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특집 1 - 해외 수산물 포장재 사용 및 재활용 기술 견학 결과

  • 한국발포스티렌재활용협회
    • 환경사랑
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    • s.57
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    • pp.6-9
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    • 2010
  • 협회 최주섭 부회장은 5월 26일부터 3박4일간 일본 츠키지 농수산물도매시장, 환경박람회 등을 한국해양수산개발원, 수산신문, 자원순환사회연대, 구리농수산물도매시장관리공사, 스티로폴 재활용사업자 등과 함께 민산관 합동으로 수산물상자 사용 및 재활용기술에 대한 현지견학을 다녀왔다. 이번 행사는 선진국의 수산물상자 사용 및 재활용실태를 기초로 하여 귀국 후 관련 전문가 간담회를 개최하여 최근 시설 현대화계획 중인 가락동, 노량진, 구리 농수산물도매시장 등 수도권 농수산물도매시장의 수산물 포장상자의 사용 및 재활용방법에 개선방안을 제시함으로서, 수산물의 유통의 청결 유지, 시장 환경 개선 및 포장상자의 자원화에 기여하고자 하였다.

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수산물표준규격 고시-상품성 향상, 유통효율 제고, 공정한 거래 실현 위해

  • Korea Foam-Styrene Recycling Association
    • 환경사랑
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    • s.48
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    • pp.7-7
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    • 2007
  • 국립수산물품질검사원은 수산물의 상품성 향상과 유통효율 제고 및 공정한 거래 실현을 위한 수산물표준규격을 지난 1월 22일 고시한 바 있다. 고시는 어종의 표준거래단위, 수산물의 포장치수, 포장재료 및 포장재료의 시험방법 등을 규정하고 있다. 고시에 따르면 포장재료는 식품위생법에 따른 용기.포장의 제조방법에 관한 기준과 그 원재료에 관한 규격에 적합하여야 한다. 고시 된 표준포장규격과 포장재료 중 P.S.대(폴리스티렌대)의 규격은 아래와 같다

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Flame Retardancy and Foaming Properties of the Waste-Polyethylene(W-PE)/Waste-Ethylene vinyl acetate copolymer(W-EVA) Blend Foams (폐폴리에틸린/폐에틸렌 비닐아세테이트공중합체 블렌드 발포체의 난연 및 발포 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.38 no.4
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    • pp.316-325
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    • 2003
  • The blends of waste-polyethylene (W-PE)/waste-ethylene vinyl acetate copolymer (W-EVA) with inorganic and phosphorous flame retardants (i.e., aluminium hydroxide, magnesium hydroxide, and so on) were prepared by melt mixing techniques at different compositions and foamed. The flame retardancy and foaming properties of the blends, limiting oxygen index (LOI), heat release rate (HRR), carbon monoxide yield (COY), total heat release (THR), effective heat of combustion (EHC), expandability and cell structure were investigated using cone calorimeter, SEM, LOI tester and polarizing microscope. When the composition ratios of the W-PE/W-EVA blends were 50/50 (w/w), and the ranges of the flame retardants contents were $175{\sim}220 phr$, we could obtain foams with the uniform and closed cell, high expandability (1900 % or more), high LOI, and low HRR values. These results depend on crosslinking and loaming conditions, a char formation and smoke suppressing effect. Aluminium hydroxide had more effect in the increase of LOI than magnesium hydroxide, while magnesium hydroxide considerably affected the decrease of HRR and COY.

A Basic Study on Light-weight Concrete Using Wasted Form Polyurethane (폐발포 폴리우레탄이 혼입된 경량 콘크리트의 기초적 연구)

  • Park, Sang-Hyo;Lee, Seong-Gyu;Lee, Min-Hi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.356-362
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    • 2016
  • Light-weight concrete uses forming agents for reducing weight and high heat insulation property. However, the forming agents make problems of decreased volume and compressive strength of the concrete. This research aims to having weight-reduction and securing heat insulation property using recycled wasted form polyurethane without any forming agents. A small quantity of admixture used for constructability and avoiding material segregation. We picked admixtures from two different companies which shows evenly dispersed of wasted form polyurethane. This research conducts a study on the effect of mixing ratio of admixture on the light-weight concrete used wasted form polyurethane. As a result of the test, increased mixing ratio of the admixtures results reduced fluidity of concrete. On the other hand, percentage of moisture content and compressive strength are increased slightly. Combustibility performance and sound insulation performance are also secured, as well.

