• Title/Summary/Keyword: 중간복토재

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Contamination and Geochemical Speciation of Heavy Metals in Middle Cover Soils and Clay Liner from the Kumheung Landfill, Gongju City (공주 금흥매립지의 중간복토재 및 차수재(논토양)의 중금속 오염과 존재형태 연구)

  • 이평구;박성원;염승준
    • Economic and Environmental Geology
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    • v.34 no.3
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    • pp.283-299
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    • 2001
  • The middle cover soils and clay liners collected from the Kumheung landfill in Gongiu City were analysed for As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, Ti and Zn concentrations using 0.] N HCl digestion and total/sequential extraction experiments followed by ICP-AES determination. The uncontaminated soil and sediment samples were also analyzed for the comparison. The results of sequential extraction showed that Cu was dominant in the oxidizable fraction, and As, Ni, Sr, Ba, and Mn were in the exchangeable fraction. Zinc and Mn occurred mostly in association with reducible, residual and carbonate fractions. Most of Cd and Pb were bound to the reducible and oxidizable fractions. The main carrier of Co, Cr, Fe and 11 was the residual fraction and another important carrier was the reducible fraction. The percentage of the metals of organically-bound form in the middle cover soils and clay liner was in the order of Cu(48%) > Ti(42%) > Pb(27%) > As(25%) > Cd(20%). As deduced from sequential extraction analysis, potential order of metal mobility in the middle cover soils and clay liner from the landfill was proposed: Cd > Sr > As > Ni > Mn > Ba > Cu > Pb > Zn » Co > 11 > Fe > Cr. Based on the 'geoaccumulation index' and the 'enrichment factor' normalized to A], the level of contamination of Cu, Ni and C1' was significant in the samples from Kumheung landfill and surrounding farmland. Their enrichments were attributed partly to anthropogenic pollutions.

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An Experimental Study on the Utilization of Phosphogypsum as Daily and Intermediate Cover Materials (일일 및 중간복토재로서 인산석고 재활용을 위한 실험 연구)

  • 이용수;정형식
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.133-140
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    • 2002
  • Phosphogypsum is a by-product from the phosphoric acid process for manufacturing fertilizers. It consists mainly of $(CaSO_4.2H_2O)$ and contains some impurities such as$(P_2O_5)$, 불소$(F_-)$, and organic substances. The annual world production of this material is up to 150 million tons and is up to 1.57 million tons in Korea. Therefore studies describe application of phosphogypsum to daily and middle cover materials in landfill. For this Purpose, experiments were performed to evaluate the engineering properties of the material by sieve analysis, specific gravity, consistency of soil, compaction, CBR, permeability, mi environmental characteristics of leaching test, reactor test. The results of this study are as follows : The mixing and layer conditions of CBR value are 6.2~6.3%, coefficient of permeability is $\alpha$$\times10_{-5}~10_{-6}cm/sec$. And leaching test results are far below than those of regulatory requirement of Waste Management Act, Soil Environment Preservation Act in Korea and RCRA in USA. Therefore phosphogypsum can be used as daily and intermediate cover materials in landfill.

Leachate Behavior within the Domestic Seashore Landfill(I)- Hydrogeologic Property Identification through In-situ Tests - (폐기물 매립지 내에서의 침출수 거동(I)- 현장조사를 통한 수리지반 특성 -)

  • 장연수;조용주
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.99-109
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    • 1999
  • In the case of domestic general waste landfills, cumulated leachate level is often formed in the landfill due to the waste of high moisture content and it becomes important to characterize the hydraulic properties of the disposed waste. Although many hydrologic studies have been peformed for leachate barriers and pheriperal subsurface environments, few studies have been done to investigate the hydraulic property of the disposed waste and cover soils and to analyse the leachate flow behavior within landfills. In this paper, the geotechnical properties of the waste and buried cover soils are identified through the field experiment including pumping and slug tests. The results of various tests show that the field density of the cover soils is somewhat higher than the maximum laboratory density of cover soils and the vertical flow of leachate and gas in the landfill is prevented by the buried cover soils. The hydraulic conductivities of field pumping test and slug tests are well matched and stayed in the range of hydraulic conductivities of well compacted wastes in the literature.

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Adsorption Characteristics of Heavy Metal and VOCs of Pyrolysis Char from Organic Waste Sludge (유기성 폐슬러지의 열분해 차르에 대한 중금속 및 VOCs 흡착특성)

  • Park, Sang-Sook;Kang, Hwa-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.130-137
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    • 2005
  • This research programme include investigation of the adsorption behavior of heavy metals and VOCs by Pyrolysis char for using landfill cover material. The volatile potions in the sludge gasified during the pyrolysis period and gave birth to porosity throughout the matrix. The result of the ad/desorption experiment of nitrogen to find out the formation of some pore by the gasification of the volatile matter, we can certify that the pyrolysis char($14.56\;m^2/g$) has increased twice more than the organic wasted sludge($6.68\;m^2/g$) in specific surface area. The pyrolysis char has the adsorption characteristic of medium type of Type II and V in BDDT classification, and showed a little micro pore. In the adsorption experiment of ethylbenzene and toluene, as a result of applying the Freundlich adsorption isotherms, the pyrolysis char was higher in the adsorptivity of ethylbenzene and toluene than the granite and the organic wasted sludge. The results of the heavy metal adsorption test for the char indicated that it had some ability of adsorption. It is suggest that pyrolysis char has some advantages for utilizing as landfill covers because the pyrolysis char can adsorb/absorb hazardous substances from the landfill sites and inhibit the ground water and soil contamination.

Leachate Behavior within the Domestic Seashore Landfill(II)- Numerical Analysis of Pumping Method for Reducing Leachate Level - (폐기물 매립지 내에서의 침출수 거동(II)- 누적수위 저감을 위한 양수법의 수치해석 -)

  • 장연수;조용주
    • Journal of the Korean Geotechnical Society
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    • v.15 no.6
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    • pp.111-120
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    • 1999
  • Leachate flow behavior due to intermediate cover soil of low hydraulic conductivity and the applicability of pumping method for reducing the leachate level in the landfill are analyzed with the numerical flow model, MODFLOW. Using the hydraulic conductivity and storativity data obtained from the field pumping and slug tests(Jang and Cho, 1999), the hydraulic condition within the landfill is validated. The optimum rate of pumping, the radius of influence, and the efficiency of horizontal drain are analyzed for reducing the leachate level in the landfill. From the results of the analyses, the barrier effect that the buried cover soil of low hydraulic conductivity prevents the vertical movement of leachate flow through the cover soil, which is found from the in-situ geotechnical studies(Jang and Cho, 1999), is identified again. Also, the installation of horizontal drains to the pumping well can increase the pumping rate from 120 ton/day per a well to 300 ton/day. The length of horizontal drain did not influence significantly on the drawdown-time curve of leachate in the landfill.

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