• Title/Summary/Keyword: 제타포텐셜

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Effective Thermal Conductivities of Al203 Nanoparticles Suspended in Water with Low Concentration less than 1 Vol. % (1%미만의 부피비를 가지는 알루미나 나노유체의 유효 열전도도)

  • Hwang, Kyo-Sik;Lee, Byeong-Ho;Kim, Jun-Ho;Jang, Seok-Pil
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.15 no.3
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    • pp.1-5
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    • 2007
  • In this paper, effective thermal conductivities of water-based Al203-nanofluids with low concentration from 0.01 vol. % to 0.3 vol. % are experimentally obtained by transient hot wire method (THWM). The water-based Al203-nanofluids are manufactured by two-step method which is widely used. To examine suspension and dispersion characteristics of the water-based A1203-nanofluids, Zeta potential as well as transmission electron micrograph (TEM) is observed. We confirm the manufactured Al203-nanofluids have good suspension and dispersion. The effective thermal conductivities of the water-based Al203-nanofluids with low concentration are enhanced up to 1.64% compared with that of DI water at $21^{\circ}C$. In addition, experimental results are compared with theoretical results from Jang and Choi model.

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Thin film characteristic improvements of SWCNT-TCF through substrates pre-treatment processing

  • Park, Rak-Gyeong;Sin, Gwon-U;Han, Jong-Hun;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.371-371
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    • 2010
  • 탄소나노튜브(CNT)는 기계적인 특성이 뛰어나며, 화학적으로 안정하고, 전기적으로 도체 및 반도체성을 가지고 있을 뿐만이 아니라 직경이 최소 1nm 수준으로 종횡비 및 비표면적이 매우 큰 특성을 가지고 있다. CNT는 투명전극, 유연성 디스플레이, 전자종이 분야 등 투명 전극 응용 분야에서 ITO 대체 신소재로 각광을 받고 있다. 본 발표에서는 SWCNT 전도막의 특성을 향상시키기 위해 PET 기판에 다양한 전처리 방법을 적용하여 SWCNT의 부착력 및 접착력, 투명전극의 면저항, 투과도 및 균일도 향상을 통해 SWCNT 투명전극 특성향상 연구를 진행했다. 접촉각과 표면에너지 제어를 통한 박막특성과의 상관관계 분석, 전처리 방법에 따른 표면에너지 및 제타포텐셜 변화와 박막특성과의 관계를 규명, Roughness 조절을 통한 기판의 면저항과 투과도 향상, 플라즈마 및 polymer 처리를 통해 물리적, 화학적 기판 전처리에 따른 SWCNT 투명전극 특성 향상을 목적으로 실험을 진행했다. 플라즈마 처리 후 polymer 처리된 박막에서는 친,소수 작용기 양의 변화에 따른 상관관계를 보이지 않았지만, 플리즈마 처리 후 친,소수 작용기 양과 Roughness 변화정도에 대해서는 면저항과 투과도의 변화를 보였다.

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Computer simulation of titania particle agglomeration (티타니아 입자의 응집에 대한 컴퓨터 시뮬레이션)

  • Kim, Jong-Cheol;Auh, Keun-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.23-29
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    • 2000
  • The agglomeration of titania particles with 30 nm in radii was simulated based on the colloidal stability. For surface potential increase from 4.5 to 16.8 mV the height of energy barrier increased. This tendency may explain the experimentally observed aggregation behavior where particles with smaller size and higher potential exhibited higher stability but form bigger and harder agglomerates with irregular shapes after drying.

