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Preparation and Characterization of Polyurethane Flame-Retardant Coatings Containing Trichloro Lactone Modified Polyesters (트리클로로 락톤 변성폴리에스테르를 함유한 폴리우레탄 난연도료의 제조 및 난연특성)

  • 정충호;박형진;김성래;우종표;김명수
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.200-208
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    • 2002
  • Two-component polyurethane flame-retardant coatings were prepared by blending trichloro lactone modified polyesters (TAPTS) and isocyanate, Desmodur IL. Polycondensation reaction of trichlorobenzoic acid (TBA) as a flame-retardant component, and adipic acid with trimethylolpropane, polycaprolactone 0201, and 1,4-butanediol gave the corresponding TAPTs. The content of TBA was adjusted from 10 to 30 wt% in our experiment. It was found that various properties of these new flame-retardant coatings were comparable to other non-flame-retardant coatings. We also carried out three different tests for the measurement of flammability of flame -retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TBA were determined as 'no burn'. The results of flammability test for the coatings with 20 and 30 wt% of TBA contents indicated the limiting oxygen index (LOI) values of 25% and 27% respectively, which implied relatively good flame retardancy. They also showed the char length of 3.6-5.2 cm according to $45^{\circ}$ Meckel burner test, which can be classified as the first grade flame-retardant coatings.

Evaluation of Un-Cooked Restructured Belly and Cooked Restructured Bacon using a Protein-Emulsion Material from Pork (돈육 유래 단백유화물을 이용하여 제조한 비가열 재구성삼겹살 및 가열 재구성 베이컨의 품질특성 평가)

  • 허선진;강근호;양한술;정진연;박구부;주선태
    • Food Science of Animal Resources
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    • v.24 no.2
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    • pp.146-150
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    • 2004
  • The objectives of this study were to develope the uncooked-restructured belly (URB) and the processed-restructured bacon (PRB) using a protein-emulsion material (PEM) from pork, and to evaluate the quality characteristics of the URB and PRB. The PEM used to adhere muscle and fat tissues was prepared with a salt-soluble protein and emulsions (ratio 9:1). In color measurements, L$\^$*/, a$\^$*/ and b$\^$*/ values were significantly (p<0.05) higher in URB than PRB. There was no significant difference in L$\^$*/ value between PRB from fresh pork and PRB from thaw pork PRB showed significantly (p<0.05) higher water holding capacity compared to URB. Tensil strength of PRB was also significantly (p<0.05) higher than that of URB. However, PRB from thawed pork marked the lowest color score among restructured meats in sensory evaluation. The scores of juiciness and tenderness were significantly (p<0.05) Higher in URB compared to PRB. Consequently URB had significantly (p.<0.05) higher score of overall acceptability than PRB. These results suggested that URB made with PEM could have a better sensory characteristics compared to PRB. Results also suggested that the PEM would not be enough to adhere fresh muscle and fat tissues as much as PRB, even though the possibility of PEM was confirmed as a meat glue.

A Study on the Characteristics of Combustion and Manufacturing Process on Refuse-derived Fuel by Mixing Different Ratios with Organic and Combustible Wastes (유기성폐기물 고체연료화를 위한 연소 및 제조과정의 특성연구)

  • Ha, Sang-An
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.27-38
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    • 2009
  • To investigate the feasibility of refuse derived fuels (RDFs) combined of sewage sludge and combustible wastes such as substitutive fuels instead of a stone coal, several different RDFs made with different mixtures of sewage sludge and combustible wastes were analyzed by various experiments. The combustion characteristics for the RDFs were investigated by analyzing fuel gases, and heating values were also measured by a bomb calorimeter. The fundamental properties such as moisture contents, ratios of combustible materials, amounts of ashes, heavy metals, ratios of each chemical elements and heating values were analyzed in accordance with mixing ratios of wt(%) for researching the characteristics of the RDFs. $RDF_{k-1}$ was made of mixing materials which were dried sewage sludge, food wastes and combustible wastes. $RDF_{k-2}$ was made of mixing materials which were peat-moss, tar and sewage sludge. Combustion experiments were carried out at the optimal conditions which were m=2 under air-fuel condition and $850^{\circ}C$. The retention times in the combustor were set at 5, 10 and 15minutes. 50 g of RDFs was put in the combustor for each experiments. The ranges for heating values of $RDF_{k-1}$ with different mixing ratios were from 6,900 kcal/kg to 8120 kcal/kg. The ranges for heating values of $RDF_{k-2}$ with different mixing ratios were from 4,014 kcal/kg to 8,050 kcal/kg. As a result of this study, the heating values, moisture contents, components of chemical elements and mixing ratios of the materials in RDFs had big effects on the efficiency of the combustion. In $RDF_{k-1}$, the higher amounts of combustible wastes in the mixtures, the higher heating values, concentrations of $C_xH_y$ and amounts of ashes were produced. In $RDF_{k-2}$, the higher tar amounts in the mixtures caused the higher heating values, amounts of ashes, concentrations of CO gas and CxHy.

