• Proceedings of the Mineralogical Society of Korea Conference
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• 2001.06a
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• pp.58-59
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• 2001

부산에서 북동쪽으로 대략 25km 떨어진 지점에 위치하고 있는 일광광산 부근의 지질은 백악기 화산암ㆍ퇴적암 그리고 이를 관입한 화강암류와 이 암주 내에 발달하는 구리-중석을 함유하고 있는 각력파이프광상으로 이루어져 있다. 일광광산의 화강암류는 거의 타원형으로 felsic한 중앙부와 mafic한 양상의 주변부로 나뉘어지며, 암주 내에 수직적인 원통형의 각력파이프가 광화대를 이루고 있고, 그 주변에는 모암변질대가 발달되어 있다. 각력파이프를 충진하고 있는 vein과 화강암의 중앙부에는 전기석이 풍부하게 산출되고 있다. 일광광산에서 산출되는 전기석은 야외 관찰시 각력파이프 중심에서부터 외곽부쪽으로 전기석의 풍부함이 감소하며 산출형태도 달라진다. 파이프에서 대략반경 150m내에서 전기석은 침상형 의 방사상 모양 내지 rosettes형으로 풍부하게 산출되며, 화강암내의 mafic한 암편을 치환한 형태로 산출되기도 한다. 암주의 중앙부 주변부에서는 거의 미세한 구상형으로 산재되어 나타나고 있다. 전기석은 복잡한 화학식 {(Na, Ca)(Fe, Mg)$_3$(Al, Li)$_{6}$(BO$_3$)$_3$Si$_{6}$O$_{18}$ (OH, F)$_4$}을 갖는 붕산 규산염광물이다. 이러 한 다양한 성분은 마그마의 진화과정, 모암의 특성, 온도, 압력, 성분과 같은 물리ㆍ화학적 성질에 따라 전기석의 성분이 체계적으로 변하기 때문에 모암과 전기석 기원과의 상관관계를 파악할 수 있다. 파이프 부근의 화강암류는 현미 경상에서 전기석이 석류석과 같이 풍부하게 나타나며 장석들은 변질받은 상태로 세리사이트, 녹렴석으로 나타나고, 흑운모와 각섬석은 녹니석화되어 변질된 상태를 보이고 있다. 파이프 중심에서 외곽부로 갈수록 전기석의 함량은 줄어들고 있고 장석들이 알바이트ㆍ칼스베드 쌍정을 보이며, 흑운모가 각섬석보다는 우세하게 나타나고 있다. 전기석은 주상 결정, 자형 내지 반자형의 입자로 다색성을 보이며, 결정 중심에서 가장자리로 갈수록 파란색과 황갈색의 광학적 누대구조를 관찰할 수 있다. 일광광산에서 산출되는 전기석에 대한 현미경 관찰은 열수기원임을 지시하고 있다. 야외조사와 현미경 관찰의 예비조사에 의하면 일광광산의 전기석이 형성된 환경은 다른2가지 화학적인 저장소의 혼합 효과의 결과로 생성되어진 것으로 예상된다. 일광의 화강암류를 만든 마그마는 전기석을 형성할 만큼의 Fe-Mg성분이 충분하지 않았을 것이다. 화강암 내에 흑운모와 각섬석의 결정작용에 의해 마그마의 Fe-Mg성분이 고갈되어지고 이로 인해 그 함량이 감소하며 상대적으로 마그마 내에 남은 붕소(B$_2$O$_3$)는 열수로 용리되고 흑운모, 각섬석과 평형을 유지하며 열수에 남아있게 된다. 잔류용융체에 남은 붕소의 함량은 전기석을 만들기에 충분함에도 불구하고, Fe-Mg 함량이 부족하여 마그마 기원의 전기석 결정을 만들 수가 없다가 광맥이 형성된 시기에 또 다른 열수가 공급되면서 이전의 평형이 깨지고 기존의 흑운모와 같은 염기성 광물이 붕소(B)를 함유한 새로운 열수와 반응하여 전기석을 형성한 것으로 예상한다. 앞으로 전암과 광물에 대해 지화학적 연구를 통해 화강암류와 전기석과의 지화학적 연관성, 주성분 원소와 열수의 특성과의 상관관계, 전기석의 기원(마그마 기원인지 열수기원인지)이 보다 정확하게 파악될 것이다. 마그마 진화에 따른 전기석의 성분변화와 기원을 이용하여 일광광산의 동광화대를 형성한 마그마 계에서 열수계로 이어지는 지질학적 과정을 이해할 수 있을 것이며, 암석 성인론적 지시자로서 어떠한 중요성을 갖는지 논의되어질 수 있다.

