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Double-layered Polymer Electrolyte Membrane based on Sulfonated Poly(aryl ether sulfone)s for Direct Methanol Fuel Cells (직접 메탄올 연료전지용 술폰화 폴리아릴에테르술폰 이중층 고분자 전해질 막의 제조 및 특성)

  • Hong, Young-Taik;Ko, Ha-Na;Park, Ji-Young;Choi, Jun-Kyu;Kim, Sang-Un;Kim, Hyung-Joong
    • Membrane Journal
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    • v.19 no.4
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    • pp.291-301
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    • 2009
  • Double-layered polymer electrolyte membranes were prepared from two different sulfonated poly(aryl ether sulfone) copolymers by the two-step solution casting method for direct methanol fuel cells (DMFC). Sulfonation degrees were adjusted 10% (SPAES-10) and 50% (SPAES-50) by controlling monomer ratios, and the weight ratios of SPAES-10 copolymer were varied in the range of 5~20% to investigate the effect of thickness of coating layers on the membranes. Proton conducting layers were fabricated from SPAES-50 solutions of N-methyl-2-pyrrolidone (NMP) by a solution casting technique, and coating layers formed on the semiliquid surface of the conducting layer by pouring of SPAES-10-NMP solutions onto. It was found that double-layered polymer electrolyte membrane could significantly reduce the methanol crossover through the membrane and maintain high proton conductivities being comparable to single-layered SPAES-50 membrane. The maximum power density of membrane-electrolyte assembly (MEA) at the condition of $60^{\circ}C$ and 2 M methanol-air was $134.01\;mW/cm^2$ for the membrane prepared in the 5 wt-% of SPAES-10 copolymer, and it was corresponding to the 105.5% of the performance of the commercial Nafion 115 membrane.

Assessment Selective Breeding Effect of Israeli carp (Cyprinus carpio) from Korea (국내 이스라엘 잉어의 선발육종효과 평가)

  • Kim, Jung Eun;Hwang, Ju-ae;Kim, Hyeong Su;Im, Jae Hyun;Lee, Jeong-Ho
    • Korean Journal of Ichthyology
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    • v.32 no.4
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    • pp.210-221
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    • 2020
  • Since the introduction of Israeli carp into Korea for farming in 1973, there are no breeding studies on developing Korea Israeli carp (domestic) so far. This study performed gene-based cross-breeding studies to restore genetic diversity of lowered Israeli carp through continuous inbreeding, and for rapid growth and better scales. This study produced four cross-breeding groups (F1) using Koean Israeli carp and Chinese Songpu mirror carp for the improvement of growth and scale of Israeli carp in Korea. And mating scheme for breeding groups was set in consideration of the morphological analysis and genetic distance of broodstock. In addition, this study used microsatellite markers and genotype data to analyze genetic diversity and parentage analysis. As a result, the average NA and HE values of Korean select broodstock are 8.3 and 0.743, and F1 is 13.0 and 0.764. This study shows that the genetic diversity of F1 has been recovered over Korean Israeli carp through breeding between Korean Israeli carp and Chinese Songpu mirror carp. Common Israeli carp in Korea reached 1.7 kg in 17 months, and improved Israeli carp reached to 2.2 kg. The KC (Korea×China, KC) group was 2.52 and broodstock group was 3.15. F1 showed lower scale score (0.63) than broodstock. The improved carp (F1; CK, KC) had 20% better scales than the parent group (F0), which improved 27% in weight and 25% in scales compared to common Israeli carp. The Israeli carp developed by the genetics-based breeding grew quicker and had improved genetic diversity and fewer scales, which will be of great value for Korean Israeli aquaculture industry due to good marketability.

Development of a Method for ACF Bonding Based on Machine Vision (머신비전 기반 ACF 본딩 기법 개발)

  • Lee, Seokwon
    • The Journal of the Convergence on Culture Technology
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    • v.4 no.3
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    • pp.209-212
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    • 2018
  • Anisotropic conductive film(ACF) bonding is widely used for making fine interconnections between two different materials where soldering is not easily applicable. There are three constraints for the successful implementation of ACF bonding. A bonding contact should be pressed by a hot head with the right pressure and temperature for a pre-defined curing time. In this paper, a method for ACF bonding based on machine vision system is proposed and verified through some experiments. The system calculates the position and orientation of printed circuit boards(PCBs) on a bonding table and estimates the optimal hitting point where the hot head should be applied. Experimental results show that the proposed system achieves better adhesive strength by providing head flatness over contact surfaces.

