• Title/Summary/Keyword: 접착효율

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Hydrophobicity and Adhesion of SiO2/Polyurethane Nanocomposites Topcoat for Aircraft De-icing with Different Pre-curing Time (선경화 시간에 따른 항공기 De-icing용 나노실리카/폴리우레탄 복합재료 탑코트의 소수성 및 접착특성 평가)

  • Kim, Jong-Hyun;Shin, Pyeong-Su;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.33 no.6
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    • pp.365-370
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    • 2020
  • The icing formation at aircraft occur problems such as increasing weight of the body, fuel efficiency reduction, drag reduction, the error of sensor, and etc. The viscosity of polyurethane (PU) topcoat was measured at 60℃ in real time to set the pre-curing time. SiO2 nanoparticles were dispersed in ethanol using ultra-sonication method. The SiO2/ethanol solution was sprayed on PU topcoat that was not cured fully with different pre-curing conditions. Surface roughness of SiO2/PU nanocomposites were measured using surface roughness tester and the surface roughness data was visualized using 3D mapping. The adhesion property between SiO2 and PU topcoat was evaluated using adhesion pull-off test. The static contact angle was measured using distilled water to evaluate the hydrophobicity. Finally, the pre-curing time of PU topcoat was optimized to exhibit the hydrophobicity of SiO2/PU topcoat.

Improvement of Response Time of Stimulus-responsive Hydrogel Actuator Using Photothermal Effect of PDPP3T Conjugated Polymer (PDPP3T 공액고분자의 광열효과를 이용한 자극감응성 하이드로젤 액추에이터의 반응속도 향상)

  • In Hyeok Choi;Dongmin Lee;Wonho Lee;Seog-Jin Jeon
    • Journal of Adhesion and Interface
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    • v.25 no.2
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    • pp.69-74
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    • 2024
  • Soft actuators can be applied to various fields such as the medical industry and manufacturing industry due to the flexibility and smooth movement resulted from their constituent materials. Stimuli-responsive hydrogels are a class of materials that can show large volume changes due to various surrounding stimuli and thus is suitable as a soft actuator material. However, because the change in volume of the stimuli-responsive hydrogel depends on the rate of temperature change and the rate at which the solvent diffuses into the polymer network, in most typical operating conditions, the response time of the actuator is slow due to inefficient heat transfer and diffusion process. In this study, a conjugated polymer was introduced into polydiethylacrylamide, a thermoresponsive hydrogel, to implement a soft actuator driven by light, and the improvement in response time by the photothermal effect of the conjugated polymer was investigated. It was confirmed that the response time was improved by 41% by the introduction of the conjugated polymer, due to the improvement in heat transfer efficiency. Finally, a soft gripper using the hydrogel with improved response time was fabricated and the response time of the gripper was investigated.

The Effects of Electrodeposited Lead Dioxide Structure on the Ozone Evolution (전착이산화납 결정구조가 전해에 의한 오존발생에 미치는 영향)

  • Kim, In Hwan;Lee, Choong Young;Nam, Chong Woo
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.280-288
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    • 1996
  • In the ozone evolution using $PbO_2$, which was electrodeposited on Ti plate at various conditions in electrolyte, the effects of lead dioxide structure on the current efficiency and surface structure changes of lead dioxide were investigated. Also the effects of oxygen transfer reaction on the ozone evolution were investigated by means of a $PbO_2$ electrodeposited on the platinum rotating disk electrode. In order to develope an electrode for ozone evolution, durability of lead dioxide and optimum current density were investigated. At the electrodeposited lead dioxide with the larger grain size and higher crystallinity, the efficiency for ozone evolution was higher. Optimum current density to electrodeposite lead dioxide with large grain size and high crystalinity was $50mA/cm^2$. Lead dioxide deposited in the presence of glycerin showed the best advantage of ozone evolution. Also lead dioxide electrodeposited at less than $10mA/cm^2$ or at more than $100mA/cm^2$ has poor performance of ozone evolution and poor adhesive strength to substrate. In the beginning of ozone evolution, surface structure of lead dioxide was changed and this change resulted in good effects on ozone evolution. Lead dioxide doped with other elements was favorable not to ozone evolution but to oxygen evolution, so it is speculated that ozone evolution has not intermediate stage of oxygen evolution and occurs competitively with oxygen evolution. When ozone was evolved at $0.7{\sim}0.8A/cm^2$, the current efficiency was highest.

