• Journal of Soil and Groundwater Environment
• /
• v.9 no.4
• /
• pp.1-7
• /
• 2004

To choose a organic acid and in-organic acid composite which is the most effective in soil-flushing process cleaning lead-contaminated sites, lead removal rates were investigated in the experiments with some organic acids; 0.01M of EDTA showed the highest lead-extraction rate ($69.4\%$) compared to the other organic acids. Furthermore, the lead removal rates were measured with 0.01M of EDIA and 0.1M of in-organic acid ; a EDTA and boric acid composite showed the highest lead-extraction rate ($68.8\%$) at pH5 compared to the other composites. As the concentration of boric acid was increased from 0.1M to 0.4M in a 0.01M of EDTA and boric acid composite, lead removal rate was decreased from $68\%\;to\;45\%$. But as the concentration of EDTA was increased from 0.01M to 0.04M in a EDTA and 0.1M of boric acid composite, permeability was decreased from $6.98{\times}10^{-4}cm/sec$ (0.01M of EDTA) to $5.99{\times}10^{-4}cm/sec$ (0.04M of EDTA). However, permeability was increased from $4.41{\times}10^{-4}cm/sec$ (0.03M of EDTA) to $6.26{\times}10^{-4}cm/sec$ (0.03M of EDTA and 0.1M of boric acid composite). indicating EDTA could increase lead dissolution/extraction rate and decrease permeability. In this system, lead remediation rate is the function of lead dissolution rate from soils and permeability of the composite into soils, and the optimized [EDTA]/[Boric acid] ratio is [0.01M]/[0.1M].

• Journal of Korea Soil Environment Society
• /
• v.5 no.2
• /
• pp.67-85
• /
• 2000

Fifty seven soil samples were collected from the paddy soil filled with tailings in the vicinity of the Seosung Pb-Zn mine. Those samples were analyzed for As, Cd, Co, Cr, Cu, Pb, and Zn in order to investigate heavy metal pollution levels in the paddy soil. Analyses of the soil samples were carried out using Inductively Coupled Plasma Atomic Emission Spectrometry(ICP-AES) . Paddy soils show pH range from 6.55 to 8.26. X-ray diffraction analyses of the paddy soil indicate that the soils consist predominantly ankerite, siderite, quartz, mica, and clay minerals with minor amounts of amphibole and chlorite. The mineral composition of the waste rocks consists of massive galena, sphalerite, and minor amounts of pyrite, arsenopyrite, chalcopyrite, calcite, siderite, Pb-sulfosalt, and marcasite. The paddy soils were significantly contaminated by heavy metals(average concentrations, As: 334.4 ppm, Cd: 37.6 ppm, Co: 15.7 ppm, Cu: 214.1 ppm, Pb: 4,612 ppm, and Zn: 4,468 ppm).

• Journal of Korean Society of Environmental Engineers
• /
• v.32 no.7
• /
• pp.682-689
• /
• 2010

The purpose of this study was to determine any detrimental effects on surrounding environments by using bottom ash, waste tire, and mixture as a fill material to raise the ground level. Three different initial pHs (4, 6, 8) were applied to bottom ash and initial pH of 4 was used to waste tire and mixture. Among 7 heavy metals, Pb and Zn were exceeded drinking water standards but their concentrations decreased below drinking water standards within 1 PVE. Among 5 anions, sulfate exceeded 10 times of drinking water standards and further higher partition coefficients resulted in increased PVE of 8.21. For the mixture of bottom ash and waste tire, its concentrations of heavy metals and anions were decreased due to the dilution effect and lowered PVE from 8.21 (BA) to 5.89.

• Journal of Korea Soil Environment Society
• /
• v.3 no.1
• /
• pp.75-81
• /
• 1998

In most of studies on solidification/stabilization with waste, small columns have been used to examinate adsorption or leachate. However, these experiments using small apparatus have been limited to apply with the field. In this study, considering an application to the field, a large Lysimeter(100cm$\times$100cm$\times$100cm) used for the simulation. Then, the open dumping waste was mixed directly with bentonite to simulate the stabilization of waste, environmental aspects and several basic tests. As a result, the concentration of heavy metals and contaminated substances changed with bentonite rate. Most of contaminated substances were decreased in leaching with increased mixing rate of bentonite. Especially, the concentration of CODcr removed 25~30%. Also, the residual soil in dumping waste produced approximately 80% of total volume by 40$\times$40mm screen.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.4
• /
• pp.377-389
• /
• 2020

In this study, pollution characteristics were investigated for the Andong Dam sediments in the Nakdong River. Sediment samples were collected from the middle, left, and right points of the lake up to 40km upstream of the Andong Dam at intervals of about 5km by stratification and turnover period. In the case of nutrients and total organics such as loss of ignition, total nitrogen, and phosphorus, the degree of contamination is low, but heavy metals of arsenic and cadmium is very high. The contamination level of sediments in the dam area is higher than that of the branch of river and the control group, and concentration of chromium, copper, and lead are higher in the stratification period, and that of zinc is higher in turnover period. Arsenic, cadmium, manganese, and zinc showed contamination variation between upstream and downstream but chromium, copper, mercury, iron and lead didn't show the variation.

