ho;Yun HyeSu
    • Economic and Environmental Geology
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    • v.38 no.6 s.175
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    • pp.707-716
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    • 2005
  • Organic geochemical analyses including Rock-Eval pyrolysis, elemental analysis and stable carbon isotope analysis were performed to evaluate the characteristics of organic matter in the ODP Leg 127 Site 794A sediments and to understand paleoceanographic changes. Based on the TOC contents, C/N ratio, HI vs. OI, $\delta^{13}C_{org}$ and C/S ratio, results imply that dark layers containing a large amount of terrigenous organic matter were deposited under the suboxic/anoxic conditions, whereas the light layers containing largely marine organic matter were deposited under the oxic conditions. These results indicate that increasing surface-productivity by the input of a large amount of terrigenous organic matter from adjacent continent led to the deposition of dark layers during the interglacial highstands, whereas marine primary production and dilution caused by Kosa from the China desert area led to the deposition of light layers with the decreased to terrigenous organic matter during the glacial lowstands.

Geophysical and Geochemical Studies for the Saline Water Intrusion under the Paddy Field in Kyoung-gi area, Korea (경기 지역 농경지 하부로의 해수 침투에 관한 지구물리 및 지구화학적 연구)

  • Lee Sang-Ho;Kim Kyoung-Woong;Lee Sang-Kyu
    • Geophysics and Geophysical Exploration
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    • v.2 no.2
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    • pp.96-103
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    • 1999
  • Most of saline water inousions have been diagnosed by geophysical or geochemical approach independently. The objective of this study is to provide the effective method to detect the saline water intrusion on the ground water in the vicinity of seashore using these two methods. Schulumberger sounding, frequency domain electromagnetic sounding and geochemical analysis of ground water were carried out to explore saline water intrusion. Schulumberger sounding was implemented in dry surface condition before irrigation water was introduced into the field, while electromagnetic sounding was carried out in wet ground condition after the irrigation. The purpose of duplicated measurements on the equivalent spot at different times was to investigate the variation of anomaly zone depending on the amount of ground water. It was possible to discriminate the anomalous zone due to high water saturation from the low electric resistivity zone by high salt concentrations through this way. For the verification of the geophysical result, the ground water samples in the study area were collected and analysed at the 23 points near the measuring spots. The groundwater at the spot nearest to the sea water intrusion identified by geophysical method indicates higher salinity than the standard limit concentration for agricultural irrigation water (250 mg/1). Isotope analysis of $D({^2}H)$ vs. is ${^18}O$ and PCA analysis were used to discriminate the anthropogenic pollution from those of high salinity from sea water intrusion.

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A Design of Chemical Analysis for the CD-R Recording Layer's Nano-structure and Composition Analysis (CD-R 기록층의 나노구조 및 성분 분석을 위한 화학분석 설계 사례)

  • Cho, Namjun
    • The Journal of Korean Institute for Practical Engineering Education
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    • v.4 no.2
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    • pp.84-90
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    • 2012
  • It is described that the total analysis of CD-R, a digital recording media, including the planning and performing chemical analysis of cross sectional structure of recording layer, dye composition and chemical structure as an example of design for chemical analysis. Since chemical analysis of unknown sample is often involved the complicated process requiring many experiences and knowledge, students feel difficulties in planning the procedure of chemical analysis and selecting analytical methods. Thus, an example of chemical analysis is provided here to help student understanding the hole procedure of CD-R analysis. In this study, SEM is used to determine the cross sectional structure of PC substrate and recoding layer of CD-R. The dyes in recording layer is dissolved with solvent and separated with using TLC, analyzed with using UV-Vis absorption spectrometer. Then, the chemical structure of each component is determined with using GC-MS, NMR and mass spectrometer.

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Analysis of Chemical Accident-Causing Substances Using a Proton Transfer Reaction-Time of Flight Mass Spectrometer (양자전이 비행시간 질량분석기를 이용한 화학사고 원인물질 분석)

  • Kim, So-Young
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.80-86
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    • 2019
  • In Korea, a total of 556 chemical accidents occurred from 2012 to 2018 caused by adverse reactions of two or more chemicals, which required significant amounts of time to identify the causative chemicals. Rapid analysis is required for effective incident response and probing. In this study, a quantum transition time-of-flight mass spectrometer was used to identify the causative agents of chemical accidents caused by adverse reactions. The analyzer enabled fast real-time analysis without the need for sample collection and pretreatment. Quantitative and qualitative analysis of most volatile organic compounds with high hydrogen affinity was performed to investigate the cause of the chemical accidents. In fact, in the month of 201◯, methanol and toluene were detected as causative agents of the accident using a quantum transition time mass spectrometer, and were also the cause of the reported odor.