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Preparation of Polystyrene Particles Containing Poly(ethylene glycol) Groups and Their Surface Charge Characterization in Dielectric Medium (폴리(에틸렌 글리콜)기를 갖는 폴리스티렌 입자의 제조와 유전 매질내에서의 표면 전하 특성)

  • 김성훈;김배중;권대익;박기홍
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.524-530
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    • 2004
  • Polystyrene particles (PS) with poly(ethylene glycol) units on surface were formed by an emulsifier-free emulsion polymerization using styrene, poly(ethylene glycol) methacrylate (PEG-MMA) or poly(ethylene glycol) dimethacrylate (PEG-diMMA) at pH 7, and followed by freeze-drying to give the corresponding powders. The structures of PS particles were confirmed by FT-IR spectroscopy, and the particle size and distribution the PS particle were observed by scanning electron microscopy and particle analyzer. Monodisperse polymer particles were obtained at a concentration of PEG-MMA 2∼5 mol% or PEG-diMMA 1 mol% relative to styrene. The highest zeta potential of polymer surface was measured to be 183 mV at a polymer of PEG-MMA 5 mol%, which was measured in dielectric medium by means of ELS-8000 dynamic light scattering.

Effective Thermal Conductivities $Al_2O_3$ Nanoparticles Suspended in Water with Low Concentration (1%미만의 부피비를 가지는 알루미나 나노유체의 유효 열전도도)

  • Lee, Byeong-Ho;Kim, Jun-Ho;Kong, Yu-Chan;Jang, Seok-Pil;Koo, Ja-Ye
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2177-2181
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    • 2007
  • In this paper, effective thermal conductivities of water-based $Al_2O_3$-nanofluids with low concentration from 0.01 vol. % to 0.3 vol. % are experimentally obtained by transient hot wire method (THWM). The water-based $Al_2O_3$-nanofluids are manufactured by two-step method which is widely used. To examine suspension and dispersion characteristics of the water-based $Al_2O_3$-nanofluids, Zeta potential as well as transmission electron micrograph (TEM) is observed. We confirm the manufactured $Al_2O_3$-nanofluids have good suspension and dispersion. The effective thermal conductivities of the water-based $Al_2O_3$-nanofluids with low concentration are enhanced up to 1.64% compared with that of DI water at $21^{\circ}C$. In addition, experimental results are compared with theoretical results from Jang and Choi model.

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Analysis of Electroosmosis Drainage in Clayey Soil (점성토의 전기삼투 배수에 관한 분석)

  • 김병일;한상재;김수삼
    • Journal of the Korean Geotechnical Society
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    • v.19 no.1
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    • pp.131-142
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    • 2003
  • The characteristics of electroosmosis drainage in clayey soil were investigated, when an electrokinetic technique was applied for the purpose of separating heavy metals in contaminated ground. A series of laboratory tests, considering voltage, zeta potential, pH distribution, and current, were performed for a lead-contaminated kaolin. The results of laboratory tests were compared with numerical analysis of finite difference method. The 1311owing conclusions were obtained: The flow velocity in electroosmosis was very sensitive to the chemical and electrical characteristics of the clay. As the concentration of ion increases, the flow rate decreases and the amount of drainage also decreases as time elapses.

Fabrication of Y-TZP/Ce-TZP Multilayer Composites Using Slip Casting(I) (슬립주입에 의한 Y-TZP/Ce-TZP 다층복합체의 제조(I))

  • Kim, Min-Ju;Lee, Yun-Bok;Kim, Yeong-U;Jeon, Byeong-Se;Park, Hong-Chae
    • Korean Journal of Materials Research
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    • v.10 no.8
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    • pp.545-550
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    • 2000
  • 3Y-TZP, 12Ce-TZP 및 3Y-TZP, 12Ce-TZP 현탁액의 제타포텐셜과 겉보기점도의 측정으로부터 슬립주입공정에 의한 다층복합체의 제조조건을 조사하였다. 아울러 다층복합체의 소결밀도, 미세구조, 결정상에 미치는 열처리의 영향을 검토하였다. 3Y-TZP와 12Ce-TZP 현탁액의 등전점을 pH 8부근이었으나 3Y-TZP/12Ce-TZP의 등전점은 pH8.6이었다. 현탁액은 전단속도의 증가와 더불어 점도가 감소하는 의가소성유동을 나타내었다. 15 및 20vol% 고체함량을 갖는 3Y-TZP와 3Y-TZP/12Ce-TZP 현탁액은 소량(0.3wt%)의 유기해교제의 첨가만으로 슬립주입에 적당한 유동성을 보유하였으나, 12Ce-TZP의 경우는 점도를 감소시키기 위하여 부가적인 전해질이 필요하였다. 이론밀도의 98% 이상을 보유하고 0.3~$2.2\mu\textrm{m}$의 입경을 갖는 치밀한 다층복합체가$ 1500^{\circ}C$ 소결로 얻어졌다.

