• Title/Summary/Keyword: 조절반응

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Molecular holographic QSPR analysis on the reactivity between glycine and ninhydrin analogues as latent fingerprints detector (잠재지문 검출제로서 Ninhydrin 유도체들과 Glycine과의 반응성에 관한 분자 홀로그래픽적인 QSPR 분석)

  • Kim, Se-Gon;Jang, Seok-Chan;Cho, Yun-Gi;Hwang, Tae-Yeon;Park, Sung-Woo;Sung, Nack-Do
    • Analytical Science and Technology
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    • v.20 no.4
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    • pp.339-346
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    • 2007
  • To search the ninhydrin derivatives that have high chromogenic and fluorogenic properties, molecular holographic quantitative structure property relationship (HQSPR) models on the reactivity between glycine and ninhydrin analogues as latent fingerprint detector were derived and investigated quantitatively. The ${\varepsilon}LUMO$ (e.v.) energy of ninhydrin molecule was an important factor to reactivity of ninhydrin. And, it is suggested that the nucleophilic reaction by orbital-controlled reaction from the frontier molecular orbital (FMO) interaction between glycine and ninhydrin derivatives was more superior than that of electrophilic reaction by charged controlled reaction. The analytical results in atomic contribution maps also shows that the reactivity of ninhydrin was increased by meta-substituents as strong electron withdrawing groups on the benzo ring. Therefore, it is sugested by HQSPR and QSPR model that the 5,6-dinitroninhydrin molecule would increase the reactivity as much as three times as compared to none substituted ninhydrin molecule.

Thermo-physiological Responses of the Lower Grade Elementary School Children -A Comparison Between Japanese and Korean Children- (초등학교 저학년 아동의 체온조절반응 -일본아동과 한국아동의 비교-)

  • Kim Seong-Hee;Lee Uk-Ja;Tamura Teruko
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.12 s.148
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    • pp.1527-1534
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    • 2005
  • In order to clarify the characteristics of the thermo-physiological responses of the child and to understand the influence of the country where the child has grown up on the responses, the thermo-physiological responses of the Japanese children(J group) and the Korean children(K group) were examined. The subject wearing shorts was exposed first to a thermo neutral room$(Ta=28.5^{\circ}C)$ for 1 hour, then transferred to a cold$(Ta=22^{\circ}C)$ or a hot$(Ta=37^{\circ}C)$ room for 1 hour. The experiment was done in the climate chamber of Bunka Women's University in the summer of 1997 for Japan, and in the climate chamber in the Keimyung University in the summer of 1998 for Korea. The subjects consisted of 5 boys and 5 girls aged 7-9 years in Japan and 4 boys and 4 girls aged 7-9 years in Korea. As a result: 1) The rectal temperature increased slightly with a rise in air temperature. K group showed a slightly higher rectal temperature. 2) The skin temperature of the hand and foot decreased conspicuously during cold exposure. It was more in the K group than in the J group. 3) Relative local sweat rates were similar in the two groups at $22^{\circ}C\;and\;28.5^{\circ}C$, while they were considerably different at $37^{\circ}C$. Even perspiration was observed over the whole body in the J group but the perspiration was large in the trunk and low in the extremity in the K group. 4) The heart rate was higher in the J group than in the K group but it increased with the rise of the air temperature in both groups.

Ca2+ Regulators affect the Gravitropism and Ethylene Production Induced by Malformin A1 in Maize Root (옥수수 뿌리에서 칼슘 이온 조절제가 malformin A1에 의해 유도된 굴중성과 에틸렌 생합성에 미치는 영향)

