• Title/Summary/Keyword: 중화법

Search Result 121, Processing Time 0.036 seconds

Preparation and Properties of Polyurethane Dispersions with Aromatic/Aliphatic Mixed Diisocyanate (방향족/지방족 혼합 Diisocyanate를 포함하는 Polyurethane 분산체의 제조와 성질)

  • Kim, Hyoung Sug;Noh, Si Tae
    • Applied Chemistry for Engineering
    • /
    • v.20 no.3
    • /
    • pp.258-265
    • /
    • 2009
  • An anionic polyurethane dispersions (PUDs) were synthesized from the poly (tetramethylene glycol) (PTMG, Mw = 2000 g/mol), mixed isocyanate of dicyclohexylmethane-4,4'-diisocyanate $(H_{12}-MDI)$ and 4,4'-diphenylmethane diisocyanate (MDI), and dimethylol propionic acid (DMPA) as anionic site, following a prepolymer mixing process. Triethylamine (TEA) was used as a neutralization agent and the ethylenediamine (EDA) as the chain extender of the prepolymer. The effects of the DMPA molar ratio and aromatic diisocyanate content in the mixed isocyanate on the particle size and viscosity of PUD were studied. Also, the mechanical and thermal properties of the PUD cast films were discussed according to the molar ratio of DMPA and aromatic isocyanate content. It was found that the particle size and the viscosity of an anionic PUD decreased with increasing DMPA molar ratio but increased with increasing aromatic isocyanate (MDI) content in the mixed isocyanate at the constant DMPA content. Tensile strength of the PUD cast films increased and elongation at break decreased with increasing DMPA content at the constant mixed isocyanate molar ratios. In thermal degradation temperature of PUD cast films, the effect of DMPA contents was great but the effect of aromatic isocyanate contents at the low DMPA content was very slight respectively.

Effect of Residual Chloride Ion on Thermal Decomposition Behaviour os Stannic Acid and Physical Properties of $SnO_2$ Powder Fabricated for Gas Sensor (가스센서용 $SnO_2$분말 제조시 잔류 염소이온이 Sn수화물의 열분해거동 및 분말물성에 미치는 영향)

  • Song, Guk-Hyeon;Choe, Byeong-U;Park, Jae-Hwan;Park, Sun-Ja
    • Korean Journal of Materials Research
    • /
    • v.4 no.8
    • /
    • pp.934-944
    • /
    • 1994
  • Effects of residual chloride on thermal decomposition behaviour of a-stannic acid and physical properties of $SnO_{2}$ powder were observed. The powder was fabricated by hydroxide method; $\alpha$-stannic acid was precipitated by mixing acqueous solutions of $SnCl_{4}$ and $NH_{4}$OH . The precipitate was washed with $NH_{4}NO_{3}$ solution while washing was controlled to be of three grades to modify its residual chloride content. The precipitate was dried at $1100^{\circ}C$ ~ 24h and calcined in air at $500^{\circ}C$ ~ $1100^{\circ}C$ for one hour. Thermal decomposition behaviour of $\alpha$-stannic acid was examined by a DT-TGA and a FTIR. Chemical composition and physical properties of $SnO_{2}$ powder were observed by an AES, a BET and a TEM, respectively. With a reduction in chloride content, the relative crystallite size of $SnO_{2}$ powder slightly increased by a low-temperature-calcining. However, at a high calcining temperature(T), the reverse relation occured. It was suggested that chloride ion replaces part of lattice oxygen site of a-stannic acid. Also, chloride ion on the site was suggested to retard de-hydration as well as crystalization at a low T while to promote crystal growth of $SnO_{2}$ by forming oxygen vacancy at a high T.

  • PDF

A Study of the Generation of Transgenic Chickens That Express Human SOD-3 Protein (사람의 SOD-3 단백질을 발현하는 형질전환 닭 생산 연구)

  • Byun, S.J.;Park, C.;Kim, J.A.;Woo, J.S.;Lee, H.C.;Kim, T.Y.;Kim, S.H.;Seong, H.H.;Park, J.K.;Jeon, I.S.
    • Korean Journal of Poultry Science
    • /
    • v.35 no.3
    • /
    • pp.241-245
    • /
    • 2008
  • Lentiviral vector system is efficient vehicles for the delivery of exogenous genes, and it is generally used in the generation of transgenic chickens. In this study, we used recombinant lentiviral vectors to generate transgenic chicks that express the human superoxide dismutase-3 gene driven by the chicken ovalbumin promoter. It is well known that superoxide dismutases(SODs) are believed to play a crucial role in protecting cells against oxygen toxicity. There are three forms of SOD proteins: cytosolic Cu-Zn SOD, mitochondrial Mn SOD, and extracellular SOD(SOD-3). The recombinant lentivirus containing the human SOD-3 gene was injected into the subgerminal cavity of freshly laid eggs. Subsequently, the embryos were incubated to hatch using phases II and III of the surrogate shell ex vivo culture system. From 341 injected embryos, the 78 chicks hatched after 21 days incubation. The hatched chicks were screened for the human SOD-3 gene by using PCR. Two of 47 male chickens that survived to sexual maturity contained the human SOD-3 gene in their semen. These results showed that our transgenic chicken generation system was completely established.

