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Characteristic of Partial Oxidation of Methane and Ni Catalyst Reforming using GlidArc Plasma (GlidArc 플라즈마를 이용한 메탄 부분산화 및 Ni 촉매 개질 특성)

  • Kim, Seong-Cheon;Chun, Young-Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1268-1272
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    • 2008
  • Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

The Study on the Separation Characteristics of ion with ion Exchange Membrane - I.The Characteristics of ion Exchange Membrane with the Separator of All-Vanadium Redox Flow Battery - (이온교환막을 이용한 이온의 분리특성에 관한 연구 - I. 전바나듐계 레독스-흐름 전지의 격막용 이온 교환막의 특성 -)

  • Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.393-402
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    • 1993
  • Redox flow secondary battery have been studied actively as one of the most promising electrochemical energy storage devices for a wide range of applications, such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants. In all-vanadium redox flow battery using solution of vanadium-sulfuric acid as a active material, the difficulty in developing an efficient ion selective membrane can still be identified. The asymmetric cation exchange membrane(M-30) as a separator of all-vanadium redox flow battery which were obtained by the reaction of chlorosulfonation for 30 minutes under the irradiation of UV, showed its superiority in the transport number of 0.94 and electrical resistivity of $0.5{\Omega}{\cdot}cm^2$. The base membrane were prepared by lamination a low density polyethlene film of $10{\mu}m$ thickness on polyolefin membrane(HIPORE 120). The electrical resistivity of M-30 membrane in real solution of vanadium-sulfuric acid was $3.79{\Omega}{\cdot}cm^2$ and it was similar to that of Nafion 117 membrane. Also the cell resistivity was $6.6{\Omega}{\cdot}cm^2$and lower than that of Nafion 117. In considertion of electrochemical properties and costs of membranes, M-30 membrane was better than that of Nafion 117 and CMV of Asahi glass Co. as a separator of all-vanadium redox flow battery.

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An Analysis of Application Performance of Defense R&D Technologies Acquired by Offset Programs (절충교역을 통해 획득한 연구개발 기술의 활용성과 분석)

  • Hong, Seoksoo;Seo, Jaehyun;Shim, Sang-Ryul
    • Journal of Technology Innovation
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    • v.22 no.2
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    • pp.1-30
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    • 2014
  • Offset trade has been applied in Republic of Korea's defense acquisition programs since early 1980s and used for national economic development as well as enhancement of military capabilities. The accumulated offset trade value amounts to over 10 billion dollars by 2010. However, questions in regards to the effectiveness of offset trade have been constantly raised. As it is a quite difficult task to analyze and calculate the application performance of defense technologies acquired by offsets objectively, limited level of quantitative analysis of application performance have been conducted so far. Hence, in this paper, we came to understand the overall status of application of those technologies through in-depth performance analysis and suggested some specific policies for the further development of offset trade based on the analysis results. To begin with, we developed a questionnaire based on performance indicator deducted through literature review of relevant researches, and conducted survey of major offset recipients. Also, another survey of offset experts belonged to the army, government organization, research institute and companies was conducted to evaluate the performance and effectiveness of offsets qualitatively. And we analyzed the efficiency of application performance using DEA. The results of all surveys are showing that there is positive accomplishment in the technological aspect, but in economic aspect, it shows relatively inactive outcome. Based on these results, policy direction is considered to be changed from the emphasis on the acquisition of core technology to revitalization of domestic defense industry in line with new government's policy orientation.

Research for refining processes to produce high-purity polycrystalline silicon from domestic quartzite mine (국내 규석광으로부터 고순도 실리콘 제조를 위한 정련 공정에 관한 연구)