  • Hong, Sung-Hyun;Oh, Seung-Eun;Kim, Kun-Woo;Jeong, Hyung-Jin;Kim, Soon-Young
    • Journal of Life Science
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    • v.17 no.2 s.82
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    • pp.174-178
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    • 2007
  • Treatment of malformin A1 is known to increase ethylene production 130% at 4 hr and 56% at 8 hr after treatment in maize root compared to untreated plants. The ethylene production by malformin A1 was maximum level at 4 hr and slowly decreased up to 8 hr. Calcium ion regulators such as A23187 (calcium ionophore) and verapamil (calcium channel blocker) stimulated ethylene production. Treatment of both calcium ion regulators increased about 30% of ethylene production at 4 hr, and 20% at 8 hr. Both calcium ion regulators did not stimulate malformin A1-induced ethylene production at 4 hr as malformin A1 itself did. However, the treatment of calcium ion regulators with malformin A1 maintains the ethylene production for 8 hr. These results suggested that the proper concentration of calcium might need to confer the effect of malformin A1 on the ethylene production. Malformin A1 suppressed the gravitropic curvature of maize root about 58% at 4 hr and 42% at 8 hr compared to control plant. Verapamil inhibited the gravitropic curvature about 54% at 4 hr and 23% at 8 hr compared to control, respectively. But A23187 could not. In addition, verapamil showed more inhibition in malformin A1-induced gravitropic curvature than A23187 in malformin A1 induced. These data suggested that calcium ion regulators affect the malformin A1-induced ethylene production and gravitropic curvature, and give the evidence that calcium ion play an important role in gravitropic curvature in maize root.

A Clinical Study on Relation among Accommodative Amplitude, Response, and Facility in young adults (근시성 굴절부등에 대한 임상적 고찰)

  • Joo, Seok-Hee;Shim, Moon-Sik;Shim, Hyun-Seog
    • Journal of Korean Ophthalmic Optics Society
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    • v.14 no.1
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    • pp.121-125
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    • 2009
  • Purpose: This study has been conducted to know the prevalence of anisometropia and corneal refraction, accommodative response of myopic anisometropia. Methods: The study subject were 67 persons who myopic anisometropia of at least 1.00D, from among 808 total subject without ophthalmic diseases history from age 5 to 89 and the test were used to examine with both eyes open-view autorefractometer (NvisionK-5001). Results: The case which anisometropia were 85(10.5%) persons and myopic anisometropia were 67(78.8%) persons among the anisometropia. Difference between higher myopic eye and lower myopic eye were -1.22D${\pm}$0.94 in spherical equivalent, -0.25D${\pm}$0.72 in accommodative response, 0.04D${\pm}$0.68 in corneal refraction. In addition, the same case of both eyes accommodative response were 33(49.3%) persons, the great case of lower myopic eye accommodative response were 25(37.3%) persons and the great case of higher myopic eye accommodative response were 9(13.4%) persons. Conclusions: Myopic anisometropia was not affected by corneal refraction and both eyes difference of spherical equivalent was less as compared with both eyes difference of accommodative response.

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The Regulation of Stress Responses by Non-tandem CCCH Zinc Finger Genes in Plants (식물에서 non-tandem CCCH zinc finger 그룹 유전자에 의한 스트레스 반응 조절)

  • Hye-Yeon Seok;Md Bayzid;Swarnali Sarker;Sun-Young Lee;Yong-Hwan Moon
    • Journal of Life Science
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    • v.33 no.11
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    • pp.956-965
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    • 2023
  • In plants, there are many CCCH zinc finger proteins consisting of three cysteine residues and one histidine residue, which bind to zinc ions with finger configuration. CCCH-type zinc finger proteins are divided into tandem CCCH-type zinc finger (TZF) and non-TZF proteins: TZF proteins contain exactly two tandem CCCH-type zinc finger motifs whereas non-TZF proteins have fewer or greater than two CCCH-type zinc finger motifs. The functions of TZF genes, especially plant-specific RR-TZF genes, have been well studied in several plants, whereas the functional roles of non-TZF genes have not been adequately researched compared to TZF genes. Many non-TZF genes have been identified as being involved in the responses to biotic and abiotic stresses, such as pathogen, high salt, drought, cold, heat, and oxidative stresses. Some non-TZF proteins bind to RNA and are involved in the post-transcriptional regulation of stress-responsive genes in the cytoplasm. In addition, other non-TZF proteins act as transcriptional activators or repressors that regulate the expression of stress-responsive genes in the nucleus. Despite these studies, stress signal transduction and upstream and downstream genes of non-TZF genes have not been sufficiently researched, suggesting that additional studies of the functions of non-TZF genes' functions in plants' stress responses are needed. In this review, we describe non-TZF genes involved in biotic abiotic stress responses in plants and their molecular functions.

