• Applied Chemistry for Engineering
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• v.32 no.4
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• pp.461-466
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• 2021

In this article, a portable and cost-effective voltammetric biosensor with nanoparticles was developed for the measurements of heterogeneous nuclear ribonucleoprotein A1 protein (hnRNP A1) biomarker which can potentially be used for lung cancer diagnosis. Gold nanoparticles were first electrodeposited onto screen printed carbon electrode (SPCE) followed by immobilizing a single stranded DNA aptamer specific to hnRNP A1 onto the electrode surface. Ethanolamine was also used when immobilizing DNA aptamer on the surface to prevent signals from non-specific adsorption events. Sequential injection of hnRNP A1 biomarker and anti-hnRNP A1 conjugated with alkaline phosphatase (ALP) onto the aptamer chip surface allows to form the sandwich complex of DNA aptamer/hnRNP A1/ALP-anti-hnRNP A1 on the electrode surface which further reacted with 4-aminophenyl phosphate (APP). The electrocatalytic reaction of the enzyme, ALP, and the substrate, APP, resulting in the oxidative current response changes at -0.05 and -0.17 V (vs. Ag/AgCl) against the hnRNP A1 concentration was measured using cyclic and differential pulse voltammetry, respectively. The Au nanoparticles-integrated voltammetric biosensor was applied to analyze human normal serum solutions possibly suggesting potential applicability for lung cancer diagnosis.

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.933-937
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• 2012

In the present study, we evaluate the sensitivity and optimal stripping voltammetry (SV) conditions of copper (Cu), which is one of the main trace heavy metals inducing the environmental contamination, using carbon nanotube (CNT) electrode. In addition, the reaction mechanism of stripping reaction of Cu is investigated. The electrochemical analyses such as squarewave stripping voltammetry (SWSV) and linear scan voltammetry (LSV) are used for the evaluations. As a result of that, the best SWSV conditions like squarewave amplitude of 15 mV, frequency of 60 Hz, deposition potential of -1.0V vs. Ag/AgCl and deposition time of 200s are determined with the measured Cu sensitivity of $1.824{\mu}A/{\mu}M$. As a driving force affecting the stripping reaction of Cu, surface reaction is more dominant one than diffusion. These results are compared with other reference results and it is confirmed that our suggested CNT electrode gives rise to better Cu sensitivity result than other references.

• 한국전기화학회:학술대회논문집
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• 2002.10a
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• pp.45-45
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• 2002

• 한국전기화학회:학술대회논문집
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• 1999.10a
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• pp.23-23
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• 1999

• 한국전기화학회:학술대회논문집
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• 1998.10a
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• pp.25-25
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• 1998

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.353-355
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• 2007

피접지체의 접지는 전력설비의 절연파괴,낙뢰 등으로 전압이 침입할 경우 접지전극의 접지저항이 높으면 접지전극으로 유입되는 전류와 접지저항의 곱에 해당하는 접지전극의 전위가 상승하게 되므로 설비의 파손 인축의 피해 등이 발생 할 수 있다. 따라서 접지저항은 낮은 값으로 유지하는것이 필요하고 정기적으로 측정하여 관리하도록 규정하고 있다. 대표적인 접지저항측정방법으로는 3전극법(Fall of potential method)과 Hook-on 측정법이 있다. 그러나 3전극법은 측정하고자 하는 접지전극으로부터 일정한 거리에 전류를 흘려주고 이때 대지 전위를 측정 할 수 있는 2개의 보조전극 설치가 필수적이나 접지극과 접지선의 단자와는 설치 위치가 다르므로 접지전극의 설치점을 확인하기 곤란하고 건물내부, 지하철, 터널 등에는 보조전극의 설치가 거의 불가능하므로 처음 설치한 접지극의 접지저항측정관리에 어려움이 크다. 또한 Hook-on 측정법은 다중 접지 계통에 사용하는 방법으로 접지극이 수십 또는 수백개를 병렬로 연결한 경우 측정하고저 하는 접지그의 접지저항값에 비해 나머지 접지전극 전체의 합성저항이 무시할 수 있을 만큼 적은 경우에만 측정할 수 있으므로 건물이나 변전실 등 수개의 접지극이 설치된 경우는 사용할 수 없다. 본 연구는 보조전극을 설치하지 않고 측정하고자하는 접지전극 상호간의 전류분배 비율을 저항의 역수 비율로 하여 각각의 접지 전극의 접지저항값을 운전 중인 상태에서 간단하고 정확하게 측정할 수 있는 새로운 접지저항 측정 방법에 관한 연구이다.

