• Title/Summary/Keyword: 전기침투

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Evaluation on Chloride Binding Capacity of Mineral Mixed Paste Containing an Alkaline Activator (알칼리 활성화제를 사용한 무기질 혼합 페이스트의 염화물이온 고정화 평가)

  • Cho, Gyu-Hwan;Yeo, In-Hwan;Ji, Dong-Hun
    • Journal of the Korea Concrete Institute
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    • v.28 no.2
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    • pp.157-165
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    • 2016
  • It is possible to achieve high strength ranging from 40 MPa to 70 MPa in alkali-activated slag concrete (AASC), and AASC is also known to have a finer pore structure due to its high latent hydraulicity and fineness of slag cement, which makes it difficult for chloride ions to penetrate. Electrophoresis is mostly used to calculate the effective diffusion coefficient of chloride ions, and then to evaluate resistance to salt damage. Few studies have been conducted on the fixation capacity of chloride ions in AASC. For this reason, in this study the chloride fixation within the hardened paste was evaluated according to the type and the amount of alkaline activators. As a result, it was revealed that among the test specimens, the chloride fixation was greatest in the paste containing $Na_2SiO_3$. In addition, it was found that as more activator was added, a higher level of chloride fixation was observed. Through this analysis, it can be concluded that the type and the amount of alkaline activators have a high correlation with the amount of C-S-H produced.

Resistance to Corrosion of Reinforcing Steel and Critical Chloride Content of High Volume Fly Ash Concrete (하이볼륨 플라이애시 콘크리트의 철근부식 저항성 및 임계 염화물량)

  • Lee, Hyun-Jin;Bae, Su-Ho;Jung, Sang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.375-381
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    • 2017
  • Recently, due to the increasing of interest about the eco-friendly concrete, it is being increased to use concretes containing by-products of industry such as fly ash, ground granulated blast furnace slag, silica fume, and etc. Especially, these are well known for improving the resistance to reinforcement corrosion in concrete and decreasing chloride ion penetration. The purpose of this experimental research is to evaluate the resistance to corrosion of reinforcement and critical chloride content of high volume fly ash concrete(HVFAC) which is replaced with fly ash for approximately 50% cement content. For this purpose, corrosion monitoring of reinforcement by half cell potential method was carried out for the cylindrical test specimens that the upper of reinforcement in concrete was exposed to detect the time of corrosion initiation for reinforcement. It was observed from the test result that the the time of corrosion initiation for reinforcement of HVFAC by the accelerated corrosion tests increased 1.2~1.3 times than plain concrete and the critical chloride contents of plain concrete and HVFAC were found to range $0.80{\sim}1.20kg/m^3$, $0.89{\sim}1.60kg/m^3$, respectively.

Study on High-speed Cyber Penetration Attack Analysis Technology based on Static Feature Base Applicable to Endpoints (Endpoint에 적용 가능한 정적 feature 기반 고속의 사이버 침투공격 분석기술 연구)

  • Hwang, Jun-ho;Hwang, Seon-bin;Kim, Su-jeong;Lee, Tae-jin
    • Journal of Internet Computing and Services
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    • v.19 no.5
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    • pp.21-31
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    • 2018
  • Cyber penetration attacks can not only damage cyber space but can attack entire infrastructure such as electricity, gas, water, and nuclear power, which can cause enormous damage to the lives of the people. Also, cyber space has already been defined as the fifth battlefield, and strategic responses are very important. Most of recent cyber attacks are caused by malicious code, and since the number is more than 1.6 million per day, automated analysis technology to cope with a large amount of malicious code is very important. However, it is difficult to deal with malicious code encryption, obfuscation and packing, and the dynamic analysis technique is not limited to the performance requirements of dynamic analysis but also to the virtual There is a limit in coping with environment avoiding technology. In this paper, we propose a machine learning based malicious code analysis technique which improve the weakness of the detection performance of existing analysis technology while maintaining the light and high-speed analysis performance applicable to commercial endpoints. The results of this study show that 99.13% accuracy, 99.26% precision and 99.09% recall analysis performance of 71,000 normal file and malicious code in commercial environment and analysis time in PC environment can be analyzed more than 5 per second, and it can be operated independently in the endpoint environment and it is considered that it works in complementary form in operation in conjunction with existing antivirus technology and static and dynamic analysis technology. It is also expected to be used as a core element of EDR technology and malware variant analysis.

