• Title/Summary/Keyword: 중간지지

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Transesterification Reaction of Soybean Oil over KF/MgO Catalyst (KF/MgO 촉매를 이용한 대두유의 전이에스테르화 반응)

  • Jo, Yongbeom;Jeon, Jong-Ki;Park, Sung Hoon;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.344-347
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    • 2012
  • The basic strength of the MgO catalyst was enhanced by impregnating it with KF to synthesize a highly active catalyst for the bio-diesel production. To increase basicity, KF impregnated on synthesized MgO in laboratory. The synthesized catalyst was characterized using $N_2$ adsorption-desorption, X-Ray diffraction, X-Ray fluorescence, and $CO_2$ temperature programmed desorption analyses. Bio-diesel was produced from soybean and methanol and its fatty acid methyl ester content was measured to evaluate the activity of the catalyst. The catalyst impregnated with 30 wt% KF exhibited the highest activity, which was attributed to its abundant intermediate base site.

Dynamic Analysis of the Multi-Span Beam on Elastic Foundation Part one : Natural Frequencies (탄성지반 위에 놓여있는 다지지 보의 동적해석 제1보 : 고유진동수)

  • Y.C. Kim;K.J. Choi
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.1
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    • pp.83-91
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    • 1991
  • In this paper the dynamic analysis of the multi-span beam on elastic foundation, which include discrete transnational and rotational springs, was performed. Furthermore, the effects of the intermediate supports were investigated. As a solution method, first the orthogonal polynomial functions which satisfy both the geometric and dynamic boundary conditions are obtained by imposing the orthogonality conditions. Then, the Galerkin's method is used to obtain the natural frequencies of the system. From numerical tests for various constraint and boundary conditions, it was found that the higher order orthogonal polynomial functions obtained by the present method can be used to get the accurate solution.

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Modal Analysis and Testing for a Middle Spacer Grid of a Nuclear Fuel Rod (핵 연료봉 중간 지지격자의 모달 해석 및 실험)

  • Ryu, Bong-Jo;Koo, Kyung-Wan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.12
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    • pp.1948-1952
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    • 2012
  • The paper presents modal testing and analysis in order to obtain the dynamic characteristics of a middle spacer grids of a nuclear fuel rod. A spacer grid is one of the important structural elements supporting nuclear fuel rods. Such a fuel rod can be oscillated by its thermal expansion, neutron irradiation and etc. due to cooling water flow under the operation of a nuclear power plant. When the fuel rod vibrates, fretting wear due to repeated friction motion between the fuel rods and spacer grids can be occurred, and so the fuel rod is damaged. In this paper, through modal analysis and testing, natural frequencies and modes of a middle spacer grid were calculated, and the following conclusions were obtained. Firstly the numerical first-seven natural frequencies for spacer grids of a fuel rod having complicated structures have a small difference within 3.8% with experimental natural frequencies, and so the suitability of simulation results was verified. Secondly, experimental mode shapes for a middle spacer grid of a nuclear fuel rod were verified by obtaining lower non-diagonal terms through MAC(Modal Assurance Criteria), and were confirmed by the simulation modes.

Free Vibration Analysis of Rectangular Plate with Elastic Supports - Formulation by the Transfer Infiuence Coefficient Method - (탄성지대를 갖는 사각형 평판의 자유진동해석)

  • Moon, Deok-Hong;Yeo, Dong-Jun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.27 no.4
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    • pp.313-320
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    • 1991
  • The paper describes the formulation for the analysis of the flexural free vibration of rectangular plate structure by the transfer influence coefficient method, which was developed on the base of the concept of the successive transmission of dynamic influence coefficients. For the analysis of rectangular plate which two opposite sides are simply-supported edge condition, the results of simple numerical examples demonstrate the validity of the present method, that is, the numerical high accuracy, the high speed and the flexibility for programming, compared with results of the transfer matrix method and exact solution or Leissa's method.

