• Title/Summary/Keyword: 중염소

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Assessment of material analysis for Non-flammable of cable (케이블 연소방지제의 재료에 대한 성능평가 기술)

  • Soh, Jin-Joong;Shim, Dae-Sub
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1472-1474
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    • 2003
  • 연소방지재(난연테이프, 난연도료, 난연seal, 난연레진, 난연보드 등)란 지중 배전케이블, 접속재 및 통신케이블 등의 외피에 화재확산 방지를 위해 도포하여 사용하는 것으로서 화재 시 발포하거나 단열의 효과가 있어 케이블, 전선 등이 연소하는 것을 지연시킨다. 따라서 본 평가 기술에서는 수직불꽃시험, 산소지수, 저 염소시험, 발연농도, 케이블 허용전류저감률 등 주 재료시험에 대한 시험방법을 검토하고 시험에 적용하여 시험 시 문제점을 도출하여 시험방법을 정립하고자 한다.

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A Survey on the Residues of Organochlorine Pesticides in Some Marine Foods from South Coast of Korea (남해안산(南海岸産) 수산식품(水産食品) 중 유기염소계 잔류농약(殘留農藥)에 관한 조사연구(調査硏究))

  • Lee, Su-Rae;Kang, Soon-Young
    • Korean Journal of Food Science and Technology
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    • v.8 no.4
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    • pp.219-224
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    • 1976
  • The appearance of organochlorine pesticide residues in shellfish, seaweed, mud and water samples collected from south coast of Korean peninsula in September 1974 was surveyed to obtain the following results. 1) The residues in shellfish samples were found to be in the orders of Choongmoo > Yeosoo > Busan > Mokpo area, top-shell >short-necked clam > mussel > hard clam > red-shell, aldrin > ${\alpha}-BHC$ > heptachlor> ${\gamma}-BHC$ > dieldrin > heptachlor epoxide > endrin and in the range of $0-49\;{\mu}g/kg$ edible fresh muscle. 2) The residues in seaweed samples from Wando area were found to be in the orders of tangle > green laver > laver, ${\alpha}-BHC$ > ${\gamma}-BHC$ > aldrin > dieldrin > heptachlor > heptachlor epoxide > endrin and in the range of $0-60\;{\mu}g/kg$ dry matter. 3) The residues in water samples were found to be in the orders of Yeongsan River > Nakdong River > Seomjin River > Choongmoo shellfish farm, ${\alpha}-BHC$ > ${\gamma}-BHC$ > aldrin > heptachlor > dieldrin > heptachlor epoxide > endrin and in the range of $0-180\;{\mu}g/kl$ while those in mud samples were in the order of ${\alpha}-BHC$ > ${\gamma}-BHC$> aldrin > dieldrin > heptachlor > heptachlor epoxide > endrin and in the range of $0.7-18\;{\mu}g/kg$ dry matter. It should be noted that BHC contents of water samples from Yeongsan and Nakdong rivers were far above the recommended environmental levels in USA.

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Distribution of PCDDs/PCDFs in the Ambient Air of Seoul (서울시내 환경대기 중 다이옥신 농도 분포 조사)

  • 엄정훈;최용석;유인철;정종흡;윤중섭;김민영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.411-412
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    • 2003
  • 다이옥신은 주로 연소과정에서 소각부산물로 생성되는 염소계 유기화합물로서 이들의 최종 수용체는 토양이나 저질이 되지만 최초 배출형태는 주로 대기오염물의 특성이 있어 호흡에 의한 섭취량을 생각하지 않을 수 없다. 일단 대기환경 중 다이옥신 농토는 1999년부터 환경부와 국립환경연구원에서 전국적으로 조사하여 발표하고 있으나 서울시에 대해서는 단지 2∼3개 지점에 대해서만 조사하는 등 사례가 드물어 서울시내 대기환경관리 정책에 어려움이 있을 것으로 사료되어 이번 조사에서는 현재 서울시 일원의 환경대기 중 다이옥신 농도 현황을 파악하여 이의 관리대책을 위한 자료를 제공하고자 실시하였다. (중략)

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The concentration of Hexachlorocyclohexane in air (대기중 Hexachlorocyclohexane(HCH)의 농도)