• Journal of the Mineralogical Society of Korea
• /
• v.23 no.2
• /
• pp.125-139
• /
• 2010

Behavior of heavy metals and arsenic in the tailings of Songcheon Au-Ag mine was characterized via both mineralogical and geochemical methods. Mineral composition of the tailings was investigated by X-ray diffractometry, energy-dispersive spectroscopy, and electron probe micro-analyzer (EPMA) and total concentrations of heavy metals and arsenic and their chemical forms were analyzed by total digestion of aqua regia and sequential extraction method, respectively. The results of mineralogical study indicate that the tailings included mineral particles of resinous shape mainly consisting of galena, sphalerite, pyrite, quartz, and scorodite, and specifically socordite was identified in the form of matrix. EPMA quantitative analyses were performed to evaluate the weatherability of each mineral, and the results suggest that it decreased in the sequence of arsenopyrite > galena > sphalerite > pyrite. The weathering pattern of galena was observed to show distinctive zonal structure consisting of secondary minerals such as anglesite and beudantite. In addition, almost all of arsenopyrite has been altered to scorodite existing asmatrix and galena, sphalerite, and pyrite which have lower weatherability than arsenopyrite were identified within the matrix of scorodite. During the process of alteration of arsenopyrite into scorodite, it is likely that a portion of arsenic was lixiviated and caused a great deal of detrimental effects to surrounding environment. The results of EPMA quantitative analyses verify that the stability of scorodite was relatively high and this stable scorodite has restrained the weathering of other primary minerals within tailings as a result of its coating of mineral surfaces. For this reason, Songcheon tailings show the characteristics of the first weathering stage, although they have been exposed to the surface environment for a long time. Based on the overall results of mineralogical and geochemical studies undertaken in this research, if the tailings are kept to be exposed to the surface environment and the weathering process is continuous, not only hazardous heavy metals, such as lead and arsenic seem to be significantly leached out because their larger portions are being partitioned in weakly-bound (highly-mobile) fractions, but the potential of arsenic leaching is likely to be high as the stability of scorodite is gradually decreased. Consequently, it is speculated that the environmental hazard of Songcheon mine is significantly high.

• Korean Journal of Environmental Agriculture
• /
• v.29 no.2
• /
• pp.152-158
• /
• 2010

Biosorption is considered to be an alternative method to replace the present adsorbent systems for the treatment of metal contaminated wastewater. In this study, by-product which was abandoned from brewing factory was used to remove metal component in aqueous solution. The experimental results showed that the range of the removal efficiency is 60~91% and adsorption equilibrium was reached in about 3 hr. FT-IR and stereo microscope has been used to observe the surface conditions and changes in functional groups by calcination. At the end of elution, the amount of nitrogen and phosphorus in water was increased 11 and 7 times compare raw sample to calcinated samples. The Langmuir isotherm adequately described the adsorption of waste materials and the maximum adsorption capacity was 28.17 mg/g for Cd. The overall results suggested that waste material might can be used for biosorption of Cd.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.9 no.2
• /
• pp.71-76
• /
• 2001

Recently, sludge disposal becomes one of the most serious environmental problems. Because the landfilling and ocean dumping of sludge materials will be prohibited in the near future, the proper treatment?disposal methods should be investigated. Also, oyster shells, piled at the coast, cause adverse effects in coastal fishery, public water surface, natural landscape, public health and so on. Thus, the purpose of this study is to evaluate the dissolution characteristic of metal compounds during soil application experiment using sewage treatment sludge mixed with oyster shells. The dissolution experiment conducted 100days under artificial rainfall and farming soil, mixed with sewage treatment sludge and oyster shells, was put into the pots(approx. 0.5L). The results from dissolution experiment as follows. 1. K, Na was $5{\sim}20mg/{\ell}$, and Ca was less than $90mg/{\ell}$. 2. Heavy metals such as Cd, Cu, As, Pb, Cr, Hg are dissoluted far less than the soil pollution guideline. The application of sewage sludge mixed with oyster shells increases pH(soil acidity)and buffer capacity(CEC) of farming soil, and heavy metals are thought to be attached to soil as insoluble forms.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.3
• /
• pp.345-351
• /
• 2008

Fe-impregnated activated carbon(Fe-AC) was prepared by Fe(III) loading on activated carbon(AC) in various preparation pH. In order to evaluate the stability of Fe-AC, dissolution of iron from Fe-AC in acidic conditions was measured. In addition, batch experiments were conducted to monitor the removal efficiency of copper by Fe-AC. Results of stability test for Fe-AC showed that the amount of extracted iron increased with contact time but decreased with increasing solution pH. The dissolved amount of iron gradually increased at solution pH 2 and finally 13% of the total iron loaded on activated carbon was extracted after 12 hr. However dissolution of iron was negligible over solution pH 3. Removal of Cu(II) by Fe-AC was greatly affected by solution pH and was decreased as solution pH increased as well as initial Cu(II) concentration decreased. Surface complexation modeling was performed by considering inner-sphere complexation reaction and using the diffuse layer model with MINTEQA2 program.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.24 no.3
• /
• pp.107-112
• /
• 2018

The purpose of this study was to investigate the migration levels of lead (Pb), cadmium (Cd) and arsenic (As) from polycarbonate food contact materials into food simulant at different temperatures ($70^{\circ}C$ and $100^{\circ}C$). The method was validated by linearity of calibration curves, limit of detection (LOD), limit of quantification (LOQ), recovery, precision and uncertainty. All of 200 samples, including bottles, cups, containers, ladles, spoons and tongs were purchased from domestic markets and analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Mean concentrations of positive samples were higher at $100^{\circ}C$ than $70^{\circ}C$ as showing a dependency of migration temperature. The migration concentrations ranged from not-detected (ND) to $4.67{\mu}g/L$, ND to $0.49{\mu}g/L$L and ND to $2.91{\mu}g/L$ for Pb, Cd and As, respectively, which were far below the migration limits of Korea standards and specifications for food utensils, containers and packages.