• Title/Summary/Keyword: 정화율

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Al2O3 산화막 방전관을 통한 개선된 오존발생장치에 관한 연구

  • Lee, Seong-Ho;Min, Jeong-Hwan;Gong, Seong-Uk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.457-457
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    • 2014
  • 오존발생방법은 다양한 방식으로 구현이 가능하나 대용량 장치를 만들기 위해서는 DBD (Dielectric barrier discharge) 구조의 형태의 가지고 있다. 이러한, DBD는 반도체의 MOS (Metal On Semiconductor)의 반대 구조를 가진 SOM (Semiconductor On Metal)의 형태를 가지고 있으며 대부분이 Oxidation 산화물을 가지고 구현한다. 오존발생기는 반도체 공정, 환경 및 정화 등 다양한 분야에 사용이 되고 있는 상황으로 성능개선을 위한 연구가 필요한 상황이다. 대표적으로 사용되는 물질인 $SiO_2$를 가지고 있는 상황이며 Silicon은 에너지 Bandgap이 1.1 eV로 금속위에 증착되어 통상적으로 사용되는 문턱전압은 0.7 V에 해당이 된다. 현재 점차적으로 연구가 진행되고 있는 $Al_2O_3$는 8.8 eV의 bandgap을 가지고 있으며 유전 상수가 9로 $SiO_2$인 3.9보다 높은 유전률 특징을 가지고 있다. 따라서, 본 연구는 오존 발생장치에 사용되는 방전관을 기존의 $SiO_2$에서 $Al_2O_3$ 방식으로 대체하므로써 실제적인 유전율의 값의 차이와 오존 발생시 오존변화율 증대에 관하여 연구하였다. $SiO_2$ 방전관은 Fe 메탈위에 약 3 mm정도의 두께를 binding시켜 N4L사의 PSM1700 모델 LCR meter를 사용하여 1.3 kHz시 7.2 pF의 유전율 확인 할 수 있으며 동일한 조건의 금속 메탈위에 $Al_2O_3$를 binding 시켜 측정한 결과 1.07 kHz시 10.7 pF의 유전율을 가지게 되어 40% 이상 높은 유전율을 가지게 되는 것을 확인 할 수 있다. 오존발생을 위하여 가변 주파수형 트랜스 드라이버를 통한 공진 주파수를 생성하여 방전 증폭을 위한 Amplifier를 통하여 변환률을 높이는 방식을 적용하여 MIDAC사의 I1801모델 적외선 분광기(FT-IR)를 통한 오존발생량을 측정하여 기존의 $SiO_2$의 방전관은 시간당 54 g의 오존 발생률 가지게 된다. $Al_2O_3$는 시간당 70 g 정도의 오존 발생률 가지므로 기존의 $SiO_2$ 보다 발생률 높은 것을 확인 할 수 있다.

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Remediation Process by using Lime and Calcium Carbonate for Heavy Metal Contaminated Groundwater Originated from Landfills (소석회$(Ca(OH)_2)$와 탄산칼슘$(CaCO_3)$을 이용한 매립장 주변 중금속 오염 지하수 정화)

  • Song Nain;Lee Yesun;Lee Minhee
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.273-284
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    • 2005
  • Coagulation and precipitation process by using lime$(Ca(OH)_2)$ and calcium carbonate $(CaCO_3)$ were applied to remove heavy metals from groundwater in laboratory scale. From results of batch tests, by the addition of $0.3\;wt.\%$ lime, more than $90\%$ of As and Mn were removed and $70-80\%$ of Cd and Zn were removed by using $0.5\;wt.\%$ of lime. Removal efficiency of Pb almost reached $100\%$ with only $0.1\;wt.\%$ of calcium carbonate and more than $93\%$ of Cd were removed by the addition of $0.1\;wt.\%$of calcium carbonate. Pilot scale column experiments were performed to remove heavy metals in the separation process of precipitated Hoc to supernatant after the coagulation/ precipitation. For lime as a coagulant, more than $99\%$of As were removed from artificial groundwater and removal efficiencies of Cd, Mn, and Zn were over $80\%$. By using calcium carbonate, more than $95\%$ of Cd and Pb were removed in column experiment. Fe and Mn contaminated groundwater taken from a real landfill site, Ulsan was used for the column experiment and more than $99\%$ of Fe and Mn were removed by the addition of $1\;wt.\%$ lime in column experiment, suggesting that the coagulation/precipitation process by using lime and calcium carbonate have a great possibility to remove heavy metals from contaminated groundwater.

