• Journal of the Korean Ceramic Society
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• v.12 no.3
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• pp.18-23
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• 1975

본 연구는 다결정질 바리움 페라이트의 고상간의 반응에 있어서 입자성장기구의 규명 및 기타 유용한 자료를 얻고저 수행되었으며 아울러 첨가물의 첨가효과도 관찰하였다. 실험은 115$0^{\circ}C$부터 130$0^{\circ}C$까지 25도의 간격으로 행해졌으며 입자성장현상은 전자현미경으로 관찰되었다. 실험결과, 115$0^{\circ}C$부터 120$0^{\circ}C$까지는 식 D2-D20=Kt(D: 반응이 진행된 ttlrksgn의 입자경, D0: t=0때의 입자경, K: 반응속도)로 표현되었으며 비교적 고온에서는 증발-응축기구가 관여됨을 관찰하였다. 한편 실험적으로 구한 활성에너지는 130$\pm$20 Kcal/mole이었으며 소량의 첨가물 SiO2는 반응속도를 저하시키나 활성화 에너지에 대해서는 큰 영향을 미치지 못하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.5
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• pp.718-724
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• 2000

A model for depicting the rocket engine combustion process is presented and several experiments near a design point are provided with a FOOF type of unlike impinging injector for a propellant combination of Jet A-1 fuel and liquid-oxygen. The model is based on the assumption that the vaporization is the rate-controlling combustion process. The effects of initial drop size and initial drop velocity are systematically shown and discussed. It is seen that in the midst of considered parameters the change of initial drop size is more sensitive to the performance. The proposed model describes qualitative trends of combustion process well despite of its simplicity.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.472-475
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• 2010

Theoretical consideration on the combustion behavior of nano-aluminum and water mixture was conducted. The regions are divided into; 1)water+aluminum 2)steam+aluminum 3)reaction zone. Latent heat of vaporization was considered as a function of pressure in case of phase change of water. Also, pressure exponent was studied of various sized nano particles within the range of 0.1MPa ~ 10MPa.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1999.04a
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• pp.8-8
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• 1999

2-유체 인젝터의 분무연소에 대한 통찰 및 구조에 대한 이해와 연료-공기 혼합과 연소반응의 물리적 이해에 필요한 수치적 모델의 개발 및 검증을 위해서는 2유체 시스템에서 액체 및 기체 각각의 기본적 특성인 액적크기, 액적속도, 액적의 질량플럭스(flux), 가스상의 속도측정 등이 필요하다. 특히, 액체분무에서는 액적의 크기를 예측하는 것이 매우 중요한 과제이며, 액적의 크기에 영향을 주는 인자들로는 노즐의 형태, 분사액체의 물성치(점도, 표면장력, 밀도), 주위기체의 조건(온도, 압력, 응축과 증발현상), 분사압력 등이 있다. 그러나, 실제 분무액적의 크기는 분포를 가지므로 같은 SMD를 가지더라도 그 분포의 정도는 크게 다를 수 있어 결과적으로 분무액적의 크기를 평균값만으로 표현하는 것은 불충분할 뿐만 아니라 그 적용에도 한계를 가지게 된다. 따라서 분무액적의 평균크기와 함께 그 분포의 정도 등을 함께 나타내려는 시도가 많은 과학자들에 의하여 연구되었다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.6
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• pp.519-526
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• 2015

To measure the physical parameters of the simple microlayer model for the prediction of the heat flux and heat transfer rate due to the evaporation of the microlayer during nucleate boiling, the microlayer geometry was experimentally examined. The parameters, including initial thickness, moving velocity and microlayer radius, were measured by total reflection and interferometry techniques using a laser. Single-bubble nucleate boiling experiments were conducted using saturated water on a horizontal surface under atmospheric pressure. The geometric characteristics of the microlayer underneath the bubbles periodically nucleating at a nucleation site at an average heat flux of $200kW/m^2$ were analyzed. The experimental results in the present study show that the maximum initial thickness of the microlayer and the horizontal moving velocity are $5.4{\mu}m$ and 0.12 m/s, respectively.

• Journal of Navigation and Port Research
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• v.26 no.1
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• pp.120-126
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• 2002

ZnS thin films were prepared on glass substrate at various deposition conditions by a HW apparatus and were systematically investigated the growth characteristics, in terms of deposition edges by a double beam spectro- photometer, and structural analysis by a x-ray diffraction rates were increased with incresing the cell temperature and vapor pressure of sulfur, but were decreased with increasing substrate temperature. The optical characteristics of thin films depends on the deposition rates. The band gap energies of 3.46∼3.52eV measured at room temperature are smaller than the theoretical value of 3.54eV, indicating that impurities exist in the crystal. All ZnS thin films are oriented in the (III) principal direction of a zincblende structure. By introducing the S vapor, optical and crystalline properties have been improved.