• The Journal of Engineering Geology
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• v.8 no.2
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• pp.131-143
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• 1998

The study area, Beulgok-myon Nonsan-goon Chungcheongnan-do is consist of Changri slate(Och, okcheon system), lithic tuff(Kslt, kyoungsang system), granite (Kqb, kyoungsang system) and quartz porphyry(Kgf, kyoungsang system). More than 3000 joints were measured and classified by direction. Main dipdirection/dips of Kqb are 228~257/73~88, 010~150/70~85, Och are 134~164/40~90, 214~249/55~89, Kslt are 291~332/75~82, 235~241/73~71. But Kgf are not appeared distinct directions of joint. In field, p-wave velocities(Vp) are measured on the bed rock. Vp of Kgf are $5000m(240^{\circ})~2380(360^{\circ})m/s$, Kqb are $3846(210^{\circ})~1408(150^{\circ})m/s$, Kslt are $5000(360^{\circ})~2323(150^{\circ})m/s$ and Och are $6657(180^{\circ})~2000(030^{\circ})m/s$. Also P-wave velocities on specimen are measured. It is slightely higher than it's measured on the bed rock. For engineering properties of rock, we measured Poisson's ratio, rigidity, Young's modulus and bulk modulus by dynamic method.

• Korean Journal of Food Science and Technology
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• v.23 no.3
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• pp.341-348
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• 1991

Physicochemical properties and gelatinization patterns of defatted and lipid-reintroduced moist (Hwangmi) and dry (Suwon 147) type sweet potato starches were investigated. Starch granules of sweet potato were polygonal and round, and the sizes of starch granules ranged $5{\sim}13\;{\mu}m$. All starches showed Ca type in X-ray diffraction but relative crystallinity was decreased by defatting and reintroduction. The amylose content of defatted starches increased, but that of lipid-reintroduced starches decreased. The swelling power and solubility at each temperature increased by defatting, but decreased by reintroduction. Transmittance of Hwangmi and Suwon 147 showed a rapid increase at $60,\;65^{\circ}C$, respectively. The initial pasting temperature by amylograph of Hwangmi and Suwon 147 were $67.5^{\circ}C\;and\;72.7^{\circ}C$, respectively. The peak viscosity and the height at $50^{\circ}C$ on amylogram of Hwangmi were lower than those of Suwon 147. Hot paste viscosity and setback decreased by defatting but setbak and consistency drastically increased by reintroduction. The peak temperature for gelatinization by the DSC was $65.7^{\circ}C$ for Hwangmi and $68.5^{\circ}C$ for Suwon 147. The gelatinization temperature and enthalpy of the DSC decreased and amylose-lipid melting peak was lost by defatting. The gelatinization temperature and enthalpy decreased by reintroduction.

• Economic and Environmental Geology
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• v.48 no.4
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• pp.351-360
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• 2015

Hamangun Dohangri $6^{th}$ tumulus was characterized by using geological, geophysical, and geotechnical surveys in terms of the shape of the tombs, origin and geotechnical properties of tomb materials, safety of grave mound and burial chamber. The bedrock (Haman Formation sedimentary rock) forming the ground of the tomb, is weathered such that men can excavate the ground. The mound tomb is classified into soil part and rock part by low resistivity and high resistivity, respectively, through electrical resistivity survey. The burial chamber is mostly made by Haman Formation while some part is composed of granitic rock that is distributed in the most southern district of the study area. According to soil tests, the soil part of mound tomb shows low water content, low pore ratio, and proper unit weight that indicate highly compacted material. Additionally, the mound tomb is safe because the strength of the rock part of the mound tomb exceeds that of general rock.

• The Journal of Engineering Geology
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• v.27 no.3
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• pp.267-274
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• 2017

Behavior of rock mass depend on the mechanical properties of intact rock and geometrical property of discontinuity distributed in rock mass. In case of rock slope, particularly, location of slope failure surface and behavior after failure are changed due to discontinuities. In this study, two 3D slope stability analysis methods were developed for two different failure types which are circular failure and planar failure, considering that failure type of rock slope is dependent on scale of discontinuity which was then applied to real rock slope to review the applicability. In case of circular failure, stable condition was maintained in natural dry condition, which however became unstable when the moisture content of the surface was increased by rainfall. In case of planar failure, rock slope become more unstable comparing to dry condition which is attributable to decrease in friction angle of discontinuity surface due to rainfall. Viewing analysis result above, analysis method proved to have well incorporated the phenomenon occurred on real slope from the analysis result, demonstrating its applicability to reviewing the slope stability as well as to maintaining the slope.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.1
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• pp.97-103
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• 1993

This paper presents a quasi-analytical method using integral equations to obtain head distributions in unsaturated porous media with different hydrogeologic properties. One-dimensional soultion algorithms were developed for two cases of boundary conditions at the top: 1) constant head and 2) constant flux. Water table elevation at the bottom was assumed known for both cases. The methodology was applied to a fly ash disposal facility in an alluvium area. The results showed that the pressure head distributions had high nonlinearity with large gradients slightly above the interface of two media which made preliminary numerical solutions implausible. The developed method helped to structure finite element grids for improving convergence and accuracy.

