• Journal of the Korean Society of Food Science and Nutrition
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• v.18 no.3
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• pp.316-320
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• 1989

This study was performed to assess the contamination levels of the heavy metals (Pb, Cd, Cr, Cu, Fe, Zn and Mn) for common restaurant meals in Seoul area. The samples were seolong-tang, galbi-tang, yeukge-jang, kalguksoo, doenjang-chige, bibim-bab, bibim-nangmyon, bulgogi, chazang-myon, yanggobchang and zumuluk, which were seperated draind residues from fluids. The heavy metal contents were determined by atomic absorption spectrophotometer. The results obtained were as follows : ${\circ}$ The total amount of heavy metals per meals were $131.8{\mu}g\;lead,\;18.4{\mu}g\;cadmium,\;135.5{\mu}g\;chromium,\;804.9{\mu}g\;copper,\;7430.6{\mu}g\;iron,\;2807.4{\mu}g\;zinc,\;and\;841.6{\mu}g$ manganese. ${\circ}$ Intake levels per daily through common restaurant meals were lower than the daily intake limit established by FAO/WHO.

• Journal of the Korean Society of Food Science and Nutrition
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• v.29 no.3
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• pp.380-383
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• 2000

국내에서 생산되는 농산물 통조림 중 황도, 백도, 파인애플, 밀감, 포도, 후르츠칵테일, 김치 통조림을 선택하여 실온에서 1년 동안 저장하면서 3개월 간격으로 개봉하여 pH를 비롯하여 주석, 납 함량을 조사하여 다음과 같은 결과를 얻었다. pH는 김치통조림을 제외한 모든 통조림에 서 저장기간의 증가에 따른 변화가 거의 없었다. 통조림 검사항목 중 중금속에 해당하는 납과 주석의 경우 저장기간 증가에 따라 함량이 증가하였으며, pH가 비교적 낮은 통조림의 경우 그 용출정도가 다소 높았으며 pH가 4이상인 김치 통조림에서는 타 시료에 비해 주석 함량이 비교적 낮았다. 저장기간이 12개월 경과 후에도 납, 주석함량은 모두 기준치에 비해 상당히 낮아 식품으로서 안전한 것으로 생각된다.

• Proceedings of the KSEEG Conference
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• 1999.04a
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• pp.39-42
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• 1999

1) 서울 지역 도로가 퇴적물에서는 특히 Cu와 Zn의 오염이 도심 지역을 중심으로 심각하게 진행되고 있으며. Pb는 무연 휘발유의 사용량 증가와 더불어 감소 추세이나 여전히 높은 함량을 나타내고 있다. 2) Pb와 Cr의 함량은 공간적 지배가 강하여 Pb는 주로 교통 혼잡 지역, Cr은 공구상 밀집 지역에서 높게 나타난다. 반면, Cu, Cd, Zn 함량은 시간적 및 공간적 변화를 모두 보여주어 금속 산업 밀집도 및 강우량 변화에 따라 변화된다. 3) 특히 오염이 심화되고 있는 지역의 도로가 퇴적물이 하수계로 직접 유입되지 못하도록 차단하는 적절한 시설이 필요하며, 아울러 오염된 퇴적물을 집적하여 처분할 때는 주변 토양의 오염에 유의해야 할 것이다.

• Food Industry
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• s.121
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• pp.11-14
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• 1993

• Korean Journal of Food Science and Technology
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• v.36 no.4
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• pp.523-526
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• 2004

There are few studies on toxic metals in fruits. Therefore, we examined contents of toxic metals in fruits (n=386) available in Korean markets. The samples were digested with acids, then analyzed by inductively coupled plasma spectrometer (ICP) or atomic absorption spectrophotometer (AAS) for lead (Pb), cadmium (Cd), and arsenic (As). The contents of mercury (Hg) were also determined using a mercury analyzer, Contents of toxic metals in fruits were as follows [minimum-maximum (mean), mg/kg]; Hg 0.0001-0.019 (0.001), Pb 0.001-0.410 (0.013), Cd 0.001-0.035 (0.000), and As 0.001-0.210 (0.017). Our results showed that metal contents in fruits in Korean markets were similar to those reported in other countries. Average weekly intakes of Hg, Pb, and Cd from fruits are about 1-2% of Provisional Tolerable Weekly Intakes (PTWI) set by FAO/WHO Joint Food Additive and Contaminants Committee for safety evaluation.

• Korean Journal of Environmental Agriculture
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• v.19 no.4
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• pp.319-323
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• 2000

