• Journal of the Korean Electrochemical Society
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• v.19 no.1
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• pp.21-27
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• 2016

Vanadium redox flow batteries (VRFBs) using the electrolytes containing various vanadium ions in sulfuric acid as supporting solution are one of the energy storage devices in alternatively charging and discharging operation modes. The positive electrolyte contains $V^{5+}/V^{4+}$ and the negative electrolyte $V^{2+}/V^{3+}$ depending on the operation mode. To prevent the mixing of two solutions, proton exchange membranes are mainly used in VRFBs. Nafion 117 could be the most promising candidate due to the strong oxidative property of $V^{5+}$ ion, but causes high crossover of electroactive species to result in a decrease in coulombic efficiency. In this study, the composite membranes using Nafion ionomer and porous polyethylene substrate were prepared to keep good chemical stability and to decrease the cost of membranes, and were compared to the properties and performance of the commercially available electrolyte membrane, Nafion 117. As a result, the water uptake and ionic conductivity of the composite membranes increased as the thickness of the composite membranes increased, but those of Nafion 117 slightly decreased. The permeability of vanadium ions for the composite membranes significantly decreased compared to that for Nafion 117. In a single cell test for the composite membranes, the voltage efficiency decreased and the coulombic efficiency increased, finally resulting in the similar energy efficiency. In conclusion, the less cost of the composite membranes by decreasing 6.4 wt.% of the amount of perfluorinated sulfonic acid polymer due to the introduction of porous substrate and lower vanadium ion permeability to decrease self-discharge were achieved than Nafion 117.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.46-46
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• 2000

과학기술 및 산업의 발달로 인하여 실험 중 또는 공정 상에서 in situ, 실시간으로 측정하고 분석하며 이를 되먹임하는 품질제어의 중요성이 대두되고 있다. 반도체 공정 또는 박막제조 공정 중에서 박막의 두께, 굴절율, 물질의 조성비 등을 알아내는 것이 긴요한 과제로 대두되고 있으며, 이를 위하여 공정중인 제품의 품질을 실시간으로 평가하는 장비가 요구되고 있는 것이다. 나아가 공정중의 예상하지 못한 시료의 특성변화를 그대로 감지하여 적절히 보정해 주는 되먹임 기법은 높은 수율을 보장하는 첨단기법이라 할 수 있다. 이러한요구에 부응할 수 있는 본 제품(Elli-situ 2000)은 박막의 두께 표면변화를 sub 의 정밀도를 가지고 in situ, 실시간으로 정밀 측정할 수 있는 첨단 계측장비로서 빛의 편광상태 변화를 측정하기 때문에 공정 중의 시료에 영향을 주지 않는 비간섭 특성과 비접촉 특성의 장점 뿐만 아니라 공기중에서는 물론 진공이나 액체 등의 매질에서도 사용될 수 있어서 매질에 대한 제약이 거의 없다는 장점도 가지고 있다. 편광상태의 제어 및 측정을 필요한 광학장비의 경우, 제작이 까다롭기 때문에 대부분 가격이 높은 편이고 사용방법이나 측정 데이터에 대한 해석이 어렵다는 단점이 있으나, Elli-situ 2000의 경우 상용화된 외국제품(국내제품은 없슴)과 비교하여 성능 및 가격경쟁력에 있어서도 우위에 있으며 간단, 명료한 장비조작 및 컴퓨터를 사용한 구동의 전자동화를 이룸으로써 초보자도 쉽게 측정하고 데이터를 처리할 수 있도록 하였다. 또한 취부대의 경우, 진공포트 플랜지의 표준규격(2-3" Del-Seal 플랜지 규격)에 맞춤으로써 기존의 진공챔버에 부착하여 진공에 전혀 영향을 주지 않는 상태에서 시료의 변화를 in situ, 실시간으로 정밀 측정할 수 있도록 하였다. 하였다.O 박막은 산소 가스압력과 기판온도, 인가 전류를 변화시켜가며 증착하였으며 이에 따른 박막의 결정성 변화를 알아보았다. 기판온도를 실온에서 점차 증가시켜나가면 $\Delta$$\theta$50은 급격히 감소하며 30$0^{\circ}C$에서는 결정성이 우수한 막을 얻을 수 있었다. 또한 산소 가스 압력이 0.5~1mTorr에서 $\Delta$$\theta$50은 양호한 값을 나타내었지만 그 이상에서는 c-축 배향성이 나빠짐을 확인하였다. 따라서 대향타겟식스퍼터 장치를 이용하여 ZnO 박막을 증착시 가스압력 0.5~1mTorr, 기판온도 20$0^{\circ}C$이상의 막 제작조건에서 결정성이 우수하게 나타나는 것을 확인할 수 있었다. gluten이 단단해졌음을 알수 있었다. 유화제 stearly 칼슘, 혹은 hemicellulase를 amarans 10% 대체한 밀가루에 첨가하면 확연히 비용적을 증대시킬 수 있다는 사실을 알 수 있었다. quinoa는 명아주과 Chenopodium에 속하고 페루, 볼리비아 등의 고산지에서 재배 되어지는 것을 시료로 사용하였다. quinoa 분말은 중량의 5-20%을 quinoa를 대체하고 더욱이 분말중량에 대하여 0-200ppm의 lipase를 lipid(밀가루의 2-3배)에 대하여 품질개량제로서 이용했다. 그 결과 quinoa 대량 7.5%에서 비용적, gas cell이 가장 긍정적 결과를 산출했고 반죽의 조직구조가 강화되었다. 또 quinoa 대체에 의해 전분-지질 복합제의 흡열량이 증대된 것으로부터 전분-지질복합제의 형성 촉진이 시사되었다.이것으로 인하여 호화억제에 의한 노화 방지효과가 기대되었지만 실제로 빵의 노화는 현저히 진행되었다. 이것은

