• Applied Chemistry for Engineering
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• v.10 no.2
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• pp.237-241
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• 1999

Nickel was impregnated on the $SiO_2$ and $Al_2O_3$ supports and applied to the reduction reaction of CFC-113 ($CF_2Cl$-$CFCl_2$) with hydrogen to 3FCl ($CF_2$=CFCl, CFC-1113). The conversion was rapidly declined on the Ni/$SiO_2$(or $Al_2O_3$) and the deactivation accelerated as the increase of Ni content. However, the selectivity of 3FCl was maintained at around 80% level. The simultaneous coprecipitation of copper and lithium on Ni/$Al_2O_3$ improved both the conversion and selectivity to 3FCl, but an excessive amount of lithium reduced the conversion as well as the selectivity of 3FCl. However, in the case of Ni/$SiO_2$, the conversion was greatly reduced possibly due to a loss of silica support with high surface area by the reaction of $SiO_2$ with HF. Such a reduction in conversion also can be ascribed to the decrease in active sites, caused by the addition of alkali metal compound, LiOH.

• Polymer(Korea)
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• v.37 no.2
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• pp.127-134
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• 2013

The vascular endothelial cells are the inner layers of blood vessels. It regulates the function of blood vessels and proliferation of vascular smooth muscle cells. Poly(lactide-co-glycolic acid) (PLGA) is a biodegradable synthetic polymer with a well-controlled degradation rate and an acceptable mechanical strength. It can be easily fabricated into many shapes. Silk consists of 18 amino acids. It found important for attaching cells cultured in vitro, and maintaining cell functions. In this study, we fabricated silk/PLGA biomaterial hybrid films of 0, 10, 20, 40 and 80 wt% silk. We performed MTT, SEM, ELISA, and immunocytochemistry analyses. We confirmed the adhesion and the proliferation of HAECs on silk/PLGA according to the content of silk, and 40 wt% silk/PLGA hybrid films have superior adhesion and proliferation properties. These results demonstrate that silk/PLGA hybrid films provide suitable surfaces for HAECs, and there is the effect of silk on cell growth and proliferation.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.10
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• pp.933-940
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• 2009

To evaluate characteristics in spray flame, laminar counterflow is investigated on the effects of equivalence ratio and fuel by a two-dimensional DNS (direct numerical simulation). For the gaseous phase, Eulerian mass, momentum, energy, and species conservation equations are solved. For the disperse phase, all individual droplets are calculated by the Lagrangian method without the parcel model. n-Decane ($C_{10}H_{22}$) and n-heptane ($C_7H_{16}$) is used as a liquid spray fuel, and a one-step global reaction is employed for the combustion reaction model. As equivalence ratio increases, the fuel ignites early and the high temperature region spreads wider. The peak value of temperature, however, tends to once increase and then decreases with increasing equivalence ratio. The decrease in the peak value of temperature for the higher equivalence ratio condition is caused by the cooling effect associated with droplet group combustion. Since the evaporation of n-heptane is early, the high temperature region spreads wider than ndecane, but the peak values of temperature for both n-heptane and n-decane is almost same.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.201-207
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• 2013

When hot weather concrete is utilized, the cooling methods of cooling pipe, liquid nitrogen, ice, etc., are used to prevent the poor consistency and cold joint due to high temperature. These methods, however, spike the production cost and energy consumption, and make quality control difficult. Among these methods is one that involves the use of a retarder. Although economical, retarder is caused difficulty of retarded hardening and setting time control due to inaccurate weighing and poor working condition. Therefore, how to make a tablet for hot weather concrete, as with the existing pharmacy and foods, is discussed in this study, including the following items: mortar setting time, flow test by elapsed time, physical and mechanical properties of concrete. As a result, gluconic acid is superior to lignosulfonic acid and the possibility of using them for such purpose without quality degradation was confirmed in this study, when retarder is tabletting.

• Geotechnical Engineering
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• v.8 no.2
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• pp.5-20
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• 1992