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Numerical Analysis on Mixing in a Microchannel with Inhomogeneous Surface Charge (불균일 표면전하를 지닌 미소채널 내에서의 혼합에 관한 수치 해석적 연구)

  • Song, Kyung-Suk;Lee, Do-Hyung
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1004-1009
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    • 2003
  • Electroosmotic flow induced by an applied electrostatic potential field in microchannel is analyzed in this study. The electroosmotic flow is an alternative to pressure driven flow in microchannels, but the usage has been limited to the simple cases. In this study, We analyze electroosmotic flow driven by inhomogeneous surface charge on the channel wall. The surface charge varies along a direction perpendicular to the electric field in order to generate the electroosmotic flow. A numerical results substantiate the highly efficient mixing performance. It is highly the beneficial to fabrication process since only straight microchannel rather than complex geometry is enough to yield efficient mixing.

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The Fundamental Study on th e Soil Remediation for Copper Contaminated Soil using Nanobubble Water (나노버블수에 의한 구리 오염 토양의 정화에 관한 기초 연구)

  • Jeong, So-Hee;Kim, Dong-Chan;Han, Jung-Geun
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.1
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    • pp.31-39
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    • 2017
  • The fundamental study for an application of nanobubble as a soil remediation enhancer on heavy metal contaminated soil was carried out. The existence and long-term stability of hydrogen nanobubbles were investigated by particle analysis and zeta-potential analysis. And the removal efficiency of copper using nanobubble water(NBW) and distilled water(DW) were compared and analyzed through a batch desorption test. As a result, it is confirmed that nanobubble which was fabricated by compression-dissolution type generator can exist for more than 14 days. The results of batch test show that copper removal of NBW was higher than that of DW irrespectively to soil type and increased as solid-liquid ratio and contact time increased, respectively. According to the pH change, the removal of copper on sand was higher on the acid side but the removal difference was slightly lower on the clay. It is considered that a high efficiency of NBW in copper removal is due to the large surface area and high zeta-potential of nanobubbles. Therefore, the nanobubble can be applied to soil remediation for heavy-metal contaminated soil as an eco-friendly enhancer.

A Study on the Positively Charged Filter for Removing Fine Particles in Water (양전하가 부가된 수처리 필터의 입자제거특성에 관한 연구)

  • Jung, Sung-Hak;Kim, Jong-Won;Kim, Sang-Hee;Jeon, Byung-Heon;Lee, Seung-Gap;Lee, Jae-Keun;Ahn, Young-Chull
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.5
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    • pp.454-460
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    • 2012
  • The purpose of the present work is to investigate the removal characteristics of positively charged filters for capturing negatively charged particles such as bacteria and virus in water. In order to reduce the pressure drop and increase the filtration efficiency, the filter media, modified by charge modifier having positive functional groups, is developed and evaluated. Improved liquid filters have been developed with the modified surface charge to capture and adsorb particles by electrokinetic interaction between the filter surface and particles contained in an aqueous liquid. The positively charged filter media is composed of glass fiber, cellulose and poly-ethylenimine resin for positively charging with the variation of volume ratio. The zeta potential value of the positively charged filter is +37.92 mV at the glass fiber and cellulose content ratio of 50 : 50 with resin content of 100%, while that of the PSL test particle is -23.5 mV at pH 7. The removal efficiency of the electro-positively charged filter is 98% for PSL particles of 0.11 ${\mu}m$, while that of the negatively charged filter is 7%. The positively charged filter media showed the potential to be an effective method for removing fine particles from the contaminated water for liquid filtration.