• The Journal of Engineering Geology
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• v.21 no.3
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• pp.239-246
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• 2011

Upon encountering weathering soil at a construction site, it may be necessary to change the design and construction plans for geotechnical structures. When weathering soil is exposed to air, the weathering process proceeds rapidly, resulting in significant damage to geotechnical structures, particle defects, and an increase in moisture sensitivity. The management of weathering-soil compaction is challenging. Because the engineering properties of weathering-soils vary regionally, it is important to report the result of research into the regional characteristics of such soils. At two locations of granite gneiss in the Gansung area of Gangwon-do, geological studies were performed at 22 and 8 sites, respectively. At each site, test samples were collected for analysis by XRD and to measure particle size, consistency, and compaction. To evaluate the suitability of the material for road subgrade, we examined the interrelationship between CBR value and the uniformity coefficient, the 200 sieve passing ratio and the aggregate ${\geq}$ 2 mm) content. We found that for the weathered granite soil, aggregate sized > 2 mm has a significant effect on the CBR value. In addition, the mixing of aggregate sized > 2 mm with sub-quality soil improves the soil condition.

• Economic and Environmental Geology
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• v.19 no.4
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• pp.265-276
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• 1986

The Jangseong manganese deposits are supergene oxidation products of hydrothermal rhodochrosite. The manganese ore veins are developed in the Dongjeom Quartzite, and Dumudong Formation. The deposits consist of primary manganese carbonate ores in the deeper part and manganese oxide ores near the surface. The manganese carbonate ores are composed of rhodochrosite and small amounts of sulfides. The manganese oxide ores are composed of birnessite, nsutite, todorokite, chalcophanite, and pyrolusite. Microscopic, X-ray diffraction, infrared, thermal and EPMA analyses have been made for manganese oxide minerals and other associated minerals. The manganese minerals were formed in the following sequence. Rhodochrosite$\rightarrow$birnessite$\rightarrow$todorokite$\rightarrow$nsutite-pyrolusite. Thermochemical properties of chalcophanite were studied by methods of X-ray powder diffraction, infrared absorption spectroscopic analysis and dehydration experiments. Chalcophanite changes to $4.8{\AA}$ phase at $90{\sim}110^{\circ}C$. Chemical analyses show that the manganese oxide minerals generally have high concentration in Zn.

• Economic and Environmental Geology
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• v.43 no.1
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• pp.43-52
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• 2010

The geochemical and nitrogen isotopic analyses for shallow groundwater of Ogcheon area were carried out to characterize the geochemical characteristics of the groundwater and to identify the source of nitrate. Groundwater shows a neutral pH to weakly alkalic condition with pH values ranging from 6.9 to 8.4. The average of EC, Eh and DO is $344.2\;{\mu}s/cm$, 195 mV, 4 mg/L, respectively. According to piper diagram, chemical composition of groundwater is dominantly characterized by Ca-$HCO_3$ type. On the other hand, groundwater type in the study area include Ca-Cl+$NO_3$ type that were highly influenced by agricultural activities. $NO_3$-N concentration of the collected samples(n=45) range from 12.4 to 34.2 mg/l. These data show that the $NO_3$-N concentration exceeds Korea Drinking Water Standard (10 mg/l). The $\delta^{15}N-NO_3$ values range from $2.7^{\circ}/_{\circ\circ}$ to $18.8^{\circ}/_{\circ\circ}$. The enrichments of heavy isotope in the groundwater indicate that major origin of nitrate pollution were associated with animal and human waste. Also the denitrification may have partly contributed as one of the sources of nitrogen.

• Economic and Environmental Geology
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• v.11 no.3
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• pp.89-98
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• 1978

Mineralogy, beneficiation, and processes of titanium ores are reviewed from petrographic viewpoints. The most important titanium minerals are ilmenite ($FeTiO_3$) and rutile ($TiO_2$). Ilmenite will play major role :for raw material, because rutile are rapidly diminishing. Thus, there is a need to develope a successful process for producing high grade Ti02 from ilmenite. Commercial, as well as R and D processes to treat more abundant ilmenite ores fall in three general classess: 1. Iron in ilmenite is partially or completely reduced and separated either physically or chemically. 2. Iron is reduced to ferrous state and chemically leached away from the titanium. 3. Ore is treated to make chlorides either selectively or with subsequent separation and purification of $TiC_4$. Routes and efficiencies of these process technologies are primarily influenced by the particular ore deposit to be mined and secondly by environmental considerations. One deposit parameters which influence ilmenite process technologies are: 1. Complexity of microtextures of ilmenite intergrown with Fe-oxide minerals. 2. Composition of concentrates; ilmenites contain minor amounts of substituted Mg, Mn, and V. These elements plus iron and gangue minerals can cause difficulties to complete reactions, substantial acid consumption, difficulties of removing waste solids, and waste disposal problems. Major contributions to be made by petrologists for process optimization are: characterization and interpretation of compositional and physical changes of raw materials and solids derived from process streams. These informations can play significant role in selecting and improving process steps for titania production.