• Title/Summary/Keyword: 전이 금속

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Colossal Magnetoresistance and Mossbauer Studies of La-Ca-Mn-O Compound Doped with $^{57}Fe$ ($^{57}Fe$를 미량 치환한 La-Ca-Mn-O의 초거대자기저항과 Mossbauer분광학연구)

  • 박승일;김성철
    • Journal of the Korean Magnetics Society
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    • v.8 no.6
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    • pp.335-340
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    • 1998
  • Colossal magnetoresistance $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ material has been produced by a metal-salt routed sol-gel process method. Magnetic properties of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ have been studied with x-ray diffraction, Rutherford back-scattering spectroscopy(RBS), vibrating sample magnetometer, and Mossbauer spectroscopy. Crystalline $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ was perovskite cubic structure with a lattice parameter $a_0=3.868$\AA$$. And there was no appreciable change in the value of the lattice parameter when a small amount (x=0.01) of iron was added. However, Mossbauer and VSM data indicate the Curie temperature of the $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ decreased from 282 to 270 k and also the saturation magnetization from 84 to 81 emu/g at 77 K. Mossbauer spectra of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ have been taken at various temperatures ranging form 4.2 K to room temperature. Analysis of $^{57}Fe$ Mossbauer data in terms of the local configurations of Mn atoms has permitted the influence of the magnetic hyperfine interactions to be monitored. The isomer shifts show that the charge state of all Fe ions are ferric. The magnetoresistance of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ was about 33 % at semiconductor-metal transition temperature $T_{SC-M}=250K$.

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Magnetic and Magneto-Optical Properties of $Mn_{1-x}Cr_xPt_3$ Ordered Alloy Films ($Mn_{1-x}Cr_xPt_3$ 박막의 자기 및 자기광학 특성)

  • 박문기;조재경
    • Journal of the Korean Magnetics Society
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    • v.8 no.6
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    • pp.374-379
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    • 1998
  • $Mn_1-xCr_xPt_3$ alloy films have been prepared by depositing (Mn, Cr)/Pt multilayers using a rf magnetron sputterer followed by heat treatment. Small and wide angle x-ray diffractometry, magnetic hysteresis loops and Kerr rotation angle spectra of the films have been measured and used to investigate structural, magnetic and magneto-optic properties of the films. The films had a crystal structure of ordered AuCu$_3$ type and the strong preferred orientation of a (111)plane parallel to the film surface. The saturation magnetization of the films was decreased with Cr content reaching almost zero near x=0.58 and then increased for further increasement of Cr content up to x=0.77 over that stayed almost constant. This indicated that Cr atoms were antiferromagnetically coupled with Mn atoms. The magnetic easy axis of MnPt$_3$(x=0) film was parallel to the film surface but those of the films with x$\geq$0.58 increased as Cr content increased reaching about 4 kOe at x=1(CrPt$_3$). The dependence of the Kerr rotation angle on the Cr content was similar to that of the saturation magnetization on the Cr content. The films with x=0.77 and x=1 showed the larger Kerr rotation angle at the wavelengths of near infrared compared to the magneto-optic recording medium, TbFeCo, currently being used.

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DENTAL TREATMENT IN A PATIENT WITH ATYPICAL TERATOID RHABDOIDAL TUMOR UNDER GENERAL ANESTHESIA (비정형 유기형/간상 종양(Atypical teratoid rhabdoidal tumor) 환자의 전신마취 하 치과치료)

  • Kim, Hyuntae;Song, Ji-Soo;Hyun, Hong-Keun;Kim, Young-Jae;Kim, Jung-Wook;Jang, Ki-Taeg;Lee, Sang-Hoon;Shin, Teo Jeon
    • The Journal of Korea Assosiation for Disability and Oral Health
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    • v.15 no.1
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    • pp.74-78
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    • 2019
  • Atypical teratoid rhabdoidal tumor(AT/RT) is a rare and fast-growing tumor usually diagnosed in childhood. Routine magnetic resonance imaging(MRI) assessment of AT/RT patients is done to detect metastatic tumors and recurrent lesions. The purpose of this case report is to present a case about caries treatment of a 3-year-8-month old female patient with AT/RT under general anesthesia. A 3-year-8-month old patient with AT/RT visited Seoul National University Dental Hospital for caries treatment. At the first dental visit, she was receiving chemotherapy. Multiple caries were observed from clinical and radiographic examination. The dental procedure was successfully performed under general anesthesia. Patients with brain tumor may take routine MRI to detect metastatic tumors and recurrent lesions. Dentists should take into consideration of possible dislodgement of restoration by ferromagnetic properties and artifact formation on MRI image. Ready-made zirconia crowns can be a good restoration option for such patients.

