• Title/Summary/Keyword: 전이부

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Developing efficient transition metal-based water splitting catalyst using rechargeable battery materials (배터리 소재를 이용한 전이금속 화합물 기반 물 분해 촉매 개발)

  • Kim, Hyunah;Kang, Kisuk
    • Ceramist
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    • v.21 no.4
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    • pp.416-426
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    • 2018
  • Water splitting is regarded as one of the most environmentally benign routes for hydrogen production. Nevertheless, the low energy efficiency to produce the hydrogen has been a critical bottleneck, which is attributable to the multi-electron and multi-step reactions during water splitting reaction. In this respect, the development of efficient, durable, and inexpensive catalysts that can promote the reaction is indispensable. Extensive searching for new catalysts has been carried out for past decades, identifying several promising catalysts. Recently, researchers have found that conventional battery materials; particularly high-voltage intercalation-based cathode materials, could exhibit remarkable performance in catalyzing the water splitting process. One of the unique capabilities in this class of materials is that the valency state of metals and the atomic arrangement of the structure can be easily tailored, based on simple intercalation chemistry. Moreover, taking advantage of the rich prior knowledge on the intercalation compounds can offer the unexplored path to identify new water splitting catalysts.

A Use of Expectation Maximization Clustering for Constructing a Markov Chain of Human Mobility Model (기대치 최대화 기반의 군집화를 통한 인간 이동 패턴의 마르코프 연쇄모델 도출)

  • Kim, Hyunuk;Song, Ha Yoon
    • Proceedings of the Korea Information Processing Society Conference
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    • 2012.04a
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    • pp.864-867
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    • 2012
  • 사람들이 휴대용 위치정보 수집 장비나 혹은 스마트폰을 사용하면서 사람의 이동 정보인 위치정보들을 모으는 일이 가능해 졌다. 이러한 위치정보들을 가지고 본 논문에서는 사람의 이동 모델을 나타내고자 하였다. 이동 정보들은 머물러 있는(Stay)상태와 이동하는(Moving) 상태로 나눌 수 있는데 이러한 상태 중 머물러 있는 상태가 군집화가 되어 연쇄 모델속의 하나의 상태(State)로 나타나 질 수 있다. 물론 이동 정보들을 통해 연쇄모델 속 각 상태간의 전이 확률 또한 계산 할 수 있다. 이러한 일련의 과정을 본 논문에서는 기대치 최대화 기반 군집화 과정을 통해 연속시간 연쇄 모델의 형태로 인간의 이동성을 표현하였다. 또한 이러한 모델에서 대표 군집(macro)과 그 부속 군집(micro)을 표현할 수 있었고 이러한 모습은 대표적인 큰 군집 속의 작은 군집의 형태로 나타나게 된다.

Development of Deep Learning-Based House-Tree-Person Test Analysis Model (딥러닝 기반 집-나무-사람 검사 분석 모델의 개발)

  • Cho, Seung-Je;Cho, Geon-Woo;Kim, Young-wook
    • Proceedings of the Korea Information Processing Society Conference
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    • 2021.11a
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    • pp.558-561
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    • 2021
  • 심리학에서 사람의 심리 상태를 알아보기 위해 사용되는 검사 방법 중, 집-나무-사람 검사(HTP Test)는 피실험자가 그린 집, 나무, 사람을 포함하는 그림을 사용하여 피실험자의 심리를 분석하는 투영 검사법이다. 본 논문에서는 딥러닝 모델을 이용해 HTP Test 에 사용되는 그림을 분석하는 시스템을 제안하며, 성능 평가를 통해 심리학에서의 딥러닝 모델 적용 가능성을 확인한다. 또한 그림 데이터 분석에 적합한 사전 훈련 모델을 개발하기 위해, ImageNet 과 스케치 데이터셋으로 사전 훈련하여 성능을 비교한다. 본 논문에서 제안하는 시스템은 크게 감정 분석을 위한 이미지 객체 추출부, 추출된 객체로 피실험자의 감정을 분류하는 감정 분류부로 구성되어 있다. 객체 추출과 이미지 분류 모두 CNN(Convolution Neural Network) 기반의 딥러닝 모델을 사용하며, 이미지 분류 모델은 서로 다른 데이터셋으로 모델을 사전 훈련한 후, 훈련 데이터셋으로 전이 학습하여 모델의 성능을 비교한다. 그림 심리 분석을 위한 HTP test 스케치 데이터셋은, HTP Test 와 동일하게 피실험자가 3 개 클래스의 집, 나무, 사람의 그림을 그려 자체 수집하였다.