Effects of Diffusibility of Bubbling Tablet Herbicide Formulations for Paddy Rice (수도용 발포성정제 제초제의 확산성에 미치는 영향)

  • Kim, Man-Ho;Ryang, Kwang-Rok;Lee, Chang-Hyeuk;Shim, Jae-Weon;Kim, Kyung-Hyun;Yoon, Cheol-Su;You, Yong-Man;Pyon, Jong-Yeong
    • The Korean Journal of Pesticide Science
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    • v.9 no.4
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    • pp.401-410
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    • 2005
  • A series of studies involving formulation processes, bubbling activity test, diffusibility test and biological efficacy test was undertaken to develop Jumbo herbicide formulations in paddy rice field. Gas evolution speed from the tablets prepared by different organic acids was in the order of oxalic acid, malonic acid, citric acid, and tartaric acid. The total volume of evolved gas from the tablet and diffusibility of the active ingredient in the submerged water were increased with increase of water temperature; the volume from 1 g of tablet at 10, 15, 25 and $30^{\circ}C$ for 5 minutes after immersion into water was 20, 25, 28, 45, 57 mL, respectively. The concentration of halosulfuron-methyl and pyriminobac-methyl in submerged water at 5, 15, 20 and $30^{\circ}C$ at the 2.4 m distance from the applied spot of the tablet was 20, 48, 85, and 97% of the concentration of treated spot, respectively. The evolved gas volume from the tablets was not affected by pH of submerged water. The concentration of halosulfuron-methyl in different sizes of submerged water within 24 hours after treatment of the tablet was maintained 0.16 ppm, which is ideal concentration at standard dosage regardless of the submerged water area. The concentration of pyriminobac-methyl was also uniformly dispersed in the water within 24 hours after applying it into the submerged water. The wind velocity of 5 m $sec^{-1}$ on concentration distribution of halosulfuron-methyl and pyriminobac-methyl in the submerged water 24 hours after treatment was not influenced; an equal concentration in the up the wind and down the wind from the applied spot was maintained. Spot treatments of one tablet formulations(5 g) including 4 times higher dosage at 4 different spots resulted in even concentration distribution of active ingredient in the water 24 hours after applying it into the submerged water.

Dependence of physical properties of artificial lightweight aggregates upon a flux and a bloating agent addition (인공경량골재 특성의 발포제 및 융제 첨가 의존성)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.1
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    • pp.48-53
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    • 2009
  • The effect of bloating and fluxing agent on the microstructure and physical properties were studied in manufacturing the artificial lightweight aggregates of bulk density below] using clay and stone sludge. In case of the aggregates added only with bloating agent, the bulk density and water absorption were $0.5{\sim}1.0$ and $41{\sim}110%$ respectively but the microstucture was not uniform with a rough appearance. For the aggregates added with a fluxing agent and one bloating agent, a part of shell was lost due to explosion of specimen caused by over-bloating during a sintering. The mixed addition of bloating agents with vacuum oil, carbon and ${Fe_2}{O_3}$ made the microstructure homogeneous by generating an uniform black core and shell structure. The aggregates added with mixed agents and sintered at $1200^{\circ}C$ showed the bulk density 67 % lower and water absorption 48 times higher than those of the specimen with no additives. ]n this study, the artificial lightweight aggregates showing the bulk density of $0.5{\sim}1.0$ and water absorption of $50{\sim}125%$ could be fabricated to apply to various fields.

Investigation of Compressive Strength and Foaming Characteristics of Acid Anhydride Epoxy Foam by Foaming Agent (발포제에 따른 산무수물계 에폭시 폼의 압축강도 및 포밍특성 분석)

  • Kwon, Dong-Jun;Kim, Jong-Hyun;Park, Sung-Min;Kwon, Il-Jun;Park, Joung-Man
    • Composites Research
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    • v.31 no.4
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    • pp.133-138
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    • 2018
  • Polymer foams were used to fill the void in the structure in addition to flame retardant and heat insulation. Polymer foams such as polyurethane, polyisocyanurate, poly(vinyl chloride), polyethylene terephthalate were used to weight lighting materials. In this study, epoxy foam was used to improve mechanical properties of polymer foam. Acid anhydride type hardener reacts with polyol. Using this phenomenon, if blowing agent was added into epoxy resin using acid anhydride type hardener, formation and compressive properties of epoxy foam was studied. Formation of polymer foam was compared with type of blowing agent and concentration of blowing agent via compressive test. As these results, optimized condition of epoxy foam was found and epoxy foam had better compressive property than other polymer foam.