• 전기의세계
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• v.14 no.3
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• pp.37-40
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• 1965

전기기구의 절연성을 향상시킨다는 것은 품질이나 수명을 향상시키는것과 똑같은 의의를 갖는 것이며, 따라서 기기의 수명은 절연성에 있다해도 과언이 아니다. 절연내력을 높이기 위해서는 질량의 절연재료와 고도의 절연가공기술 및 절연구조의 개량등의 요건을 필요로 하나 건조 처리기술에 의하여도 상당히 전기특성을 회복시킬수 있다. 주지의 사항과 같이 건조 처리법에는 열풍건조법, 열유(분무 및 순환) 건조법증기건조법, 전류건조(냉상전류법 및 단락순환건조법)법, 등등에 진공건조를 병용한 처리법이 있으며 어떤나라의 전력계통에서도 계통의 감시 또는 정기보수시 전력용 변압기를 건조(현지)해야 되는 작업은 기기 maker에서 공장건조해야 되는것과 똑같이 거쳐야 하는 공정중의 하나인 것이다. 여기서 언급코져 하는 변압기 tank 유도가열법은 본인이 일본 삼릉전기에서 연수중 조사한 바 있는것으로서 소련, 일본등지에서는 벌써부터 타 건조처리법과 병용해서 척용하고 있으며, 보유하고 있는 건조실의 size가 적을때나 또는 수송 제한조건때문에 현지 조립을 요하는 지역에서는 편리한 처리법의 하나라 할 수 있다. 이하 그 설계 계산법과 설계예를 간략한다.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.421-428
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• 2012

We investigated an electrochemical properties for Langmuir-Blodgett (LB) nano-films of polyimide and phospholipid mixture. LB films of polyamic acid and phospholipid monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in $KClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100, 150, 200 and 250 mV/s, respectively. As a result, monolayer LB films of polyamic acid and phospholipid mixture was appeared on irreversible process caused by the reduction current from the cyclic voltammogram. Diffusion coefficient (D) effect in the polyamic acid and phospholipid mixture was used in the LAPC with LLPC fewer than the diffusion coefficient values.

• Journal of the Korean Applied Science and Technology
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• v.29 no.2
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• pp.311-316
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• 2012

We are investigated to an electrochemical characteristic for Langmuir-Blodgett (LB) films by cyclic voltammetry method. The phospholipid compound was deposited by using the LB method on the Indium tin oxide(ITO) glass. We tried to measure the electrochemical by using cyclic voltammetry with three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential -1350 mV, continuously oxidized to 1650 mV. As a result, LB films of the phospholipid compounds are appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of phospholipid compound amount.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.208-215
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• 2006

A simply prepared graphite, pencil-type working electrode was utilized to monitor fenitrothion concentrations, using the cyclic voltammetry (CV) and square-wave (SW) stripping voltammetry methods. The optimum conditions for analysis were sought. A very low detection limit was obtained compared to that obtained when other common voltammetry methods are used. The optimal parameters of the pencil-type electrode were found to be as follows: a pH of 3.7, a frequency of 500 Hz, an SW amplitude of 0.1 V, an increment potential of 0.005 V, an initial potential of -0.9V, and a deposition time of 500 sec. The analytical detection limit was determined to be 6.0 ngL-1 (2.16410-11 molL-1) fenitrothion at SW anodic and CV, and the relative standard deviation at the fenitrothion concentration of SW anodic 10 ugL-1 was 0.30% (n = 15) under the optimum conditions. Analysis was directly conducted through in-vivo real-time assay.