The Effect of DMPA Contents on the Water Dispersability and Mechanical Properties of Urea Resin (DMPA의 함량이 우레아 수지의 수분산 안정성과 기계적 성질에 미치는 영향)

  • Park, Jae Cheol;Kim, Dong Soo;Lee, Soo
    • Journal of the Korean Applied Science and Technology
    • /
    • v.36 no.4
    • /
    • pp.1128-1135
    • /
    • 2019
  • In this study, different types of polyether amines and H12MDI were used to synthesize water dispersed urea resins, which can be applied to coating material on the concrete slabs for bicycle road using the ordinary application equipments. The concentrations of several polyether amines with different molecular weights and the number of amine functionality were varied to set up the optimal condition for water dispersed urea resin preparation with both an excellent tensile strength and an elongation. In addition, the effect of DMPA[2,2-Bis(hydroxymethyl)propanoic acid] concentration on the storage stability of the water dispersed urea resin was also investigated. The formation of urea bonds from isocyanate and polyether amines was confirmed through FT-IR ATR spectroscopy. From the mechanical properties of urea resins, PU-4 and PU-6, which were prepared with both diamines and triamine of different molecular weights and number of functionality, showed the tensile strength of 10.5 N/㎟ and 12.7 N/㎟, respectively and the elongation of 1165 % and 969%, respectively. Among the water dispersed urea resin synthesized with different contents of DMPA, PU-6 showed the highest mechanical properties, a tensile strength of 14.2 N/㎟ and an elongation of 993%. In addition, the water dispersion state of this PU-6 was the most stable even after 8 weeks.

Preparation of $TiO_2$ Coated Coal Fly Ash and Photocatalytic Characterization ($TiO_2$ 피복 석탄회의 제조와 광촉매 특성에 관한 연구)

  • Yu, Yeon-Tae;Choi, Young-Yoon;Kim, Byoung-Gyu;Lee, Hee-Jung;Lee, Byong-Taek
    • Korean Journal of Materials Research
    • /
    • v.11 no.8
    • /
    • pp.690-696
    • /
    • 2001
  • $TiO_2$ coated coal fly ash has been prepared in order to develop the low price $TiO_2$ photocatalyst and spread out its utilizing field. $TiO_2$ particles is coated on the surface of coal fly ash by precipitation method. In this method, $TiCl_4$ aqueous solution was used as a titanium stock solution and $NH_4HCO_3$ was used as a precipitant. The titanium hydroxide precipitated on the surface of coal fly ash in these neutralizing reaction process was oxidized by heat treatment in temperature ranges of $300~700^{\circ}C$. The crystal structure of the generated titanium dioxide showed anatase type. The crystal size of titanium dioxide increased with raising the temperature of heat treatment, but the removal ability of NO gas decreased. When the titanium dioxide was heated at temperature ranges of $300~ 400^{\circ}C$ for 2 hours, the crystal size of titanium dioxide appeared about 9nm, and the removal rate of NO gas showed 85~ 92%. The whiteness of $TiO_2$ coated coal fly ash increased with raising the coating rate of titanium dioxide and the temperature of heat treatment.

  • PDF

Influence of Activation Temperature on Surface and Adsorption Properties of PAN-based Activated Carbon Fibers/Phenolic Resin Matrix Composites (활성화 온도에 의한 PAN계 활성탄소섬유/페놀수지 복합재료의 표면 및 흡착특성)

  • 박수진;김기동;이재락
    • Polymer(Korea)
    • /
    • v.24 no.1
    • /
    • pp.97-104
    • /
    • 2000
  • PAN-based activated carbon fibers/phenolic resin matrix composites (ACFCs) were manufactured via molding process with oxidized carbon fabrics (plain-type) and phenolic resin (resole-type) compounded by 70 : 30 wt%. The green body (as molded) was submitted to carbonization (at 100$0^{\circ}C$) in an inert environment and activation (at 700, 800, 900 and 100$0^{\circ}C$) in a $CO_2$ environment. In this work, the influence of activation temperatures was investigated in surface properties, such as pH, acid- and base-values by titration method, and in adsorption properties, i.e., specific surface area and pore structures by BET-method of the composites. Also, the pressure drops of the specimens were calibrated by ASTM. As a result, the activation temperature influenced the surface property of ACFCs. When the activation temperature was higher than 90$0^{\circ}C$, the surface was gradually developed in basic nature. And, the evolutions of specific surface area, total pore volume and pore size distribution of ACFCs could be easily confirmed the dependence on the activation temperature. Among them, well-developed pore structure from adsorption characteristics was changed of the ACFCs activated at 90$0^{\circ}C$. Also, the pressure drop was slightly decreased with increasing the temperature due to increasing the burn-off with heat treatment temperature of ACFCs.