FEA(Finite Element Analysis) Study for Electronic Hydrogen Regulator of Confidentiality Improvement (전자식 수소레귤레이터 기밀성 향상을 위한 FEA 연구)

  • Son, Won-Sik;Song, Jae-Wook;Jeon, Wan-Jae;Kim, Seung-Mo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.9
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    • pp.175-181
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    • 2019
  • In the case of a conventional single stage decompression regulator used for large depressurization in the hydrogen fuel cell system of a fuel cell electric vehicle (FCEV), problems can arise, such as pulsation, slow response, hydrogen brittleness, leakage, high weight, and high cost due to high decompression. Most of these problems can be overcome easily using two decompression mechanisms (two-stage structures). In addition, a wide outlet-pressure control range can be secured if an electronic solenoid is applied to the second decompression. Accordingly, it is necessary to improve the precision of the outlet pressure of a two-stage pressure-reducing regulator and develop techniques, such as leakage prevention, durability, light weight, and price reduction. Therefore, to improve the outlet pressure accuracy and prevent leakage, the structural part before and after decompression to improve the air tightness were divided and the analysis was carried out assuming that the valve part was closed (open ratio: 0%) after each initial internal pressure application.

Influence of Charging Condition of Al-dross on Maximum Concentration of Al in Molten Steel : Fundamental study for improvement of chemical energy in EAF process (용강 중 Al 최대 농도에 대한 Al 드로스 장입 조건의 영향: 전기로 공정 내 화학 에너지 향상을 위한 기반 연구)

  • Kim, Gyu-Wan;Kim, Sun-Joong
    • Resources Recycling
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    • v.28 no.4
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    • pp.44-50
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    • 2019
  • In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.

A Study on Conservation and Manufacturing Techniques of a Seated Avalokiteshvara with a Thousand Hands of Goryeo Dynasty (고려시대 금동제십일면천수관음보살좌상의 보존처리 및 제작기술 연구)

  • Gwak, Hong In;Kwon, Mi Hye
    • Journal of Conservation Science
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    • v.35 no.3
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    • pp.253-258
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    • 2019
  • The gilt bronze statue, Seated Avalokiteshvara with a Thousand Hands, of the Goryeo dynasty, is the only one in Korea of its kind that has undergone a conservation process for the special exhibition entitled GORYEO: The Glory of Korea. For the conservation treatment, first, a component analysis (XRF) was conducted, and a manufacturing technique (CT) was analyzed. The results of the investigation revealed that the statue was alloyed with Cu, Sn, and Pb ternary bronze. Its surface, except for the detached plating layers, was originally plated using the mercury amalgam method. This statue was assembled after separately casting each part of the body, such as the left and right arms and the wrists, including the hands, with objects. In particular, each wrist was cast and fitted with a metal nail to express each object in the hands more precisely. Inside the statue, there were five iron cores: two for the head, one for the left elbow, one for the right flank, and one for the right waist. For the preservative treatment, natural adhesive agents, including vegetable gelatin and glue (20%), were mixed with alcohol to protect the base metal and adhere to the plating layers. Using synthetic resin (CDK 520+SN-sheet) for the damaged parts, the restored parts could be attached and detached to/from the statue. Eventually, the compositional analysis and conservation treatment left the statue in a stable condition and ready for exhibitions and future studies.

Verification of the Reliability of the Numerical Analysis for the Crash Impact Test of Rotorcraft Fuel Tank (회전익항공기용 연료탱크 충돌충격시험에 대한 수치해석 신뢰성 검증)

  • Kim, Sungchan;Kim, Hyun-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.918-923
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    • 2018
  • The main function of a fuel tank is to store fuel. On the other hand, the structural soundness of the fuel tank is related directly to the survival of the crew in an emergency situation, such as an aircraft crash, and the relevant performance is demonstrated by a crash impact test. Because crash impact tests have a high risk of failure due to the high impact loads, various efforts have been made to minimize the possibility of trial and error in the actual test at the beginning of the design. Numerical analysis performed before the actual test is a part of such efforts. For the results of numerical analysis to be reflected in the design, however, the reliability of numerical analysis needs to be ensured. In this study, the results of numerical analysis and actual test data were compared to ensure the reliability of numerical analysis for the crash impact test of a rotorcraft fuel tank. For the numerical analysis of a crash impact test, LS-DYNA, crash analysis software, was used and the ALE (arbitrary Lagrangian Eulerian) technique was applied as the analysis method. To obtain actual test data, strain gages were installed on the metal fittings of the fuel tank and linked to the data acquisition equipment. The strain and stress of the fuel tank fitting were calculated by numerical analysis. The reliability of the numerical analysis was enhanced by assessing the error between the strain measurement of the upper fitting obtained from an actual fuel tank and the strain calculated from numerical analysis.