  • 최민규;여현구;한효경;김태욱;천만영;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.157-158
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    • 2001
  • Hexachlorocyclohexane(HCH, 또한 benzene hexachioride(BHC)라고도 부름)은 세계 도처에서 발견되는 주요 난분해성 유기염소계 화합물들(persistent organochlorine compounds)중 하나이며, 또한 환경중 거동 및 영향들과 관련하여 가장 많이 연구되어진 살충제중 하나이다(Li et al., 1996). Technical HCH mixture($\alpha$-, $\beta$-, ${\gamma}$-, $\delta$- 및 $\varepsilon$-HCH 이성질체들의 혼합물)와 technical lindane(거의 단일의 ${\gamma}$-HCH 이성질체로 구성)은 농업, 산림 및 위생 방면에 다양한 목적을 위해 1940년말 이래로 많은 양이 사용되어져 왔다(Li et al., 1996; Breivik et al., 1999). (중략)

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Bacteriocidal Effect of Chamical Sanitizers on Natural Microflora and Pathogenic Bacteria in Fish (화학적 살균소독제를 활용한 생선중 존재하는 자연균총 및 주요 식중독균 제어)

  • Kim Il-Jin;Kim Yong-Soo;Ha Sang-Do
    • Journal of Food Hygiene and Safety
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    • v.21 no.2
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    • pp.65-69
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    • 2006
  • In this study, we evaluated bacteriocidal effect of CaO (scallop shell powder) for the reduction of microorganism in Scomber japonicus and Pseudosciaena ciean manchurica, and compared with main chemical sanitizers such as chlorine, ethanol, hydrogen peroxide. As a result, the effectiveness of CaO showed dramatic reduction rate for total aerobic bacteria, Escherichia coli and Vibrio parahaemolyticus. The reduction rates of total aerobic bacteria for Scomber japonicus and Pseudosciaena ciean manchurica showed $2.6{\times}10^3\;and\;3.2{\times}10^4$ respectively; Those of Escherichia Coli were $6.3{\times}10^3\;and\;1.2{\times}10^4$, those of Vibrio parahaemolyticus were $5.4{\times}10^4\;and\;5.6{\times}\2.6{\times}10^310^4$, respectively. According to this result, bacteriocidal effect of CaO was about $10^4$ and was similar to bacteriocidal effects of other three chemical sanitizers. According to these results, CaO can alternate the currently used chemical sanitizers due to its natural origin as well as the effectiveness for sterilization.

Removal of Algogenic Organic Matter in Drinking Water Treatment Process (정수처리공정에서 조류유래 유기물질의 제거)

  • Park, Se-Jin;Cha, Il-Kwon;Yoon, Tai-Il
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.377-384
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    • 2005
  • Algae causes not only the eutrophication of lake, but also the deterioration of drinking water process. Especially, algogenic organic matters(AOM) are assumed as disinfection by-products(DBPs) precursors like humic and fulvic acids. In this study, it was investigated the characteristics changes of algogenic organic matter(AOM) by prechlorination and coagulation treatment. Evaluation of enhanced coagulation and applicability of UV oxidation process were also evaluated as the drinking water treatment system for the eutrophicated water source. prechlorination was effective process for algae removal but caused releasing of dissolved organic matter(DOC) into water due to the destruction of algae's cell. In coagulation treatment with Fe(III) coagulant, reaction pH is an important factor for the removal of AOM and triholomathanes(THMs). At pH 5, removal efficiency of DOC and THMs were dramatically improved by 50% and 28%, respectively, in comparison with the conventional coagulation treatment at about pH 7. Photo-Fenton($UV/H_2O_2/Fe^{3+}$) process among the UV oxidations is the most effective system to remove AOM, but its removal efficiency was lower than that of enhanced coagulation treatment at pH 5.

Influence of Natural Salt Treatments on Soil Chemical Properties and Inorganic Contents of Garlic (천일염 살포가 토양 화학성과 마늘(Allium sativum L.)의 무기성분 함량에 미치는 영향)

  • Kim, Myung-Sook;Kim, Yoo-Hak;Kang, Seong-Soo;Yun, Hong-Bae;Gong, Hyo-Young;Lee, Sang-Beom
    • Korean Journal of Organic Agriculture
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    • v.20 no.2
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    • pp.231-241
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    • 2012
  • Farming using natural salts for supply of nutrients to crops is increasing recently. It is necessary to evaluate the salt accumulation in soil and the effects on crop growth by treatment of natural salt. This study was conducted at the organic cultivation fields which garlics were planted. The treatments were no natural salts (control) and plots applied 100~600 $kg\;ha^{-1}$ with natural salts. Soil samples were taken from the 0 to 25 cm depth at 12 and 107 day (harvest time) after natural salts application. The results showed that electrical conductivity (EC), exchangeable Na (Exch.$-Na^+$) and Cl- were increased by application of natural salts. But, pH and exchangeable cations ($K^+$, $Ca^{2+}$ and $Mg^{2+}$) had not significantly differences among treatments. In 300 $kg\;ha^{-1}$ plots of natural salt, the level of EC, Exch.$-Na^+$ and $Cl^-$ in top soil (0-5 cm) was were increased more 0.3, 3.7, and 12.7 times than control plot, respectively. EC, Exch.$-Na^+$, and $Cl^-$ were highest in the top 5 cm of soil and decreased with depth at 12 days after natural salts application, but were decreased in the plower layer (0-15cm) at the harvest time because they were leached with natural rain. An increasing the application level of natural salt resulted in increasing of sodium adsorption ratio, exchangeable sodium percentage, and percentage of soil dispersion. The concentration of nutrient uptake such as total nitrogen (T-N), chloride (Cl) in garlic had significant difference between control and plots applied with natural salts The content of T-N of garlic in plots with natural salt application was lower than control plot, but Cl is higher than control plot.

