• Title/Summary/Keyword: 중합 효과

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Synthesis of Polymerized Vesicles for Cholesterol Extraction (콜레스테롤의 추출을 위한 고분자화된 Vesicles의 합성)

  • Cho, Iwhan;Kim, Sang-Hee;Shin, Jae-Sup
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.273-279
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    • 1992
  • Polymerized vesicles were prepared from monomeric cholesterol-containing surfactant. These vesicles were used to extract the free cholesterol. A polymerized vesicle was formed both monomeric cholesterol-containing surfactant and monomeric surfactant containing two alkyl chain(50 : 50 weight ratio). This vesicle got the better extracting capacity compared with the vesicle which got the other weight ratio of the surfactants. This vesicle also exhibited the fastest substrate permeability. These all results showed that considerable vacant room is necessary in polymerized vesicles in order to extract more cholesterols.

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Study on the Graft Effect in Emulsion Polymerization of Poly(vinyl acetate-co-ethylene) Using Poly(vinyl alcohol) as Emulsifier (Poly(vinyl alcohol)를 이용한 Poly(vinyl acetate-co-ethylene) 에멀젼 중합에서 그라프트 연구)

  • Choi, Yong-Hae
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.1-10
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    • 2011
  • An automated reaction calorimeter was used to directly monitor the rate of emulsion polymerization of vinyl acetate using poly(vinyl alcohol) (PVAs) having different degrees of blockiness. By using this technique in conjunction with other off-line measurements of the evolution of particle size distributions, important details of the process were observed. No constant graft rate period was observed for both low and high initial monomer-water ratios. The gel effect was observed for the low monomer-water ratio recipe. The particle size distributions were broad (particle diameter 40~100 nm) and bimodal. Continuous nucleation was observed to be accompanied by 'limited aggregation' and flocculation during the particle growth stages. It was speculated to be due to the occurrence of the extensive 'limited aggregation' and chain transfer to PVA leading to grafting.

Spectroscopic Analysis of the Remote-plasma-polymerized Methyl Methacrylate Film (원격 플라즈마 중합된 메틸메타크릴레이트 필름의 분광학적 분석)

  • Seomoon, Kyu
    • Applied Chemistry for Engineering
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    • v.32 no.1
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    • pp.49-54
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    • 2021
  • Plasma-polymerized methyl methacrylate (MMA) thin films were synthesized by remote plasma, and effects of plasma power, reaction pressure and direct-indirect plasma on the growth rate and chemical bonding were investigated with alpha-step, FT-IR, XPS and Langmüir probe method. As the plasma power and pressure increased, the tendency of growth rate showed maximum value at a certain range. FT-IR and XPS analyses revealed that composition ratio of C/O and hydrocarbon (C-C) % in the deposited films increased with plasma power, but ester (COO) C % decreased with it. Direct plasma method was effective for fast growth rate, but indirect plasma method was favorable for maintaining the chemical structure of MMA.

Dispersion Stability of Pigments in Aqueous Solution of Anionic Oligo Type Surfactants(Parts 1)-Dispersion of Phthalocyanine or Carbon Black- (올리고머형 음이온성 계면활성제 수용액에서 안료의 분산성(제1보) - Phthalocyanine이나 Carbon Black의 분산 -)

  • Lee, H.W.;Yun, Y.K.;Park, H.Ch.;Nam, K.D.
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.1-5
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    • 1998
  • The dispersing behaviors of oligomer-type anionic surfactants, cooligomers of diethyl maleate(CmD-Na) or maleic anhydride (CmM-Na) and $C_4{\sim}C_{16}$ alkyl vinylether, which have a different alkyl chain length of the hydrophobic group or degree of polymerization, were studied on the aqueous suspension of ${\alpha}-$ and ${\beta}-$ copper phthalocyanine and carbon black particles. In case of the side alkyl chain length of $C_4{\sim}C_{10}$ of CmD-Na, the dispersing actions were good in the concentration range of 0.01 to 0.1%. Especially, side alkyl groups played an important role in the orientation adsorption on the surface of pigment particles, and oligomers having smaller degrees of polymerization were more effective in the dispersing action, but did not affect the dispersability of carbon black.

