• Korean Journal of Materials Research
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• v.8 no.7
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• pp.621-627
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• 1998

The formation of Co-silicide between Co/Zr bilayer on the amorphous and crystalline Si substrates has been investigated. The films of Zr(50$\AA$) and Co(l50$\AA$) were deposited with e-beam evaporation system and were heattreated with the rapid thermal annealing system at the temperatures between 50$0^{\circ}C$ and 80$0^{\circ}C$ with 10$0^{\circ}C$ increments for 30 seconds. The phase identification of Co-silicide was carried out by XRD and the chemical analysis was examined by AES and RBS. The interface morphologies of Co/Zr bilayer films were investigated by cross sectional TEM and HRTEM. $CoSi_2$ was formed epitaxially on the crystalline Si substrate above $700^{\circ}C$ while polycrystalline $CoSi_2$ was grown on the amorphous Si substrate. The formation temperature of Co-silicide on the amorphous Si substrate was about 100 C lower than that on the crystalline Si. The COzSi phase was not identified on the both Si substrates. The formation temperature of first phase of Co-silicide on ColZr bilayer was higher than that on Co mono layer. CoSizlayer formed on the amorphous Si substrate exhibits better uniformity compared to the CoSiz formed on the crystalline substrate. The sheet resistance of CoSiz layer on crystalline Si was lower than that on the amorphous Si at high temperatures.tures.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.2
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• pp.183-202
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• 2019

For design and performance assessment of a high-level radioactive waste (HLW) disposal system, it is necessary to understand the characteristics of coupled thermo-hydro-mechanical (THM) behavior. However, in previous studies for the Korean Reference HLW Disposal System (KRS), thermal analysis was performed to determine the spacing of disposal tunnels and interval of disposition holes without consideration of the coupled THM behavior. Therefore, in this study, TOUGH2-MP/FLAC3D is used to conduct THM modeling for performance assessment of the Korean Reference HLW Disposal System (KRS). The peak temperature remains below the temperature limit of $100^{\circ}C$ for the whole period. A rapid rise of temperature caused by decay heat occurs in the early years, and then temperature begins to decrease as decay heat from the waste decreases. The peak temperature at the bentonite buffer is around $96.2^{\circ}C$ after about 3 years, and peak temperature at the rockmass is $68.2^{\circ}C$ after about 17 years. Saturation of the bentonite block near the canister decreases in the early stage, because water evaporation occurs owing to temperature increase. Then, saturation of the bentonite buffer and backfill increases because of water intake from the rockmass, and bentonite buffer and backfill are fully saturated after about 266 years. The stress is calculated to investigate the effect of thermal stress and swelling pressure on the mechanical behavior of the rockmass. The calculated stress is compared to a spalling criterion and the Mohr-Coulumb criterion for investigation of potential failure. The stress at the rockmass remains below the spalling strength and Mohr-Coulumb criterion for the whole period. The methodology of using the TOUGH2-MP/FLAC3D simulator can be applied to predict the long-term behavior of the KRS under various conditions; these methods will be useful for the design and performance assessment of alternative concepts such as multi-layer and multi-canister concepts for geological spent fuel repositories.

• Journal of The Korean Society of Grassland and Forage Science
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• v.36 no.4
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• pp.393-401
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• 2016

Anaerobic digestion is a collection of naturally occurring processes that convert organic matter and liquid residue, so-called digestate. The use of digestate biofertilizers is one of the important components of integrated nutrient management, as they are renewable sources of plant nutrients for sustainable agriculture. Seeds of Italian ryegrass (Lolium multiflorum L.) were germinated in different concentration of Chlorella in order to investigate it's the effect of Chlorella on growth parameters, seed germination and early growth. The experiment using plug tray was conducted at the green house placed in the Sangji University. The experiment consisted of nine treatments including different concentrations of Chlorella sp. culture solution and non-treated control. The germination percentage at the treatment with 25% Chlorella sp. culture solution was greater than that of control. The 50% concentration of Chlorella sp. culture solution was found to promote a better seedling growth in terms of shoot length, fresh weight and dry weight compared to the anaerobic digestate. Results showed that the best concentration of Chlorella culture solution was achieved by the 50% concentration of Chlorella culture solution treatment. As a conclusion, the application of Chlorella culture solution was found to be able to promote the germination and shoots growth of Italian ryegrass.

