• Title/Summary/Keyword: 중금속 분석

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Analysis of Heavy Metal Concentration on Working Clothes for Waste Incinerating Workers (생활폐기물 소각장 작업복의 중금속 분석)

  • Park, Soon-Ja
    • The Korean Journal of Community Living Science
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    • v.18 no.1
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    • pp.39-53
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    • 2007
  • The purpose of this study was to determine the characteristics of an experimental protective clothing material with regard to comfort and isolation from the hazardous heavy metals produced in municipal waste incineration. An analysis was conducted on the total concentrations of heavy metals in some parts such as surface, middle layer, and interior for the treated fabric, and the untreated one, and working clothes. We conclude that the processed fabric with charcoal for working clothes showed the least exposure to heavy metals of the three. Working clothes worn by workers during waste incineration were much more contaminated than the untreated and treated materials. The material of working clothes could be chosen according to the function with regard to its original chemical characteristics, which are the proper results of the dyeing process. The processed fabric material has high degrees of moisture regain, thermal insulation, water vapor penetration, and antibacterial function; consequently, it is much more comfortable to wear. The fabric material proposed in this research contributed much more to blocking heavy metal concentrations (such as Cd, Pb, Cu, Cr, Zn, Mn) than did the fabric of working clothes at present. Consequently, we strongly suggest that the material of working clothes be upgraded by adopting the above-mentioned charcoal-processed fabric. Materials of working clothes must be improved to increase comfort and prevent harmful gas, flying dust, and heavy metals from permeating the fabrics.

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Characteristics of Specimens Made from Primary Clay and Red Hwangto with MSWI Fly Ash by Sintering Process (Sintering process에 의한 MSWI fly ash를 혼합한 일차점토(一次粘土)와 적황토(赤黃土) 공시체(公試體)의 특성(特性))

  • Yoo, Seung-Chol;Kwon, Moon-Sun;Park, Sang-Min
    • Resources Recycling
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    • v.19 no.2
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    • pp.10-18
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    • 2010
  • This research investigates the feasibility of ceramic specimens made from Primary clay and Red Hwangto with MSWI fly ash. Specimens preduced by mix-design maximum 20 wt% MSWI fly ash were analysed by SEM, UTM, ICP, etc. As a result of measurement,$P_{10}$ specimen was improved on bending strength and $R_5$ specimen was improved on compressive and bending strength. Also amount of extracted heavy metal was suitable for regulatory limits. This indicates that MSWI fly ash is indeed suitable for the partial replacement of ceramic materials in bricks.

New Analytical Method for Separation and Identification of Heavy Metals (I) (중금속의 분리 및 검출을 위한 분석화학적 연구 (제 1 보). 새로운 분리방법의 개발)

  • Kim, Youn-Doo;Bae, Jun-Heon;Shin, Young-Kook
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.231-235
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    • 1987
  • In 10M chloride (4M HCl + 6M LiCl) solution, cobalt, but not nickel, formed complex anion (${CoCl_3}^-$), and this anion was extracted by a liquid anion exchanger with Amberlite LA-2. The ion exchange capacity was 2.175meq of cobalt complex per unit ml of Amberlite LA-2. Upon eluting the resin with 0.4M nitric acid, the cobalt complex was stripped and transfered into eluate quantitatively. By using this separation method in the chloride solution dissolved with 50mg of cobalt (II) and 500mg of nikel(II), recovery of cobalt were 99.6 percent.

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The Study on Pre-treatment Method of Filter for Analysing the Heavy Metals in Air Quality (대기중의 중금속 분석을 위한 여지의 전처리 방법에 관한 연구)

  • 김광래;이상칠;어수미;김민영;신재영;이재영
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2002.04a
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    • pp.16-19
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    • 2002
  • This study was carried out to establish the standardized analysis method in order to decide accurate concentrations of hazardous metals in the air. Acid decomposition method used usually was compared to microwave digestion method. Comparing results of tested background concentration in blank filter, we found that the magnitude of element concentration was Na, Ca, K, Mg, Al and Ba by order. The element concentrations of Glass fiber filter were higher than those of Quartz fiber filter, and the number of undetected components in Glass fiber filter was lower than that in Quartz fiber filter. Thus it is supposed that the concentration of background elements in Glass fiber filter was higher than those in Quartz fiber filter The extraction rate of microwave digestion method was superior to those of acid decomposition method during the test of blank filter as well as SRM of NIST. In case of the SRM of NIST, the average extraction efficiency of acid decomposition Method and microwave pretreatment is 53.8∼82.7%, 81.3∼97.1%, respectively. This result might be caused by the closed system of Microwave, which make outflow and loss of components less. Also microwave digestion method has other merits such as the minimization of time, reagents, and contamination. Furthermore, if the extraction condition, extraction time and used acids are optimized, the better results will be represented.

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Research with Statistical Model to Analyze Efficiency of Heavy Metal Soil Washing (통계학적 모델을 이용한 중금속 토양 세척의 효율 분석에 관한 연구)

  • Oh, Sangyoung;Yoo, Jongchan;Baek, Kitae;Kim, Hanseung;Park, Jaewoo
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.14-24
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    • 2018
  • In soil washing, there are many variables including types of reagent and contaminant, washing time, soil-liquid ratio, washing cycles, washing agent concentrations, and etc. To identify the most influencing factors on soil washing process, regression analysis was performed for eight single variables and five combined variables. A quantitative model that employs W/H (molar ratio of washing agent to heavy metal) as a major variable was established based on the regression. The validity of the model was demonstrated by conducting lab experiments with Cu, Pb, Zn, Ni and As-contaminated soils, and various washing reagents including acetic acid, citric acid, malic acid, oxalic acid, ethylenediamine tetraacetic acid (EDTA) and nitriloacetic acid (NTA). The washing efficiencies were compared with the EDTA washing data reported in the literature. The correlation between W/H and removal efficiency was analyzed after dividing data into two groups according to the heavy metal mobility.