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Spray Characteristics of Water-Gel Propellant by Impinging Injector (Water-Gel 모사 추진제의 충돌 분무 특성 연구)

  • Hwang, Tae-Jin;Lee, In-Chul;Kim, Sang-Sun;Koo, Ja-Ye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.11-14
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    • 2009
  • The implementation of gelled propellants systems offers high performance, thrust-control, energy management of propulsion, storability, and high density impulse of solid propulsion. Present study focused on the spray behavior of liquid sheets formed by impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are then compared with experiments conducted on spray images formed by impinging jets concerning with air-blast effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure, closed rim pattern shape appeared. As increasing air mass flow rate(decreasing GLR), spray breakup and atomization phenomenon better improved and spray structure instabilities for the effect of air-blast are also increased.

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A Convergence Study on Comparison of the Difference in the Blue-Light Transmittance by Goggles and Dental Curing Light Unit Tips (청색광이 광중합기용 팁과 보안경에 따라 투과되는 투과율 차이 비교의 융합적 연구)

  • Lee, Sook-Jeong
    • Journal of the Korea Convergence Society
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    • v.10 no.12
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    • pp.177-181
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    • 2019
  • The purpose of this study was to investigate the degree of blocking of blue light of the tips and goggles of the curing light during the dental treatment using the blue light of the light curing. The light curing tips and goggles were placed on a UV-Vis spectrometer and the results of light transmission were analyzed. Comparative analysis. As a result, all four types of light curing tips used in the analysis showed excellent blue light blocking effect. In the case of safety goggles, red-type goggles showed blue light transmittance similar to those of light curing than yellow-type goggles. As a result, it is recommended that the attachment of the light curing with high degree of blue light blocking and the wearing of safety glasses are necessary to protect the eyes. This behavior is thought to reduce persistent irritation and fatigue in the eyes.

Effect of Foliar Uptake of Azoxystrobin and Kresoxim-methyl on Fungicidal Activity against Cucumber Powdery Mildew (Azoxystrobin과 Kresoxim-methyl의 오이 엽면 침투성과 오이 흰가루병 방제 효과)

  • Yu, Ju-Hyun;Choi, Gyung-Ja;Kim, Heung-Tae
    • Applied Biological Chemistry
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    • v.51 no.2
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    • pp.108-113
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    • 2008
  • Azoxystrobin applied by aqueous WP suspension 50 mg/l was slightly absorbed into cucumber leaf in the absence of activator surfactant 24 h after spraying, but was increased to 25.7% by adding polyoxyethylene monohexadecyl ether (12 moles of ethylene oxide, CE-12) 500 mg/l. Only 4.1% of kresoxim-methyl WDG 100 mg/l in the absence of surfactant was absorbed into cucumber leaf 24 h after spraying, but was increased to 58.0% by adding polyoxyethylene monooctadecyl ether (14 moles of ethylene oxide, SE-14) 1,000 mg/l. The effect of CE-12 500 mg/l on foliar uptake of kresoxim-methyl at 50 mg/l was twice bigger than on azoxystrobin. Fungicidal activity of azoxystrobin WP against cucumber powdery mildew was marginally increased by adding surfactants to facilitate foliar uptake of azoxystrobin, so that the further increase of azoxystrobin uptake into cucumber plant by the addition of adjuvant was not a practical mean for enhancing the formulation efficacy in view of fungicidal activity. It was not possible for kresoxim-methyl to assess the adjuvant effect on the fungicidal activity in a greenhouse trial due to the vapor effect of active ingredient.

