• Economic and Environmental Geology
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• v.36 no.4
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• pp.285-293
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• 2003

Tailings of Dukum mine in the vadose and saturated zone were investigated to reveal the mobility of metal elements and the condition of mineralogical solubility according to redox environments throughout the geochemical analysis, thermodynamic modelling, and mineralogical study for solid-samples and water samples(vadose zone; distilled water: tailings=5 : 1 reacted, saturated zone; pore-water extracted). In the vadose zone, sulfide oxidation has generated low-pH(2.72∼6.91) condition and high concentration levels of S $O_4$$^{2-}$(561∼1430mg/L) and other metals(Zn : 0.12∼l57 mg/L, Pb : 0.06∼0.83 mg/L, Cd : 0.06∼l.35 mg/L). Jarosite$(KFe_3(SO_4)_2(OH)_6)$ and gypsum$(CaSO_4{\cdot}2H_2O$) were identified on XRD patterns and thermodynamics modelling. In the saturated zone, concentration of metal ions decreased because pH values were neutral(7.25∼8.10). But Fe and Mn susceptible to redox potential increased by low-pe values(7.40∼3.40) as the depth increased. Rhodochrosite$(MnCO_3)$ identified by XRD and thermodynamics modelling suggested that $Mn^{4+}$ or $Mn^{3+}$ was reduced to $Mn^{2+}$. Along pH conditions, concentrations of dissolved metal ions has been most abundant in vadose zone throughout borehole samples. It was observed that pH had more effect on metal solubilities than redox potential. How-ever, the release of co-precipitated heavy metals following the dissolution of Fe-Mn oxyhydroxides could be the mechanism by which reduced condition affected heavy metal solubility considering the decrease of pe as depth increased in tile saturated zone.

• The Journal of the Acoustical Society of Korea
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• v.23 no.1
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• pp.47-53
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• 2004

We propose a new speech enhancement algorithm based on left-right Hidden Markov Model (HMM) with state decision using Log-likelihood Ratio Test (LRT). Since the conventional HMM-based speech enhancement methods try to improve speech quality for all states, they introduce huge computational loads inappropriate to real-time implementation. In the left-right HMM, only the current and the next state are considered for a possible state transition so to reduce the computational complexity. In this paper, we propose a method to decide the current state by using the LRT on the previous state. Experimental results show that the proposed method improves the speed up to 60% with 0.2∼0.4 dB degradation of speech quality compared to the conventional method.

• Journal of the Korean Chemical Society
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• v.43 no.2
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• pp.161-166
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• 1999

Transfer of lanthanide ions across the liquid/liquid interface facilitated by ionopore ETH4120 has been studied by using cyclic voltammetry (CV) and chronopotentiometry with cyclic linear current-scanning (CPCLCS) under the condition where the concentration of ETH4120 in nitrobenzene was much smaller than the concentration of lanthanide ions in aqueous solution. One cathodic current peak (transfer from aqueous to nitrobenzene phase) and two anodic current waves (transfer from nitrobenzene to aqueous phase) were observed. The cathodic wave was due to the formation of 1:1 (metal:ligand) complex and two anodic waves showed successive formation of 1:2 and 1:3 complexes in nitrobenzene solution. But there was no cathodic wave corresponding to two anodic waves. The ion transfer mechanism has also been discussed.

• The Journal of Engineering Geology
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• v.18 no.1
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• pp.7-16
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• 2008

Limestone area have mostly certain geological defects such as the internal cavities due to melting and fractured zone by external pressures. Especially, in case of constructing grand bridge, the treatment of the limestone cavities area having the geological defects is inevitable. In order to reduce foundation settlement and to reinforce the ground in the limestone cavities area, high pressure jet grouting has been carried out as a countermeasure method. Despite the fact that high pressure jet grouting method has already adopted at a lot of limestone cavities area, but the amount of research and technical data on the high pressure jet grouting have not been accumulated properly so for. Therefore this paper intends to investigate the strength characteristics and deformation characteristics for reinforced limestone cavities area by high pressure jet grouting method. In addition, load carrying capacity obtained by static pile load test with load transfer measuring system is analyzed.

• Korean Journal of Applied Biomechanics
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• v.18 no.4
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• pp.179-189
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• 2008

The purpose of this study was to investigate interjoint and intersegmental coordination of lower segments in skill process. For the investigation, we examined the difference of resultant linear velocity of segments and angle vs angle graph. Novice subjects were 9 male middle school students who have never been experienced a taekwondo. We analyzed kinematic variables of Side Kick motion through videographical analysis. The conclusions were as follows. 1. Examining the graph of novice subjects' maximal resultant linear velocity of the thigh, shank, and foot segment, as it gets closer to the end of the training, the maximal resultant linear velocity in each segment increases which can be assumed to be a result of the effective momentum transfer between adjacent segments. 2 This research showed a sequential transfer from trunk, to thigh, and then to shank as it gets closer to the end of learning at intersegment angular velocity, and it also showed pattern of throwlike motion and pushlike motion. 3. In three dimension of flexion-extension, adduction-abduction and internal-external rotation of the thigh and shank segment, the angle-angle diagram of knee joint and of hip joint showed that dynamic change was indicated at the beginning of learning but stable coordination pattern was indicated like skilled subject as novice subjects became skilled.