  • Moon, Byung Moon;Kim, Gangjune;Koo, Hyun Jin;Park, Dong Ho;Yu, Tae U
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.48-48
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    • 2011
  • 2010년 약 19.5 GWp 의 규모로 성장한 태양광 시장의 주요 소재는 실리콘을 이용한 태양전지이며, 고성능 및 고효율 태양전지 시장이 급성장 하였다. 이러한 고품질 태양전지에 사용되는 주요 원료인 9N 급 폴리실리콘은 2008년 4월 $265/kg 까지 상승하였으나, 점차 하향안정세에 있으며, 급속한 가격 경쟁을 통해 당분간 장기공급가가 50$/kg 이하로 하락할 것으로 전망된다. 이러한 실리콘 제조기술 중 가장 많이 사용되는 기술은 Trichloro-silane (TCS) 또는 Mono-silane (MS)를 사용하는 기상법인 일명 Siemens 공정이다. 이러한 기상법의 경우 12N 이상의 초고품질 실리콘 제조가 가능하나, 대규모의 설비투자(1억원/폴리실리콘 1톤)와 높은 에너지(120 kWh/kg)가 요구된다. 이에 최근 기상법이 아닌 야금학적인 정련법에 대한 기술이 개발되고 있으며, 이는 금속 실리콘을 슬래그 처리, 편석 분리, 응고 급랭, 전자빔, 플라즈마 등을 이용하여 정련하는 공정을 말한다. 야금학적 정련법은 순도 면에서 기상법에 비하여 낮은 단점이 있음에도 불구하고, 여러 장점들로 인해 활발히 연구되며 점차 실용화 되고 있는 매우 유용한 기술이다. 야금학적 정련법의 주요 장점은 기상법에 비해 약 25% 정도의 설비 투자비로 가능하고, 금속 실리콘을 직접 사용하며, 에너지 payback이 짧다. 또한, 산 및 염화실렌을 사용하지 않으므로 환경 문제를 적게 야기하고, 생산설비의 확장성도 매우 높다. 본 연구에서는 국내 규석광을 이용하여 일련의 정련 공정을 거쳐 고순도SG(Solar Grade)급 실리콘을 제조하고자 하였다. 실리콘 용융 환원로를 개발하고 순도를 높이기 위해 슬래그정련법을 이용하였으며, 생산된 3N 급의 금속 실리콘을 비기상법정련 방식인 일방향 응고와 플라즈마 정련 및 전자기유도 용해법을 이용하여 고순도의 실리콘을 제조하였다. 본 연구에서는 상업생산을 개시한 외국의 E사와 비교하여 산침출공정을 거치지 않으므로 실리콘회수율 및 환경부하 절감의 장점을 갖고 있으며 최종 순도 실리콘 6N 이상, 보론 함유량 0.2 ppm 이하를 달성하였으며, 기존 기상법 대비 약 20%의 전력 감소와 약 13%의 금속실리콘 원료 절감 효과가 있었다. 저가/고순도 SG급실리콘의 제조기술 개발은 향후 세계 태양광 시장에 대한 경쟁력을 확보하고, 시장 점유율 상승에 기여할 수 있으며, 산업 확대를 통한 주변 산업으로의 파급 효과가 매우 클 것으로 예상된다.

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Optimization Technique for Estimation of Potential Hydroelectric Energy at Existion Ahricultural Reservoir (최적화기법을 이용한 기존 농업용 저수지에서의 부존 수력발전량 추정)

  • An, Tae-Jin;Ryu, Hui-Jeong;Park, Jeong-Eung
    • Journal of Korea Water Resources Association
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    • v.32 no.3
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    • pp.281-289
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    • 1999
  • Small-scale hydropower projects at existing agricultural reservoirs can contribute to produce electric energy by maximizing the use of releases from the reservoirs. The irrigation water duration, the reservoir hydropower simulation, and the nonlinear programming model are employed to estimate potential hydroelectric energy at an existing reservoir. The nonlinear programming model consists of finding a maximum hydroelectric energy subject to irrigation water demand constraints. The sample reservoir given a set of inflow and irrigation water is considered. The optimal solutions by the optimization model yield the most hydroelectric energy for the analysis period in the three methods. Consequently, the nonlinear programming model uses the most water for hydropower generation with respect to the total inflow of the sample reservoir. It is also found that additional storage by increasing the normal water level of the sample reservoir does not significantly increase the annual hydroelectric energy for the given reservoir. It is expected that the optimization model and the proposed procedure for estimating potential hydroelectric energy can be applied to evaluate feasibility analysis for small scale hydropower additions at existing agricultural dams.

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Development of vegetation model for Restoration of Degraded stream Landscape (훼손된 하천 경관을 복원하기 위한 식생 복원 모델 개발)