• Membrane Journal
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• v.6 no.1
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• pp.22-31
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• 1996

Pervaporation experiments of isopropanol-water mixtures through a polydimethytsiloxane(PDMS) membrane were carried out at 35$^{\circ}$C and the effect of isopropanol concentration on the separation characteristics was investigated. The total permeation rate showed the largest deviation from the ideal permeation rate at the isoprpanol volume fraction from 0.5 to 0.7, which resulted from the interaction effect between permeants. The plasticizing effect of isopropanol enhanced the permeation of water, while the existance of water resulted in the depression of isopropanol permeation. Both the permeation rate and the selectivity were predicted using Flory-Huggins thermodynamics and modified Maxwell-Stefan equation. The concentration-dependent diffusion coefficients were expressed by Vignes equation. The Flory-Huggins interaction parameter between isopropanol and water was calculated using excess Gibbs energy correlation and the interaction parameters between liquid and polymer membrane were determined by equilibrium swelling experiments. The predicted permeation rates were in accord with the experimental ones within maximum error range of 35 %. The predicted permeation selectivities were in good agreement with the experimental values.

• KSBB Journal
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• v.8 no.3
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• pp.200-208
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• 1993

As a separation membrane for water-ethanol mixtures, alginic acid has been used which is hydrophilic polysaccharide and has excellent bonding capacity with divalent metal ions. Pervaporation characteristics of the alginic acid membrane were examined. The membrane was crosslinked with metal ions for the improvement of mechanical strength and chemical affinity. And its pervaporation characteristics were investigated. The first group(I A) metal complexed membrane cannot be used because of their brittleness and excessive swelling in low concentrations of ethanol solution. But the permeation characteristics of other metal complexed membrane were more improved than that of the alginic acid membrane because of their contraction of the membrane and hydrophilic property of metal ion.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.24-24
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• 2010

Chalcopyrite $Cu(In,Ga)Se_2$ (CIGS) 화합물 반도체는 고효율 박막태양전지의 광 흡수층으로 사용되는 물질 중 가장 우수한 효율 (19.9%, NREL 2008)을 보유하고 있다. CIGS는 직접천이형 에너지밴드갭 (direct bandgap)을 가지고 있고, 광흡수계수가 $1{\times}10^5\;cm^{-1}$로서 반도체 중 서 가장 흡수율이 높은 재료에 속하여 두께 $1{\sim}2\;{\mu}m$의 박막으로도 고효율의 태양전지 제조가 가능하고, 또한 장기적으로 전기광학적 안정성이 매우 우수한 특성을 지니고 있다. 현재 고효율 CIGS 셀생성을 위해 널리 사용되고 있는 CIGS 흡수층 성장공정은 "co-evaporation(동시증발법)"과 2-step 공정이라 불리는 "sputter-selenization(스퍼터-셀렌화)" 방법이다. 동시증발법은 개별원소 Cu, In, Ga, Se 들을 고진공 분위기에서 고온 ($550{\sim}600^{\circ}C$)기판위에 증착하는 방법으로 소면적에서 가장 좋은 효율(~20%)을 보이는 공정이다. 하지만, 고온, 고진공 공정조건과 대면적 증착시 온도 및 조성 불균일 등의 문제점 등으로 상용화에 어려움이 있다. 스퍼터-셀렌화 공정은 1단계에서 스퍼터링 방식으로 CuGaIn 전구체를 증착하고, 2단계에서 고온($550{\sim}600^{\circ}C$)하에 $H_2Se$ 혹은 Se vapor와 반응시켜 CIGS를 생성한다. 일본의 Showa Shell와 Honda Soltec 등에 의해 이미 상업화 되었듯이, 저비용 대면적으로 상업화 가능성이 높은 공정으로 평가되고 있다. 하지만, 2단계에서 사용되는 $H_2Se$ 및 Se vapor의 유독성, 기상 Se과 금속전구체 간의 느린 셀렌화 반응속도, 셀렌화반응 후 생성된 CIGS 박막 두께방향으로의 Ga 불균일분포, 생성된 CIGS/Mo 계면 접착력 저하등의 문제점들이 해결되어야만 상업화에 성공할 수 있을 것이다. 본 Tutorial에서는 CIGS 물질의 열역학 상평형과 반응메카니즘에 대해 설명하고, 다양한 생성 공정들을 소개할 것이다.

• International Journal of Highway Engineering
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• v.7 no.1 s.23
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• pp.31-38
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• 2005

Concrete has higher vapor pressure than its surrounding ambient air immediately after placement. Moisture at concrete surface evaporates to the ambient air to adjust equilibrium of the vapor pressure between them. The moisture inside the concrete moves to the surface because the evaporation at the surface causes gradient of vapor pressure inside the concrete. Plastic cracking, degree of hydration, strength development, and others caused by velocity of the moisture movement significantly influences quality of concrete. In this paper, the moisture diffusivity of early-age concrete was back-calculated using governing equation of the moisture diffusion, and temperature and relative humidity of concrete measured in a laboratory. The moisture diffusivity of the concrete was modeled using the back-calculated moisture diffusivity. The relative humidity of the concrete calculated by finite element method (FEM) using the modeled moisture diffusivity as Input data coincided with the measured relative humidity well.