• Title/Summary/Keyword: 중금속 분석

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A study of origins and characteristics of metallic elements in PM10 and PM2.5 at a suburban site in Taean, Chungchengnam-do (충청남도 태안 교외대기 PM10, PM2.5의 중금속 농도 특성과 기원 추적연구)

  • Sangmin Oh;Suk-Hee Yoon;Jaeseon Park;Yu-Jung Heo;Soohyung Lee;Eun-Jin Yoo;Min-Seob Kim
    • Particle and aerosol research
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    • v.19 no.4
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    • pp.111-128
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    • 2023
  • Chungcheongnam-do has various emission sources, including large-scale facilities such as power plants, steel and petrochemical industry complexes, which can lead to the severe PM pollution. Here, we measured concentrations of PM10, PM2.5, and its metallic elements at a suburban site in Taean, Chungcheongnam-do from September 2017 to June 2022. During the measurement period, the average concentrations of PM10 and PM2.5 were 58.6 ㎍/m3 (9.6~379.0 ㎍/m3) and 35.0 ㎍/m3 (6.1~132.2 ㎍/m3), respectively. The concentration of PM10 and PM2.5 showed typical seasonal variation, with higher concentration in winter and lower concentration in summer. When high concentrations of PM2.5 occurred, particulary in winter, the fraction of Zn and Pb components considerably increased, indicating a significant contribution of Zn and Pb to high-PM2.5 concentration. In addition, Zn and Pb exhibited the highest correlation coefficient among all other metallic elements of PM2.5. A backward trajectory cluster analysis and CPF model were performed to examine the origin of PM2.5. The high concentration of PM2.5 was primarily influenced by emissions from industrial complexes located in the northeast and northwest areas.

Introduction of Clean Techniques for Trace Metal Analysis in Seawater (해수 중의 미량금속 분석을 위한 청결기술의 소개)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Ra, Kong-Tae;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.2
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    • pp.157-164
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    • 2009
  • The metals such as Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc are present at very low concentration in seawater and are classified as so-called trace metals. Whiles some of them are used in metabolism of living organism as a micronutrient, they may show toxic effects on organisms in case of a limited threshold concentration of them Plenty of studies on trace metals have been performed bemuse trace metals have a persistent influence and an adverse effect on marine environment and ecosystem. For long years, when the concentration of trace metals in natural waters such as seawater and fresh water are measured with high precision and accuracy, some systematic errors have been recognized to be present in measurements. Since 1975 in US and European countries, the measured concentration of trace metals in seawater have been found to be lower by factors of 10-1,000 than the previous data of trace metals measurements and the vertical profiles of the measurements have been shown to reflect well-known biological, physical and geochemical processes. These results are attributed to great advances in analytical instrumentation and methodology for trace metals measurements. Precautions against the contamination of samples are required to be taken in the process of sampling, storage, and analysis of samples. However, in Korea, erroneous data of trace metals with regard to ocean and marine environment related survey and investigations are reported The lock of exact understanding and information regarding precautions in sampling, storage and analysis of samples lead to the deterioration of data quality, especially in the analysis of trace metals. The major procedures to obtain the accurate data of trace metals in natural waters are introduced for applying to the study and assessment of marine environments.

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SRF Conversion Potential of Biomass and Mixed Plastic Waste Generated in D City (D시 내에서 발생하는 바이오매스 및 폐플라스틱 혼합 폐기물의 SRF 전환 포텐셜 분석)

  • Yang, Han-Sol;Kim, Ki-Kwang;Lim, Chae-Wook;Hyun, Jae-Hyuk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.3
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    • pp.55-61
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    • 2018
  • This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.

Effects of Distiller Solubles(Bekseju) Application on the Growth of Rice Plant(Oryza sativa L.) and Improvement of Soil Fertility (백세주 주정박이 벼의 생육과 토양비옥도 개선에 미치는 영향)

