• Journal of Wetlands Research
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• v.9 no.3
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• pp.35-42
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• 2007

The paved areas such as parking lots and roads are stormwater intensive landuses since they are impervious and have high pollutant mass emissions from vehicular activity. Vehicle emissions include different pollutants such as heavy metals, oil and grease, particulates from sources such as fuels, brake pad wear and tire wear. Especially, the released heavy metals can be easily absorbed on the surface area of small particulate materials because of its ionic strength. Therefore, by constructing the sedimental tank in structural BMPs as a pre-treatment facility, the particles and heavy metals both can be removed from the runoff at an instant. To understand the physico-chemical characteristics of sediments from sedimentation tank, one-year study at an infiltration trench and filtration system was conducted to quantify the metal mass absorbed on sediments with various particle sizes. The structural BMPs for this study are located in Yongin City, Kyunggido. The research results show that Cu, Zn and Pb are dominant metal compounds in the sediments. Also the metal concentrations are highest at the ranges of $425-850{\mu}m$ particle sizes. The results will provide the basic physico-chemical information of sediments to treat it as solid wastes and to determine the design criteria of sedimentation tank in structural BMPs.

• Journal of Wetlands Research
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• v.21 no.2
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• pp.173-180
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• 2019

This study was conducted to understand factors affecting TSS and heavy metals transport on the road, parking lot and roof. During storm events, heavy metals, which were mostly attached to TSS, were also transported when TSS was washed off in the road, parking lot and roof. This finding may be supported by the significant correlations between TSS load and total and soluble heavy metals load including Cr, Fe, Cu, and Pb (Pearson r value: 0.52 to 0.73; probability p value<0.01). Generation and transport of TSS and heavy metals were greater in the road and parking lot compared to the roof due to vehicular activities, slope and greater catchment areas of these sites. It was found that TSS transport during peak flows of storm events ranges from 65% to 75% implying that by controlling peak flows, TSS transportation to nearby water bodies may be decreased. Depending on the target TSS and heavy metal reduction, sizing of low impact development (LID) technologies and green infrastructures (GI) such as infiltration trench, tree box filter, and rain garden may be calculated. Future researchers were recommended to assess the limitations of the systems and determine the design considerations for these types of facilities.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.19-27
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• 2022

Fish that inhabited in the watersheds of Andong, Imha and Yeongju Dam in the upper Nakdong River were analyzed heavy metals by separated into muscle, gill, stomach and liver part. Thirteen fish species such as dark chub, skygager, coreoperca herzi, Korean piscivorous chub, cornet fish, Japan crucian carp, catfish, bass, crucian carp, mandarin fish, carp, long-nosed barbel, Korean sharpbelly were analyzed using ICP/MS. The results of the analysis based on the overall average concentration showed that the muscle part is lower than other parts in all heavy metal items except mercury. The gill part showed high concentrations of chromium, manganese, nickel, and lead, the stomach part has high zinc, and the liver part showed high concentrations of iron, copper, arsenic, and cadmium.

• Analytical Science and Technology
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• v.21 no.2
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• pp.135-142
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• 2008

Plasticizer and heavy metals in domestic PVC wallpaper manufactured in Korea after 2005 were analyzed to identify the contained quantity in comparison with the 2002 manufactured PVC wallpapers. Plasticizer of wallpapers was analyzed by the method KSM1991 which uses soxhlet extraction with n-hexane and GC/FID. Heavy metals were pre-treated with 0.07 mol/L hydrochloric acid (HCl) and analyzed by ICP/OES according to the EN 71-part 3 method. DEHP, DINP, DEP, acetyl tributyl citrate were identified from wallpaper. Contents of DEHP, DINP were 0.2~11.3%, 17.9~27.8% respectively in 6 wallpapers, DEP and acetyl tributyl citrate were 1.5%, 8.9% respectively in one wallpaper. Plasticizers have changed from DEHP that has possibility of hazards to DINP, DEP and acetyl tributyl citrate as compared with 2002. Heavy metals were detected under guide line from all of the wallpapers except fire-retardant wallpaper contain antimony. While PVC wallpaper was improved by use of various plasticizer, functional wallpapers such as fire-resistant wallpaper contain high antimony in this study.