MLPA Applications in Genetic Testing (유전자진단에 있어서 Multiplex Ligation Dependent Probe Amplification (MLPA)의 이론과 실제)

  • Kim, Gu-Hwan;Lee, Beom-Hee;Yoo, Han-Wook
    • Journal of Genetic Medicine
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    • v.6 no.2
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    • pp.146-154
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    • 2009
  • Multiplex ligation dependent probe amplification (MLPA) is a PCR-based method to detect gene dosage. Since its introduction, MLPA has been used to test a large number of genes for major deletions or duplications. Genetic testing, as a diagnostic tool for genetic disease, has been used primarily to identify point mutations, including base substitutions and small insertions/deletions, using PCR and sequence analysis. However, it is difficult to identify large deletions or duplications using routine PCR- gel based assays, especially in heterozygotes. The MLPA is a more feasible method for identification of gene dosage than another routine PCR-based methods, and better able to detect deleterious deletions or duplications. In addition to detection of gene dosage, MLPA can be applied to identify methylation patterns of target genes, aneuploidy during prenatal diagnoses, and large deletions or duplications that may be associated with various cancers. The MLPA method offers numerous advantages, as it requires only a small amount of template DNA, is applicable to a wide variety of applications, and is high-throughput. On the other hand, this method suffers from disadvantages including the possibility of false positive results affected by template DNA quality, difficulties identifying SNPs located in probe sequences, and analytical complications in quantitative aspects.

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Multicomponent RVSP Survey for Imaging Thin Layer Bearing Oil Sand (박층 오일샌드 영상화를 위한 다성분 역VSP 탐사)

  • Jeong, Soo-Cheol;Byun, Joong-Moo
    • Geophysics and Geophysical Exploration
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    • v.14 no.3
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    • pp.234-241
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    • 2011
  • Recently, exploration and development of oil sands are thriving due to high oil price. Because oil sands reservoir usually exists as a thin layer, multicomponent VSP, which has the advantage of the high-resolution around the borehole, is more effective than surface seismic survey in exploring oil sand reservoir. In addition, prestack phase-screen migration is effective for multicomponent seismic data because it is based on an one-way wave equation. In this study, we examined the applicability of the prestack phase-screen migration for multicomponent RVSP data to image the thin oil sand reservoir. As a preprocessing tool, we presented a method for separating P-wave and PS-wave from multicomponent RVSP data by using incidence angle and rotation matrix. To verify it, we have applied the developed wavefield separation method to synthetic data obtained from the velocity model including a horizontal layer and dipping layers. Also, we compared the migrated image by using P-wave with that by using PS-wave. As a result, the PS-wave migrated image has higher resolution and wide coverage than P-wave migrated image. Finally, we have applied the prestack phase-screen migration to the synthetic data from the velocity model simulating oil sand reservoir in Canada. The results show that the PS-wave migrated image describe the top and bottom boundaries of the thin oil sand reservoir more clearly than the P-wave migrated image.

A Modeling Study on the AVO and Complex Trace Analyses of the Fracture Bone Reflection (파쇄대 반사에너지의 AVO 및 복소트레이스 분석에 관한 모형연구)

  • Han Soo-Hyung;Kim Ji-Soo;Ha Hee-Sang;Min Dong-Joo
    • Geophysics and Geophysical Exploration
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    • v.2 no.1
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    • pp.33-42
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    • 1999
  • AVO and complex trace analyses mainly used to characterize natural gas reservoir were tested in this paper for a possible application to detection of major geological discontinuities such as fracture zones. The test data used in this study were calculated by utilizing a viscoelastic numerical program which was based on the generalized Maxwell body for a horizontal fracture model. In AVO analysis of a horizontal fracture zone, p-wave reflection appears to be variant depending upon the acoustic-impedence contrast and the offset distance. The fracture zone is also effectively clarified both in gradient stack and range-limited stack in which fracture zone reflection is attenuated with the increasing offset distance. In complex attribute plots (instantaneous amplitude, frequency, and phase), the top and bottom of the fracture Tone are characterized by a zone of strong amplitudes and an event of the same phase. Low frequency characteristics appear at the fracture zone and the underneath. Amplitude attenuation and waveform dispersion are dependent on Q-contrast between the fracture zone and the surrounding media. They were properly compensated by optimum inverse Q-filtering.

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