Study on the elution of biostimulant for in-situ bioremediation of contaminated coastal sediment (오염된 연안저질의 현장생물정화를 위한 미생물활성촉진제의 용출특성 연구)

  • Woo, Jung-Hui;Song, Young-Chae;Senthilkumar, Palaninaicker
    • Journal of Navigation and Port Research
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    • v.38 no.3
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    • pp.239-246
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    • 2014
  • A study on the elution characteristics of biostimulating agents (sulfate and nitrate) from biostimulants which are used for in-situ bioremediation for the coastal sediment contaminated with organic matter was performed. The biostimulating agents were mixed with the coastal sediment, and then massed the mixture into ball. Two kinds of ball type biostimulant were prepared by coating the ball surface with two different polymers, cellulose acetate and polysulfone. A granular type biostimulant (GTB) was also prepared by impregnating a granular activated carbon in the biostimulating agent solution. The image of scanning electron microscopy for the biostimulant coated with cellulose acetate (CAB) showed that the inner side of the coating layer consisted of irregular and bigger size of pores, and the surface layer had tight structure like beehive. For the biostimulant coated with polyfulfone (PSB), the whole coating layer had a fine structure without pore. The elution rate of the biostimulating agents for the CAB was higher than that for the PSB, and the elution rate for the GTB was considerably higher than that for the PSB in distilled water as well as in sea water. The elution rate of the biostimulating agents in turbulent water flow was about 3 times higher than that in standing water, and the elution rate of nitrate was higher than that of sulfate from the stimulating agents.

The Effect of Microorganisms, Nutrients, and Surfactants on the Bioremediation of Oil-Contaminated Soil (유류오염토양의 정화에서 미생물, 영양제 및 계면활성제의 영향)

  • Seon, Yong-Ho
    • KSBB Journal
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    • v.24 no.1
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    • pp.53-58
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    • 2009
  • This study was focused on the investigation of the characteristics of TPH and BTEX removal in oil-contaminated sandy soil and fine soil with injection of microorganisms, nutrients, and surfactants. As the result of the experiments maintained moisture contents by 10${\sim}$20%, the TPH removal efficiency in oil-contaminated sandy soil was the highest in C-1 (microorganisms+nutrients), and the efficiency in C-2 (microorganisms+nutrients+surfactants) was higher than the efficiency in C-0(microorganisms). In 81 days, TPH removal efficiency in case of C-0, C-1 and C-2 showed 51%, 83%, 63% respectively. The results of D group with fine soil showed similar trends as C group, but the TPH removal efficiency of D group was lower than that of C group. Those of both C and D group were the highest in 1 group (microganisms+nutrients). The pH of fine soil was some lower than that of sandy soil or was similar to sandy soil. In 14 days, BTEX removal efficiency in case of C-0, C-1, C-2, D-0, D-1 and D-2 showed 99.8%, 99.4%, 96.0%, 99.5%, 99.2%, 96.3% respectively. Those of both C and D group were the highest in 0 group (microganisms).

The Larval Development of Beet Armyworm,Spodoptera exigua (Hubner),(Lepidoptera:Noctuidae) by the Widths of the Head Capsule (파밤나방 유충의 영기별 생장율 비교)

  • 고현관;이상계;최귀문;김정화
    • Korean journal of applied entomology
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    • v.30 no.1
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    • pp.54-57
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    • 1991
  • The width of head capsule of the beet armyworm, Spodoptera exigua (Hubner), was measured on the 5th generation larvae reared with artificial diet. The mean widths of head capsule of each instar were: 1st, 0.246 mm; 2nd, 0.35 mm; 3rd, 0.546 mm; 4th, 0.809 mm; 5th, 1.242 mm; and 6th, 2.185 mm. The coefficient of variation (%) of each instar were: 1st, 8.6; 2nd, 9.5; 3rd, 15.1; 4th, 11.2; 5th, 12.0; and 6th, 12.9. The growth ratio of each instar were: 2nd, 1.43; 3rd, 1.55; 4th, 1.48; 5th, 1.54; and 6th, 1.76. The fitness(%) to Dyar's law of the measurement of head capsule width were: 1st, 94.7; 2nd, 98.3; 3rd, 98.7; 4th, 94.8; 5th, 94.6; and 6th, 92.2. When the logarithm of the width is plotted against the number of instars, the calculated regression line is highly significient (Log Y = -0.819 + 0.1872X, $r^2$ = $0.9977*{**}$) and Dyar's constant was 1.54.

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Study on the Self-Sustainability of AMBIDEXTER Lattice Using Equivalent Burnup Approximation (등가연소도 근사법을 이용한 AMBIDEXTER 로심격자의 핵적 자활성에 관한 연구)

  • 조재국;원성희;임현진;오세기;김택겸
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1998.05a
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    • pp.221-228
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    • 1998
  • 2차원 노심핵설계 코드 HELIOS를 이용하여 $^{7}$ LiF-BeF$_2$-ThF$_4$-$^{233}$ UF$_4$ 용융염 핵연료와 흑연(Graphite) 감속재로 구성된 AMBIDEXTER(Advanced Molten-salt Break-even Inherently-safe Dual-mission EXperimental and TEst Reactor) 원자로의 육각주형 로심격자에 대해 핵적 자활성 요건의 설계해석을 수행하였다. AMBIDEXTER 원자로는 액체 핵연료의 유동성을 이용한 온라인 핵연료 정화ㆍ처리ㆍ재생의 연속공정을 도입하여 노내의 잔류 핵분열 생성물질의 포화양을 최소로 유지시키고 중성자 경제성을 극대화하므로 높은 전환율을 얻는 설계이다. 핵연료 내에 잔류하는 핵분열생성물질의 포화농도에 대응하는 연소도를 등가연소도로 정의할 때, 열출력 250MW$_{th}$ AMBIDEXTER 원자로의 등가연소도 374MWD/TeH.E.의 평형 로심 모델에 대해 핵적 자활성을 지배하는 주요 핵설계 인자로서 용융염 핵연료의 $^{233}$ U Mole 분율, 흑연-대-용융염의 체적비, 노심격자 간격 및 출력 밀도의 변화에 따른 임계도 및 전환율을 평가하였다. 그 결과, $^{233}$ U Mole 분율과 혹연-대-용융염 체적비를 좌표축으로 하는 2차원상공간에서 핵적 자활성 요건 상태함수는 각 노심격자간격에 대해 완만한 선형 함수로 표현할 수 있음을 확인하였다.