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Ammonia Decomposition over Ni Catalysts Supported on Zeolites for Clean Hydrogen Production (청정수소 생산을 위한 암모니아 분해 반응에서 Ni/Zeolite 촉매의 반응활성에 관한 연구)

  • Jiyu Kim;Kyoung Deok Kim;Unho Jung;Yongha Park;Ki Bong Lee;Kee Young Koo
    • Journal of the Korean Institute of Gas
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    • v.27 no.3
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    • pp.19-26
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    • 2023
  • Hydrogen, a clean energy source free of COx emissions, is poised to replace fossil fuels, with its usage on the rise. Despite its high energy content per unit mass, hydrogen faces limitations in storage and transportation due to its low storage density and challenges in long-term storage. In contrast, ammonia offers a high storage capacity per unit volume and is relatively easy to liquefy, making it an attractive option for storing and transporting large volumes of hydrogen. While NH3 decomposition is an endothermic reaction, achieving excellent low-temperature catalytic activity is essential for process efficiency and cost-effectiveness. The study examined the effects of different zeolite types (5A, NaY, ZSM5) on NH3 decomposition activity, considering differences in pore structure, cations, and Si/Al-ratio. Notably, the 5A zeolite facilitated the high dispersion of Ni across the surface, inside pores, and within the structure. Its low Si/Al ratio contributed to abundant acidity, enhancing ammonia adsorption. Additionally, the presence of Na and Ca cations in the support created medium basic sites that improved N2 desorption rates. As a result, among the prepared catalysts, the 15 wt%Ni/5A catalyst exhibited the highest NH3 conversion and a high H2 formation rate of 23.5 mmol/gcat·min (30,000 mL/gcat·h, 600 ℃). This performance was attributed to the strong metal-support interaction and the enhancement of N2 desorption rates through the presence of medium basic sites.

Evaluation of Field Nonlinear Modulus of Subgrnde Soils Using Repetitive Static Plate Bearing Load Test (반복식 평판재하시험을 이용한 노상토의 현장 변형계수 평가)

  • Kim Dong-Soo;Seo Won-Seok;Kweon Gi-Chul
    • Journal of the Korean Geotechnical Society
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    • v.21 no.6
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    • pp.67-79
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    • 2005
  • The field plate load test has a good potential for determining modulus since it measures both plate pressure and settlement. Conventionally the modulus has been assumed to be a constant secant value defined from the settlement of the plate at a given load intensity. A constant modulus (modulus of subgrade reaction, k), however, may not be a representative value of subgrade soil under working load. Field strain(o. stress)-dependent modulus characteristics of subgrade soils, at relatively low to intermediate strains, are important in the pavement design. In this study, the field strain dependent moduli of subgrade soils were obtained using cyclic plate load test. Testing procedure and data reduction method are proposed. The field crosshole and laboratory resonant column tests were also performed to determine field nonlinear modulus at $0.001\%\;to\;0.1\%$ strains, and the modulus values and nonlinear trends are compared to those obtained by cyclic plate load tests. Both modulus values match relatively well when the different state of stress between two tests was considered, and the applicability of field cyclic plate load test for determining nonlinear modulus values of subgrade soils is verified.

Kinetic Analysis of The foot and ankle during walking (보행시 발과 족관절의 운동학적 분석)

  • Lee, Yun-Seob;Shin, Hyung-Soo
    • PNF and Movement
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    • v.4 no.1
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    • pp.45-50
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    • 2006
  • Purpose : This study shows the movements of the ankle and the foot in walking stages, and helps to diagnose and treat the problems of the ankle and the foot. The foot in human is a mean of the transportation, body support, and shock absorber. However, the slightest changes in the anatomical position can cause a significant increase of the stress and force in the ankle and the foot. The regular compressive force in the ankle of the normal person is generated by the contraction of the gastrocnemius and popliteus muscles, and transmitted to the achilles tendon. The plantar flexion about 10 degrees occurs immediately after the heel strike, getting ready for the weight acceptance. The shear force about 80 % of the body weight is generated immediately after the heel off of the mid stance phase. In those who have a problem in the ankle, the compression force at the ankle decreased to 1/3 of the body weight, and the shear force decreased, and the compressive force was reached at their maximum level earlier than the normal people. Conclusion : Analysis of the movements at the ankle and the foot in walking phase can make the effort to diagnose and treat the ankle and foot with the problems. However, the further study is necessary.