• Journal of Wetlands Research
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• v.18 no.4
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• pp.481-487
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• 2016

In this research, a pilot scale hybrid rain garden system was developed in order to investigate the efficiency in the different components of the hybrid rain garden system and at the same time evaluate the initial efficiency of the system in treating urban stormwater runoff prior to its actual use in the field. Experimental runs were conducted using synthetic runoff having target concentrations similar to that of the typical runoff characteristics found in different countries and in Korea. With the employment of the hybrid rain garden system, hydrologic improvement was observed as the system demonstrates an approximately 95% reduction in the influent runoff volume with 80% retained in the system, and 15% recharged to groundwater. The reduction was contributed by the retention capabilities of ST and infiltration capabilities in PB and IT. With the combined mechanisms such as filtration-infiltration, biological uptake from plants and soil and phytoremediation that are incorporated in PB and IT, the system effectively reduces the amount of pollutant concentration wherein the initial mean removal efficiency for TSS is 87%, while an approximate mean removal efficiency of 76%, 46% and 56% was observed in terms of organics, nutrients and heavy metal, respectively. With these findings, the research helps in the further improvement, innovation and optimization of rain garden systems and other facilities as well.

• Journal of the Korean GEO-environmental Society
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• v.1 no.1
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• pp.79-85
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• 2000

The environmental assessment on the open dumping landfill of small scale which was situated in local small city was carried out to reuse the landfill site as the residental, commercial and other purposes through the analysis of the leachate of landfill, extracted solution from landfill waste. The waste was landfilled at 5.5~8m depth and the covered layer so poor as 20~50cm thickness. The biodegradable organic matters were almost degraded and the result of the leachate of landfill showed that the BOD/COD ratio were measured as 0.079, pH 7.2~7.6, SS 47736mg/L, COD 6193.8mg/L, T-N 596mg/L, and T-P 123.9mg/L respectively. These results were higher than those of extracted solution of landfill waste as the COD and BOD were measured as low values and T-N 7.77mg/L and T-P as 0.20mg/L lower concentrations the landfill appears the maturation phase. As the result of the assessment on the open dumping landfill of small scale, if appears that this landfill is maturation phase and the formation leachate is reduced. If the treatment facility of leachate from landfill and the layer which protects the inflow/infiltration is prepared, it can be safely used as this landfill site.

• Journal of the Korean GEO-environmental Society
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• v.9 no.6
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• pp.21-29
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• 2008

As household and industrial wastes continue to rapidly increase every year, the demands for landfill sites are also increasing. However, the construction of landfill sites causes many problems due to the high costs of liners, while the leachate from the landfills generates secondary contamination of surrounding lands and groundwater. The purpose of this study is to determine the proper mixing ratio to meet the liner conditions (must be less than $1{\times}10^{-7}cm/sec$), using the local soil as the main material and using fly ash, bentonite, and cement as the mixing materials. The possibility of using this mixture as the liner for landfill sites was examined. To determine the proper mixing ratio, this study conducted basic physical properties tests, compaction tests, consolidation tests, and uniaxial compression tests. It was found that the higher the ratio of bentonite, the lower the coefficient of permeability, and the higher the ratio of fly ash, the higher the coefficient of permeability. The reason for this is that, while bentonite expands and fills pores, fly ash cannot fill the pores because the particles have a round shape and do not have adhesion. In conclusion, the optimum coefficient of permeability that meets the landfill liner condition was obtained when the ratio of bentonite was 15% or higher. If fly ash was mixed, the landfill liner condition was met when the ratio of bentonite was 15% or higher and the ratio of fly ash was 20% or lower.