This study was conducted to compare fractionations and availability of heavy metal in paddy soils near five abandoned mining areas. The sequential extraction procedure was used to fractionate the heavy metals in soils into the designated from water $soluble(H_2O)$, $exchangeable(0.5M\;KNO_3)$, organically bound(0.5M NaOH), $oxide/carbonate(0.05M\;Na_2-EDTA)$, and $sulfide/residual(4M\;HNO_3)$. EDTA and $HNO_3$ extractable of Cd, Pb, and Zn, and NaOH and $HNO_3$, extractable of Cu were predominant chemical forms. The ratio of $H_2O+KNO_3$ extractable of Cd, Zn, Cu, and Pb were 25.1, 8.7, 4.0, and 0.4%, respectively. The ratio of $H_2O+KNO_3$ extractable heavy metal were negatively correlated with soil pH, while $EDTA+HNO_3$ extractable heavy metal were positively correlated. The most consistent distribution patterns were found when the soil samples were grouped according to their total contents. Specially, the ratio of $H_2O+KNO_3$ extractable heavy metal were higher as total contents of heavy metal were increased. The ratio of $H_2O+KNO_3$ extractable heavy metal(Cd 1.06, Cu 0.15, Pb 0.01, and Zn 0.05%) were lower at the high soil pH than those(Cd 31.31, Cu 4.06, Pb 1.75, and Zn 10.16%) at the low level. Compared to other chemical forms, the degree of contribution for $KNO_3$ extractable form to the Cd uptake to brown rice was high, whereas that for EDTA and $HNO_3$ extractable forms were high to the Zn.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.135-138
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• 2004

본 연구는 중금속으로 오염된 폐수처리에 있어 친환경적 유기흡착제로서 휴믹물질의 활용성을 평가하기 위한 기초 연구로서 이탄(peat moss)으로부터 Humin을 분리 한 후, 중금속 이온(Cd(II),Cu(II))과의 흡착특성을 조사하였다. 이탄으로부터 추출한 peat-Humin의 함량은 94%이상을 나타냈으며, 분자의 작용기 특성은 일반 토양 휴믹물질(soil humic substance)과 유사하였다. peat-Humin과 중금속 이온(Cd(II),Cu(II))과의 흡착 반응은 5분내에 빠른 흡착형을 보였으며, pH 5-6에서 가장 높은 중금속 제거율을 보였다. pH 3의 산성조건에서도 50%정도의 제거율을 보였다. pH 5에서의 등온흡착 실험결과를 Freundlich 등온식에 적용하여 해석한 결과, 각의 중금속에 대한 peat-Humin의 흡착상수(Kf)는 Cd(II)이 8.07 그리고 Cu(II)가 4.56으로 나타났다.

• Journal of Energy Engineering
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• v.8 no.1
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• pp.127-136
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• 1999

Bench Scale급 기류층 석탄가스화기에서 배출된 슬form의 특성을 파악하기 위해서 Drayton 석탄과 Kideco 석탄으로부터 생성된 슬래그의 조성, 형상, 잔존탄소함량 및 중금속 성분들을 분석하였다. Drayton 석탄 슬래그의 형상은 표면이 매끄럽고 단단하며 다공성을 띄면서 crack이 거의 없고 결정구조가 비정형인 반면에, Kideco석탄 슬래그의 경우는 표면이 거칠고 crack이 상당히 많이 존재하며 주결정상은 pyroxene과 anorthnite 등으로 이루어져있다. 슬래그의 재활용시 판단 기준이 되는 잔존탄소함량은 두 대상탄 모두 1% 이하를 나타내어 재활용이 가능하며, 슬래그의 용출수 분석결과 석탄중에 함유된 중금속은 슬래그중에 용융되어 안정한 화합물로 존재하므로 중금속 유출로 인한 2차적인 환경오염 문제는 없을 것으로 판단된다.

• Journal of Korea Soil Environment Society
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• v.5 no.3
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• pp.25-33
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• 2001

The study was performed to examine the influence of sea tide on a tideland composition by Saemankeum reclamation and to evaluate a correlation between the characteristics of physical and the pollution level of heavy metals. Also, it was investigated the characteristics of heavy metal adsorption through a batch experiment and applied to adsorption isotherm equations. In the results, the flow of sea tide occurred to accumulation action and had an effect on the content of heavy metals. It suggests that influence factors for the content of heavy metals in the tidal flat be grain size, cation exchange capacity and organic matter content. Adsorption capacity of heavy metals occurs to 90% adsorption rate for injection concentration within 30 minutes. The flow patterns in Saemankeum area will undergo a change for soil size distribution. In result, this soil size changed will effect the adsorption capacity of heavy metals.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.3
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• pp.289-295
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• 2010

Monitoring of the heavy metals at paddy rice agriculture is very important for environmental agriculture. A study was carried out of heavy metal concentrations in 260 paddy soil samples every four years from 1999 to 2007 in Gyeongnam Province. Heavy metals such as Cd, Cr, Cu, Ni, Pb, Zn, and As in paddy soils were analyzed. Average concentrations of heavy metal were Cd 0.426 (ranged 0.003-1.379) mg $kg^{-1}$ for Cd, 1.189 (0.003-3.264) mg $kg^{-1}$, for Cr, 9.68 (0.05-22.38) mg $kg^{-1}$ for Cu, 2.64 (0.01-7.36) mg $kg^{-1}$ for Ni, 23.7 (0.7-54.1) mg $kg^{-1}$ for Pb, 20.8 (0.7-131.2) mg $kg^{-1}$ for Zn, and 1.054 (0.001-2.110) mg $kg^{-1}$ for As, respectively. Long-term changes of heavy metals were showed that Cd, Ni, and Zn were significantly increased whereas Cr, Cu, and As were significantly decreased. Principle component analysis (PCA) of heavy metals in paddy soils was obtained with eigenvalues > 1 summing 34.3% of variance for PC1, 17.5% of variance for PC2, and 51.8% of the total variance in soil heavy metals.