A Study of Accommodative Response on Emmetropia (정시안의 조절반응량에 관한 연구)

  • Shim, Hyun-Seog;Shim, Moon-Sik;Joo, Seog-Hee
    • Journal of Korean Ophthalmic Optics Society
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    • v.11 no.3
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    • pp.187-192
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    • 2006
  • The purpose of this research was to measurement real accmmnodative response amount of emmetropia using both eyes open-view auto-refractometer. We classified 377(male 146, female 231)eyes showing good naked vision at least 1.0, with a spherical equivalent refraction of under ${\pm}0.50D$ and cylindercal refraction of under -0.75D, from 10 to 59(mean $25.8{\pm}12.4$) years into 5 groups with 10 year interval and analyzed change of the near astigmatism and accommodative response amount to distinction of age. Age comparison, total mean 1.47D, 10 years age group 1.63D, 20 years age group 1.57D, 30 years age group 1.71D, 40 years age group 0.97D, and 50 years age group 0.05D. It was no difference between 10 to 30 years age group, But it showed the decre8.se which is remarkable from above 40 years age group and it does not almost response from above 50 years age group. Sexual difference, the man appeared some highly in male(mean $26.4{\pm}12.3$ years) 1.56D m female(mean $26.4{\pm}12.3$) 1.43D. Near-astigmatism power change, mean +0.12D, 10 years age group +0.06D, 20 years age group +0.16D, 30 years age group +0.09D, 40 years age group +0.05D, and 50 years age group +0,06D. No significant difference of astigmatism powers among the an groups, but from all years age group the astigmatism power appeared more highly far-astigmatism than near-astigmatism. Near-astigmatism axis change in the far-astigmatism changes at under ${\pm}10^{\circ}$ 103 eyes, above ${\pm}10^{\circ}$ rotation clockwise direction 108 eyes, above ${\pm}10^{\circ}$ rotation counter-clockwise direction 101 eyes. It was analyzed near-astigmatism axis change.

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Accommodative response measurement using both eyes open-view autorefractometer (양안 개방형 자동굴절검사기를 이용한 조절반응량 검사)

  • Shim, Hyun-Seog;Lee, Seong-Wook;Shim, Moon-Sik;Choi, Sun-Mi;Jang, Seong-Ju
    • Journal of Korean Ophthalmic Optics Society
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    • v.10 no.4
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    • pp.323-328
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    • 2005
  • The purpose of this research was to measurement real Accommodative response amount using both eyes open-view autorefractometer. Compared each Accommodative response amount to distinction of sex, age, kind of ametropia, amount of astigmatism and kind of astigmatism. The subjects were 153 healthy men and women between the age of 20~80 years. Age comparison, 20 years 1.15D, 30 years 1.23D and above 40 years 0.60D. It was no difference between 20 to 30 years old. But, is decrescent remarkably above 40 years old. Ametropia examined by hypermetropia 1.78D, emmetropia 1.51D, low myopia 1.08D, middle myopia 0.72D, high myopia 0.643D. Myopia increased, Accommodative response amount was expose that decrease. Astigmatism examined by non astigmatism 1.13D, low astigmatism 1.12D, middle astigmatism 0.85D, high astigmatism 0.83D. Astigmatism increased, Accommodative response amount was expose that decrease. The sex and astigmatism type difference appeared with the fact that the result is not a difference.

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Properties of Methane Steam Reforming in Micro Channel Reactor (미세유로 반응기를 이용한 메탄 스팀 개질 반응 특성)