• The Journal of Engineering Geology
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• v.30 no.3
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• pp.289-302
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• 2020

To determine the shallow subsurface structure and sliding surface of land creeping in 2016 at Hadong-gun, Gyeongsangnam-do, geophysical surveys (electric resistivity, and refraction seismic methods, borehole televiewer) and slope stability analysis were conducted. The subsurface structure delineated with borehole lithologies and seismic velocity structures provided the information that the sediment layer on the top of the slope was rather as thick as 20 m and the underlying weathered rock (anorthosite) was thinner than 1 m. Based on the tension cracks observed during the geological mapping, televiewer scanning was performed at the borehole BH-2 and detected the intensive fracture zones at the ground-water level, associated with the slip weak zones mapped in dipole-dipole electrical resistivity section. Downslope sliding and slightly upward pushing at the apex of high resistive bedrock explains the curved slip plane of the land creeping. Such a convex structure might play a role of natural toe abutment for preventing the downward development of slip weak zones. In slope stability analysis, the safety factors of the slip weak zone are calculated with varying the groundwater levels for dry and rainy seasons and the downslope is founded to be unstable with safety factor of 0.89 due to fully saturated material in rainy season.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.3
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• pp.249-256
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• 2005

Thermal decomposition and stabilization characteristics of the solid cake after the dissolution of nitrate of the lagoon sludge was investigated. Most of the nitrates were dissolved in the water and removed to the filtrate, but small amount of nitrates, calcium carbonate and uranium were remained in the solid cake. The solid cake was thermally decomposed in the muffle furnace at $900^{\circ}C$ for 5 hours. Uranium, which is in the lagoon 1, was stabilized with $NaNO_3$ decomposition to $Na_{2}O{\cdot}2UO_3$ form. For the lagoon 2, it is confirmed that CaO, which was created by thermal decomposition of the $Ca(NO_3)_2$ and $CaCO_3$, was transferred to $Ca(OH)_2$ in the air with water. Because it is known that $Ca(OH)_2$ is stable material, further additives did not need to the stabilization of the thermal decomposition of the lagoons.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.21-34
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• 1997

Retention ponds have been dug along some of the motorways in France to minimize environmental pollution by preventing pollutants from spreading over the surrounding area. A series of studies have been conducted to determine the physicochemical characteristics of the particles settling down in such a pond to evaluate the effectiveness of the pond as a trap for heavy metals such as Pb, Zn and Cd. The highly contaminated roadside soil and the uncontaminated background soil were also studied for comparison. The settling particles exhibited heavy metal concentrations of 2 to 8 times as much as the background Sologne soil, depending on the metal species. However, the heavy metal concentrations in the roadside soil were 7 to 26 times higher than those in the· settling particles. Sequential extraction experiments illustrated that the highly contaminated roadside soil consisted mainly of the readily soluble fractions (FII, FIII and FIV) for all three heavy metals, but little W which is hardly soluble. The proportion of W considerably increased up to one third of the total in the settling particles for Pb and Zn. This result as well as the large concentration differences between the roadside soil and the settling particles indicates that most of the heavy metals were lost to the surroundings even before reaching the retention pond. Cd exhibited somewhat different behavior in that the most soluble FI, which is negligible for Pb and Zn, occupied as much as one fourth of the total in the roadside soil. In addition, FV for Cd did not increase in the settling particles.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.35-44
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• 1997

A column study using artificial acid rain was conducted to evaluate the buffering capacities in soil layer and host rock. In an effort to compare the effect of composition of host root two valleys of which compositions of host rock are different were chosen within the study area and the pHs of the water flowing in the valleys were measured from May, 1996 to October, 1996. The pHs of the artificial acid rain prepared by adding appropriate amounts of both sulfuric and nitric acids to distilled water were 3, 4, and 5, and the column effluents were analyzed for major cations and anions. The cation exchange capacities(CECs) of A Horizon and the B Horizon were 9.68 and 6.16 meq/100g, respectively, Compared to the B Horizon, the pH in the column effluent of A Horizon with larger CEC was higher. The sums of $Ca^{2+}$, $Mg^{2+}$, $Na^{+}$in the column effluents gradually decreased, indicating the loss of CEC by acid rain. The field study showed that pHs of the surface water in the valleys increased as the water flows downwards. The magnitude of this buffering capacity was greater for the valley in which smectite in addition to kaolinite and illite was a weathered product of host rocks. This also indicates that host rock as well as soil layer retains the buffering capacity.