• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.5 no.2
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• pp.24-30
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• 1999

The migration mechanism of trace elements, Pb, Cd, Cu, Zn and Sn from brass food-contact utensiles was investigated. The migration of metals from brass was affected by the migration temperature (30, 60, 80 and $95^{\circ}C$), the simulant pH (2.5, 4.3, 6.0 and 7.0) and the migration time (30, 90, 180 and 360 min.). The amount of Pb migration was maximum at $95^{\circ}C$ with pH 2.5. This study indicated that the equilibrium of Pb migration was reached at 180 minutes. The mechanism of Pb migration was investigated with Scanning Electron Microscope (SEM) and Electron Probe Micro Analyzer (EPMA). To correlate the relations between the migration and the content of Pb in brass samples, ten brass samples having known content of Pb (the quantities of Pb in brass ; 0, 0.02, 0.09, 0.1, 0.2, 0.5, 0.9, 1.4, 5.4 and 9.2% (w/w)) were tested in the following conditions, 4% acetic acid, $95^{\circ}C$ and 30 minutes. The result represented that content of Pb in brass samples must be below 0.2% (w/w) to satisfy the 1.0 ppm (as Pb) of Korea Food Code.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.3
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• pp.56-64
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• 2019

Various approaches have been attempted to develop recycling technologies related to industrial waste resources containing metals. Among them, glass is not decomposed into microorganisms, so landfill is not suitable, and interest in the recycling of waste glass is increasing. In this paper, by incorporating chelate resin to suppress the elution of heavy metals in waste glass and using waste glass as a fine aggregate and we want to evaluate the strength, drying shrinkage, alkali-silica reaction and heavy metal leaching of shielded filler materials and to provide basic data for utilizing waste glass as an economical and environmentally friendly shielding filler. As a result of the test, it was found that the use of waste glass as a fine aggregate was effective in the development of strength, but the incorporation of chelate resin had an influence on the strength development. In addition, the addition of chelate resin was effective in improving drying shrinkage but it was found to affect the alkali - silica reaction. As a result of the heavy metal leaching test, the KSLP test method satisfies all the criteria for heavy metal leaching. However, in case of lead, the limit of US ANSI 67-2007a was exceeded and further study should be done.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.427-428
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• 2009

In order to utilize fly ash as a shotcrete material, this research conducted a heavy-metal leaching test to inspect the influence on environmental. The measured amount of the heavy metals in the leachate was well below the suggested guidelines from Korea and U.S.A.

• Economic and Environmental Geology
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• v.45 no.3
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• pp.255-264
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• 2012

The stabilization using limestone ($CaCO_3$) and steel making slag as the immobilization amendments for Cu and Pb contaminated farmland soils was investigated by batch tests, continuous column experiments and the pilot scale feasibility study with 4 testing grounds at the contaminated site. From the results of batch experiment, the amendment with the mixture of 3% of limestone and 2% of steel making slag reduced more than 85% of Cu and Pb compared with the soil without amendment. The acryl column (1 m in length and 15 cm in diameter) equipped with valves, tubes and a sprinkler was used for the continuous column experiments. Without the amendment, the Pb concentration of the leachate from the column maintained higher than 0.1 mg/L (groundwater tolerance limit). However, the amendment with 3% limestone and 2% steel making slag reduced more than 60% of Pb leaching concentration within 1 year and the Pb concentration of leachate maintained below 0.04 mg/L. For the testing ground without the amendment, the Pb and Cu concentrations of soil water after 60 days incubation were 0.38 mg/L and 0.69 mg/l, respectively, suggesting that the continuous leaching of Cu and Pb may occur from the site. For the testing ground amended with mixture of 3% of limestone + 2% of steel making slag, no water soluble Pb and Cu were detected after 20 days incubation. For all testing grounds, the ratio of Pb and Cu transfer to plant showed as following: root > leaves(including stem) > rice grain. The amendment with limestone and steel making slag reduced more than 75% Pb and Cu transfer to plant comparing with no amendment. The results of this study showed that the amendment with mixture of limestone and steel making slag decreases not only the leaching of heavy metals but also the plant transfer from the soil.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.2
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• pp.161-166
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• 2021

This study was on leaching test(KSLT) of the aggregate for the products to evaluate the characteristics of contaminants and the possibility of contamination arising from the aggregate. On the basis pH, conductivity, turbidity, TN, TP, COD and heavy metal contents in the aggregate increased as the particle size of the aggregate was smaller. The pH appeared to be 9.9~11.4 which is relatively higher than soil, however, heavy metal has investigated within the 1 region's standard value of soil pollution standards. From the leaching test, there is strong indication that the risk of pollution due to elution of pollutants gets higher with the smaller grain size. Especially conductivity and turbidity are the potential water pollution source and recycled aggregates of 10mm or less could be a potential pollution source since it could elute soluble matters and suspended solid, but there is no proper management standard for them. As a result of evaluating water pollution possibility of the aggregate, the pH displayed in items with a very high possibility of contamination, TN and TP did in item with a low possibility of contamination and on the other hand the heavy metals did in item with a very low possibility of contamination.