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정책정보 - 냉동식품 HACCP 관리 기준

  • 한국식품공업협회
    • Food Industry
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    • s.220
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    • pp.22-65
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    • 2011
  • ${\bigcirc}$ 본 업소는 냉동식품(냉동만두류, 냉동면류, 냉동피자)를 생산하는 식품제조 가공업소로서 총 5명의 인원이 냉동식품 3개 제품을 생산하여 매출액은 (약00원)이며 주로 대형 유통 판매업소에 판매하고 있다. ${\bigcirc}$ 본 업소의 냉동식품은 축산물(돈육) 농산물 등과 밀가루, 소금 등을 배합 성형 후 가열 등의 공정을 거쳐 생산된 제품으로 원료 취급과정에서의 오염이나 불충분한 가열, 교착오염 등으로 식중독균(병원성대장균, 황색포도상구균등)과 원료 및 제조과정에서 이물(금속등)이 혼입할 수 있으며, ${\bigcirc}$ 이로 인한 주요클레임 발생사례는 최근 3년간 관계당국으로부터 대장균군 검출 3건, 소비자클레임 2건이 있었다. - 연도별 주요 클레임내용은 '08년도에는 대장균군 검출 3건(냉동만두류), '09년도 날벌레 이물검출 1건(냉동피자), '10년도에는 철수세미1건(냉동면류)이었다. ${\bigcirc}$ 이러한 위해발생을 사전에 예방하기 위해 중점관리해야하는 공정은 가열(중숙, 탕숙, 가열 굽기)공정, 세척공정으로 판단되며, 금속 등의 이물 혼입 또한 중점적으로 관리할 필요성이 있다. ${\bigcirc}$ 본 업소에서 생산하는 냉동식품(냉동만두류, 냉동면류, 냉동피자)는 가열(중숙/탕숙/가열/굽기)공정 및 세척공정에서의 가열(중숙/탕숙/가열/굽기) 후 품온을 설정하여 CCP 1로, 세척시간과 세척수량, 원물량을 설정하여 CCP 2로 관리하고 있으며, 2시간마다 모니터링하고 한계기준 이탈여부를 기록하도록 하고 있다. ${\bigcirc}$ 종합적인 공정 및 일반위생관리를 위해 개인위생 상태, 냉동 냉장고 온도 확인 등 총 30개 항목에 대하여 정기적 점검(매일 18, 주간 4, 월간 4, 분기 1, 연간 3)을 실시하고 있으며, ${\bigcirc}$ 따라서 지속적인 모니터링을 통해 미흡사항의 원인으로 파악하고 문제점 제거를 위해 체계적이고 지속적인 관리가 필요한다.

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Effect on the Quality Characteristics of Beef Jerky Ripened by Wine (와인 숙성이 우육포의 품질특성에 미치는 영향)

  • Lee, Kyung-Soo;Moon, Yoon-Hee;Jung, In-Chul
    • Journal of Life Science
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    • v.18 no.11
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    • pp.1538-1542
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    • 2008
  • This study was carried out to investigate the effect of wine ripening on quality characteristics such as chemical compositions, Hunter's color, rheological properties, water activity, pH, TBARS value, VBN content, total plate count and sensory score. Beef jerky was prepared by three types such as beef jerky containing water 50 ml (T0), beef jerky containing water 25 ml and wine 25 ml (T1), and beef jerky containing wine 50 ml (T2). The moisture, crude protein, crude fat, crude ash, $L^*$ (lightness), $a^*$ (redness), $b^*$ (yellowness), hardness, springiness, cohesiveness, gumminess and chewiness were not significantly different among the beef jerky. The Aw, pH and TBARS value were not significantly different among the beef jerky, the VBN content and total plate count of T2 had the lowest among the beef jerky (p<0.05). The flavor of T2 was superior to the T0 (p<0.05), and the taste, color, tenderness, juiciness and overall acceptability were not significantly different among the beef jerky.