Conservation and Restoration of Bamboo Brush Stand with Carved Design (죽제조문필통(竹製彫文筆筒)의 보존과 복원)

  • Son, Jongmin;Yi, Yonghee
    • Conservation Science in Museum
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    • v.10
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    • pp.21-27
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    • 2009
  • This bamboo brush stand was made by attaching two bamboo tubes together, each 80mm in diameter. On the bottom is a "∞-shaped"wood board made of Ailanthus altissima. The surfaces are decorated with exquisite and dynamic designs of a dragon and clouds, and a deer and pine trees. Part of this bamboo brush stand was damaged, lost, or worn down, prior to conservation treatment. After conservation and recovery treatment, its original form was restored. Earth powder, chalk, and gluten mixture were used as materials to fill in the missing parts. After the original form was restored, thin silk fabric was attached to the inner surface of the glued part to prevent cracking. Traditional materials and repair techniques were used to allow for reversal of treatment, if necessary, as seen in the surface of the restored part being made antiquated with lacquer varnish.

Availability of Bone Scan in Chest Trauma Patients (흉곽부위 골절에 대한 골스캔의 유용성 고찰)

    • Journal of Chest Surgery
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    • v.31 no.11
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    • pp.1085-1088
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    • 1998
  • Background: In trauma patients, bony thorax are exposured to the trauma in many cases. With simple x-ray, we can not detect all definitive bony abnormalities, especially in less severe cases. Bone scan is very sensitive diagnostic method in such cases. Materials and methods: We experienced 680 cases and results were as follows. Results: 1. Diagnostic sensitivity was 97.4% and false negative rate was 2.6%. 2. In sensitivity study, the time factor(when we perform bone scan) was the most important thing according to trauma pattern. In rib fracture, sensitive test time was after 1 week. In sternal fracture, sensitive test time was after 1 week, too. In costochondral junction fracture and combined cases, it was after 3 days. Conclusions: We recommend timely using of bone scan as definitive diagnostic method in bony thorax trauma patients.

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Characterization of ITO surfaces treated by the remote plasma (원거리 플라즈마에 의해 처리된 ITO 표면 상태의 특징)

  • 김석훈;김양도;전형탁
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.130-130
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    • 2003
  • 일반적으로 Indium tin oxide (ITO)는 유기EL 소자 제작 공정에서 필수 불가결한 물질로 알려져 있다. ITO는 정공 수송의 기능을 하게 되는데 정공 주입의 효율을 향상시키기 위해서는 ITO 표면의 저 저항화와 ITO/유기박막 접합계면의 일함수 값의 적절한 균형이 중요하다. 그리고 현재 플라즈마를 이용한 ITO 기판의 세정은 산소 래디칼을 이용하여 표면을 산화하는 방식인 산소 플라즈마를 이용한 세정 방법이 널리 이용되고 있다. 본 연구에서는 ITO 표면의 탄소 오염물을 제거하여 저항특성을 향상시키기 위하여 원거리 산소와 수소 플라즈마 세정을 적용하였고, 그에 따른 탄소를 포함하는 오염물의 제거 효율과 산소와 수소 플라즈마로 처리된 ITO 표면의 특징을 기술하였다. 실험에 사용된 플라즈마 소스는 radio-frequency(RF) 플라즈마이고, 원거리 플라즈마 세정 시스템과 표면 분석 장비인 X-ray photoelectron spectroscopy(XPS)가 in-situ로 연결되어 있는 진공장비로 분석을 하였다 플라즈마 세정 전에 전처리 세정을 시행하지 알았으며, 세정 후 in-situ XPS에 의해서 화학 조성 및 결합 구조의 변화를 분석하였다. 또한 일함수와 면저항 값을 측정하고 그에 따른 표면의 저항 특성 및 표면 전위에 관하여 세정 효율과 연관지어 해석하였다. 원거리 산소/수소 플라즈마 세정 후 ITO 표면의 탄소오염물이 검출한계 이하로 효과적으로 제거된 것을 in-situ XPS 분석 결과로 확인하였고, 플라즈마 처리 순서 및 플라즈마 파워를 변화하여 그에 따른 표면의 결합 상태 및 화학 조성의 변화를 비교 분석하였다.

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Mechanical Characteristics Analysis of Structural Light-weight Aluminum Foam (구조용 경량 알루미늄 발포금속의 기계적 특성 연구 분석)

  • Ma, Jeong Beom;Lee, Jeong Ick
    • Journal of the Korea Convergence Society
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    • v.2 no.3
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    • pp.1-6
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    • 2011
  • Aluminum foam is one of the representative light-weight materials. In this study we analyzed the mechanical properties of the aluminum foam structures. Aluminum materials with pores have novel mechanical characteristics such as flame retardancy, damping, and energy absorption which are superior to those of polymer foam. Furthermore its reusable properties draw considerable interests. General properties, energy and acoustic absorption will be investigated and future research issues such as binding techniques of foam materials with other structures will be discussed through foam application examples.