• Geophysics and Geophysical Exploration
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• v.20 no.1
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• pp.18-24
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• 2017

We performed seismic imaging based on relative S-wave travel times to examine S-wave velocity of upper mantle structure beneath East Asia. We used teleseismic events recorded at 129 broadband stations of the Korea Institute of Geoscience and Mineral Resources (KIGAM), Korea Meteorological Administration (KMA), and National Research Institute for Earth Science and Disaster Prevention (NIED). Relative travel time residuals were obtained by a multi-channel cross-correlation method designed to automatically determine accurate relative phase arrival times. The resulting images show high-velocity anomalies along plate boundaries around the Japanese islands region. These anomalies may indicate subducting Pacific and Philippine Sea plates. On the other hand, a low-velocity anomaly is revealed beneath east of the Korean peninsula down to around 300 km depth, which is thought to be related to the formation of the Ulleung basin and the Ulleung island. Low-velocity anomalies revealed beneath the Jeju island may imply that the formation and volcanism of the Jeju island have been caused by magmatic sources from the deep mantle.

• Ocean and Polar Research
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• v.35 no.4
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• pp.415-425
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• 2013

In order to understand phytoplankton and bacterial distribution in tropical coral reef ecosystems in relation to the mangrove community, their biomass and activities were measured in the sea waters of the Chuuk and the Kosrae lagoons located in Micronesia. Chlorophyll a and bacterial abundance showed maximal values in the seawater near the mangrove forests, and then steeply decreased as the distance increased from the mangrove forests, indicating that environmental conditions for these microorganisms changed greatly in lagoon waters. Together with chlorophyll a, abundance of Synechococcus and phototrophic picoeukaryotes and a variety of indicator pigments for dinoflagellates, diatoms, green algae and cryptophytes also showed similar spatial distribution patterns, suggesting that phytoplankton assemblages respond to the environmental gradient by changing community compositions. In addition, primary production and bacterial production were also highest in the bay surrounded by mangrove forest and lowest outside of the lagoon. These results suggest that mangrove waters play an important role in energy production and nutrient cycling in tropical coasts, undoubtedly receiving large inputs of organic matter from shore vegetation such as mangroves. However, the steep decrease of biomass and production of phytoplankton and heterotrophic bacteria within a short distance from the bay to the level of oligotrophic waters indicates that the effect of mangrove waters does not extend far away.

• Economic and Environmental Geology
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• v.28 no.4
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• pp.327-335
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• 1995

Illite/smectite (I/S) in the Beaufort-Mackenzie Basin, Arctic Canada has been scrutinized on the basis of mineralogical analysis of 215 core and drill-cutting samples from 22 exploratory wells onshore and offshore. I/S in the Beaufort-Mackenzie Basin includes the following four types: random, a mixture of random and ordered, R1-ordered, and R>1-ordered I/S. A mixture of random and ordered I/S occurs in the transitional interval between random and R>1-ordered I/S, and may represent a metastable state in the ordering reaction. A widespread occurrence of the mixture in natural environments suggests that the ordering reaction may be a slow process that results in co-existence of reactants and products. K-saturation experiments show that layer charges of expandable layers in I/S are variable. High-charge expandable layers transform into illite-like layers upon simple K-saturation. K-saturation alters the composition and/or the degree of ordering in I/S, suggesting that illitization in nature can be transformational.

• KSBB Journal
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• v.22 no.4
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• pp.222-227
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• 2007

Biodiesel (fatty acid methyl esters) have used to as substitutes for petro-diesel by mixed-form with petro-diesel. In several processes of biodiesel production, alkali-catalyst transesterification produced to biodiesel of high contents with short reaction time. In this study, we investigate the optimal condition of alkali-catalyst transesterification of rapeseed oil produced at Jeju island in Korea using response surface methodology. The optimal condition of biodiesel production is reaction temperature 59.7$^{\circ}C$, catalyst amount 1.18%, oil to methanol molar ratio 1:8.75, and reaction time 5.18 min. At that reaction condition, the fatty acid methyl ester contents of product are above 97%. Our results may provide useful information with regard to the development of more economic and efficient biodiesel production system.

• Journal of the Korean Chemical Society
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• v.38 no.2
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• pp.160-168
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• 1994

Pentadentate Schiff base molybdenum(Ⅴ) complexes such as [Mo(Ⅴ)O(Sal-DET)(NCS)] and [Mo(Ⅴ)O(Sal-DPT)(NCS)] were synthesized by Sabat method. The structure of these complexes were identified by elemental analysis, spectroscopy, and thermogravimetric analysis(T.G.A.). It was found that the mole ratio of Schiff base ligand to the complexes was found to be 1 : 1. The redox processes of the complexes were investigated by cyclic voltammetric and differential pulse polarographic technique in nonaqueous solvent containing 0. 1 M tetraethyl ammonium perchlorate(TEAP) as supporting electrolyte at glassy carbon electrode. It was found that diffusion controlled reduction processes of four steps with one electron were 2Mo(Ⅴ)$\rightleftarrow^{e-}$ Mo(Ⅴ)Mo(Ⅳ) $\longrightarrow^{e-}$ 2Mo(Ⅳ), Mo(Ⅳ) $\longrightarrow^{e-}$ Mo(Ⅲ) $\longrightarrow^{e-}$ Mo(Ⅱ)