• Title/Summary/Keyword: 주울열

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Production of Ammonia Water and Sulfuric Acid from Ammonium Sulfate by Electrodialysis with a Bipolar Membrane (바이폴라막 전기투석을 이용한 황산암모늄으로부터 암모니아수와 황산의 제조)

  • Hwang, Ui-Son;Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.36-42
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    • 2005
  • This study examined the feasibility of producing sulfuric acid and ammonia water from ammonium sulfate solution using two-compartment electrodialysis with a bipolar membrane (EDBM). Electrodialysis experiments were carried out with 20 wt% ammonium sulfate at different current densities and sulfuric acid concentrations in a concentrate compartment. The current efficiency increased with the current density from 25 to $100\;mA/cm^2$. Nevertheless, the efficiency was relatively low compared with that of general desalting electrodialysis, owing to the diffusion of sulfuric acid from the concentrate compartment to the diluate. The diffusion rate through the anion exchange membrane increased with the sulfuric acid concentration in the concentrate compartment, which decreased the current efficiency. Conversely, the electrical resistance decreased with increasing current density owing to the Joulian heat generated during water dissociation in the transition region of the bipolar membrane under a high electric field. From the experimental results, we concluded that operating at a higher current density is effective from the perspective of current efficiency and electrical resistance when producing sulfuric acid and ammonia water from ammonium sulfate using a two-compartment EDBM process. Further studies on the effects of increasing the sulfuric acid concentration on current efficiency are required to apply the EDBM process practically.

Multistable Microactuators Functioning on the Basis of Electromagnetic Lorentz Force: Nonlinear Structural and Electrothermal Analyses (전자기 로렌츠력을 이용한 다중안정성 마이크로 액추에이터의 비선형 구조 및 전기-열 해석)

  • Han, Jeong-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1119-1127
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    • 2010
  • In this paper, the design and nonlinear simulation of a multistable electromagnetic microactuator, which provides four stable equilibrium positions within its operating range, have been discussed. Quadstable actuator motion has been made possible by using both X- and Y-directional bistable structures with snapping curved beams. Two pairs of the curved beams are attached to an inner frame in both X- and Y-directions to realize independent bistable behavior in each direction. For the actuation of the actuator at the micrometer scale, an electromagnetic actuation method in which Lorentz force is taken into consideration was used. By using this method, micrometer-stroke quadstability in a plane parallel to a substrate was possible. The feasibility of designing an actuator that can realize quadstable motion by using the electromagnetic actuation method has been thoroughly clarified by performing nonlinear static and dynamic analyses and electrothermal coupled-field analysis of the multistable microactuator.