• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.207-207
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• 2013

기존의 그래핀 성장에 관한 연구는 열화학기상증착법(Chemical vapor deposition; CVD)을 이용한다. 그래핀 성장 제어 요소로는 촉매 기판인 전이 금속[Ru, Ir, Co, Re, Pt, Pd, Ni, Cu], 기판 전처리 과정, 수소/메탄 가스 혼합비, 작업 진공 상태, 기판온도[$800{\sim}1,000^{\circ}C$, 냉각 속도 등으로 보고 되고 있다. 그래핀 성장 원리는 Cu 촉매 기판에 메탄 가스를 $1,000^{\circ}C$ 온도에서 분해해서 탄소를 고용 시킨 후 급랭하는 도중에 석출되는 탄소에 의해 그래핀 시트가 형성되는 것으로 알려져 있다. 기존의 CVD를 열원을 이용할 경우 내부 챔버에 생기는 잠열에 의해 cooling profile의 제어가 용이하지 않다. 본 연구에서는 근적외선(Near Infrared; NIR) 열원을 이용한 CVD로 챔버 내부 잠열을 최소화하고, 냉각 공정을 Natural, Linear, Convex cooling type으로 디자인해서 cooling profile 제어가 그래핀 성장에 미치는 영향을 연구 하였다. 이렇게 성장된 그래핀을 임의의 기판(SiO2, Glass, PET film) 위에 습식방법으로 전이 시킨 후, 전기적 구조적 및 광학적 특성을 면저항(four-point probe), 전계방사 주사전자현미경(Field Emission Scanning Electron Microscope; FE-SEM), 마이크로 라만 분광법(Micro Raman spectroscopy) 및 광학현미경(optical microscope), 투과도(UV/Vis spectrometer)의 측정으로 잠열이 최소화된 NIR-CVD에서 cooling profile에 따른 그래핀 성장을 평가하였다.

• Journal of the Korean Ceramic Society
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• v.40 no.11
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• pp.1132-1137
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• 2003

For the application of environment conscious glass-fertilizer, dissolution characteristics of phosphate glass was investigated. In 0.1K₂O-0.1SiO₂-0.6P₂O/sub 5/ glass system, the compositions were designed according to variation of CaO & MgO contents, and glass formation region was confirmed. From the glass composition, the confirmed glasses were investigated to figure out thermal and dissolution properties. It was detected that glass transition & softening temperature of the glasses increased with increasing MgO contents. The dissolution properties of the glasses was affected by CaO and MgO content ratio.

• Clean Technology
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• v.6 no.1
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• pp.17-25
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• 2000

Catalytic oxidation of volatile organic compounds(benzene, toluene, xylene) over transition metals/ALO-6 catalysts was investigated in a fixed bed flow reactor system at atmospheric pressure. The orders of catalytic activities for the complete oxidation of toluene were Cu>Mn>Fe>V>Mo>Co>Ni>Zn for 15% transition metals/ALO-6 catalyst system. Increasing the calcination temperature resulted in decreasing the specific surface areas of catalyst, subsequently the catalytic activity. The loading of Cu on ALO-6 had a great effect on the catalytic activity and 5% Cu/ALO-6 catalyst showed higher catalytic activity, which may be contributed to the uniformly distributed active sites. Benzene, toluene and xylene were completely oxidized to carbon dioxide over 5% Cu/ALO-6 catalyst at over $380^{\circ}C$ and 4.5 g-cat.hr./g-mole. The orders of the kinds of reactants for catalytic activity over 5% Cu/ALO-6 were toluene>xylene>benzene. As the concentration of reactant increased, the catalytic activity decreased due to self-poison of reactant.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.1
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• pp.537-544
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• 2011

This work was conducted to investigate the oxidation characteristics of methane having the highest ignition temperature among the other hydrocarbon gases using transition metal catalysts. The catalyst used for methane oxidation was manganese oxide having a various oxidation number, such as MnO, $MnO_2$, $Mn_2O_3$, $Mn_3O_4$, $Mn_4O_5$. The manganese oxide(MnxOy) catalyst is impregnated on $TiO_2$, $Al_2O_3$ for methane oxidation. To enhanced both of activity and life time of catalysts, Ni and Co was used as a promoter. In this study, various co-catalysts were synthesized by using excess wet impregnation method. The effect of reaction temperature and space velocity was measured to calculate the activity of catalysts such as, activation energy of $T_{50}$, and $T_{90}$. The life time of bi-metallic manganese mixture, such as Mn-Co and Mn-Ni catalysts, were increased more 10 % than manganese oxide catalyst, but activity of those was decreased slightly.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.230-236
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• 2017

We synthesized liquid crystalline polymers containing isosorbide group as a cholesteric derivative and methylene group for controlling the transition temperature to the liquid crystal phase. Effects of the concentration of the isosorbide group and the position of the methylene group on the properties of the liquid crystalline polymer were investigated. Among all the synthesized polymers, polymers (MnHI-x) with a methylene group in the main chain showed higher melting transition temperature and thermal stability than those (SnBI-x) with a methylene group in the side chain. All the synthesized polymers showed an enantiotropic liquid crystal phase. The polymers having 10 mol% isosorbide as a cholesteric liquid crystal phase derivative showed nematic phase, and those having 20 mol% or more isosorbide showed a cholesteric or chiral smectic phase. Thus, we can conclude that the isosorbide group plays a role as a cholesteric liquid crystal phase derivative.