• Transactions of the KSME C: Technology and Education
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• v.3 no.4
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• pp.285-290
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• 2015

Oxy gasification was performed for the production of high quality syngas from the waste. $CO_2$ was used as reactant with $O_2$ for $CO_2$ gasification and greenhouse gas reduction. Therefore, gasification was performed at high temperature of $1000-1400^{\circ}C$. RPF was gasified in the thermobalance and 0.5 ton/day pilot plant gasifier. Weight variation with temperature and CO production by Boudouard reaction were studied for $CO_2$ gasification of RPF in thermobalance reactor. Syngas of high $H_2$ concentration was produced from oxy gasification in 0.5 ton/day pilot system, which showed appropriate $H_2$/CO ratio for the production of transport fuel and chemical products.

• Korean Journal of Construction Engineering and Management
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• v.4 no.4 s.16
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• pp.173-181
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• 2003

During the last few years, the use of Pre-tensioned spun high strength concrete piles(PHC pile) has been gradually increased in many construction sites. Cutting work of the concrete pile is an important task to crush a part of pile head which is compressed with more than 800$\cal{kg}f/cm^2$. It is usually performed by a crusher and three to four skilled workers. Recent analysis results of the pile cutting work reveal that it frequently makes a lot of cracks which significantly reduce the strength of the pile and is labor-intensive work. The primary objective of this study is to propose conceptual designs for developing an automated pile cutting machine. It is anticipated that the development of the automated pile cutting machine would be able to bring improvements in safety, productivity, quality as well as cost saving.

• The Journal of Engineering Geology
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• v.28 no.1
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• pp.25-34
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• 2018

The physical properties and unsaturated characteristics of acid sulfate soils were investigated and analyzed. As the results of measuring physical properties of the acid sulfate soils obtained around the Ilkwang mine area, the dry unit weight is $1.246t/m^3$ and this soil is classified into the silty sand (SM) by USCS. Soil Water Characteristics Curves (SWCC) of the drying and wetting paths were measured by the automated SWCC apparatus. Also, Hydraulic Conductivity Functions (HCF) of the drying and wetting paths were estimated by the van Geunchten (1980) model which is the most well-known parameter estimation method. The hydraulic conductivity of acid sulfate soils in the dry path was continuously decreased with increasing the matric suction. However, the hydraulic conductivity in the wetting path was decreased relatively small with increasing matric suction and decreased suddenly just before water entry value of matric suction. Meanwhile, the hysteresis phenomenon was occurred in SWCCs and HCFs during the drying and wetting paths.