The Inhibitive Effect of Electrochemical Treatment Applied to Fresh/hardened Concrete (철근 부식 방식을 위한 굳지 않은/굳은 콘크리트의 전기방식 적용에 관한 연구)

  • Kim, Sung-Wook;Moon, Jae-Heum;Ann, Ki-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.67-76
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    • 2013
  • In this study, the inhibitive effect of electrochemical treatment subjected to fresh and hardened concrete and literature reviews in terms of the treatment were performed. In hardened concrete, chloride ions are mixed during casting to destroy the passivity of steel, and then the current was provided for 2 weeks with 250, 500 and $750mA/m^2$. After completion of electrochemical treatment, the extraction of chloride ions was quantified and repassivation of steel was observed. Simultaneously, the equated levels of current density for 2 weeks were applied to fresh concrete. Steel-concrete interface in concrete was observed by BSE image analysis and the concrete properties in terms of the diffusivity of chloride ions and the resistance of steel corrosion was measured. As the result, electrochemical treatment is very effectiveness to rehabilitate the passive film on the steel surface and 63-73% of chloride ions in concrete were extracted by the treatment. As the treatment was applied to fresh concrete, the resistance of steel corrosion was improved due to the densification of $Ca(OH)_2$ layers in the vicinity of steel. However, an increase in the current density resulted in an increase in surface chloride content of concrete.

Investigation of Characteristics of Incinerator Bottom Ash and Assessment for Recycle due to the Change of MSW Composition (생활폐기물 성상변화에 따른 소각시설 바닥재의 특성 변화와 시멘트 클링커 원료로 재활용 가능성 평가)

  • Lee, Woo Chan;Shin, Deuk Chol;Dong, Jong In
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.103-106
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    • 2014
  • Recycling of bottom ash from municipal solid waste (MSW) incinerator has been strictly limited due to its composition of high level chlorine and other unfavorable substances. The composition of MSW has been, however, changed after the introduction of garbage-bag sales system, extended producer responsibility (EPR) policy and the prohibition of direct landfill of food waste. Recent waste shows reduced moisture and chlorine content, increased calorific value due to the separation of food waste, incombustible materials and PVC. The main purpose of this study is to investigate the trend of composition changes of MSW incinerator bottom ash and to compare the analytical results with those before the separation system was introduced. CaO content of bottom ash, one of the major component of cement clinker, increased from 26.7% in 2001 to 34.0% in 2006. The chlorine content showed a dramatic decrease from 1.84% in 2001 to 0.00655% in 2006, which is closely compatible with that of the fly ash of coal-utilizing thermal power plants, which is mainly due to the changes of MSW composition. It is eventually considered that there is a possibility of utilizing the incinerator bottom ash as a raw material of cement clinker feed substances.

Combustion Study of 1MWe Circulating Fluidized Boiler for RDF (1MWe급 순환유동층 열병합 보일러 운전연구)

  • Shun, Do-Won;Bae, Dal-Hea;Jo, Sung-Ho;Lee, Seung-Yong
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.837-842
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    • 2012
  • A pilot scale circulating fluidized boiler (CFB) for refuse derived fuel (RDF) is designed and constructed to demonstrate a performance of CFB technology for waste fuel utilization. The boiler has a design capacity of 6 MWth with $400^{\circ}C$ 38 ata steam generation performance. The maximum steam rate of the boiler was about 8 ton/h. The main component of the fuel was RDF (Refuse Derived Fuel) with high volatile contents and showed fast ignition and easy combustion. The pilot plant showed over 99.5% of combustion efficiency. Stable operation of RDF CFBC depended on the content of non combustion materials other than ash and fast removal of them. Emission level was under legal limit except that of HCl without external flue gas treatment facilities. Also about 60% of fuel chlorine was absorbed to fly ash particles. For HCl emission control flue gas treatment technology is required such as wet and dry scrubber in order to comply with Korean regulation.