  • Kim, In-Su;Ryu, Su-Jin;Choe, Yeong-Hwan;Park, Young-Gu;Kim, Gye-Won;Bae, Jung-Ho
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2009.12a
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    • pp.306-306
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    • 2009
  • 본 실험은 백세주 주정박이 벼의 생육과 토양 비옥도 개선에 미치는 영향을 조사하였다. 백세주 주정박은 압착된 주박을 재 발효시켜 단식증류기로 증류하여 알코올을 회수 후 발생된다. 실험 처리구는 무시용, 요소, 주정박 처리구로 하였고, 벼 질소비료 표준시비량 11kg N/10a를 기준으로 하여 전량 기비로 사용하였다. 백세주 주정박의 유효성분과 유해성분을 분석하였고, 토양에 주정박을 시용 전 후의 이화학적 분석을 하였다. 벼 실험 품종은 오대벼(Oryza sativa L.)이고, 벼의 생육과 수량 및 미질을 분석하였다. 백세주 주정박의 pH는 3.60, 유기물함량 90.12%, 염농도 0.72ds/cm, 수분함량 88%, 질소 0.21%, 인산 0.24%, 칼리 0.09%로 나타났다. 유해성분(중금속)분석결과 비소 0.03ppm, 크롬 0.09ppm, 구리0.91ppm, 납 0.05ppm, 니켈 0.05ppm, 아연 1.30ppm, 망간 3.28ppm, 철 34.86ppm로 나타났다. 토양이화학적 분석결과 주정박 시용처리구의 유기물함량과 질소 및 인산은 각각 23.0g/kg. 0.11%, 89mg/kg로 무시용과 요소처리구에 비해 유의한 차이를 보였다. 벼 이식 후 140일째 생육분석결과 초장 82.60cm, 옆폭 1.40cm, 옆장 37.70cm, 지상부건물중 59.21g로 다른 2개 처리구에 비해 유의한 차이를 보였다. 벼의 수량은 주정박 시용 처리구가 449.0kg/10a로 무시용 89.66kg/10a와 요소 401.66kg/10a에 비해 유의적인 차이를 보였다. 백세주 주정박 시용을 통해 토양 개량 효과를 기대할 수 있고, 공시 토양의 토양 개량 효과가 벼의 생육에 긍정적인 영향을 끼치는 것으로 나타남에 따라 백세주 주정박의 토양개량제로서의 활용 가능성을 확인하였다.

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Water Quality and Particle Size Distributions of Road Runoff in Storm Event (강우시 도로유출수 수질특성 및 입경분포)

  • Lee, Jun-Ho;Cho, Yong-Jin;Bang, Ki-Woong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.777-784
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    • 2005
  • The first flush phenomenon is defined as the initial period of road runoff during which the concentration of pollutants was significantly high. Road runoff contains significant loads of micro-particles, heavy metals and organic constituents. There were two major objectives of this study. The first objective was to characterize the road runoff. The second objective was to measure and evaluate particle sire distribution of the road runoff, Stormwater runoff was monitored on two sites of four lane road areas along with traffic volume. A total six storm events were monitored to characterize the road runoff. The quantity of road runoff and quality constituents, including chemical oxygen demand ($COD_{Cr}$), suspended solids(SS), total Kjeldahl nitrogen (TKN), ortho-phosphorus ($PO_4-P$), total phosphorus(TP), heavy metals and particle size distribution were analyzed. The results indicate that the concentration of SS, $COD_{Cr}$, TKN and TP ranges were $45{\sim}2,396\;mg/L$, $40{\sim}931\;mg/L$, $0.1{\sim}19.6\;mg/L$, and $0.2{\sim}25.1\;mg/L$, respectively. The results of the regression analysis between SS and the others constituents shows that $COD_{Cr}$, TP, Cu, Pb were highly correlated. And the results showed that the mean range of particle size and uniformity coefficient for road runoff were $6.7{\sim}23.4{\mu}$ and $6.4{\sim}10.2$, respectively.

Hair Mineral Analysis of People Suffering from Hair Loss According to Their Age and Gender (연령 및 성별에 따른 탈모 모발의 미네랄 함량 분석)

  • So, Young-Jin;Lee, Myung-Ho
    • Culinary science and hospitality research
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    • v.19 no.5
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    • pp.100-109
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    • 2013
  • This study aims to analyze 19 kinds of mineral contents in hair targeting 311 people in Seoul who suffer from hair loss. The results are as follows: 1. The average contents of all kinds of minerals were within the standards. 2. Sodium, potassium, and selenium were more detected in men than in women; calcium, magnesium, copper, and manganese were more detected in women than in men; toxic elements, mercury, antimony, and arsenic were more detected in men than in women, which was statistically significant. 3. As the age increased, potassium (p<.05), iron (p<.01), manganese (p<.05), chromium (p<.01), and mercury (P<0.01) increased gradually, which was statistically significant. In particular, the content of mercury exceeded its standard in those over fifty. 4. Selenium (p<.01), lead (p<.05), aluminum (p<.05), and arsenic (p<.01) were more detected in natural hair than in permanent or colored hair. Calcium (p<.001), magnesium (p<.001), and manganese (p<.01) were more detected in permanent or colored hair than in natural hair. They were all statistically significant.

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Pollutant Content of the Sediments in the Drain Channel of Paved Catchments in Coastal Areas (연안역 불투수지역 배수구 퇴적물의 오염특성에 관한 연구)