The physical-based and lumped-parameter hydrologic groundwater flow model for predicting the rainfall-triggered rise of groundwater levels in hillside slopes is developed in this paper to assess the risk of landslides. The developed model consists of a vertical infiltration model for unsaturated zone linked to a linear storage reservoir model(LSRM) for saturated zone. The groundwater flow model has uncertain constants like soil depttL slope angle, saturated permeability, and potential evapotranspiration and four free model parameters like a, b, c, and K. The free model parameters could be estimated from known input-output records. The BARD algorithm is uses as the parameter estimation technique which is based on a linearization of the proposed model by Gauss -Newton method and Taylor series expansion. The application to examine the capacity of prediction shows that the developed model has a potential of use in forecast systems of predicting landslides and that the optimal estimate of potential 'a' in infiltration model is the most important in the global optimum analysis because small variation of it results in the large change of the objective function, the sum of squares of deviations of the observed and computed groundwater levels. 본 논문에서는 가파른 산사면에서 산사태의 발생을 예측하기 위한 수문학적 인 지하수 흐름 모델을 개발하였다. 이 모델은 물리적인 개념에 기본하였으며, Lumped-parameter를 이용하였다. 개발된 지하수 흐름 모델은 두 모델을 조합하여 구성되어 있으며, 비포화대 흐름을 위해서는 수정된 abcd 모델을, 포화대 흐름에 대해서는 시간 지체 효과를 고려할 수 있는 선형 저수지 모델을 이용하였다. 지하수 흐름 모델은 토층의 두께, 산사면의 경사각, 포화투수계수, 잠재 증발산 량과 같은 불확실한 상수들과 a, b, c, 그리고 K와 같은 자유모델변수들을 가진다. 자유모델변수들은 유입-유출 자료들로부터 평가할 수 있으며, 이를 위해서 본 논문에서는 Gauss-Newton 방법을 이용한 Bard 알고리즘을 사용하였다. 서울 구로구 시흥동 산사태 발생 지역의 산사면에 대하여 개발된 모델을 적용하여 예제 해석을 수행함으로써, 지하수 흐름 모델이 산사태 발생 예측을 위하여 이용할 수 있음을 입증하였다. 또한, 매개변수분석 연구를 통하여, 변수 a값은 작은 변화에 대하여 목적함수값에 큰 변화를 일으키므로 a의 값에 대한 최적값을 구하는 것이 가장 중요한 요소라는 결론을 얻었다.

• Journal of the Korean Institute of Gas
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• v.18 no.4
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• pp.13-20
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• 2014

In natural gas distribution system, gas pressure is regulated correspond to requirement using throttle valve which is releasing huge pressure energy as useless form. The waste pressure can be recovered by using turbo machinery devices such as a turbo expander. In this process, excessive temperature drop occurs due to Joule-Thompson effect during the expansion process. Installing natural gas boiler before or after the turbo expander prevents temperature drop. Fuel cell or gas engine hybrid system further improve the efficiency, but 1~2% of total transporting natural gas is used for operating the hybrid system. In this study, a heat pump system is proposed as a preheating device which can be operated without using transporting natural gas. Thermodynamic analysis on evaporating and condensing temperatures and refrigerants is conducted. Results show that R717 is proper refrigerant for the hybrid system with high COP and low turbine work within the defined operating conditions. In domestic usage in Korea, the heat pump system has more economic feasibility owing to natural gas being imported with a high price of LNG form.

• Clean Technology
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• v.20 no.4
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• pp.383-389
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• 2014

$CO_2$ absorption processes have a good potential for large scale capture of $CO_2$ but a large amount of absorbing solution has to be regenerated, undesirably increasing the consumption of energy such as sensible heat and latent heat of vaporization. In this study, a cooling crystallization process which would separate the $CO_2$-rich potassium bicarbonate crystals from $CO_2$-lean water was developed to reduce the energy penalty. Sterically hindered alkanolamine additives were used to enhance the $CO_2$ removal efficiency and their antisolvent effect on the crystallization was found in a continuous cooling crystallizer. The production yields of crystals were increased in the sequence of 2-amino-2-methyl-1-propanol (AMP) < 2-amino-2-methyl-1,3-propanediol (AMPD) < 2-amino-2-hydroxymethyl-1,3-propanediol (AHPD), which are related to the number of hydroxyl groups in the additive molecules. Using $^{13}carbon$ nuclear magnetic resonance, the additives favored the formation of bicarbonate ions by steric hindrance effect and increased the supersaturation of $KHCO_3$. It is shown that the additives increase the mean size of crystals and crystal growth rate by increasing supersaturation. The additives are promising for enhancing the $CO_2$ removal efficiency and reducing the regeneration energy cost of $CO_2$ absorbing solution by promoting $KHCO_3$ crystallization.

• Proceedings of the ESK Conference
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• 1993.10a
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• pp.223-235
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• 1993