• Korean Journal of Food Science and Technology
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• v.22 no.4
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• pp.479-485
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• 1990

For the automation of a evaporation process, computer based evaporation system was built and applied to acquisition of the process variables with an centrifugal thin film evaporator(Centri-Therm, CT-1B). Controls of the process conditions were performed by computer system for pressure, feeding rate, steam, evaporation temperature and flow rate of cooling water. The data acquisitions were also performed by computer system for the changes in the concentration and temperature readings for steam, evaporation and cooling water at the both inlet and outlet. The control and the acquisition variables were collected through the interface device and analyzed by programs using the PASCAL language. To control the feeding rate during the concentration process, inverter was used. The cooling water for the vapor condensation was controlled by the valve controller and should be supplied with the flow rate of 125 kg/h. The maximum vapor condensation rate was 41.7kg/h at the feeding rate of 125 kg/h.

• Journal of Navigation and Port Research
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• v.40 no.6
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• pp.361-368
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• 2016

A ship's rolling motion can make crew and passengers sick and/or apply forces to the structure that cause damage.. Therefore bilge keels are equipped in most ships for anti-rolling. In special cases, anti-rolling tanks (ARTs), fin stabilizers, or gyroscopes can be installed. However, ARTs require a large area to install, and fin stabilizers and gyroscopes are costly to install and expensive to operate. This paper suggests a Anti-rolling pendulum (ARP) to reduce roll motion. ARPs acts like ARTs. However, the ARP has a circular shaped guidance arc instead of the string or wire of a simple pendulum. The device suggested has about 1/ 8 the weight and 1/ 6 the volume of a ART and is more effective. This study derives the nonlinear and linear differential equations of system motion.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.9
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• pp.613-620
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• 2016

In order to scrutinize the fluid conductivity effects on the electromagnetic flowmeter(EMF) characteristics, a small scale EMF was designed and fabricated. The measuring tube has a $3mm{\times}4mm$ rectangular cross-section, 9 mm length, and a $2mm{\times}3mm$ plate electrode and a ${\Phi}1.5mm$ point electrode. The design parameters, such as the magnetizing frequency and the number of coil turns, and the diameter were optimized. The EMF was tested with a gravimetric calibrator and showed good linearity in the range of 0 to $1.17{\times}10^{-5}m^3/s$. The fluid conductivity was varied between 3 and $11{\mu}S/cm$, and the magnitude of the flow signal was proportional to the fluid conductivity and the wetted area of the electrode. The design information and the test results provide flow measurement techniques for very low flowrate.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.24 no.5
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• pp.543-551
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• 2011

The paper deals with the comparative study of design optimization based on various approximation techniques in strength design of riser support structure installed on floating production storage and offloading unit(FPSO) using offshore operation loading conditions. The design optimization problem is formulated such that structural member sizing variables are determined by minimizing the weight of riser support structure subject to the constraints of structural strength in terms of loading conditions. The approximation techniques used in the comparative study are response surface method based sequential approximate optimization(RBSAO), Kriging based sequential approximate optimization(KBSAO), and the enhanced moving least squares method(MLSM) based approximate optimization such as CF(constraint feasible)-MLSM and Post-MLSM. Commercial process integration and design optimization(PIDO) tools are employed for the applications of RBSAO and KBSAO. The enhanced MLSM based approximate optimization techniques are newly developed to ensure the constraint feasibility. In the context of numerical performances such as design solution and computational cost, the solution results from approximate techniques based design optimization are compared to actual non-approximate design optimization.

• Proceedings of the Korean Geotechical Society Conference
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• 2010.03a
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• pp.1452-1457
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• 2010

Recently, coal ash is used as resources to make controlled low-strength material (CLSM) which a self-compacted, cementitious material used primarily as a backfill in lieu of compacted fill. Pozzolanic reaction is strongly related with self-cementation of coal ashes. However, this reaction depends on pozzolanic content in fill materials and is disappeared in 2-3 days after placement of coal ash fill. Therefore, state of coal ash fill is commonly very loose and not appropriate for foundations of structures without special treatments. In this study, a coal ash placement device was developed to place coal ashes effectively to improve density of coal ash fills. The device consists of a ribbon type mixer to obtain homogeneous materials mixture and a piston type pump for density control of fill materials. Based on several laboratory test results, more stable coal ash fill state can be obtained with controlling placement pressure.