• Journal of Korean Society of Forest Science
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• v.88 no.4
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• pp.429-437
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• 1999

Heavy metals(Cd, Cu, Pb and Zn) in tree rings of P. thunbergii growing at Onsan Industrial Complex of air polluted area were analyzed to study the condition of heavy metal pollution. The tree ring width began to decrease after operation of factories and decreased abruptly at Onsan Industrial Complex after 1991. Cd contents in tree rings showed 119.4ppb to 867.0ppb level and suddenly increased after 1991. Cu contents showed 309.5ppb to 3686.8ppb, and Pb contents 911.33ppb to 7997.1ppb and fluctuations of those were high after operation of factories. Zn contents showed the highest level of 3528.7ppb to 23826.7ppb and largely ascended after 1960, and increased suddenly after 1992, as compared to former tendency. On the other hand, heavy metal contents in tree rings of P. thunbergii at Gosung of non-air polluted area were far lower than Onsan I. C., and there was a wide difference between both areas after 1990. On the heavy metal contents accumulated in bark of P. thunbergii of both areas, it was higher to 10 times in Cd, 1,000 times in Cu, 285 times in Pb and 133 times in Zn contents at Onsan than at Gosung. In the heavy metal analysis for circle plate and cores, heavy metal contents in cores were generally higher than those in disk and Pb contents showed specially high difference, but pattern of variation by tree age showed a similar tendency.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.497-497
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• 2016

페루의 Rimac강은 수도인 Rima시를 관통하는 강으로 각종 용수공급 등의 기능을 담당하는 중요한 강이지만 광산, 공장 및 도시 등 점?비점오염원으로 인해 오염이 심각해지고 있는 실정이다. 본 연구에서는 Rimac강의 하천복원을 위하여 3단계 수질개선 목표를 설정하고 각 단계별 BOD, TP 및 중금속(Al, As, Cd, Fe) 예측을 수행함으로써 목표달성 가능 평가를 수행하였다. Rimac강 지류인 Rio Santa Eulalia 하천 유입후부터 하구까지 총 57 km를 대상으로 4개의 대구간(Reach), 57개의 소구간(Element)으로 구분하여 QUAL2E 모델을 구축하였다. 2013년을 대상으로 저유량시기(건기)인 12월과 고유량시기(우기)인 1월을 대상으로 BOD, TP, Al, As, Cd, Fe의 모델 재현성을 검토한 결과, Rimac강 하류의 Huaycoloro강 유입이후 BOD, TP가 증가하는 현상을 적절히 재현하는 것으로 나타났다. 중금속은 Romac강 상류와 하류 Huaycoloro강 유입 수질 농도차이가 크지 않아 거리별로 일정한 농도를 나타내는 것으로 모의되었으나 실측정값은 하구로 갈수록 낮아지는 경향이 다소 나타났지만 대체적으로 실측값의 경향을 따르는 것으로 모의되었다. 수질개선 시나리오는 1단계(2016-2018년), 2단계(2019-2021년) 및 최종 3단계(2022-2024년)로 구분하여 저유량시기와 고유량시기의 수질개선 대책에 따른 수질변화를 예측하여 Rimac강 하류의 대표 지점인 La Atargea 취수장 지점에서 목표수질 달성여부를 평가하였다. 저유량시기의 경우, BOD는 1단계 이후 5.9 mg/L에서 목표수질 5.0 mg/L 이하로 농도가 감소되었으며 최종 3단계에 2.2 mg/L로 63.3% 개선하는 것으로 예측되었다. TP는 1단계 25.8% 개선, 3단계는 51.6% 개선되어 목표수질인 0.15 mg/L를 만족하는 것으로 예측되었다. 중금속의 경우 Cd는 당초 수질목표를 만족시키는 상황이었으며 그 외 항목은 Al>As>Fe 순으로 개선효과가 나타났고, 3단계 이후 모두 목표수질을 달성할 것으로 예측되었다. 고유량시기 수질예측 결과, 1단계 BOD, TP는 약 49, 19% 저감효과가 나타났으며 3단계 이후 57, 25%까지 개선되는 것으로 예측되어 목표수질을 만족시키는 것으로 분석되었다. 중금속은 Al이 가장 큰 개선 효과가 나타났으며 3단계에서 77.5%의 개선 효과가 분석되었다. 페루 리막강 유역 수질개선 대책 수립에 따른 수질개선효과 분석 결과, 3단계까지 모든 수질항목의 목표수질 달성이 가능한 것으로 분석되었으나 TP, Al 및 As의 경우에 2단계까지 목표수질 달성이 어려워 더욱 체계적인 관리가 필요할 것으로 판단되었다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1997.05a
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• pp.17-20
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• 1997