소규모 업소용 HACCP 표준 관리 기준

  • 식품의약품안전청
    • Food Industry
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    • s.218
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    • pp.24-49
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    • 2010
  • ${\bigcirc}$ 본 업소는 어묵류(튀김어묵, 찐어묵, 구운어묵)을 생산하는 식품제조 가공업소로서 총 5명의 인원이 어묵류 15개 제품을 생산하여 매출액은(약 00원)이며 주도 대형 유통판매업소에 판매하고 있다. ${\bigcirc}$ 본 업소의 어묵은 연육, 농산물 등과 식품첨가물을 배합 성형 후 가열 등의 공정을 거쳐 생산된 제품으로, 원료 취급과정에서의 오염이나 불충분한 가열, 교차오염 등으로 식중독균(병원성대장균, 황색포도상구균 등)과 원료 및 제조과정에서 이물(금속 등)이 혼입될 수 있으며, ${\bigcirc}$ 이로 인한 주요클레임 발생사례는 최근 3년간 관계당국으로부터 대장균군 검출 3건, 소비자클레임 2건이 있었다. - 연도별 주요 클레임내용은 '08년도에는 대장균군 검출 3건, '09년도 튀김어묵에서 날벌레 이물 검출 1건, '10년도에는 찐어묵에서 철수세미 1건 이었다. ${\bigcirc}$이러한 위해발생을 사전에 예방하기 위해 중점관리해야 하는 공정은 가열공정으로 판단되며, 금속등의 이물혼입 또한 중점적으로 관리할 필요성이 있다. ${\bigcirc}$ 본 업소에서 생산하는 어묵류(튀김어묵, 찐어묵, 구운어묵)는 가열공정에서의 가열온도와 시간을 각각 설정하여 CCP 1로 관리하고 있으며, 품온이 $85^{\circ}C$이상으로 유지될 수 있도록 2시간마다 모니터링하고 한계기준 이탈여부를 기록하도록 하고 있다. ${\bigcirc}$또한 금속검출공정을 CCP 2로 관리하여 2mm${\varphi}$ 이상의 금속이물 혼입여부를 상시 확인하고 있으며, 금속검출기의 정상 작동여부를 4시간마다 모니터링하고 기록하도록 하고 있다. ${\bigcirc}$종합적인 공정 및 일반위생관리를 위해 개인위생 상태 냉동, 냉장고 온도 확인 등 총 29개 항목에 대하여 정기적 점검(매일 17, 주간 4, 월간 4, 분기 1, 연간 3)을 실시하고 있으며, ${\bigcirc}$따라서 지속적인 모니터링을 통해 미흡사항의 원인으로 파악하고 문제점 제거를 위해 체계적이고 지속적인 관리가 필요하다.

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Studies on the Durable Softners (II) -Applications of Alkyl Imidazoline Derivatives as the Durable Softners- (내구성유연제에 관한 연구 (II) -알킬이미다졸린 유도체의 내구성유연제로서의 응용-)

  • Kim, Young-Geun;Park, Hong-Soo;Song, Kab Jun
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.168-175
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    • 1990
  • Softners-BHICS, BBICS, and BTICS were prepared from 1, 2-disubstituted imidazoline compounds, such as 1-behenoylaminoethyl-1-glycidyl-2-heneicosylimidazolinium chloride(BHIC), 1-behenoylbis(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride (BBIC), and 1-behenoyltris(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride(BTIC), and treated to acrylic fiber. The measurements of softness, lubricating and antistatic properties showed that they have not only good softness and lubricating property but also a little antistatic property. Furthermore, the initial bending resistance for BBICS and BTICS was 5 grade, and remained 3~4 grade after 5 times washing. As results of these tests, they showed good softner effects having durability. The prepared softners were proved to be durable softner through a series of experimental results for washable properties of feeling by varying treating temperature and pH change.