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Monitoring Technology on the Surface Condition after Conservation Treatment of Stone Cultural Heritage (석조문화재의 보존처리 후 표면상태 모니터링 기술 연구)

  • Park, Sung Mi;Chun, Yu Gun;Lee, Myeong Seong
    • 보존과학연구
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    • s.34
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    • pp.32-48
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    • 2013
  • This study examined the applicability of deterioration monitoring techniques to establish efficient conservation and management system for stone cultural heritage which conservation treatment has been done. It was confirmed that deterioration mapping combined with photography and grid work, and adhesive tape test for the surface were very applicable to investigate the surface change due to deterioration, and assess the degree of granular disintegration quantitatively. The portable microscopic survey and ultrasonic measurement were efficient techniques to observe mineral looseness and microcrack, and to track the strength change of the stone before-and-after the conservation treatment. These techniques can be easily used by manage practitioners in the field through simple guidance and technical education. Also, it can contribute to build a long-term and methodical conservation and management system of the stone cultural heritage.

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Solvent-assisted sealing of poly(methylmethacrylate) microchannel under mild conditions (용매를 이용한 Poly(methylmethacrylate)의 저온 저압 본딩 및 마이크로 채널 표면의 선택적 소수성 코팅기법 개발)

  • Lee, Jae-Seon;Lee, Nae-Yun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.110-110
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    • 2017
  • 마이크로 플루이딕 디바이스는 화학, 생물학 실험 및 생체 의학 진단을 위한 플랫폼으로 지난 20년간 그 사용 및 연구가 증가되어 왔다. 마이크로 플루이딕 디바이스를 제작하는 데 있어 가장 일반적으로 사용되는 재료는 실리콘이지만 비용이 많이 들고 불투명하므로 광학 검출이 필요한 곳에 적용이 제한된다. 이러한 측면에서 열가소성 플라스틱은 상업화의 중요한 요소인 대량 생산에 있어 큰 잠재력을 가지고 있으며 저렴하고, 가공이 쉽고, 유연하고, 광학적으로 투명하고, 화학적으로 불활성이며, 생체적합성을 가진다. 본 연구에서는 열가소성 플라스틱의 일종인 PMMA Poly(methylmethacrylate)를 효율적으로 접합하기 위해 비교적 낮은 온도와 낮은 압력에서 에탄올을 활용한 접착방식을 개발하였다. 먼저, PMMA 기판의 전체 표면을 $80^{\circ}C$에서 20 분 동안 에탄올로 처리한 후, $60^{\circ}C$에서 20 분간 열 압착하는 방식으로 영구적인 결합이 이루어졌다. 결합 강도 및 채널의 sealing 정도를 확인하기 위해, 인장 강도, 누수 및 파열 테스트를 수행하였다. 결합강도는 약 12.4 MPa로 타 연구와 비교할 때 매우 높았으며 마이크로 채널의 전체 내부 체적보다 거의 450 배 높은 강한 액체 흐름을 견딜 정도로 견고한 결합이 유지되었다. 열가소성 플라스틱의 본딩에 사용되는 유기 용매는 광학 특성을 희생시키지 않으면서 결합 속도를 높일 수 있지만, 결합 공정 중에 용매로 인해 마이크로 채널이 막히는 현상이 발생될 수 있다. 따라서, 견고한 본딩을 유지하면서 채널 막힘을 방지하기 위해 마이크로 채널을 소수성으로 선택적으로 처리하여 내벽의 표면 특성을 튜닝해 주는 기법을 추가로 적용하였다. 본 연구에서 사용한 방법은 아민-PDMS (polydimethylsiloxane) 링커를 적용하여 기판 표면의 극성을 변경시켜 주었다. 아민-PDMS 링커는 PC (polycarbonate), PET (polyethylene terephthalate), PVC (polyvinyl chloride) 및 PI (polyimide)와 같은 다양한 열가소성 플라스틱의 표면 소수성을 현저히 증가시키며 화학적, 열적 안정성이 뛰어나다. 아민-PDMS 링커는 PMMA의 카보닐 그룹과 반응할 수 있는 아민 사이드 그룹을 포함하는 PDMS 백본으로 구성되며 처리된 대상표면을 소수성으로 만든다. 아민-PDMS 링커 처리 이후 채널은 소수성으로 변화되었으며 이는 접촉각(contact angle)의 증가로 확인되었다. 코팅된 채널을 에탄올로 30분간 80도에서 처리하여도 소수성은 그대로 유지되어 마이크로 채널의 선택적인 소수성 코팅이 성공적으로 수행되었다.

