• Title/Summary/Keyword: 접합체

Search Result 871, Processing Time 0.029 seconds

Acceleration Test of Membrane-Electrode Assembly in PEMFC (고분자연료전지의 전해질-전극 접합체의 열화 가속시험)

  • Lee, Jung-Hun;Yoon, Young-Gi;Jung, Eun-Ha;Lee, Won-Yong;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.06a
    • /
    • pp.93-96
    • /
    • 2007
  • Recently, much attentions have been paid on the commercialization of PEMFC, especially for the applications of residential and portable. In order to achieve the early commercialization of PEMFC, thee are two hurdles to overcome. One is cost down and the other is improvement of durability of the system components. Numerous companies have tried to reduce the production cost and the main research topics have been changed from performance to durability improvement. In this work, acceleration test were performed to find and evaluate the main reason of degradation of the MEA(membrane-electrode assembly) which is one of the core component of the PEMFC system. Based upon the test results, a way to make durable MEA was suggested. Acceleration tests were made by applying high voltage of 1.2V to the several kinds of single cells to increase the growth of catalyst particles. Cell performance, ac-impedance and electrochemically active area measurements were made atfter every 8 hours of acceleration test. Degradations of catalyst and membrane were examined by SEM, TEM and XRD. Obtained results were discussed in terms of structural stability and loss of catalyt and ionomers in the electrode layer. In addition, the way to make highly durable MEA was suggested.

  • PDF

An Experimental Study on Flexural/Shear Load Properties of SC(Steel Plate Concrete) Structure with Reinforced Concrete Joint (강판콘크리트 구조 이질접합부의 면외 휨/면내 전단하중 특성에 관한 실험연구)

  • Lee, Kyung-Jin;Hwang, Kyeong-Min;Hahm, Kyung-Won;Kim, Woo-Bum
    • Journal of Korean Society of Steel Construction
    • /
    • v.24 no.2
    • /
    • pp.137-147
    • /
    • 2012
  • This paper describes an experimental study on the mechanical characteristic and behavior of a structure that has a joint between the reinforced concrete (RC) member and steel plate concrete (SC) member. An out-of-plane flexural test on an L-type test specimen and in-plane shear test on an I-type test specimen were carried out by means of repeated cyclic loading until their failure. Based on the results, the former showed pull-out failure mode of anchored vertical bars while the latter exhibited flexural failure mode of the basement member. These results reveal that the maximum capacity of the specimens is 96% and 82%, respectively, compared with the theoretical value.

Block Shear Rupture and Shear Lag of Single angle in Tension Joint -Single angle with three or four bolt connection- (단일 ㄱ형강의 블록전단 파단 및 전단지체 현상 -고력볼트 3개 또는 4개로 접합된 단일 ㄱ형강-)

  • Lee, Hyang Ha;Shim, Hyun Ju;Lee, Eun Taik
    • Journal of Korean Society of Steel Construction
    • /
    • v.16 no.5 s.72
    • /
    • pp.565-574
    • /
    • 2004
  • The purpose of this paper was to investigate the block shear and the fracture in the net section, according to AISC Specifications, by analysing the shear lag effect in the block shear rupture of the single angle with three or four bolt connection. Specimen with three or four bolt connections showed that failure generally went from block shear with some net section failures to classic net section failures. From the test results, showed that the connection length, the thickness of angle, and reduction factor, which affect the block shear rupture, were investigated. According to the test results, it is suggested that the calculation of the net section rupture capacity by using the reduction factor of U, that was suggested by Kulak, is needed.

Fabrication of membrane electrode assemblies by low temperature decal methods (저온 전사법을 이용한 고성능 MEA 제조)

  • Cho, Jae-Hyoung;Kim, Jang-Mi;Prabhuram, Joghee;Hwang, Sang-Youp;Ahn, Dong-June;Ha, Heung-Yong;Kim, Soo-Kil
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.37-39
    • /
    • 2008
  • 본 연구에서는 저온 데칼 전사법을 이용하여 막 전극 접합체(Membrane Electrode Assembly, MEA)를 제조하였다. 제조된 MEA는 직접 메탄올 연료 전지(Direct Methanol Fuel Cell, DMFC)를 이용하여 성능 테스트를 하였다. 저온 데칼 전사법은 $140^{\circ}C$의 낮은 온도에서 촉매 층을 데칼 기판에서 멤브레인으로 전사시키고, 전사된 촉매 층의 표면에 형성되는 것으로 알려진 이오노머 스킨 층의 형성을 막기 위해 이오노머/촉매/카본/기판의 구조로 되어 있는 데칼 기판을 사용한다. 저온 데칼 전사법으로 제조 된 카본 층이 있는 MEA의 DMFC 성능이 카본 층이 없이 데칼 전사법으로 제조된 MEA나 전통적인 고온 데칼 전사법으로 제조된 MEA, 또는 직접 스프레이 코팅법으로 제조된 MEA의 성능보다 높게 나온 것을 알 수 있다. 저온 데칼 전사법으로 제조된 MEA의 DMFC 성능이 향상된 것은 촉매 층 위에 이오노머 스킨이 형성되지 않아 반응물의 확산이 원활하게 이루어지기 때문이다. 이를 위한 특성 분석으로 EIS, CV를 측정하였다.

