• Title/Summary/Keyword: 점토벽돌

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Slagging Effect of Combustion Gas containing Sulfur on Refractories (내화물에 대한 황함유 연소가스의 영향)

  • 임응극;이영희
    • Journal of the Korean Ceramic Society
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    • v.11 no.4
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    • pp.5-18
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    • 1974
  • 본 연구에 있어서는 연료유의 연소에 의한 내화물의 부식을 연구하기 위하여 시멘트소성용 회전가마, 보일러 및 판유리제조용 탱크가마에 쓰이는 여러 내화물을 짤라서 그 가운데에 구멍을 파고 중유재의 주성분인 V2O5, Na2CO3, Fe2O3, Fe 및 황산철을 미리 그 구멍속에 넣어 응용 확산시킨 다음 이들을 그들의 상용온도인 145$0^{\circ}C$로 황 함유량이 다른 연류유로 소성하여 얻은 결과는 다음과 같다. 일반적으로 5산화 바나듐-알루미나, 고알루미나질 및 염기성 내화물; 산화나트륨-고알루미나질, 실리마나이트질 및 염기성 내화물은 2%미만의 황 함유 연류유소성에 의하여 부식이 적고 3.5%이상의 황하유 연료유소성시는 황에 의하여 대개가 침식을 당하였다. 무수 아황산 분위기속에서 규산알루미늄 및 구석계의 내화점토질내화물은 산화철이 환원되어 색이 연해지고 고알루미나질 벽돌은 색이 짙어지는 경향이 있고 산화철은 황산철로 변하여 풍화의 원인이 되어 침식을 당하게 되었고, 소성시간이 길면 길수록 부식은 증가하고 황산소다보다 탄산소다에 의하여 훨씬 더 많이 부식을 당하였다.

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The control of liquid phase behavior during sintering of Clay/EAF dust bodies (Clay/EAF dust계 시편의 소결과정 중 액상거동 제어)

  • Kim, Kwang-Soo;Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.2
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    • pp.68-74
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    • 2005
  • The electrical arc furnace (EAF) classified as a special waste contains many flux components producing melts during a sintering process, so it decreases the sintering temperature and improves the mechanical properties of specimens. Increasing dust content in a clay-dust system brick, however, may cause the fraction defective higher due to the excessive liquid produced. To control the liquid behavior produced during sintering process for the clay-dust system specimens, the $Al_2O_3$ was added and the physical properties were analyzed. The microstructure for the clay-dust system body sintered with $Al_2O_3$ became homogeneous and the overall size of pores decreased. Adding $Al_2O_3$ to clay-dust system body increased the mechanical properties and the temperature of maximum strength increased as much as $50^{\circ}C$, and the apparent density increased and the absorption decreased. The mullite ($3Al_2O_3{\cdot}2SiO_2$) was produced during sintering process by reaction of $Al_2O_3$ and $SiO_2$ which could participate to liquid-producing-process and the viscosity of melts increased which was proved by measuring a critical viscosity temperature (Tcv) therefore, the refractoriness of specimens were improved to lower the fraction defective.

Fundamental Study on Recycling as Construction Material of Dredged Harbor Soil Mixed with Clay and Glass Frit (점토와 유리프리트를 혼합한 항만준설토의 건축자재 재활용에 관한 기초연구)

  • Im, Dong-Su;Kim, Kyung-Nam;Cho, Yeon-Bae;Park, Joon-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.575-585
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    • 2013
  • This research was performed to evaluate the recycling feasibility as a construction material of dredged harbor soil mixed with clay and glass frit. Concentration of heavy metals of the dredged soil from D harbor was severly high, showing Zn of 526.0~13,150.1 mg/kg. The dredged soil was maily composed of 48.30 wt% $SiO_2$, 16.60 wt% $Al_2O_3$, 10.10 wt% CaO, 7.75 wt% $Fe_2O_3$. The clay and the glass frit contained 70.82 wt% $SiO_2$ and $Al_2O_3$ 18.78 wt%, and 71.75 wt% $SiO_2$, 13.99 wt% CaO, 8.51 wt% $Na_2O$, respectively. After adding 10~40 wt% to the clay and sintering them at $1,000^{\circ}C$ or $1,100^{\circ}C$, the compressive strength of the sintered specimens showed $132.6{\sim}178.5kgf/cm^2$ or $581.2{\sim}793.7kgf/cm^2$, respectively. In case of SC46 with the addition 40 wt% of the dredged soil to the clay, the compressive strength ($793.7kgf/cm^2$) of specimen sintered at $1,100^{\circ}C$ was over 5 times higher than that at $1,000^{\circ}C$. The specimen mixed with 40 wt% of dredged soil, 60 wt% of clay and 1 wt% of glass frit satisfied the 1st grade standard for clay brick by KS L 4201. The results of all specimens by Korean Standard Leaching Test also satisfied the standard criteria.