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Analysis of Signal Transfer Characteristics of Implantable Middle Ear System using Acoustic Model (청각모델을 이용한 이식형 인공중이 시스템의 신호 전달 특성 해석)

  • 송병섭;조진호
    • Journal of Biomedical Engineering Research
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    • v.23 no.3
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    • pp.227-233
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    • 2002
  • The IME(implantable middle ear) system is Promising due to its ability to free from sound feedback and Produce a good sound quality and intelligibility with low distortion even if it is operated with high gain for severe hearing impaired. The differential electromagnetic vibration transducer. which was developed for using in IME system and has two small magnets attached the same Pole facing in the coil. is not influenced by environmental external magnetic field. Besides, it has high vibration efficiency and good frequency response characteristics. In this Paper, using acoustic model of the transducer and ear model of normal Person. the signal transfer characteristics of the IME system are analyzed and investigated From the differences of the characteristics between normal ear and the IME system, it is Possible that design of the IME system that have the signal transfer characteristics similar to normal person's ear.

Basic Study on Fiber Composite Panel Production for Impact·Blast Resistant (방호·방폭 보강용 복합섬유 패널 제작을 위한 기초연구)

  • Kim, Woonhak;Kang, Seokwon;Yun, Seunggyu
    • Journal of the Society of Disaster Information
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    • v.11 no.2
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    • pp.235-243
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    • 2015
  • The methods to improve the protection and explosion-proof performance of concrete structures include the backside reinforcement or concrete material property improvement and the addition of structural members or supports to increase the resistance performance, but they are inefficient in terms of economics and structural characteristics. This study is about the basic study on the fiber composite panel cover, and the nano-composite material and adhesive as the filler, to maximize the specific performance of each layer and the protection and explosion-proof performance as the composite panel component by improving the tensile strength, light weight, adhesion and fire-proof performances. The fiber composite panel cover (aramid-polyester ratios of 6:4 and 6.5:3.5) had a 2,348 MPa maximum tensile strength and a 1.8% maximum elongation. The filler that contained the nano-composite material and adhesive had a 4 MPa maximum tensile shear adhesive strength. In addition, the nano-composite filler was 30% lighter than the normal portland cement

The Content and Chemical and Physical Properties of the Pectin in Tangerine Peel (한국산 감귤류 폐과피 내의 펙틴함량과 펙틴의 특성에 관한 연구)

  • Moon, Soo-Jae;Sohn, Kyung-Hee;Yun, Seon;Lee, Myung-Hae;Lee, Myung-Hee
    • Korean Journal of Food Science and Technology
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    • v.14 no.1
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    • pp.63-66
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    • 1982
  • The pectin content in tangerine peel and the characteristics of extracted pectin and its gel were determined. The pectin contents of citrus peel and citrus albedo were 11.52% and 9.3% on a dry weight basis, respectively The equivalent weight, methoxyl content and acetyl content of the extracted citrus peel pectin were 596, 13.41% and 0.125% respectively. The intrinsic viscosity and molecular weight of extracted citrus peel pectin were higher than those of commercial citrus pectin samples. The anhydrouronic acid content and jelly grade of the extracted pectins were 98.4% and 138.1, respectively. These were higher than those of commercial citrus pectin. In the textural characteristics of gels, the gel made from the extracted pectin was shown to have lower values in hardness, cohesiveness, adhesiveness and gumminess than the gels made from commercial citrus pectins.