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냉동수산식품 HACCP 관리 기준

  • 식품의약품안전청
    • Food Industry
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    • s.219
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    • pp.24-60
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    • 2011
  • ${\bigcirc}$ 본 업소는 수산물가공품(냉동어류, 냉동연체류, 조미가공품)을 생산하는 식품제조 가공업소로서 총 5명의 인원이 수산물가공품 8개 제품을 생산하여 매출액은(약 00원)이며 주로 집단급식소에 판매하고 있다. ${\bigcirc}$ 본 업소의 수산물가공품은 냉동생선 해동(또는 냉장생선 이용), 전처리(냉장제거 등) 이후 세척 후 급냉하여 포장하거나(냉동어류 및 냉동연체류) 가열 후 포장하여 급냉하는(조미가공품) 공정을 거쳐 생산된 제품으로 원료 취급과정에서의 오염이나 불충분한 가열, 교차오염 등으로 식중독균(병원성대장균, 황색포도상구균 등)과 원료 및 제조과정에서 이물(금속 등)이 혼입할수 있으며, ${\bigcirc}$ 이로 안한 주요클레임 발생사례는 최근 3년간 관계당국으로부터 대장균군 검출 3건, 소비자클레임 2건이 있었다. - 연도별 주요 클레임내용은 '08년도에는 대장균군 검출 3건, '09년도 냉동어류에서 날벌레 이물 검출 1건, '10년도에는 냉동연체류에서 철수세미 1건 이었다. ${\bigcirc}$ 이러한 위해발생을 사전에 예방하기 위해 중점관리해야 하는 공정은 세척공정(냉동어류 및 냉동연제류) 및 가열공정(조미가공품)으로 판단되며, 금속 등의 이물 혼입 또한 중점적으로 관리할 필요성이 있다. ${\bigcirc}$ 본 업소에서 생산하는 냉동어류 및 냉동연체류는 세척공정에서 세척시간과 세척수량, 원물량을 각각 설정하여 CCP 1로 관리하고 2시간마다 모니터링하고 있으며, ${\bigcirc}$ 조미가공품은 가열온도와 시간을 각각 설정하여 CCP 2로 관리하고 있으며, 품온이 $85^{\circ}C$이상 유지할수 있도록 2시간마다 모니터링하고 한계기준 이별여부를 기록하도록 하고 있다. ${\bigcirc}$ 또한 금속검출공정을 CCP 2로 관리하여 2mm${\varphi}$ 이상의 금속이물 혼입여부를 상시 확인하고 있으며, 금속검출기가 정상 작동여부를 4시간마다 모니터링하고 기록하도록 하고 있다. ${\bigcirc}$ 종합적인 공정 및 일반위생관리를 위해 개인위생 상태 냉동 냉장고 온도 확인 등 총 29개 항목에 대하여 정기적 점검(매일 17 주간 4 월간 4 분기 1, 연간 3)을 실시하고 있으며, ${\bigcirc}$ 따라서 지속적인 모니터링을 통해 미흡사항의 원인으로 파악하고 문제점 제거를 위해 체계적이고 지속적인 관리가 필요하다.

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Corporate Valuation of Difference in Operating and Financial Leverages (레버리지도 차이에 따른 국내기업 가치분석)

  • Chung, Bhum-Suk
    • Management & Information Systems Review
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    • v.30 no.4
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    • pp.175-193
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    • 2011
  • This paper tests a correlation between degrees of operating leverage(DOL) and financial leverage(DFL). For an empirical analysis, this paper extracted information from financial statements of manufacturing companies listed in the Korea Stock Exchange. Data extend from 1990 to 2009. The DOL continued to increase until 1997, but decreased dramatically after the IMF financial crisis. However, the DOL has been at a higher level than companies of other countries such as USA and Japan. The DFL has been maintained at a much higher level, as expected. The empirical results indicate a positive correlation between the DOL and the DFL. To further investigate, we divide the whole sample into subgroups according to such management elements as asset size, IMF crisis. The results for sub-samples are different from those of whole sample. This indicates we need to incorporate specific managerial factors in order to correctly explain financial decision processes.

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Changes in the Quality Characteristics of Bean Sprout, Radish, and Pork During the Unit Processing in Frozen Bibimbab Production (냉동 비빔밥 제조 공정 중 콩나물, 무채 및 돈육의 품질 변화)

  • Kim, Yiseul;Seon, Minji;Hong, Geun-Pyo
    • Food Engineering Progress
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    • v.21 no.4
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    • pp.332-340
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    • 2017
  • This study investigated the changes in the physicochemical properties of soybean sprout, radish, and pork loin during frozen Bibimbab production. The qualities of soybean sprout were affected by the blanching, thawing, and cooking processes, with the blanching process particularly regarded as an important process to attribute the overall quality of the soybean sprouts in the final product. High weight loss of radish was found in the thawing and cooking processes, while the weight loss was relatively lower than that of soybean sprout. However, mixing with hot rice can be attributed for the steep decrease in shear force of the radish. For pork meat, normally thermal treatment such as mixing with hot rice and cooking manifested quality deterioration. Based on the results, mixing process appeared to be the most important process which affected the final quality of the materials. To improve the quality of final frozen Bibimbab, therefore, it was recommended to freeze the food ingredient separately from rice prior to packaging, which warranted the follow up exploration.