• Journal of the Korean GEO-environmental Society
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• v.2 no.2
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• pp.5-12
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• 2001

The physical characteristics and contaminant level of the dredged material generated by the channel maintenance and water quality improvement was analysed in a series of the study of the beneficial uses of dredged material in harbor. Dredged materials were sampled at Kunsan, Kohyun, Samchunpo, and Pohang Harbors and tested in the laboratory(leaching Test). From the experimental results, the specific gravity does not shows large differences, while almost grains are composed of silts and oyster shells except Pohang harbor containing gravels. The COD release rate and ignition loss is high in Kunsan dredged materials because of the watershed pollutants loads. The nutrient release rate is also relatively high. The release concentration of the heavy metals shows the highest values on Zn, Pb, Cd, Cu constituents at Kohyun, Kunsan, Samchunpo, Kunsan, respectively.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.808-811
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• 2007

본 연구는 3톤/일급 이하 가스화 용융로에서 $1,400{\sim}1,500^{\cdot}C$, $7.5{\sim}8.0$ kg/$cm^2$의 안정적인 운전조건일 때, 시료로 Kideco 탄을 사용하고 이때 발생한 슬랙의 특성 및 슬랙의 재활용을 위한 벽돌제조 특성을 고찰하였다. 발생된 슬랙은 $Fe_2SiO_4$와 $SiO_2$가 결정상태로 일부 존재하거나, 중금속들이 결합되어 엉킨 구조인 비결정상태의 치밀한 형태로 이루어져 있었으며, 잔존탄소 함량이 0.06%로 미량 존재하였다. 또한 슬랙에는 중금속 농도가 Kideco탄보다 고농도로 존재하지만, 용출되는 중금속의 농도는 매우 낮아 환경적으로 안정한 물질로서 재활용이 가능한 특성을 지니고 있다. 슬랙 첨가 점토벽돌의 적합성을 평가하기위해 슬랙을 0%, 10%, 30% 첨가하여 벽돌을 제조하고 KS 산업규격에 따라 시험을 실시하였다. 분석결과 슬랙을 첨가할수록 제조한 벽돌의 흡수율이 낮아져 기존 제품에 비하여 우수한 것으로 측정되었다. 또한 압축강도와 휨강도는 기존 제품의 $80{\sim}86%$ 정도인 것으로 측정되었지만 KS 산업규격의 기준치보다 높은 수치를 나타내였고, 내산성, 내알칼리성, 열충격강도 또한 양호한 것으로 나타나, 슬랙을 이용하여 벽돌로 재활용하여 충분히 사용 가능한 것으로 확인되었다.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.71-76
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• 2011

In this study, a heavy metal stabilization treatment using waste resource stabilizing agents was utilized on army firing range soil contaminated with Pb and Cu. Both calcined oyster shells (COS; 5% w/w) and waste cow bone (WCB; 3% w/w) were applied for a wet-curing duration of 28 days. Following the stabilization treatment, the process efficiency was evaluated by various extraction methods for Pb and Cu. Neutral and weak acid extraction methods, such as water soluble extraction and SPLP, did not show positive results for heavy metal stabilization with very low leachability. On the other hand, TCLP and 0.1 N HCl extraction showed that the stabilizing agents significantly reduced the amount of the heavy metals leached from the soil, which strongly supports that the treatment efficiency is positively evaluated in acidic leaching conditions. Specifically, in the 0.1 N HCl extraction, the reduction efficiencies of Pb and Cu leaching were 99.9% and 83.9%, respectively. From the sequential extraction results, a difference between Pb and Cu stabilization was observed, which supports that Pb stabilization is more effective due to the formation of insoluble Pb complexes. This study demonstrates that the application of waste resources for the stabilization of heavy metals is feasible.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.293-301
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• 2005

We conducted several different leaching experiments for assessing the potential environmental risk when utilizing recycled concrete for stabilizing bridge pier. The methods include continuous batch leaching test (DIN 38414-S4), availability test (NEN 7341), pH-stat test (CEN/TC 292/WG6) and tank diffusion test (NEN 7345). The concentration ranges vary depending on the testing method. Nearly all the trace elements were low, some elements recording under detection limit. The maximum concentrations for trace elements leached throughout the whole tests are (as mg/L); Cd (0.029), Cu (0.437), Pb (0.14), Ni, Zn (0.95), Hg (0.005). Although the testing methods we used in this study are much more rigorous than other commonly adapted method including TCLP and domestic testing method for solid waste, the trace elemental concentrations are under the criteria for hazardous material set by the TCLP and domestic method. The result seems to suggest that applying the recycled concrete on stream water will be accepatable practice as for as trace elements are concerned. However, the influence of inorganics such as Ca, Mg, Ni and $SO_4^{2-}$ on aquatic ecology should be further examined.

• Journal of Navigation and Port Research
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• v.38 no.6
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• pp.655-661
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• 2014

In this study, stabilization treatment of heavy metals such as Ni, Cu, Pb, and Zn in contaminated marine sediment was achieved using bentonite. Stabilization experiment was accomplished by wet-curing with bentonite for 150 days. From the sequential extraction results of heavy metals, it was observed that the easily extractable fraction (exchangeable, carbonate, and oxides forms) of Ni, Cu, Pb, and Zn in a treated sediment decreased to 8.5%, 5.6%, 19.2%, and 28.2%, respectively, compared with untreated sediment. Moreover, the TCLP(Toxicity Characteristic Leaching Procedure) results evaluating efficiency of extraction reduction of heavy metals showed that extraction of heavy metals reduced drastically to 95.7%, 96.8%, 99.2%, 85.9% for Ni, Cu, Pb, and Zn by stabilization when compared to untreated sediment. From these results, we can confirm that bentonite as a capping material exhibits good stabilization of heavy metals in contaminated marine sediment.