마그네트론 스퍼터링을 이용하여 TiN 박막을 증착한 도전성 섬유

  • Jang, Jin-Hyeok;Mun, Seon-U;Kim, Gyeong-Hun;Kim, Seong-Min;Lee, Seung-Min;Kim, Jeong-Su;Han, Seung-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.168-168
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    • 2013
  • 도전성 섬유(Conductive textile)는 섬유자체의 고유 특성을 유지하면서 전기적인 도전 특성을 갖는 섬유로서, Cu, Ag, Ni 등의 전기전도성이 높은 금속 박막을 증착하여 제작하고 있다. 그러나, 이러한 금속은 공기 중의 산소와 결합하여 쉽게 산화되는 특성을 지니고 있기 때문에 사용 중에 산화되어 도전 특성이 감소하는 단점이 있다. TiN은 금속 못지않은 높은 전기전도성을 지니고 있을 뿐만 아니라, 금속에 비하여 높은 경도에 따른 우수한 내마모 특성, 내부식성 및 낮은 마찰계수를 지니고 있다. 그러나, TiN은 경도가 높기 때문에 섬유의 고유 특성인 유연성이 저하되는 문제가 있다. 본 연구에서는 면(Cotton), PE (Polyester), PP (Polypropylene) 등의 섬유 위에 TiN 박막을 증착하여, 섬유의 유연성을 유지하며 전기전도성과 내마모 특성이 우수한 도전성 섬유를 제작하고자 하였다. TiN 박막 증착을 위하여 ICP-assisted pulsed-DC reactive magnetron sputtering 장비를 사용하였으며, Ar:N2 유량비(Flow rate), Ti 타겟 power, ICP RF power 등을 변화시켜 Ti와 N의 조성비를 조절하였고, 이를 통하여 섬유의 휨이나 접힘에도 도전 특성이 변하지 않고 내마모 특성이 우수한 TiN 박막을 증착하였다. TiN 박막이 증착된 섬유의 전기전도도는 일정한 압력 하에 전기전도도를 측정할 수 있는 장치를 제작하여 측정하였으며, 표면 조성 분포 및 접합력 측정을 위하여 XPS (X-ray Photoelectron Spectroscopy)와 Peel-tester를 이용하였다.

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Fabrication and Characterization of Step-Edge Josephson Junctions on R-plane Al$_2O_3$ Substrates (R-면 사파이어 기판 위에 제작된 계단형 모서리 조셉슨 접합의 특성)

  • Lim, Hae-Ryong;Kim, In-Seon;Kim, Dong-Ho;Park, Yong-Ki;Park, Jong-Chul
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.147-151
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    • 1999
  • YBCO step-edge Josephson junction were fabricated on sapphire substrates. The steps were formed on R-plane sapphire substrates by using Ar ion milling with PR masks. The step angle was controlled in the wide range from 25$^{\circ}$ to 50$^{\circ}$ by adjusting both the Ar ion incident angle and the photoresist mask rotation angle relative to the incident Ar ion beam. CeO$_2$ buffer layer and in-situ YBa$_2Cu_3O_{7-{\delta}}$ (YBCO) thin films was deposited on the stepped R-plane sapphire substrates by pulsed laser deposition method. The YBCO film thickness was varied to obtain the ratio of film thickness to step height in the range from 0.5 to 1. The step edge junction exhibited RSJ-like behaviors with I$_cR_n$ product of 100 ${\sim}$ 300 ${\mu}$V, critical current density of 10$^3$ ${\sim}$ 10$^5$ A/ cm$^2$ at 77 K.

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Microstructure and Hardness of 1st layer with Crystallographic Orientation of Solidification Structure in Multipass Weld using High Mn-Ni Flux Cored Wire (고(<24%)Mn 플럭스코어드와이어를 사용한 다층 용접 시 초층 응고조직의 결정면방위에 따른 미세조직과 경도)

  • Han, Il-Wook;Eom, Jung-Bok;Yun, Joong-Gil;Lee, Bong-Geun;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.77-82
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    • 2016
  • In this study, Microstructure and hardness of 1st layer with crystallographic orientation were investigated about solidification structure in multipass weld using high Mn-Ni flux cored wire. Microstructure of solidification consisted of austenite matrix and a little ${\varepsilon}-phase$ in grain boundaries. Orientation of grains was usually (001), (101), (111). According to crystallographic orientation, morphology of primary dendrite was different. The depletion of Fe and the segregation of Mn, C, Ni, Si, Cu, Cr, O were found along the grain boundaries. The area of segregation was wide with an order of (001), (101), (111) grains. And hardness of grains with crystallographic orientation increased with an order of (001), (101), (111) grains because of the segregation along dendrite boundary.