  • Lee, Chang-Seok;Cho, Yong-Chan;Oh, Woo-Seok;Park, Sung-Ae;Seol, Eun-Sil
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1145-1148
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    • 2007
  • 한국을 비롯하여 논농사 중심지역에서는 하천 주변이 과거에는 농경지로, 그리고 오늘날은 도시지역으로 개발되어 하천의 원형이 거의 유지되지 못하고 있다. 하천은 수역과 수변으로부터 거리에 따라 여러 개의 이질적 생태적 공간이 이어지는 복합생태계로서 하나의 경관으로 볼 수 있다. 하천이 하나의 온전한 생태적 계로서 기능을 발휘하기 위해서는 이들을 모두 포함하는 하천의 원형이 복원되어야 한다. 현존하는 하천복원사업이 수변 구역의 복원에 초점을 맞추고 있지만, 진정한 복원이 이루어지기 위해서는 온전한 강변 식생의 복원이 선결과제이다. 본 연구에서는 유적군락의 형태로 잔존하는 강변 식생을 조사하여 식생복원 모델로 삼고자 한다. 수위와 침수체제에 의해 하천의 횡단구조를 수변, 홍수터 및 제방으로 구분한 후 각 지소의 적합한 식생단위를 구분하여 생태적 복원을 실현하기 위한 정보를 구축하였다. 수변식생으로는 달뿌리풀군락과 갈대군락이 자주 출현하고, 홍수터에는 갯버들군락과 키버들군락이 우세하였다. 그 중 전자의 식물군락은 하상재료가 거친 입자의 지소에 성립하고, 후자의 것은 미세한 입자의 지소에 성립하는 경향이었다. 제방역에는 버드나무군락, 다릅나무군락, 귀룽나무군락, 물푸레나무군락, 산사나무군락, 신나무군락(한탄강 지류), 참느릅나무군락, 물푸레나무-갈참나무군락(한탄강 본류), 오리나무군락(민통선 북방지역), 소나무군락, 황철나무군락, 느릅나무군락(소양강 상류), 왕버들군락(금강 중류) 등이 성립하였다. 이러한 식생정보를 하천의 지리적인 위치에 따라 구분하였고, 생태적 복원 시 도입식물을 결정하기 위한 자료로 삼기 위해 각 식생단위를 이루는 종 조성을 정보 체계화하였다.을 효율적으로 하기 위하여 Solar Unit으로부터 나오는 전기를 중전기에서 밧데리로 축전을 시키고 완전 충전 후에는 나머지 전기는 방전이 되도록 회로를 구성하였다. 사통수문 자원조사 결과에 의하면 현재 저수지에 물공급을 하는 수문은 취수탑 형식이 70% 이상을 차지하고 있으며 나머지 30%의 사통수문 중 원형수문비가 98% 이상을 차지하고 있다. 현재 대체에너지를 사용하는 저수지 사통수문은 없는 것으로 조사되었으며 전력을 사용하는 사통도 조사결과에 의하면 20% 이내로 나타났다. 이러한 결과는 향후 수리시설 개보수시 적은 예산으로 사업을 시행하는 경우 사통수문의 설치방향의 지표가 될 것으로 판단되며 수리시설의 운영관리에 대한 새로운 대안으로 제시할 수 있다.분류되었다. 지표 유거가 많아 배수등급이 매우양호로 분류되던 토양은 정 등(1995)의 분류와 비교하여 대부분 강우 유출 가능성이 큰 쪽으로 조정되었다. 새로운 수문학적 토양유형을 이용할 경우 낮은 토심에서 암반층이 발견되는 산림토양이 분포한 유역이나 산림, 밭 등에 식질 토양이 많이 분포하는 유역에서는 기존의 방법을 이용하는 것보다 강우 유출량이 높게 평가될 것으로 판단된다. 앞으로 강우 유출량 실측자료와의 비교를 통해 지속적인 보정을 하여야 할 것이며 특히 불투수층의 존재시 일괄적으로 D유형으로 분류된 토양의 경우 깊이에 따라 C 또는 D 유형으로 세분하여 조정할 필요가 있다.가 있었다. 에틸아세테이트분회물의 경우 디글로로메탄 분회물에 비해 다소 낮은 저해효과를 나타내었지만 250 ${\mu}$g/ml 농도에서 약 60%의 세포독성 효과를 나타내었다. 디클로로메탄 분획물과 에틸아세테이트 분

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On Generating Backbone Based on Energy and Connectivity for WSNs (무선 센서네트워크에서 노드의 에너지와 연결성을 고려한 클러스터 기반의 백본 생성 알고리즘)

  • Shin, In-Young;Kim, Moon-Seong;Choo, Hyun-Seung
    • Journal of Internet Computing and Services
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    • v.10 no.5
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    • pp.41-47
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    • 2009
  • Routing through a backbone, which is responsible for performing and managing multipoint communication, reduces the communication overhead and overall energy consumption in wireless sensor networks. However, the backbone nodes will need extra functionality and therefore consume more energy compared to the other nodes. The power consumption imbalance among sensor nodes may cause a network partition and failures where the transmission from some sensors to the sink node could be blocked. Hence optimal construction of the backbone is one of the pivotal problems in sensor network applications and can drastically affect the network's communication energy dissipation. In this paper a distributed algorithm is proposed to generate backbone trees through robust multi-hop clusters in wireless sensor networks. The main objective is to form a properly designed backbone through multi-hop clusters by considering energy level and degree of each node. Our improved cluster head selection method ensures that energy is consumed evenly among the nodes in the network, thereby increasing the network lifetime. Comprehensive computer simulations have indicated that the newly proposed scheme gives approximately 10.36% and 24.05% improvements in the performances related to the residual energy level and the degree of the cluster heads respectively and also prolongs the network lifetime.