요통(Lowback Pain)을 유발하는 주요원인으로 알려져있는 MMH(Manual Materials Handling) 작업에 있어서 작업조건의 변화가 근육의 활동과 피로도에 미치는 영향을 평가하기 위해 4가지 서로 다른 작업조건하에서 몸통부위(Trunk)의 주요근육에 대한 EMG 파형분석을 실시 하였다. 본 연구에서의 분석대항작업은 실제 작업조건과 유사하레 설계된 120분간의 단속적인 인양(Lifting)/하역(Lowering) 작업으로서 작업중량은 작업자의 MVIS(Maximum Voluntary Isometric Strength)를 기준으로 설정되었으며, 매 10분 간격으로 EMG 측정이 이루어졌다. 작업물이 작업자의 정면에 위치한 대칭형(Symmetric) 작업의 경우 배면부(Dorsal) 근육인 천극근(Erector Spinae)과 활배근(Latissimus Dorsi)이 활동근(Active Muscle)인 것으로 나타났으며, 정중면(Medial Plane)을 중심으로 좌우측 근육이 동일한 근력을 발휘하였다. 작업물이 작업자의 한쪽 측면에 위치한 90도 비대칭형(Asymmetric) 작업의 경우 천극근과 활배근외에 작업물과 반대쪽 외사근(External Oblique)이 활동근으로 추가되었으며, 작업물과 반대쪽의 근육들이 더욱 큰 근력을 발휘하였다. 작업의 반복에 따른 근육의 피로도를 평가하기 위해 실시한 EMG 파형의 Spectral Analysis 결과, 비대칭형 작업시 작업물과 반대쪽의 천극근에서 작업시간의 경과에 따라 중위주파수(Median Power Frequency)가 저주 파수대로 천이(Lower Shift)하는 현상이 나타났으며, 일정한 작업량이라도 작업중량을 줄이고 작업 빈도를 높여서 작업할 경우에 이러한 현상이 더욱 두드러졌다. 작업시간의 경과에 따른 MVIS의 감소 현상은 작업빈도가 높고 비대칭형 작업일 때 가장 크게 나타났다. 총손실을 줄이고, 상대적 비용절감효과를 갖게할 수 있다고 하였다. 따라서 본 연구에서는 성인 여성기성복의 치수적합성을 높이기위하여 출산 후 중년에 접어 들면서 체형이 변화되는 것을 고려하여 연령을 분류하고(18세-34세, 30세-51세), 각 연령 집단에 따른 체형을 각각 3가지로 분류하였다. 이에 따라 의복 생산시의 총손실을 줄이기위한 상의, 하의생산시 필요한 부위별 최적규격치 간격을 제시하였다.적인 기능으로 보여지는 것에 좁혀서 작업능력의 연령증가 변화에 대하여다원적 평가를 하는 것이 실제적이라고 할 수 있다. 따라서 본 연구에서는 인간이 가지고 있는 다수의 기능중에서 수지교 치성과 연령증가와의 관계를 조사한다. 만약 연령증가 만으로 수지교치성을 평가 할 수 없는 경우에는 어떠한 요인이 수지기민성의 변화에 영향을 미치는가를 검토한다.t list)에서 자동적으로 사건들의 순서가 결정되도록 확장하였으며, 설비 제어방식에 있어서도 FIFO, LIFO, 우선 순위 방식등을 선택할 수 있도록 확장하였다. SIMPLE는 자료구조 및 프로그램이 공개되어 있으므로 프로그래머가 원하는 기능을 쉽게 추가할 수 있는 장점도 있다. 아울러 SMPLE에서 새로이 추가된 자료구조와 함수 및 설비제어 방식등을 활용하여 실제 중형급 시스템에 대한 시뮬레이션 구현과 시스템 분석의 예를 보인다._3$", chain segment, with the activation energy of carriers from the shallow trap with 0.4[eV], in he amorphous regions.의 증발산율은 우기의 기상자료를 이용하여 구한 결과 0.05 - 0.10 mm/hr 의 범위로서 이로 인한 강우손실량은 큰 의미가 없음을 알았다.재발이 나타난 3례의 환자를 제외한 9례 (75%)에서는 현재까지 재발소견을 보이지 않고 있다. 이러한 결과는 다른 보고자들과 유사한 결과를

• Journal of the Society of Cosmetic Scientists of Korea
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• v.44 no.2
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• pp.201-210
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• 2018

In this study, we formulated oil-in-water emulsion composition for skin care products containing jadeite powder which is well known as far-infrared radiating material. Jadeite powder could sustain stable dispersion in aqueous solvents over a month and this helped mixing it high content in oil-in-water emulsion formulation. To identify the effect of jadeite as a far-infrared radiator materials relating to the skin surface temperature change, we applied emulsion formulation containing 2 weight percent jadeite powder onto facial skin surface and blank formulation together and analyzed surface temperature with thermo-vision. Our results showed that the temperature difference between jadeite powder formulation applied region and blank formulation reached to 1.5 ~ 2.0 degree Celsius. We also performed same test with nephrite powder and titanium dioxide powder but only jadeite powder containing formulation showed significant skin temperature change. To elucidate main cause of heat energy transfer, we tested heat radiation, energy dispersive spectrometer analysis and measured far infrared radiance emissivity, diffuse reflectance spectra and water evaporation rate. We found out jadeite powder could retard water evaporation effectively from the skin surface and resist temperature drop down. This is because of the innate chemical composition and surface structure of jadeite, which can bind with water molecules to form hydrogen bonds. It is concluded that we can develop novel skin care products for moisturizing and thermos with jadeite powder.

• Journal of the Korean Vacuum Society
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• v.17 no.4
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• pp.270-277
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• 2008

Vacuum is any air or gas pressure less than a prevailing pressure in an environmental or, specifically, any pressure lower than the atmospheric pressure and is used by a wide variety of scientists and engineering - including clean environment, thermal insulation, very long mean free path, plasma, space simulation[1]. The space environment is characterized by such a severe condition as high vacuum, and very low and high temperature. Since a satellite will be exposed to such a space environment as soon as it goes into its orbit, space environmental test should be carried out to verify the performance of the satellite on the ground under the space environmental conditions. A general and widely used method to simulate the space environment is using a thermal vacuum chamber which consists of vacuum vessel and thermally controlled shroud. As indicated by name of vacuum chamber, the vacuum technology is applied to design and manufacture of the thermal vacuum chamber. This paper describe the vacuum technology which is applied to space business.