Detection for Residual Thyroid Tissue and Metastatic Lesion after Total Thyroidectomy in Patients with Differentiated Thyroid Cancer: Comparison between Tc-99m Pertechnetate Sean and High Dose I-131 Therapy Sean (분화 갑상선암 환자의 수술후 잔여갑상선조직 및 전이병소의 진단: Tc-99m Pertechnetate 스캔과 고용량 옥소 치료 후 I-131 스캔의 비교)

  • Lee, Joo-Ryung;Ahn, Byeong-Cheol;Jeong, Shin-Young;Lee, Jae-Tae;Lee, Kyu-Bo
    • The Korean Journal of Nuclear Medicine
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    • v.37 no.2
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    • pp.120-127
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    • 2003
  • Purpose: To evaluate diagnostic sensitivity of nuclear imaging in the detection of residual thyroid tissue and metastatic lesion, we have compared neck scintigrams with Tc-99m pertechnetate (Tc-99m scan) and high dose I-131 iodide (I-131 scan) in patients with differentiated thyroid cancer. Subjects and Methods: One hundred thirty-five thyroidectomized patients for differentiated thyroid cancer were enrolled in this study. Twenty-three had a previous history of radioiodine therapy. Planar and pin-hole images of anterior neck with Tc-99m were acquired at 20 minutes after injection, followed by I-131 scan three days after high-dose radioiodine therapy within 7 days interval. Patients were asked to discontinue thyroid hormone replacement more than 4 weeks. Results: All subjects were in hypothyroid state. Seventy out of 135 patients (51.9%) showed concordant findings between Tc-99m and I-131 scans. I-131 scan showed higher number of uptake foci in all of 65 patients showing discordant finding. Tc-99m scan showed no thyroid bed uptake in 34 patients, whereas 23 of them (67.6%) showed bed uptake in I-131 scan. Tc-99m scan did not show any uptake in thyroid bed in 11 of 112 patients without previous history of radioiodine therapy, but 9 of them showed bed uptake in I-131 scan. Tc-99m scan showed no bed uptake in all of the 23 patients with previous history of radioiodine therapy, in contrast 14 of them (60.9%) showed bed uptake in I-131 scan. Conclusion: These results suggest that Tc-99m scan has poor detectability for residual thyroid tissue or metastatic lesion in thyroidectomized differentiated thyroid cancer patients, compared to high dose I-131 therapy scan. Tc-99m scan could not detect any remnant tissue or metastatic lesion in patients with previous history of radioiodine treatment, especially.

Mesenchymal Chondrosarcoma of the Calcaneous (종골에 발생한 간엽성 연골육종 - 1예 보고 -)

  • Sung, Ki-Sun;Son, Jeong-Gyeong;Cho, Eun-Yoon
    • The Journal of the Korean bone and joint tumor society
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    • v.11 no.2
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    • pp.219-223
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    • 2005
  • Mesenchymal chondrosarcoma is very rare and mostly occurs in lower extremity, especially femur, head and face, and pelvis in order. An eleven-year old male patient suffered from left heel pain for several months and underwent biopsy at another hospital. A Malignant bone tumor was suspected, so the patient was transferred to our hospital. We reviewed the outside pathologic slide, which revealed the diagnosis of mesenchymal chondrosarcoma. It was treated by a below knee amputation. Three months later, a chest computed tomography (CT) revealed multiple metastatic nodules in both lungs. All metastatic nodules were surgically excised and the patient received postoperative chemotherapy. As far as our knowledge, mesenchymal chondrosarcoma in the calcaneus is the first case in the world. Thus, we report a case of mesenchymal chondrosarcoma in the calcaneus with thorough review of documents.

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Synchronous Monomelic Juxta-articular Multicentric Chondrosarcoma -A Case Report- (동시성 단지성 관절 근접 다발성 연골 육종 -증례 보고-)

  • Oh, Joo-Han;Kim, Jae-Yoon;Gong, Hyun-Sik;Kim, Woo-Sung;Kim, Tae-Yune
    • The Journal of the Korean bone and joint tumor society
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    • v.12 no.1
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    • pp.71-77
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    • 2006
  • Chondrosarcoma is one of the most common types of primary bone sarcoma. With the exception of the mesenchymal subtype, chondrosarcomas are usually low-grade lesions and rarely show multicentricity or distant metastasis. Only rare cases of multicentric chondrosarcomas have been reported in association with Ollier's disease and Maffucci's syndrome. To our knowledge, no report has been issued of a synchronous multicentric chondrosarcoma occurrence across a joint. We experienced a 30-year-old man with a synchronous monomelic juxta-articular multicentric chondrosarcoma across a shoulder joint in the absence of pulmonary and visceral metastases. He was treated by curettage and cement filling with allograft in the acromion and wedge resection with cement filling in the proximal humerus. At the 18-month follow-up, there was no evidence of recurrence, and the patient had full range of motion without pain.