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Experiences of Korean Homestay Guardians of Early Study Abroad Students in the U.S. (미국 한인 조기유학생 홈스테이 가디언의 경험)

  • Kim, Hyun-Joo
    • Korean Journal of Comparative Education
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    • v.24 no.3
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    • pp.199-226
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    • 2014
  • The aim of this study was to determine key experiences of homestay guardians of unaccompanied minor Korean adolescents studying abroad in the United States through qualitative research method of grounded theory methodology. This study identified guardianship experiences and the process of adjustment to life with homestay students through in-depth interviews with 12 subjects who are Korean guardians in the United States. The results of this study classified "started with concern" as a category that leads guardians to start providing homestay accommodation, and "other's recommendation," "need for financial support," and "unexpectedly" as subcategories. This study identified "act as a mediator to resolve differences" as a key experience of guardians, and classified subcategories are "parental role" and "calculation of gains and losses" on a personal level; and "feel sorry for own children," "limited leeway of the family," and "formation of relationship between own children and homestay students" on a family level. Developed subcategories are "thirsty for attention," "vulnerability," "task on freedom and control," and "regrettable feeling in the absence of communication" with respect to relationship with students; "grade expectations," "one-way communication," "trapped between parents' and students' demands" in regard to relationship with parents; and "advice from school" in the aspect of school. "Cultural difference," "preparedness of students and parents," "age differences between guardian's children and students," "family support," "similar personalities," "guardian's motivation," and "parent's attitude" are subcategories that affect central phenomenon of guardians.

Synthesis and Characterization of Zeolite 4A on Activated Carbon Supports (활성탄 지지체상에서 제올라이트 4A 합성 및 특성)

  • Park, Jeong-Hwan;Suh, Jeong-Kwon;Jeong, Soon-Yong;Lee, Jung-Min;Doh, Myung-Ki
    • Applied Chemistry for Engineering
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    • v.8 no.2
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    • pp.204-210
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    • 1997
  • Zeolite 4A-impregnated complex molecular sieve was prepared by hydrothermal reaction after aluminosilicate gel was penetrated into the pore of activated carbon granule. The crystals of zeolite 4A mainly were formed in the macropore of activated carbon, and their average diameter is $0.8{\mu}m$. The pore volume of activated carbon granule is $0.67m{\ell}/g$, and the pore volume of the sample including 21.6wt% of zeolite 4A crystal is $0.41m{\ell}/g$ decreasing the pore volume by 40% due to the crystallization of zeolite 4A crystals on the internal surface of activated carbon. The calcium ion exchange capacity of zeolite 4A-impregnated sample is 320mg $CaCO_3/g$ zeolite, and this value is almost the same as that of zeolite 4A powder. The crystal of zeolite 4A was not separated from the support of activated carbon granule in the course of ultrasonic dispersion. The adsorption isotherm of water on zeolite 4A-impregnated sample shows the intermediate shape between types, I and III. In addition, zeolite 4A-impregnated sample shows the hydrophilic and hydrophobic properties simultaneously.

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Effect of Gap grade on Shear Strength of sandy soil (갭 입도 변화에 따른 사질토의 지지력 향상 효과)

  • Kim, Kab-Boo;Moon, Jun-Ho;Gu, Kyo-Young;Chun, Young-Woo;Kim, Young-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.319-324
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    • 2016
  • Soils with various particle sizes generally show good shear strength. Some soils have a relatively strong resistance to shear failure in spite of narrow particle distribution, such as gap grading. Based on this example, it can be inferred that appropriate arrangements of particle size in soils might result in an increase in shear strength. This study investigates the strength variation of soils with respect to the particle size distribution. Gap, well, and uniform graded soils were prepared with a desired ratio, and a wide range of direct shear tests were done using the prepared samples. The test results show that there is a strong relationship between the particle size ratio and internal frictional angle. Gap graded soil has a greater frictional angle than a well-graded sample, even when specimens have the same maximum particle size, which is also the case for the uniform grade specimen. The results have potential for developing a methodology for stronger soils through a simple manipulation of particle size distribution.