  • PDF

Transfer of RP4:Mu cts from E. coli to Rhizovium leguminosarum (RP4:Mu cts의 E.coli로 부터 Rhizovium leguminosarum으로의 전달)

  • 이인렬;허연주;이영록
    • Korean Journal of Microbiology
    • /
    • v.23 no.2
    • /
    • pp.107-114
    • /
    • 1985
  • In order to use for recipient strains of RP4:Mu cts, 5 strainsof Rhizobium were selected among 32 strains, which were isolated and identified in this study. Hybrid plasmin RP4::Mu cts, which, is temperature sensitive and confers resistance to ampicillin, kanamycin and tetracycline was transfered by conjugation from E. coli to other atrains of C. coli and the symbiotic nitrogen fixer, Rhizobium leguminosarum. Transfer frequencies of RP4::Mu cts plasmid from E. coli to Rhizobium were about $10^{-8}-10^{-7}$ in LB agar and YMA media. The transconjugants were confirmed by demonstrating that the drug-resistant and temperature-sensitive clones isolated were drug-resistant and temperature-sensitive clones isolated were capable of releasing phage and forming plaques. The plaque-forming units of transconjugants were about $10^2\;to\;10^3$. Stability test of RP4::Mucts in Rhizobium represented that most of the transconjugants had drug resistance and produce phage Mu cts.

  • PDF

Lateral Load Performance Evaluation of Larch Glulam Portal Frames Using GFRP-Reinforced Laminated Plate and GFRP Rod (GFRP 보강적층판 및 GFRP rod를 이용한 낙엽송 집성재 문형라멘 구조의 수평가력 성능평가)

  • Jung, Hong-Ju;Song, Yo-Jin;Lee, In-Hwan;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
    • /
    • v.44 no.1
    • /
    • pp.30-39
    • /
    • 2016
  • The evaluation of the lateral load performance for larch glulam portal frames was carried out using glass fiber reinforced plastic (GFRP) as connector in two different systems: the GFRP-reinforced laminated plates combined with veneer, and GFRP rod joints glued with epoxy resins to replace usual metal connectors for the structural glulam rahmen joints. As a result the yield strength, ultimate strength, initial stiffness of glulams of GFRP rod joints glued with epoxy resin decreased to 49%, 52% and 61% compared to those of the conventional metal connector. This connector will be a stress device where the bonding strength between the GFRP rod and glued laminated timber is important. Thus, there will be a high possibility that a problem may occur when it is applied to the field. On the other hand, the GFRP-reinforced laminated plates and wood (Eucalyptus marginata) pin were measured all within 3% for all measurements of the yield strength, ultimate strength, initial strength and ductility factor, regardless of high cross sectional loss on the glued laminated timber slit joint. In addition, the variation of stiffness on the cycle was 35%, which was the lowest, confirming that it was almost the same performance as the specimen prepared with the metal connector.

A Study on the Comparison of Brazed Joint of Zircaloy-4 with PVD-Be and Zr-Be Amorphous alloys as Filler Metals (PVD-Be와 비정질 Zr-Be 합금을 용가재로 사용한 Zircaloy-4의 브레이징 접합부의 비교 연구)