Deterioration Assessment and Conservational Scientific Diagnosis of the Stone Pagoda in the Bunhwangsa temple, Gyeongju, Korea (경주 분황사석탑의 풍화훼손도 평가와 보존과학적 진단)

  • Yi, Jeong-Eun;Lee, Chan-Hee;Lee, Myeong-Seong
    • Journal of Conservation Science
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    • v.18 s.18
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    • pp.19-32
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    • 2006
  • The stone pagoda of the Bunhwangsa temple made by piling small brick-shaped stones. The major rock forming stone bricks are andesites with variable genesis. Rock properties of the pagoda roof stone suffer partly including multiple peel-offs, exfoliation, decomposition like onion peels, cracks forming round lines and falling off stone pieces. The stylobates and tabernacles in all the four directions the pagoda are mostly composed of granitic rocks. Those rock properties are heavily contaminated by lichens and mosses with the often marks of inorganic contamination by secondary hydrates that are dark black or yellowish brown. Within the four tabernacles and northern pagoda body situated to relatively high humidity. There are even light gray precipitate looking like stalactites between the northern and western rocks of the body Their major minerals are calcite, gypsum and clays. The stone lion standing in the southeast and northeast side are alkali granite, while that in the southwest and northwest lithic tuff. Total rock properties of the pagoda are 9,708 pieces, among the all properties, fractured blocks are 11.0%, fall out blocks are 6.7% and covered blocks by precipitates are 7.0%, respectively. The pagoda has highly deteriorated the functions of the rock properties due to physical, chemical and biological weathering, therefore, we suggest that this pagoda has need to do long term monitoring and synthetic conservation researches.

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Preparation of Multi-functional Brick Using MSWI Fly Ash (소각재를 이용한 건축외장재 제조)

  • Ban, Hyo-Jin;Park, Eun-Zoo;Lee, Woo-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.2
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    • pp.114-118
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    • 2009
  • With the advance of industrialization and urbanization, a lot of waste has been discharged and treated by incineration. But fly and bottom ashes are generated in this process. In addition, the treatment method to recycle sewage sludge and melting slag is required to manage these wastes. The objective of this research was to prepare of multi-functional brick which were made from MSWI (Municipal solid wastes incinerator) fly ash, sewage sludge and slag. The bricks were made by mixing raw materials and then drying for 24 hours. Next, they were dried for 24 hours at $160^{\circ}C$ and fired for 2 hours. Calcination temperature was changed to discuss the effect of temperature from $1,080^{\circ}C$ to $1,130^{\circ}C$. Compressive strength of a brick was creased with the increase of temperature. To increase mixing ratio of fly ash and slag reduce the compressive strength the optimal condition was the mixing ratio of fly ash : melting slag : sewage sludge : clay as 10 : 20 : 5 : 65 and $1,150^{\circ}C$ of calcination temperature. Compressive strength was obtained as about 41 MPa at this condition.

The Influence of Landscape Pavements on the WBGT of Outdoor Spaces without Ventilation or Shade at Summer Midday (조경포장이 옥외공간의 온열쾌적성지수(WBGT)에 미치는 영향 - 통풍과 차광이 배제된 하절기 주간의 조건에서 -)