충격흡수용 Net 형상 Al Foam 제조기술

  • Yu, Yong-Mun;Kim, Dong-Ok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.17.2-17.2
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    • 2009
  • Al Foam 소재는 다공질 금속으로써 저밀도 및 우수한 충격에너지 흡수능으로 최근 새로운 기능성 재료로 부상하여 세계 각국에서 연구개발이 활발하게 진행되고있다. 특히 이러한 Al Foam재를 자동차용 부품의 충격흡수재로사용할 경우 뛰어난 충격흡수능으로 인해 고안전 차량 부품 개발에 획기적인 기술 적용이 기대된다. 그러나, 종래 Al Foam재를 기계부품 등에 삽입할 경우 발포금속을 제조하여 부품 형상에 따라 가공하여 삽입하였으나 이는 공정 중 추가적인 기계 가공 및 비용이 들며 이에 따라생산성이 떨어지는 단점이 있었다. 따라서 본 연구논문에서는 차량용 충격흡수 부품 제작에있어 추가적인 가공 및 공정 수를 줄일 수 있는 Y-프로세스라는 주조공법을 적용하여 Net 형상 Al Foam재를 제작하였다. Y-프로세스는 Al Foam 금속 용탕이 주형에 투하되었을 때 Net 형상의 주형을 용탕 내 삽입하여 금속 용탕의 발포 및 응고시 Net 형상을따라 발포 및 응고가 되도록 하여 Net 형상의 Al Foam이삽입된 부품을 만드는 공법을 말한다. Y-프로세스로제조된 Al Foam재는 주형 내 완전히 충진되지는 못하였으나 주형내 충진된 Al Foam재의 상하부 셀크기가 비교적 균일한 모습을 나타내어 향후 공정제어를 통해 우수한 품질의 Net 형상 Al Foam 제조가 가능함을 알 수있었다.

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FMC법(法) 적용사례

  • Kim, Jeong-Ho
    • Journal of Korea Foundry Society
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    • v.5 no.3
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    • pp.47-51
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    • 1985
  • FMC(FULL MOLD CASTING)법(法)이란 발포 polystyrene모형을 사용하여 조형후, 주형으로부터 모형을 발형치 않은채, 용탕을 주입하여 주물을 제조하는 방법을 말한다. 합성수지 발포체를 주조용(用) 모형의 재료로써 사용하는 방법은 1956년 미국의 슈로이어(H. F. Shroyer)에 의하여 발명되었으나 이것은 실제 주조에 응용하기에는 여러 곤란한 문제가 있어, 단순히 착상에 그치고 공업적으로 적용할 수 있는 기술을 확립치는 못하였다. 그후 서독 아헨대학교수로서 당시 발포폴리스티렌을 포함하는 각종단열재 제조회사 G+H 사(社)의 A. Wittmoser에 의하여 1962년에 처음으로 공업적으로 이용되어, 현재 서독, 미국, 일본등 유럽전역에서 응용되고 있다. 당사(當社)는 1977년6월 5일 첫 가동된 이후, 동(同)그룹 사(社)인 현대자동차로부터 자동차금형 (Press Die)주조를 FMC법(法)으로 생산하여 달라는 요구를 받고, 그해 12月부터 개발시험에 착수하여 이듬해 6월(月)부터 본(本) FM주조를 적용하여왔다. 그러나 1) 폴리스티렌 모형의 주입시(時) 부(不)기화 잔유물에 의한 주물표면결함 2) 도형제 박리 현상에 의한 표면결함 3) 주입시(時) 다량의 매연발생 및 4) 조형시(時) 모형의 변형에 의한 칫수결함 등의 문제가 대두되어 품질면에서는 1982년6월(月)에 와서야 어느정도 정상궤도에 도달하여 본격적인 FM 생산을 해오고 있는 중이다. 여기서 그동안 당사가 경험한 대형주물 (자동차금형:$1{\sim}10$톤/개)에 있어서의 FM 주조법의 적용사례를 본지(本誌)를 통하여 간단히 소개하고자 한다.

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Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).