  • Hwang, Yong-Hwa;Kim, Jae-Yong;Lee, Hyung-Kwon;Koh, Jin-Hyun;Oh, Se-Yong
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.7 no.2
    • /
    • pp.113-119
    • /
    • 2006
  • Brazing is an important manufacturing process in the fabrication of Heavy Water Reactor fuel rods, in which bearing and spacer pads are joined to Zircaloy-4 cladding tubes. The physical vapor deposition(PVD) technique is currently used to deposit metallic Be on the surfaces of pads as a filler metal. Amorphous Zr-Be binary alloys which are manufactured by rapid solidification process are under developing to substitute the conventional PVD-Be coating. In the present study, brazed joint with PVD and amorphous alloys of $Zr_{1-x}Be_{x}(0.3{\le}x{\le}0.5)$ as filler metals are compared by mechanism, microstructure and hardness. The thickness of brazed joint with amorphous alloys became much smaller than that of PVD-Be. The erosion of base metal did not occur in the brazed joint with amorphous alloys. The brazing mechanism for PVD-Be seems to be Be diffusion into Zr-4 with capillary action resulting from eutectic reaction while that for amorphous alloys are associated with the liquid phase formation in the brazed joint. The brazed joint microstructure with PVD-Be consists of dendrite while that with amorphous alloys is globular. The $Zr_{0.7}Be_{0.3}$ alloy shows the smooth interface with little erosion in the base metal and is recommended a most suitable brazing filler metal for Zircaloy-4.

  • PDF

An Experimental Study on Intensity property of High Strength Concrete Using Transparent Joint Separation Test Body (투명 접합분리 몰드를 사용한 고강도 콘크리트의 강도특성에 관한연구)

  • Ki, Jun-Do;Park, Hyun;Kim, Kwang-Ki;Paik, Min-Su;Lee, Young-Do;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2009.05a
    • /
    • pp.411-412
    • /
    • 2009
  • The techniques of testing and controlling intensity of structural concrete involve many problems and difficulties on the construction site. Hence this study aims at evaluating intensity of structural concrete in order to verify on-site application and structural efficiency assessment using joint separation test body.

  • PDF

자연 생태계에서 형질 전환에 의한 세균들 간의 유전 물질의 전이

  • ;Stotzky, G.
    • Korean Journal of Microbiology
    • /
    • v.33 no.3
    • /
    • pp.203-209
    • /
    • 1997
  • 형질전환은 가장 먼저 연구된 유전물질 전이 기작으로(3,29,36), 자연적 형질 전환과 인위적 형질 전환으로 구별할 수 있다. 자연적 형질 전환은 세균에게서만 일어나며, 이때 수여체 세균은 적정 조건, 즉, 형질 전환 능력이 있는 생리적 상태(competene)가 되면 능동적으로 세포의 DNA를 받아들여 그들 유전 정보에 합치게 된다. 하지만 재조합 DNA 기술이 발달된 이후로 인위적 형질 전환이 원핵세포와 진핵세포에서 사용되었다(48). 자연적 형질 전환은 DNase와의 반응이 민감하다는 점에서 접합과 형질 도입과 구별된다. 형질 전화에 의한 유전자 전이가 세포으 DNA에 의해서 일어나는 한 DNase가 공격할 수 있고, DNA는 분해되어 형질 전환이 방해될 수 있다. 하지만, 형질 도입되는 DNA는 파지의 단백질막(capsid)에 보호되어 세포외로 절대 노출되지 않아 DNase에 의해서 영향을 받지 않고, 접합에서도 DNA는 세포와 세포의 접촉에 의해서 전이되어 공여체에서 수여체로 DNA가 전이될 때 역시 DNase에 노출되지 않고 일어날 수 있다.

  • PDF

A Study on Improvement of Seismic Performance of High Strength Reinforced Concrete Interior Beam-Column Joints using High Ductile Fiber-Reinforced Mortar (고인성섬유 복합모르타르를 활용한 고강도 철근콘크리트 내부 보-기둥 접합부의 내진성능 개선 연구)

  • Ha, Gee-Joo;Hong, Kun-Ho
    • Journal of the Korea Concrete Institute
    • /
    • v.24 no.6
    • /
    • pp.753-760
    • /
    • 2012
  • In this study, experimental research was carried out to evaluate and improve the constructability and seismic performance of high strength R/C interior beam-column joints regions, with or without the shear reinforcement, using high ductile fiber-reinforced mortar. Six specimens of retrofitted the beam-column joint regions using high ductile fiber-reinforced mortar are constructed and tested for their retrofit performances. Specimens designed by retrofitting the interior beam-column joint regions (IJNS series) of existing reinforced concrete building showed a stable mode of failure and an increase in load-carrying capacity due to the enhancement of crack dispersion by fiber bridging from using new high ductile materials for retrofitting. Specimens of IJNS series, designed by the retrofitting of high ductile fiber-reinforced mortar in beam-column joint regions increased its maximum load carrying capacity by 96~102.8% and its energy dissipation capacity by 0.99~1.11 folds when compared to standard specimen of SIJC with a displacement ductility of 5.