Analysis of Trace Metal in Agricultural Products (농산물 중의 미량금속함량 분석)

  • 박정숙;나환식
    • The Korean Journal of Food And Nutrition
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    • v.13 no.6
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    • pp.595-601
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    • 2000
  • The seven trace metals contents of agricultural products in Kwang-ju were investigated to provide the basic data for its residual limits. Ten kinds of agricultural products (onion, welsh onion, garlic, lettuce, cabbage, pepper, spinach, radish, pear, peach) collected within from Kwang-ju in 1999 were analyzed by Mercury Analyzer for mercury. Inductively Coupled Plasma spectrometer and Atomic Absorption spectrophotometer equipped with Vapor Generation Accessory for Cu, Cd, Mn, Pb, Zn and As. Hg contents were not detected in all samples and As content were detected N.D. ∼0.005 ppm. Cd and Pb contents were detected N.D ∼0.088 ppm and N.D.∼0.096 ppm, respectively, Cu, Mn and Zn contents were 0.109∼1.072 ppm. 0.829∼6.195 ppd and 0.731∼6.176 ppm, respectively. The trace metal concentrations of the agricultural products in Kwang-ju called clean area were within the background level which growth is facilitated.

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Chlorophyll, Mineral Contents and SOD-like Activities of Leeks Harvested at Different Times (부추의 수확시기에 따른 클로로필, 무기질 및 superoxide dismutase 유사활성의 변화)

  • 곽연주;전희정;김정상
    • Korean journal of food and cookery science
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    • v.14 no.5
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    • pp.513-515
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    • 1998
  • This study was performed to determine the contents of mineral and bioactive components in leek samples harvested at different times. Analysis of chlorophyll contents of leek harvested at different times showed the latest one (5th sample) had the highest level among samples. The leek harvested at the earliest (1st) had the highest amount of Fe, f and Cu while 5th sample was highest in Ca, Mn, P, Zn and Na contents. Lead (Pb) was not detected in any leek sample harvested at different times. SOD (superoxide dismutase)-like activity was the highest in leek harvested at the earliest.

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Design and Performance Analysis of Environment Friendly Double Core Bullets for Small Arms (친환경 소화기용 탄심 재료 및 2중 구조 설계 분석)

  • Hong, Jun-Hee;Jang, Tak-Soon;Song, Chang-Bin;Kim, Byung-In
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.2
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    • pp.264-270
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    • 2011
  • This paper focuses on possibility to design and fabrication new combination of bullet core to substitute current toxic material of heavy metal such as lead by environment-friendly ones. The core is designed as dual structure to manipulate the core center of gravity easily by combining materials, which of basis is tungsten of low cost and easily acquired. Those combinations are W-M series such as W-Cu, W-Sn, W-Cu-Sn, and W-Cu-Ni to target the density of lead, $11.34g/cm^3$ through powder-metallurgy. Out of four, combination of W-Cu-Ni shows the highest compression density of 96% and is confirmed as the most suitable substitution for lead due to the excellent property of matter and sintering. All combination samples is simulated on the PRODAS software for designing and structure analysis by adjusting the center of gravity of dual core samples forward and backward. The simulations confirm the similarity of current bullet core with respect to properties of mass, aero dynamics, and flying stability.

The Impact Analyses on the Downstream by the Existing Golf Course (골프장 유출수가 하류수계에 미치는 영향)

  • Lee, Byoung Ho;Kim, Seong Deuk;Cho, Hong Je;Cho, Tae Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.3
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    • pp.239-251
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    • 1992
  • There has been a great deal of controversy in the views on the impact of the pesticide pollution from the golf courses. The stream and reservoir associated with a existing golf course were investigated. The parameters include the ones related with eutrophication, heavy metals, pesticides. and aquatic ecological conditions. It was found that the impact on the aquatic ecosystem by the pollution from the golf course was not so serious. An aquatic ecological food chain was well established in the reservoir which belongs to the golf course. In contradiction to the general recognition, the livestock farming and agricultural farming gave much more adverse impacts on the stream than the golf course.

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Comparison the Effect of In-situ Mixing Method and Mixed Laying Method for Construction of Stabilizing Layer on Heavy Metal Contaminated Soil (중금속 오염토양 안정화층 시공을 위한 원위치 교반방식과 혼합포설방식의 효과비교)

  • Lee, Sang-Moo;Kim, Jin-Hwan;Yun, Yeo-Joon;Kim, Yoon-Su;Park, Nam-Seo
    • Tunnel and Underground Space
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    • v.25 no.6
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    • pp.505-514
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    • 2015
  • In this study, a stabilizing equipment was developed to resolve the problems of existing stabilization construction method for contaminated soil. The field application and workability of the stabilizing equipment were verified through field demonstration tests and laboratory tests. The field application of the stabilizing equipment was identified through field demonstration tests. As a result of laboratory tests for field mixed soil, the mixing capability of stabilizer of the developed construction method was better than that of existing construction method.