  • PDF

A design method for optical fiber filter of lattice structure (격자형 광파이버필터의 설계에 관한 연구)

  • 이채욱;문병현;김신환
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.18 no.9
    • /
    • pp.1248-1256
    • /
    • 1993
  • The propagation and delay properties in opical fiber are particularly attractive because digital signal processing and conventional analog signal processing techniques such as those using surface acoustic wave devices are limited In their usefulness for signal bandwidth exceeding one or two GHz, although they are very effective at lower frequencies. Since an accurate, low loss and short time delay elements can be obtained by using such an optical fiber, optical signal precessing has attracted much attention for high speed and broad-band signal precessing in particular channel separation filtering for optical FDM signals. In this paper, we consider a coherent optical lattice filter, which uses coherent light sources and consists of directional couplers and optical fiber delay elemnts. The optical fiber fitters are more restricted than the usual digital filters. The reasons are as follows. 1) the coupling coefficients of directional couplers are restricted to the number between 0 and 1. 2) optical signal E(complex amplitude) is divided into J If-$\boxUl$ and J L/7$\div$$\boxUl$ at the directional coupler. Considering these restrictions and in this case all the coupling coefficients of summing and branching elements are set to be equal, we have given design formulae for optical lattice filter, which make the best use of optical signal energy.

  • PDF

Studies on the Content of Lectin in Korean Mistletoe according to the Host Tree Species and Characterization for Its Application to the Quality Control (한국산 겨우살이 숙주별 렉틴 함량과 지표물질로서의 특성 조사)

  • Kim, Inbo;Yoon, Taek Joon;Park, Choon Ho;Lee, Woo Kyoung;Lee, So Hee;Kim, Jong Bae
    • The Korean Journal of Food And Nutrition
    • /
    • v.28 no.6
    • /
    • pp.1090-1097
    • /
    • 2015
  • Traditionally, mistletoe is known as an effective anti-cancer medicinal plant, and lectin is recognized as a major component with cytotoxic and immuno-stimulant activity in mistletoe. A Korean mistletoe lectin (KML) has specificity to galactose and galactosamine and is distinguish from European mistletoe lectin (EML). When we examined the concentration of lectin in mistletoe originated from five different types of host trees, the result indicate that the lectin concentration is variable depending on the host tree. Noticeably, mistletoe from chestnut tree contains ten folds higher lectins than that of an oak tree. We also tested the concentration of KML and crude extract (KM-110) of Korean mistletoe that shows 90% cytotoxicity in L5178Y-ML25 lymphoma cell. In addition, the cells show 90% and 70% viability by the treatment of two neutralizing antibodies of KML, 9H7-D10 and 8B11-2C5 neutralization effect with two monoclonal antibodies of KML, 9H7-D10 and 8B11-2C5. Therefore, the result expected that the mistletoe contain some other cytotoxic components except lectin. Finally, the production of $TNF-{\alpha}$ and IL-6 by RAW 264.7 cells stimulated with lectin free-crude extract (LFKM-110) following neutralization by 9H7-D10 monoclonal antibody shows higher than that of lectin containing-crude extract (KM-110). These results suggest that the Korean mistletoe lectin ha a great potential to be developed as therapeutic agent of cancer.

On Information Theoretical Research of the Korean Language (한국어의 정보이론적 연구 방향)