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An Optimum Design of Sandwich Panel at Fixed Edges (고정지지된 Sandwich Panel의 최적설계에 관한 연구)

  • K.S. Kim;I.T. Kim;Y.Y. Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.2
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    • pp.115-122
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    • 1992
  • A sandwich element is a special Hybrid structural form of the composite construction, which is consisted of three main parts : thin, stiff and relatively high density faces separated by a thick, light, and weaker core material. In a sandwich construction, the shear deformation of the faces. Therefore, in the calculation of the bending stiffness, the shear effect should be included. In this paper, the minimum weight is selected as an object function, as the weight critical structures are usually composed of these kind of construction. To obtain the minimum weight of sandwich panel, the principle of minimum potential energy is used and as for the design constraints, the allowable bending stress of face material, the allowable shear stress of core material, the allowable value of panel deflection and the wrinkling stress of faces are adopted, as well as the different boundary conditions. For the engineering purpose of sandwich panel design, the results are tabulated, which are calculated by using the nonlinear optimization technique SUMT.

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탄소나노튜브 에미터 기반 Flat Light Lamp 제작 시 금속전극 선폭과 간격 변화에 따른 전계방출 특성평가

  • Lee, Han-Seong;Im, Byeong-Jik;Ha, In-Ho;O, Se-Uk;Lee, Cheol-Seung;Lee, Gyeong-Il;Jo, Jin-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.520-520
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    • 2013
  • Lateral 구조를 갖는 탄소나노튜브 에미터 캐소드의 금속전극 선폭과 간격은 탄소나노튜브 에미터 밀도와 게이트에 인가되는 전계의 크기에 밀접한 관계가 있어 전계방출특성에 큰 영향을 나타내므로 조속한 상업화를 위해서는 최적화 연구가 요구된다. 따라서 본 연구에서는 금속전극의 선폭과 간격을 110/30, 80/30, 40/30과 120/20, 90/20, 20/20 ${\mu}m$로 각각 변화시켜 4.6인치 탄소나노튜브 에미터 기반 flat light lamp 개발연구를 진행하였다. 이때 사용한 금속전극은 2 mm 두께를 갖는 4.6인치 소다라임 글라스 위에 패턴 된 PR에 Ag를 sputtering하여 증착 후 PR을 lift-off하여 형성하였다. 이와 같이 형성된 금속전극은 ~1 ${\mu}m$와 12 nm의 두께와 표면단차를 각각 가지고 있었다. 형성된 금속전극 위에 유전체와 탄소나노튜브 에미터를 각각의 페이스트를 사용하여 스크린 인쇄와 소성과정을 통해 형성하였다. 이때 레이저 빔을 전극사이의 빈 공간에 조사하여 탄소나노튜브 에미터를 금속전극 위에 정밀하게 정렬하였으며 잔존하는 유기물과 유기용매를 없애기 위해 대기압 공기분위기의 $410^{\circ}C$에서 10분간 소성과정을 거친 후 접착테이프를 사용하여 잔탄 속에 있는 탄소나노튜브 에미터를 물리적 힘으로 수직하게 노출시켜 캐소드를 준비하였다. 애노드는 전계에 의해 방출된 전자의 측정과 전계방출 이미지를 얻기 위해서 P22 형광체와 Al박막이 증착된 2 mm 두께의 소다라임 글라스를 사용하였다. 캐소드와 애노드 사이의 간격은 6~10 mm로 유지하였고, 진공챔버의 기본 압력을 $5{\times}10^{-6}$ Torr 이하로 유지하였다. 캐소드와 게이트 전극에 1, 4 kHz와 3% duty를 갖는 bipolar 형태의 DC 사각펄스파를, 애노드에 ~18 kV의 DC 고전압을 각각 인가하여 평가하였으며 추후, 이렇게 제작된 다양한 선폭과 간격을 갖는 탄소나노튜브 에미터 기반 flat light lamp의 전계방출특성과 효율에 대한 비교 연구를 진행할 계획이다.

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