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A Web-based Sensor Network Query and Data Management (웹 기반의 센서네트워크 질의 및 데이타 관리)

  • Hwang, Kwang-Il;Eom, Doo-Seop
    • Journal of KIISE:Computer Systems and Theory
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    • v.33 no.11
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    • pp.820-829
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    • 2006
  • Wireless sensor networks consisting of hundreds to thousands of nodes are expected to be increasingly deployed in coming years, as they enable reliable monitoring and analysis of physical worlds. These networks have unique features that are very different from traditional networks, e.g., the numerous numbers of nodes, limitation in power, processing, and memory. Due to these unique features of wireless sensor networks, sensor data management including querying becomes a challenging problem. Furthermore, due to wide popularization of the Internet and its facility in use, it is generally accepted that an unattended network can be efficiently managed and monitored over the Internet. In particular, in order to more efficiently query and manage data in a sensor network. in this paper, the architecture of a sensor gateway including web-based query server is presented and its implementation detail is illustrated. The presented web-based gateway is largely divided into two important parts: Internet part and sensor network part. The sensor network part plays an important role of handling a variety of sensor networks, including flat or hierarchical network architecture, by using internally layered architecture for efficiently querying and managing data in a sensor network. In addition, the Internet part provides a modular gateway function for favorable exchange between the sensor network and Internet.

Cold Plasma Treatment Application to Improve Microbiological Safety of Infant Milk Powder and Onion Powder (콜드 플라즈마 처리를 이용한 분유와 양파분말 살균)

  • Oh, Yeong Ji;Lee, Hanna;Kim, Jung Eun;Lee, Seok Hoon;Cho, Hyung Yong;Min, Sea Cheol
    • Korean Journal of Food Science and Technology
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    • v.47 no.4
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    • pp.486-491
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    • 2015
  • The potential of applying cold plasma (CP) treatments to improve microbiological safety of powdered products has been investigated using infant milk powder (IMP) and onion powder (OP). Among the different kinds of CP-forming gases, He-$O_2$ (99.8:0.2) gas mixture and He gas were most effective in reducing the number of Cronobacter sakazakii in IMP and Bacillus cereus spores in OP, respectively. C. sakazakii counts in IMP decreased by $0.9{\pm}0.1{\log}\;CFU/g$ after CP treatment, and the extent of C. sakazakii inhibition increased in a time-dependent manner. CP treatment at 900 W for 20 min reduced the number of B. cereus spores by ~0.4 log spores/g. Treatments that integrated CP with microwave (MW-CP treatment) as well as those that integrated CP with heat and microwave (H-MW-CP treatment) resulted in a 90% reduction in the number of spores in OP. Thus, CP treatments demonstrated potential for decontaminating foodborne pathogens from powdered products, in combination with heat for improved effect.

Column-aware Transaction Management Scheme for Column-Oriented Databases (컬럼-지향 데이터베이스를 위한 컬럼-인지 트랜잭션 관리 기법)

  • Byun, Si-Woo
    • Journal of Internet Computing and Services
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    • v.15 no.4
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    • pp.125-133
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    • 2014
  • The column-oriented database storage is a very advanced model for large-volume data analysis systems because of its superior I/O performance. Traditional data storages exploit row-oriented storage where the attributes of a record are placed contiguously in hard disk for fast write operations. However, for search-mostly datawarehouse systems, column-oriented storage has become a more proper model because of its superior read performance. Recently, solid state drive using MLC flash memory is largely recognized as the preferred storage media for high-speed data analysis systems. The features of non-volatility, low power consumption, and fast access time for read operations are sufficient grounds to support flash memory as major storage components of modern database servers. However, we need to improve traditional transaction management scheme due to the relatively slow characteristics of column compression and flash operation as compared to RAM memory. In this research, we propose a new scheme called Column-aware Multi-Version Locking (CaMVL) scheme for efficient transaction processing. CaMVL improves transaction performance by using compression lock and multi version reads for efficiently handling slow flash write/erase operation in lock management process. We also propose a simulation model to show the performance of CaMVL. Based on the results of the performance evaluation, we conclude that CaMVL scheme outperforms the traditional scheme.