  • Lee, Sung-Wook;Lee, Chun-Boo;Kim, Kwang-Ho;Park, Jin-Woo;Hwang, Kyung-Ran;Park, Jong-Soo;Kim, Sung Hyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.114.2-114.2
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    • 2010
  • 마이크로 반응기술은 작은 반응기 부피, 높은 열전달, 넓은 반응 면적/부피 및 정확한 반응시간 조절이 가능하기 때문에 화학공정의 고집적화, 반응 선택도의 향상 및 안전도 향상을 꾀할 수 있는 장점이 있다. 이러한 마이크로 반응 기술을 중소형 천연가스 및 국내에서 소규모로 국지적으로 발생하는 메탄의 활용 방안으로서 개발함은 청정 합성유를 제조함으로서 석유 자원의 고갈과 고유가에 대비하여 에너지 자원의 다변화 및 자립을 확보 할 수 있다. 본 연구에서는 마이크로 반응기술을 적용한 미세 유로 반응기(Micro Channel Reactor)를 사용하여 메탄 스팀 개질 반응 특성을 연구하였다. 미세유로 반응기는 내부 홀이 존재하는 plate를 적층함으로 반응기내에 반응가스가 이동할 수 있는 미세유로가 존재하게 하였다. 이러한 미세유로는 반응기의 크기가 작음에도 반응기내에서 반응가스가 충분히 반응할 수 있는 시간과 높은 열전달 효율을 가질 수 있게 한다. 메탄 스팀 개질 반응에 사용된 촉매는 Ni 촉매를 사용하였고, 반응에 필요한 열원으로는 수소 연소에서 발생한 열을 사용하여 반응을 유도하였다. 본 반응기는 외부의 열원을 사용하지 않고, 반응기 내부의 수소 연소에서 발생한 열을 사용함으로 적은 발생 열만으로 메탄 스팀 개질 반응에 필요한 에너지를 얻을 수 있고, 열의 손실이 적다. 또한 메탄 스팀 개질 반응으로 발생한 일부의 수소를 열원으로 이용하여 에너지 사용면에서도 효율적인 반응 공정이다.

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Effects of pinching frequency on the growth of four carnation cultivars in hydroponics (카네이션 양액재배시 적심횟수에 따른 품종별 생육반응)

  • 정향영;김형득;최성렬;김태익;신학기;고재영;김수련
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1998.10a
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    • pp.103-106
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    • 1998
  • 카네이션에서 적심은 분지수를 늘려 종묘비를 절감하고 개화기를 조절하는데 많이 이용되고 있다. 적심횟수는 1회, 1.5회, 2회의 방법이 있으며 농가에서는 주로 1.5회를 이용하고 있다. 양액재배는 토경재배에 비해 생장속도가 빨라 개화가 빠른 것으로 일반적으로 알려져 있고 양액재배에 적합한 품종 역시 숙기가 빨라 2회 채화가 가능하거나 숙기가 늦은 품종, 절화장이 짧은 품종, 분지력이 좋은 품종이 유리한 것으로 알려지고 있다. (중략)

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방전으로 인한 화학반응과 그의 응용

  • 이덕출
    • 전기의세계
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    • v.34 no.11
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    • pp.671-677
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    • 1985
  • 지금까지 알려진 방전반응은 이외로 수가 많지만 이들을 정연하게 분리해본다는 것은 쉽지않다. 일반적으로 방전으로 인하여 화학반응은 물질에 전기에너지를 흡수시키면서 행하는 기술이고 전기적입력량을 화학적입력량으로 변환할때 복잡한 조작 파라미터를 솜씨좋게 조절해야한다. 대부분의 반응을 보면 어떠한 방전형식으로 그의 반응물질을 방전처리 하고 혹은 그중에서 방전을 행하게 하고 생성물을 분석한 것이다. 반응의 단순화 혹은 생성물이 1차 혹은 부착적으로 이루어진 것인가에 대한 검토는 적고 어떤계는 방전처리하면 이와같이 되었다고 한 예에 지나지 않는다고 본다. 방전형식에 의한 차이, 방전조건 가령 전극의 성질, 구조 및 배치, 가스압력, 조성온도, 유속 및 방전전류에 의해서도 물론 반응내용에 다소 차이가 있다고 생각된다. 특히 방전반응의 큰 결점은 소요의 소과정만을 일으키게 하는 에너지를 선택적으로 투입할 수 없는점 예를 들면 방전을 행하기 위하여는 전자가 전계내에서 가속되어 분자를 이온화하는 경우 동시에 분자의 여기 해리도 일으키는 상태가 있음으로 분자의 해리 과정만을 단일로 일으키게 하는 것은 곤란하다. 따라서 반응의 단순화가 얻을 수 없다.

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