  • Lee, Jae-Hong;Yi, Chae-Hag
    • Annual Conference on Human and Language Technology
    • /
    • 1992.10a
    • /
    • pp.367-375
    • /
    • 1992
  • 한국어는 다른 언어와는 달리 초성, 중성, 종성의 자소가 모여서 한 음절을 이룬다. 음절을 이루는 자소는 그 발생의 확률적 성질에 따라 확률변수로 간주된다. 음절 안에서 자소간의 발생의 상관관계는 자소간 조건부 확률 및 엔트로피로 표시된다. 음절이 모여서 단어를 이루고 단어를 이루는 음절은 그 발생의 확률적 성질에 따라 확률변수로 간주된다. 한국어 단어안에서 음절간의 발생의 상관관계는 음절간 조건부 확률 및 엔트로피로 표시된다. 수 있다. 그런데 가능한 음절의 종류가 매우 많기 때문에 음절 발생의 상관관계를 표시하는 지표로서 음절간 조건부 확률 대신 초성, 중성, 종성 단위의 조건부 확률을 사용하는 것이 음절간의 발생의 상관관계를 표시하는데 효과적이다. 이러한 한국어의 정보이론적 연구를 위하여서는 기초자료로서 한국어 단어의 빈도분포가 필요하다. 한국어 단어의 빈도분포의 포괄적인 조사는 1956년의 "우리말 말수 사용의 잦기 조사"가 유일한 실정이다. 시간 경과에 따른 한국어의 정보이론적 특성 변화의 분석을 위하여서는 한국어 단어 빈도의 주기적인 조사가 필요하다. 한국어에서 초성, 중성, 종성단위의 정보이론적 연구결과는 한국어 음성인식 및 함성, 자연언어처리, 암호법, 언어학, 음성학, 한국어부호 표준화 연구등에 이용될 것으로 기대된다. 남북한의 언어는 분단이 지속됨에 따라 상호 이질화가 진행되고 있다. 이러한 이질화를 극복하려는 부분적인 노력으로 남북한 언어의 한국어 영문표기의 단일화 등이 있었다. 이러한 노력에 병행하여 남한과 북한의 언어에 대한 정보이론적 비교 연구도 있어야 할 것이다. 정보를 효과적으로 캐싱할 수 있도록 인접한 데이터를 클러스터링해서 브로드캐스팅하여 이동 호스트의 구성 시간(setup time)을 최소화하였다. 그리고, 맨하탄거리(Manhattan Distance)를 사용해서 위치 의존 질의에서 사용하는 데이타를 캐싱하고 질의를 처리하는 방법을 제안한다. 맨하탄 거리를 이용해서 캐싱하면 도로에 인접해서 위치한 데이타를 효과적으로 캐싱할 수 있다. 또한, 거리 계산 방법으로 맨하탄 거리를 사용하면 도심에서 실제 이동 거리와 비슷한 값을 알 수 있고, 직선 거리 계산식에 비해서 계산식도 간단하기 때문에 시스템 계산량도 줄일 수 있다. 기준으로 라이신 부산물은 어분 단백질을 40%까지 대체가 가능하였으며, 아울러 높은 라이신 부산물의 대체 수준에 있어서 사료효율과 단백질 전환효율을 고려한다면 아미노산 첨가(라이신과 아르지닌)와 중화 효과에 좋은 결과가 있을 것으로 사료된다.의한 적정 양성수용밀도는 각고 5~6cm 크기의 경우 10~15개체가 적합하였다. 수증별 성장은 15~20 m 수층에서 빨랐으며, 성장촉진과 폐사를 줄이기 위해서는 고수온이 지속되는 7~10월에는 20~30m수층으로 채롱을 내려 양성하고 그 외 시기에는 15 m층 내외가 좋은 것으로 나타났다. 상품으로 출하 가능한 크기 인 각고 10 cm이상, 전중량 140 g 내외로 성장시 키기까지는 채묘후 22개월이 소요되었고, 출하시기는 전중량 증가가 최대에 이르는 3월에서 4월 중순이 경제적일 것으로 판단된다.er 90 % of good relative dynamic modulus of elasticity due

  • PDF

Effective Techniques for Seedling Production of Amsonia ellipotica (Thumb.) Roem. & Schult. (정향풀의 효과적인 묘 생산을 위한 육묘법)

  • Lee, Sang In;Yeon, Soo Ho;Cho, Ju-Sung;Kim, Sang Young;Cho, Won Woo;Jeong, Mi Jin;Lee, Cheol Hee
    • Korean Journal of Plant Resources
    • /
    • v.34 no.5
    • /
    • pp.470-477
    • /
    • 2021
  • Amsonia ellipotica (Thumb.) Roem. & Schult. has less than 10 native places nationwide and is evaluated as an endangered species (EN) on the Korean Red List, so systematic breeding and cultivation methods are required. This study was carried out to establish an effective method for seedling production in A. elliopotica that can be developed as a genetic resource conservation and new ornamental material. This experiment was performed by varying the seedling production container (72, 105 and 128 cell trays), number of seeds sown in a cell (1, 2, and 4 per cell), soil type [horticultural soil and neutralized peat-moss: perlite mixed in 3:1, 4:1 (v:v)], additional fertilizer concentrations (0, 250, 500 and 1000 mg/L) and shading degrees (0, 55 and 75%). As a result of the study, growth increased with the increased in measuring capacity per cell of sowing container. According to number of seeding growth, sowing one seed per cell was the best. Seedling growth increased as the treatment concentrations increased, higher growth was in 1000 mg/L. On the other hand, during the shading treatment, growth significantly decreased regardless of shading degrees.