A Novel Heptapeptide that Promotes Cellular Activity and Inhibits Photoaging in Fibroblasts (섬유아세포에서 세포 활성 촉진 및 광노화 억제 효능을 보이는 신규 헵타펩타이드)

  • Lee, Eung Ji;Kang, Hana;Hwang, Bo Byeol;Chung, Yong Ji;Kim, Eun Mi
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.2
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    • pp.157-167
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    • 2022
  • In this study, we investigated the effects of heptapeptide on cellular activation and inhibition of cellular damage induced by photoaging condition in NIH3T3 fibroblasts. Cell proliferation and extracellular matrix (ECM) expression were induced by heptapeptide. The reduced cell viability under photoaging condition through ultraviolet A (UVA) irradiation was increased by heptapeptide. And UVA-induced apoptosis, matrix metalloproteinases-1 (MMP-1) expression, and reactive oxygen species (ROS) level were decreased by heptapeptide. In addition, the inhibition of transforming growth factor-β (TGF-β)/smad signaling under UVA irradiation which resulting in reduction of ECM expression was also recovered by heptapeptide. We also tested the effect of heptapeptide under another photoaging condition through heat shock, and pre-treatment of heptapeptide prevented the phosphorylation of mitogen-activated protein kinase (MAPK) and MMP-1 expression induced by heat shock. From these results, it has been shown that the heptapeptide has protective effects on fibroblasts through the up-regulation of cellular activity and through the decreasing of intracellular ROS level induced by UVA irradiation or heat shock. It is expected that the dermal protection effect of heptapeptide can be applied as a new cosmetic material in the future.

A Study on the Resistve Switching Characteristic of Parallel Memristive Circuit of Lithium Ion Based Memristor and Capacitor (리튬 이온 기반 멤리스터 커패시터 병렬 구조의 저항변화 특성 연구)

  • Kang, Seung Hyun;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.4
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    • pp.41-45
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    • 2021
  • In this study, in order to secure the high reliability of the memristor, we adopted a patterned lithium filament seed layer as the main agent for resistive switching (RS) characteristic on the 30 nm thick ZrO2 thin film at the device manufacturing stage. Lithium filament seed layer with a thickness of 5 nm and an area of 5 ㎛ × 5 ㎛ were formed on the ZrO2 thin film, and various electrode areas were applied to investigate the effect of capacitance on filament type memristive behavior in the parallel memristive circuit of memristor and capacitor. The RS characteristics were measured in the samples before and after 250℃ post-annealing for lithium metal diffusion. In the case of conductive filaments formed by thermal diffusion (post-annealed sample), it was not available to control the filament by applying voltage, and the other hand, the as-deposited sample showed the reversible RS characteristics by the formation and rupture of filaments. Finally, via the comparison of the RS characteristics according to the electrode area, it was confirmed that capacitance is an important factor for the formation and rupture of filaments.

A review on Separation Technologies for Lithium Recovery from Waste Solutions in Recycling Process of Waste Battery (폐배터리 재활용 공정 폐액 중 리튬 회수를 위한 분리 기술 고찰)

  • Song, Daesung;Kim, Eunkyu;Vu, Thang-Toan
    • Korean Chemical Engineering Research
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    • v.60 no.4
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    • pp.473-477
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    • 2022
  • In this study, candidate technologies for lithium recovery from the process waste liquid generated in the waste battery recycling process were reviewed, and technologies applicable to the process from the commercialization point of view were reviewed from a qualitative point of view. The evaporation method is difficult to apply because it requires a large-scale land and shows a low recovery rate due to the loss of Li during the concentration process. In the case of precipitation, a commercially available technology shows a high recovery rate due to the high Li/Na selectivity of phosphoric acid, but there are disadvantages in that the process is complicated due to the use of expensive phosphoric acid, requiring a recovery step, and continuous operation is impossible because solids are handled in the Li concentration process. In the case of solvent extraction, if we find an inexpensive extractant with high Li/Na selectivity, continuous operation is possible with the method used in extraction of other metals in the previous step, and when Li is concentrated, continuous operation is possible because it is in a liquid state. If it shows a similar recovery rate compared to precipitation technology, commercialization will be the most likely.