• Title/Summary/Keyword: 정방

Search Result 626, Processing Time 0.026 seconds

Phase Stability and isothermal Phase Transformation of the Yttria-Stabilized Zirconia Powder Prepared from Alkoxide Hydrolysis (알코옥시드 가수분해법으로 합성한 이트리아 안정화 지르코니아 분말의 상안정성 및 등온상전이 특성)

  • Lee, Jong-Kook;Kim, Young-Jeong;Kim, Hwan
    • Journal of the Korean Ceramic Society
    • /
    • v.33 no.6
    • /
    • pp.637-644
    • /
    • 1996
  • Phase stability and isothermal phase transformation during gaging at 25$0^{\circ}C$ were investigated in yttria stabilized zirconia powders prepared from hydrolysis of zirconium isopropoxide. The stability of tetragonal phase at room temperature in zirconia powder was decreased with calcination temperature but increased with the addition of yttria content. During aging at 25$0^{\circ}C$ in humid atmosphere isothermal phase transformation occurred in tetragonal zirconia powder stabilized by constraint effect not by alloying effect and grain size effect. Many twins and microcrackings were found in transformed monomlinic zirconia particles.

  • PDF

Design and Fabrication of Forward -3㏈ Directional Coupler Using Asymmetrical Coupled Lines with Mentalization Thickness (도체두께를 가진 비대칭 결합선로를 이용한 정방향 -3㏈ 방향성 결합기의 설계 및 제작)

  • 홍익표;윤남일;육종관
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.28 no.8A
    • /
    • pp.626-632
    • /
    • 2003
  • In this paper, forward-wave -3㏈ directional coupler with finite-thickness conductor and asymmetrical coupled lines are designed and experimentally verified using mode-matching based design methodology. Most of studies published in the literatures about the coupled lines are mainly concentrated on the adjustment of coupling amount by changing various geometric configurations. The analysis results in this paper show that thicker metalization requires reduced coupler length in the forward-wave directional coupler composed of asymmetrical coupled lines. Several forward-wave directional -3 ㏈ couplers with finite metalization thickness composed of asymmetrical coupled microstrip lines have been designed in the 5 ㎓ based on proposed design method. The measured data show -4.05㏈∼-4.09㏈ coupling at center frequency which is very closed to design value. The tight coupling has been implemented with accurate design methodology which take mentalization thickness into account.

Transformability and Phase Transformation Behaviors of Metastable Tetragonal Phase in 2Y-TZP Powder. (2Y-TZP 분말내 준안정 정방정상 입자의 전이도 및 상전이거동)

  • Kim, Hwan;Lee, Jong-Kook
    • Korean Journal of Materials Research
    • /
    • v.2 no.5
    • /
    • pp.320-329
    • /
    • 1992
  • In 2Y-TZP powders calcined at temperature range of 80$0^{\circ}C$0 to 150$0^{\circ}C$, the effect of stabilization and the transformability of tetragonal phase on the tetragonal to monoclinic transformation have been investigated. The transformability of tetragonal phase in calcined powders shows maximum at the calcination temperature of 130$0^{\circ}C$. This result is explained by a combined effect of the increase of particle size and of constrained force among the particles with increasing the calcination temperature. The amount of transformed monoclinic phase with calcination temperature after quenching in liquid nitrogen, stress induction and isothermal aging at 25$0^{\circ}C$is also explained by the transformability of tetragonal phase determined by the sum of particle size effect and constraint effect.

  • PDF

Performance Evaluation of Cascade AOA Estimation Algorithm Based on Square Array Antenna (정방배열 안테나 기반 캐스케이드 도래각 추정 알고리즘 성능평가)

  • Kim, Tae-Yun;Hwang, Suk-Seung
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.14 no.6
    • /
    • pp.1053-1060
    • /
    • 2019
  • The satellite antenna for collecting information is mainly classified into reflector antenna, lens antenna, and phased array antenna. Among them, the phased array antenna with the excellent antenna pattern control performance for a multi-beam system is frequently used. Although the terrestrial signal information collection based on the satellite is not much effected geographically, it requires the accurate angle-of-arrival (AOA) information of the interesting signal. In this paper, we discuss the characteristics and the advantages/disadvantages of the antenna array shape employed in the phased array antenna. In addition, we present the Cascade AOA estimation algorithm based on a square array antenna mounted on the satellite receiver, and show the performance evaluation results through the computer simulation.

Preparation of $AI_2O_3/Ca-TZP$ Composites and its Characteristics ($AI_2O_3/Ca-TZP$ 복합체의 제조 및 그 특성)

  • 곽효섭;백용혁;이종국
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.2 no.2
    • /
    • pp.63-70
    • /
    • 1992
  • $AI_2O_3/Ca-TZP$ composites was prepared by using the starting powder of alumina and Ca-TZP synthesized by hydrothermal reaction and investigated to its characteristics. The ratio of tetragonal zirconia to monoclinic within $AI_2O_3$ matrix was decreased with an addition of Ca-TZP content, but the absolute amount of tetragonal phase in composites was increased with an addition of Ca-TZP content. The value of fracture toughness in $AI_2O_3/Ca-TZP$composites was proportional to the amounts of transformed tetragonal phase which formed by crack propagation in fracture, and therefore, it was gradually increased with an addition of Ca- TZP content.