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Larval Survival Rate and Growth of Pandalus gracilis Using Two Temperature Conditions Reared in the Laboratory (한국산 남방도화새우, Pandalus gracilis유생의 두 온도 구간에서의 생존율과 성장)

  • 최정화;마채우
    • Journal of Aquaculture
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    • v.17 no.1
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    • pp.58-61
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    • 2004
  • Larvae of Pandalus gracilis were reared in the laboratory under controlled conditions (salinity, 32.5∼34.5; photo-periods, 12L: 12D). The experiments were designed to examine effects of temperature (10 and 2$0^{\circ}C$) on larval development, survival, intermolt period and larval growth. The higher survival rate was obtained at 2$0^{\circ}C$ than at 1$0^{\circ}C$ and larvae reached later stages at 2$0^{\circ}C$. Intermolt period increased significantly with increasing of instar number and was longer at 1$0^{\circ}C$ than at 2$0^{\circ}C$.

Behavior of trabecular bone considered by fluid phase and strain rate (유체상과 변형율속도를 고려한 해면골의 거동해석)

  • 민성기;홍정화;문무성;이진희
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.10a
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    • pp.1078-1080
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    • 2002
  • The pressure variation of interstitial fluid is one of the most important factors in bone physiology. In order to understand the role of interstitial fluid and the biomechanical interactions between fluid and solid constituents within bone, poroelastic theory was applied. The purpose of this study is to describe the behavior of calf vertebral trabecular bone composed of the porous solid trabeculae and the viscous bone marrow by using a commercial finite element analysis program based on the poroelasticity. In this study, the model was numerically tested for 5 different strain rates, i. e., 0.001, 0.01, 0.1, 1.0, and 10 per second. The material properties of the calf vertebral trabecular bone were utilized from the previous experimental study. Two asymptotic poroelastic response, the drained and undrained deformation, were predicted. From the predicted results for the simulated five strain rate, it was found that the pore pressure generation has a linearly increasing behavior when the strain rate is the highest at 10 per second, other wise it showed a nonlinear the strain rate Increased. Based on the results of the present study, it was suggested that the calf vertebral trabecular bone could be modeled as a porous material and its strain rate dependent material behavior could be predicted.

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Effect of tebufenozide on embryonic and postembryonic development of sycamore lace bug, Corythucha ciliata(Hemiptera: Tingidae) (버즘나무방패벌레(Corythucha ciliata)의 배자발육과 후배자발육에 미치는 tebufenozide의 영향)

  • Choi, Mi-Hyun;Kim, Jeong-Wha;Kim, Gil-Hah
    • The Korean Journal of Pesticide Science
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    • v.3 no.2
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    • pp.74-80
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    • 1999
  • These studies were carried out to investigate the effects of nonsteroidal ecdysone agonist, tebufenozide on embryonic and postembryonic development of sycamore lace bug, Corythucha ciliata. Tebufenozide exhibited ovicidal activity($LC_{50}=4.0$ ppm). Susceptibility of each instar nymphs to tebufenozide was nearly same($LC_{50}=2.3{\sim}6.0$ ppm). The tebufenozide treatment in the final instar affected the emergence, longevity and fecundity of surving adults significantly. Tebufenozide applied at high concentration (10 ppm) to younger adults delayed prioviposition period, and decreased adult longevity, the number of eggs laid per female and hatchability. The treatment also inhibited the ovarian development of the female adults.

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Experimental Study on Formaldehyde Removal of Concrete by Using Activated Carbon and Functional Catalyst Materials (활성탄 및 기능성 촉매제를 이용한 콘크리트의 포름알데히드 제거에 관한 실험적 연구)

  • Yoon, Ki-Won;Lee, Joo-Hun;Choi, Myung-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.729-732
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    • 2008
  • Recently the attention against the indoor air quality that could affect health and comfort of building becomes intensively, the efforts for a problem solving is advanced with many sidedness. The research which it mixes the activated carbon and the functional catalyst materials that will be able to dissolve foul air absorbed by activated carbon in concrete with application technique of existing differently examined the basic physical properties and the removal ratio of formaldehyde so that it analyzed the effect of air purge. The test results in addition quantity increase of the activated carbon the slump showed the tendency which it decreased and the compressive strength appeared with no much difference. The test result removal ratio of formaldehyde was measured until the maximum 80%.

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