• Journal of the Korean Ceramic Society
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• v.25 no.3
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• pp.193-200
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• 1988

The starting materials were aluminum hydroxide prepared by precipitation method at the conditions of pH values; 7, 9, 10 and 11. The properties of alumina powder on heat-treatment were studied. After dehydrating structural water from amorphous aluminum hydroxide, the first formed phase was amorphous alumina and its specific surface are was decreased. The specific surface area was increased by dehydration of structural water from aluminum hydroxides except amorphous aluminum hydroxide. The specific surface area was increased with increase of the ratio of A1OOH to $A1(OH)_3$ in the region of transition aluminas. The rate of transition from aluminum hydroxide to alpha alumina occurred in the order of 7, 10, 9 and 11 of pH values. The morphology of alpha alumina powders was skeleton particles remaining outer shape of aluminum hydroxide. Both the elevation of heat-treatment temperature and the transition toalpha alumina decreased specific surface area and brought about the growth of particles.

• Membrane Journal
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• v.24 no.1
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• pp.50-62
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• 2014

An asymmetric microfiltration membranes were prepared with polysulfone by an immersion precipitation phase inversion method. Microfiltration membranes were prepared by polysulfone/N-methyl-2-pyrrolidone/polyvinylpyrrolidone/phosphoric acid casting solution and water coagulant. The vapor induced phase inversion method was used to prepare the membranes. The pore size and the morphology were changed by the phosphoric acid additive, the temperature of casting plate and the exposure time at the relative humidity of 74%. The morphology of membranes was investigated by scanning electron microscopy and microflow permporometer. By the addition of the phosphoric acid additive in the casting solution, the morphology of the prepared membranes were changed from a dense sponge structure to a loose asymmetric sponge structure. Due to the addition of catalytic amount of phosphoric acid to NMP casting solution, the mean pore size increased almost $0.2{\mu}m$ and the water flux increased about 3,000 LMH. The temperature of casting plate and exposure time had a apparent effect on the skin layer structure and the pore size and the porosity of the membrane.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1161-1168
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• 1999

The redox property of oxide materials of the 3rd period transition metals(Cr~Zn), V, Mo, and W was studied with temperature-programmed reduction/temperature-programmed oxidation(TPR/TPO) experiment. The peak temperatures of TPO spectra were equal to or lower than those of TPR spectra. And the peak shapes of TPO spectra were broader than those of TPR ones. The activation energies of TPR/TPO for the oxides of the 3rd period transition metals showed in the range of 33~149 kJ/mol, while for the oxides of V, Mo, and W, they showed relatively higher values. The change of activation energies of TPR/TPO with various metal oxides showed a similar trend to the change of their metal-oxygen bond strengths. The change of activation energies of o-xylene oxidation for various metal oxides was proportional to the difference (${\Delta}E_a$) between the activation energy of TPR and that of TPO. From these results, we concluded that the oxidation of o-xylene over various metal oxide catalysts follows the Mars-van Krevelen mechanism including the surface reduction-oxidation of the metal oxide itself.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.2
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• pp.644-650
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• 2021

This study characterized the reforming of methane with carbon dioxide, which is a major cause of global warming. The methane decomposition reaction with carbon dioxide was carried out using transition metal catalysts. The reactivity of tin was lower than that of a transition metal, such as nickel and iron. Most of the decomposition reaction occurred in the solid state. The melting point of tin is 505.03 K. Tin reacts in a liquid phase at the reaction temperature and has the advantage of separating carbon produced by the decomposition of methane from the liquid tin catalyst. Therefore, deactivation due to the deposition of carbon in the liquid tin can be prevented. Methane decomposition with carbon dioxide produced carbon monoxide and hydrogen. Ni was used to promote the catalyst performance and enhance the activity of the catalyst and lifetime. In this study, catalysts were synthesized using the excess wet impregnation method. The effect of the reaction temperature, space velocity was measured to calculate the activity of catalysts, such as the activation energy and regeneration of catalysts. The carbon-deposited tin catalyst regeneration temperature was 1023 K. The reactivity was improved using a nickel co-catalyst and a water supply.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.150-154
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• 2004

Gas explosion characteristics of hydrogen and liquefied petroleum gas(LPG) were measured in 6L cylindrical vessel, and experiment for explosion to fire transition phenomena of the gases were carried out using the 270L vessel. Explosion characteristics were measured using the stain type pressure transducer and explosion to fire transition phenomena was analyzed with the hish-speed camera. Base on the experiment, it was found that explosion pressure was most high slightly above the stoichiometric concentration, and explosion pressure rise rate and flame propagation velocity were proportional to the combustion velocity. And we find that those kind of explosion characteristics affect the explosion-to-fire transition, in addition, explosion flame temperature, flame residence time, are important parameters in explosion-to-fire transition.