  • PDF

Micromorphological Observation of Honam Series -Some characteristics of clay films in B horizon- (호남통(湖南統)에 대(對)한 토양(土壤) 미세형태학적연구(微細形態學的硏究) - B층(層)의 점토피막(粘土皮膜) 특성(特性)에 관(關)하여 -)

  • Shin, Jae Sung;Um, Ki Tae;Shin, Yong Hwa
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.7 no.2
    • /
    • pp.65-70
    • /
    • 1974
  • Micromorphological features of Bhorizon of Honam series were investigated by means of thin sections of natural undisturbed, oriented soil samples. Thin sections show that the B horizons have argillic accumulations. Argillic horizon was developed at the utmost in B21t horizon. Channel, and skew plane cutans were identified in B21t horizon and stress cutans are presented in B24t horizon. Such a continuous oriented argillans related to channels and skew planes decreased with increasing depth.

  • PDF

Fabrication of high purified zirconium dioxide (ZrO2) and stabilized zirconia (TZP: tetragonal zirconia polycrystal) powders (고순도 산화지르코늄(ZrO2) 및 안정화 지르코니아 (TZP: tetragonal zirconia polycrystal) 분말제조)

  • 최의석
    • Proceedings of the Korea Association of Crystal Growth Conference
    • /
    • 1996.06b
    • /
    • pp.55-85
    • /
    • 1996
  • 지르코니아 분말은 ZrO2 결정상이 온도변화에 따라 부피변화를 수반하는 상전이변태를 나타낸다. 단사정 ZrO2가 110$0^{\circ}C$에서는 정방정으로, 2$700^{\circ}C$ 내외에서는 입방정으로 결정구조가 가역적으로 변한다. 이 ZrO2에 금속산화물을 고용시키면 형석 (CaF2:Florite)형의 입방정 결정구조가 실온에서도 안정하게 존재하게 된다. 안정화제 산화물은 caO, MgO등 2가 산화물외에 3가 또는 4가의 금속산화물로서 Sc2O3, Y2O3, Sm2O3, Nd2O3, Gd2O3, Y2O3, CeO2 등이며 이들은 금속이온의 원자가가 변하기 쉬운 희토류 산화물이다. 안정화 지르코니아는 형석형 결정구조이며 결정화학적으로 보면 금속양이온이 산소이온에 대해서 정육면체형의 8배위를 하고 있다. 이때 이온반경비(양이온/음이온)에 따라 Zr+4자리와 O-2자리의 격자위치와 모양이 형성되므로 비틀어진 정육면체구조이건 이상적인 정육면체 형석구조를 이룬다. 이는 지르코니아의 결정상의 2상-3상인 부분안정화 지르코니아다결정체(PSZ : partially stabilized zirconia)이거나 단일상-2상인 정방정 지르코니아다결정체(TZP : tetragonal zirconia polycrystal)의 결정구조를 가지는데 기인한다. PSZ는 주로 MgO, CaO를 안정화제로 고용시켜 입방정 영역에서 소결하고 이를 다시 입방정과 정방정의 상 영역에서 열처리하여 입방정 입자내부에 정방정을 석출 형성시킨 것이며 TZP는 Y2O3 및 CeO2를 고용시켜 PSZ와 다르게 일반적인 상압소결한 정방정 결정상의 미립자이다. 산화지르코늄 분말은 지르콘사에서 열분해시킨 지르코늄소결.융해괴(caustic fusion clinker)를 산처리하여얻어진 지르코늄산용액(zirconyl acid solution : cloride, sulfide, nitride 등)으로부터 제조된다. 고순도 산화지르코늄은 용액 결정석출법에 의해 ZrOCl2.8H2O, 5ZrO2.3SO3.15H2O, ZrO(NO3)2.xH2O 등의 지르코늄 수화물만을 재결정화시킨 것으로부터 얻을 수 있으며 이 지르코늄염 수용액으로부터 입자미세구조를 효과적으로 제어하여 산화지르코늄 및 안정화 지르코니아 분말제조가 가능하다. 안정화 지르코니아 분말은 ZrO2와 안정화산화물의 고용을위하여 가열처리를 필요로 하며 일정온도에서 최적상태로 숙성하므로서 2가지 상(phase) 이상의 고용체를 가지게 된다. 안정화 지르코니아 분말은 고용처리온도를 낮추고 효과적으로 생성시키기 위해서는 지르코늄 및 안정화제염을 혼합하고 습식 직접합성하여 저온에서 고용체의 합해진상 영역을 생성시키는 것이다. 이는 지르코니아 원료분말의 미세구조를 제어하므로서 가능하며 이때 화학성분조성과 크기형태가 균일하게 분포된 입자분말을 얻을 수 있다.

  • PDF