  • Lee, Chun-Seok;Ryu, Nam-Hyung
    • Journal of the Korean Institute of Landscape Architecture
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    • v.38 no.2
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    • pp.1-8
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    • 2010
  • The purpose of the study was to evaluate the influence of landscaping pavements on WBGT(Wet-Bulb Globe Temperature) of outdoor spaces that lack ventilation and shade at summer midday. The relative humidity(RH), dry-bulb temperature(DT) and globe temperature(GT) were recorded every minute from June to October 2009 at a height of 1.2m above ten experimental beds with different pavements, by a measuring system consisting of an electric humidity sensor(GHM-15), resistance temperature detector(RTD, Pt-100), standard black globe(${\phi} 150mm$) and data acquisition systems(National Instrument's Labview and Compact FieldPoint). Additionally, the surface dry-bulb temperatures also were recorded and compared. The area of each experimental bed was 1.5m(W)${\times}$2.0m(L) and ten different kinds of pavement were used including grass, grass+cubic stone, grass+porous brick, brick, stone panels, cubic stone, interlocking blocks, clay brick, naked soil, gravel and concrete. To prevent interference from ventilation, a 1.5m height cubic steel frame was established around each bed and each vertical side of the frame was covered with transparent polyethylene film. Based on the records of the hottest period from noon to 3 PM on 26 days with a peak dry-bulb temperature over $30^{\circ}C$ at natural condition, the wet-bulb temperature(WT) and WBGT were calculated and compared. The major findings were as follows: 1. The average surface DT was $40.1^{\circ}C$, which is $9^{\circ}C$ higher than that of the natural condition. The surface DT of the pavements with grass were higher than those of concrete and interlocking block. The peak DT of the surface almost every pavement rose to above $50^{\circ}C$ during the hottest time. 2. The averages of DT, WT and GT were $40.1^{\circ}C$, $27.5^{\circ}C$ and $49.1^{\circ}C$, and the peak values rose to $48.1^{\circ}C$, $45.8^{\circ}C$ and $59.5^{\circ}C$, respectively. In spite of slight differences that resulted according to pavements, no coherent differentiating factor could be found. 3. The average WBGT of grass was the highest at $34.3^{\circ}C$ while the others were similar in the range of around $33{\pm}1^{\circ}C$. Meanwhile, the peak WBGT was highest with stone panel at $47.9^{\circ}C$. Though there were some differences according to pavements, and while grass seemed to be worst in terms of WBGT, it seems difficult to say ablolutely that grass was the worst because the measurement was conducted without ventilation and shade during summer daytime hours only, which had temperatures that rose to a dangerous degree(above $45^{\circ}C$ WBGT), withering the grass during the hottest period. The average WBGT resulted also showed that the thermal environment of the pavement without ventilation and shade were at an intolerable level for humans regardless of the pavement type. In summary, the results of this study show that ventilation and shade are more important factor than pavement type in terms of outdoor thermal comfort in summer daylight hours.

The Effect of Al2O3 upon Firing Range of Clay-EAF Dust System Body (Clay-EAF Dust계 소지의 소결온도 범위에 미치는 Al2O3의 영향)

  • 김광수;강승구;이기강;김유택;김영진;김정환
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.494-500
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    • 2003
  • The effects of $Al_2$O$_3$ addition upon the sintering range of clay-EAF dust (the specified wastes produced from steel making process) system body which would be used as a constructing bricks were investigated. The slope of apparent density to sintering temperature decreased for Clay-dust body containing 5~15 wt% A1203 sintered at 1200-125$0^{\circ}C$, and the absorption(%) of specimen sintered above 125$0^{\circ}C$ decreased due to the formation of open pores produced by pore bloating. For the specimen without any $Al_2$O$_3$ addition sintered at 1275$^{\circ}C$, the major phase was cristobalite, the small amount of mullite (3Al$_2$O$_3$ 2SiO$_2$) formed and the hematite (Fe$_2$O$_3$) remained. In the Clay-dust system body containing $Al_2$O$_3$ 15 wt%, however, the cristobalite disappeared and the major phase was mullite. Also the part of $Al_2$O$_3$ reacted with hematite to form hercynite (FeAl$_2$O$_4$). From the these results, addition of $Al_2$O$_3$ to Clay-dust system body enlarges a sintering range; decreasing an apparent density and absorption slop to sintering temperature owing to consumption of liquid phase SiO$_2$ at higher temperature and gas-forming component Fe$_2$O$_3$ at reduced atmosphere which would decrease an amount of liquid formed and increase the viscosity of the liquid produced during the sintering process.