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The Basalts and Volcanic Process in the Seondol Cinder Cone, Seobjikoji Area, Jeju Island (제주도 섭지코지 선돌 분석구의 화산작용과 현무암)

  • Koh, Jeong-Seon;Yun, Sung-Hyo;Kim, Suck-Youn
    • Journal of the Korean earth science society
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    • v.28 no.4
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    • pp.462-477
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    • 2007
  • The purpose of this study is to determine the petrology of basalt and the volcanic process in the Seondol cinder cone, Seobjikoji area, eastern Jeju Island. The Seondol cinder cone is mainly composed of spatters in the lower part, pyroclastic deposits including reddish brown blocks, ashes with volcanic bombs in the middle part, and dark black scoria deposits in the upper part. The volcanic sequences suggest volcanic processes that progress through Strombolian eruption and end with Hawaiian lava effusion which breached the cinder cone northwestward and extended over northwestward as lava delta and basalt emplaced as a volcanic neck in the central part of crater in the cinder cone. The age of basalt lava flows is about $95\;{\pm}\;3\;ka$. The basalts belong to transitional basalt and show products of fractional crystallization of clinopyroxene and olivine from a parental basalt magma on the basis of variation diagram of major, trace and rare earth elements. Basalts in the region of this study are plotted at the region of within plate basalt.

Dynamic Capacity Concept and its Determination for Managing Congested Flow (혼잡교통류 관리를 위한 동적 용량의 개념 및 산정방법)

  • Park, Eun-Mi
    • Journal of Korean Society of Transportation
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    • v.22 no.3 s.74
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    • pp.159-166
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    • 2004
  • The capacity concept presented in the Highway Capacity Manual is for steady-state traffic flow assuming that there is no restriction in downstream flowing, which is traditionally used for planning, design, and operational analyses. In the congested traffic condition, the control objective should be to keep the congested regime from growing and to recover the normal traffic condition as soon as possible. In this control case, it is important to predict the spatial-temporal pattern of congestion evolution or dissipation and to estimate the throughput reduction according to the spatial-temporal pattern. In this context, the new concept of dynamic capacity for managing congested traffic is developed in terms of spatial-temporal evolution of downstream traffic congestion and in view of the 'input' concept assuming that flow is restricted by downstream condition rather than the 'output' concept assuming that there is no restriction in downstream flowing (e.g. the mean queue discharge flow rate). This new capacity is defined as the Maximum Sustainable Throughput that is determined based on the spatial-temporal evolution pattern of downstream congestion. And the spatial-temporal evolution pattern is estimated using the Newell's simplified q-k model.

Geochemistry and Petrogenesis of the Badwater Greenstones from Crystal Falls Terrane in Northeastern Wisconsin, U.S.A. (위스콘신주 북동부 지역에 분포하는 Badwater녹암에 대한 지화학적 연구)

  • Wee, Soo-Meen
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.281-291
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    • 1996
  • Samples of Badwater greenstones from the Crystal Falls terrane in northeastern Wisconsin have been analyzed for major, trace and rare earth elements. Geochemical characteristics of the rocks provide clues to the petrologic character and paleotectonic environment of basaltic magma generation. They have chemical composition typical of continental tholeiites. The low Mg values and abundances of Ni and Cr indicate that the lavas were extensively fractionated prior to extrusion. The variations of incompatible elements suggest that the rocks were affected by interaction with crustal rocks. The samples least affected by contamination have trace element compositions similar to those of T-type mid-ocean ridge basalts. The parent was modified by crustal contamination process and this process shifted the rock compositions to that of continental tholeiites as the rock evolved. Interpretations of the chemical characteristics of the rocks, based on modem analogs, favor their emplacement in an extensional tectonic regime.

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A Study on the Negative Effects of Task Conflict and the Importance of Trust in Peers and Team Orientation (과업갈등의 부정적 효과와 신뢰가 팀 지향성의 중요성에 관한 연구)

  • Kim, Young-Hyoung
    • Journal of Digital Convergence
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    • v.18 no.3
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    • pp.123-131
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    • 2020
  • The purpose of this study was to investigate the effect of task conflict on relationship conflict and the effect of relationship conflict on team satisfaction and to examine the moderating role of trust in peers in the relationship between task conflict and relationship conflict and the moderating role of team orientation in the relationship between relationship conflict and team satisfaction. The major findings were as follows: First, it was found that task conflict had a positive effect on relationship conflict and relationship conflict had a negative effect on team satisfaction. Second, it was found that trust in peers moderated the relationship between task conflict and relationship conflict. Third, it was also found that team orientation moderated the relationship between relationship conflict and team satisfaction. Based on the findings, practical implications and suggestions for future studies were provided.