이 연구에서는 국내에 산재되어 있는 금속광산들에 대한 토양환경오염을 조사하고 적절한 환경처리를 위한 기초자료를 제공하기 위하여 대표적인 연-아연광산, 동광산 및 금-은광산을 대상으로 As. Cd, Cu, Pb, Zn 등의 오염규모와 분산정도를 규명하고자 하였다. 연구대상지역으로 삼보 연-아연강산, 달성 동-텅스텐광산 그리고 구봉, 삼광, 금왕 금-은광산을 선정하여 이들 광산 주변에서 토양을 채취하여 화학분석을 실시하였다. 그리고 연속추출법을 이용하여 토양중에 존재하는 중금속의 존재형태를 규명하였으며 화학분해방법에 따른 중금속의 추출정도를 고찰하기 위하여 강산을 이용한 분해방법과 토양환경보전법에 제시된 방법을 비교하였다. 화학분석 결과, 삼보광산 주변의 상부토양 (0-15cm 심도)에서는 평균 11.8 $\mu\textrm{g}$/g Cd, 208 $\mu\textrm{g}$/g Cu, 2,700 $\mu\textrm{g}$/g Pb, 8,300 $\mu\textrm{g}$/g Zn이 검출되었으며 일부 농경지에서는 토양환경보전법의 우려기준을 초과하는 중금속이 검출되어 광산활동에 의한 토양오염이 심각함이 조사되었다. 달성광산 주변 토양에서도 다량의 중금속이 검출되었으며 (평균 4.4 $\mu\textrm{g}$/g Cd, 1,950 $\mu\textrm{g}$/g Cu, 1,030 $\mu\textrm{g}$/g Pb, 419 $\mu\textrm{g}$/g Zn) 특히 As (평균 2,500 $\mu\textrm{g}$/g)의 오염이 심각하였다. 그리고 대표적인 금은광산인 구봉, 삼광 및 금왕광산에서는 광미와 선광장 주변에서 다량의 중금속과 As가 검출되었다. 이 연구 결과, 이들 점오염원에 대한 오염정도가 심각하므로 이를 적절하게 처리할 수 있는 오염복구사업이 실시되어야할 것으로 판단된다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.3114-3119
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• 2013

The mangrove ecosystems have the capacity to act as a sink of heavy metals entering aquatic ecosystems. Despite their potential exposure to metal contaminated sediments, mangroves appear to be highly tolerant to heavy metals. In this study, we cloned metal tolerance gene from mangrove plant. Using CTAB method, RNA were isolated from leaves and root tissue of Rhizophora stylosa habitated at Weno island in Micronesia Chuuk lagoon using CTAB method and phytochelatin synthase 1 (PCS1) gene was cloned using gene specific primers. Expression of PCS1 gene was increased 1.91 fold and 2.72 fold in mangrove propagules exposed to 100 ppb Cd and 10 ppb Cu, respectively. These results indicate that expression of PCS1 gene are promising tools for health assessment of mangrove ecosystem.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.53-63
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• 2003

Objectives of this research were to fractionate heavy metals in soil samples in the upper Okdong River basin and to assess the potential pollution index of each metal fraction. Soil samples were collected from the cultivated land soils and analyzed for physical and chemical properties. pH of cultivated soils ranged from 5.2 to 7.6. Contents of total kelhaldal nitrogen and loss on ignition were in the ranges of 0.6∼2.5%, and 1.9∼12.9%, respectively. Heavy metals in the cultivated land soils were higher in the abandoned closed coal mine near field soils than those in the paddy soils. Total concentrations of metals in the cultivated land soils were in the orders of Zn > Pb > Ni > Cu > Cd, exceed the corrective action level of the Soil Environment Conservation Law and higher than the naturals were abundance levels reported from uncontaminated cultivated land soils. Mobile fractions of metals were relatively small compared to the total concentrations. Soil Pollution Assesment Index (SPAI) values of each fraction of metals were leveled from Non polluted to Moderately polluted based on total concentrations. SPAI values of mobil fractions were lower than those of immobile fractions. Results on metal fractions and SPAI values of the cultivated land soils indicate that field soils samples were contaminated with heavy metals and had potential to cause a detrimental effects on plants. A prompt countermeasure to prevent field soils in the abandoned closed coal mine near fields are urgently needed.

• The Journal of Engineering Geology
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• v.17 no.3
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• pp.419-424
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• 2007

The contents were investigated by the monitoring survey from the soils and tailings caused by numerous abandoned mines in Korea. Cause heavy metals due to abandoned metal mines are raising significant environmental problems. But it is an important key such as a leaching and a transfer mechanism to evaluate contamination levels caused by abandoned mines. In this study the column test was carried in order to calculate a leaching level from soils and tailings. It was demonstrated that the leaching of Pb, Cd and Mn was expressed with similar behaviors and that of As and Cu was expressed with similar behaviors. For Zn, the leaching behavior was shown a serious leaching level with 40 mg/kg during the 45days. This was explained by Zn high contents of soils Zn in a natural world and ORP conditions where the leaching of Zn was occurred easily. Hence it was necessary that the survey of ORP was a key as well as total contents for the management of abandoned metal mines. We could estimate the chemical forms of heavy metals using the physical index such as ORP and pH and reduce the risk from heavy metals caused by abandoned metal mines.