  • Kim, Yeon-Seok;Park, Ki-Soo;Kim, Young-Chul
    • Journal of Wetlands Research
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    • v.13 no.3
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    • pp.523-534
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    • 2011
  • In this study, the particle size distribution and pollutants content of sediments collected from different sites in the coastal area of Chungnam province were analyzed. The sediment samples were collected from different parking lots near beaches, harbors, museum and bridges. The particle size distribution analysis showed that the particle is generally $106-500{\mu}m$ and the effective size $D_{10}$ ranges from 40 to $60{\mu}m$ while the $D_{50}$ and $D_{60}$ ranges from 200 to $810{\mu}m$ and 235 to $1005{\mu}m$, respectively. For particle size $D_{10}$, there was no significant difference in all sites. However, for $D_{50}$ and $D_{60}$, the range is large. Sediment analysis implicates that as the particle size decreases, the pollutant content increases. This is because smaller particles have higher specific surface area resulting to have more adsorption capacity. Particles from tires, emission gas from vehicles and dust particles belongs to smaller particles. For particle sizes less than $63{\mu}m$, the analysis showed that as the particles become coarser, the concentration of VS, $COD_{cr}$, TN, and TP is at least 2 to 14 times higher. Cu and Pb were detected in all sites and shows a higher concentration with smaller particle size. Cu concentration are almost the same for all sites but in the case of Pb, the sediments from Sinjindo has higher concentration of up to 2 to 3 times as compared to those collected from the other sites. In the Beach site as well as in the Seocheon Ocean Museum, Cd was contained only in fine particles. However, in Daechon Harbor and Sinjindo Bridge sites, Cd was detected in all the sediment particle size.

Comparison and Analysis on Characteristics for recycling of Multifarious Food Waste (음식물쓰레기의 자원화를 위한 배출업종별 성상 및 특성의 비교분석)

  • Joo, Hung-Soo;Ryu, Jae-Young;Phae, Chae-Gun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.4
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    • pp.117-124
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    • 2001
  • This study was executed for utilizing it as basic data in appropriate recycling way and design by examining and analyzing various characteristics of food waste which is being discharged from various restaurant and apartment house. In general, there were differences in restaurants classification and Japanese restaurant showed big differences as compared to other restaurants. Vegetable had the highest composition and its contents had big difference according to seasons. In alien substances, oyster shells were the highest and restaurants showed high rate of alien substances than apartments, therefore it was required to divide them in advance. Salinity was the highest in Japanese restaurants and most restaurants had rate of up to 1%, so it was not appropriate for recycling. However, it was considered that if there is cleaning operation in the whole process, there might not be a problem. Feed Ingredient had 28% of fiber, 25% of protein, and 11% of fats. We analyzed noxious germs and heavy metal too. However microorganisms of etiological cause were not detected and each harmful material showed less values of control concentration. In the result of analysis of each characteristic, it is required to consider collection rate from restaurants and apartments and seasonal cause into design regarding recycling. And apartments are compatible to compost than feed and food waste from Chinese, flour restaurant and collective feeding facilities are compatible for feed, as it is evaluated.

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Water Quality and Particle Size Distributions of Bridge Road Runoff in Storm Event (강우시 교량도로 유출수 수질 및 입경분포)

  • Cho, Yong-Jin;Lee, Jun-Ho;Bang, Ki-Woong;Choi, Chang-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.12
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    • pp.1353-1359
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    • 2007
  • Water quality constituents, and particle size distributions were characterized in urban bridge road runoff, Bridge road runoff contains significant loads of micro-particles, heavy metals and organic constituents. Bridge road runoff was monitored on four sites of four and six lanes bridge road areas along with traffic volume. A total seven storm events were monitored to characterize the bridge road runoff. The quantity of road runoff and quality constituents, including chemical oxygen demand(COD), suspended solids(SS), total nitrogen(T-N), ortho-phosphorus$(PO_4-P)$, total phosphorus(T-P), and particle size distribution were analyzed. The results indicate that the concentrations of SS, COD, T-N and T-P ranges were $35\sim2,390$ mg/L, $40\sim1,274$ mg/L, $0.03\sim21.25$ mg/L, and $0.05\sim4.58$ mg/L, respectively. And the results showed that the mean range of particle size and $D_{90}$ for bridge road runoff were $4.75\sim14.05{\mu}m$ and $17.33\sim58.15{\mu}m$, respectively.

The Restoration/Revision Processes of the Korean Standard Methods for Marine Environment: Heavy Metals & Organic Compounds (해양환경공정시험기준 제정/개정(안) 작성과정 소개: 중금속과 유기물질 분석 중심으로)

  • JEONG, YONG HOON;LEE, DONG GI;YANG, JAE SAM
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.21 no.2
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    • pp.78-90
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    • 2016
  • This report is to introduce detail processes during the restoration/revision project for the Korean Standard Methods for Marine Environment. The processes are composed of 3 steps: questionaries, QA/QC confirming step by CRM(Certified Reference Materials), and advisory council by specialists. The questionaries required four main topics to be included to the restoration/revision protocol: 1. the guidelines to sampling, transportation, storage, and pre-analytical procedures for the marine specimens, 2. the unified analytical method, especially for the organic compounds, 3. the QA/QC test requirement for CRM, 4. introduction of diverse analytical instruments, 5. the customer- friendly express of the protocol. Based on these new protocol, we expect two most important effects: 1, increased insurance of international credibility and equivalence by the QA/QC procedures, 2. increased conformability and representatively from wide-spread use of the protocol. Finally we suggested several residual topics remained to the inter-government cooperation.