CO2 Evaluation of Reinforced Concrete Column Exposed to Chloride Attack Considering Repair Timing (보수시기를 고려한 염해에 노출된 콘크리트 교각의 탄소량 평가)

  • Kim, Seong-Jun;Kim, Young-Joon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.1-9
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    • 2014
  • In this paper, $CO_2$ amount is evaluated considering repairing timing and unit $CO_2$ amount per repair method including various stage of material manufacturing, moving, and construction. Four mix proportions with mineral admixture are considered and repairing timing/numbers are simulated based on the results from Life 365 which can handle chloride penetration. Furthermore two repair methods (simple cover concrete replacement and replacement with electro-chemical method for removing chloride content) are considered and the related $CO_2$ emissions are evaluated. From the study, the case with high W/B (water to binder ratio) ratio shows smaller $CO_2$ emission in construction stage but it increases more rapidly with increasing number of repair. $CO_2$ emission considering electro-chemical method greatly increases with the increasing unit $CO_2$ for the repairing method. The numbers of jumping step (repairing number) are evaluated to be 9 for WB37-OPC, 18 for WB50-OPC, 4 for WB40-SG, and 7 for WB47-SG respectively. RC structures with the longer maintenance free period are evaluated to be advantageous for saving $CO_2$ emission.

A Study on the Micellization of Sodium Dodecyl Sulfate in 𝜔-Phenylakylammonium Salt Solution (𝜔-Phenylalkylammonium Salt의 수용액에서 Sodium Dodecyl Sulfate의 미셀에 관한 연구)

  • Ryu, Yeanho;Oh, Jung Hee
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.1041-1047
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    • 1997
  • The influence of $\omega$-phenylalkylammonium salt on the critical micelle concentration (CMC) of SDS has been examined using the electric conductivity method. CMC of SDS exhibited the tendency to decrease with the length of alkyl group of additives. The effect of temperature on CMC of SDS in additive solutions has been observed in the range of $18^{\circ}C-50^{\circ}C$. The free energy(${\Delta}G_m^{\circ}$) for the micellization of SDS is negative and the entropy(${\Delta}S_m^{\circ}$) is a large positive value. The enthalpy(ΔHm0is positive in low temperature($18^{\circ}C$) and negative in high temperature($>25^{\circ}C$). In the prensence of organic additives, the micellization of SDS was considered as a spontaneous process and to involve a phase transition. The values of ΔGm0has shown the tendency to increase but the values of ${\Delta}S_m^{\circ}$ and ${\Delta}H_m^{\circ}$ to decrease with the length of alklyl group of additive salts. The changes in ${\Delta}\kappa$(difference of specific conductivity) with increasing mole ratio of additives in the mixed solutions indicated the formation of mixed micelles between SDS and additives. The effect of the length of alkyl chain on the micellization of SDS demonstrated the penetration of organic additives into the palisade layer of the SDS micelle.

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The Long-term Durability Evaluation of PC Box for Near-surface Transit System manufactured by Microwave Heat curing (마이크로웨이브 발열양생에 의해 제작된 저심도 철도시스템용 PC BOX의 장기내구성 평가)

  • Koh, Tae-Hoon;Yoo, Han-Ju
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.766-771
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    • 2016
  • This study examined the long-term durability of PC boxes, which was manufactured by low-carbon eco-friendly concrete using an alternative binder to cement and alternative fine aggregate to sand and microwave heat curing system to reduce the construction cost of a near-surface transit system. Based on the test results, the initial compressive strength of microwave heat cured concrete was higher than that of the steam cured concrete, but those were similar in the long-term age. In addition, there was no significant difference between the two curing conditions in the chemical resistance and the freeze-thawing resistance, and the chloride ion penetration level of the concrete cured by two methods was very low. Therefore, low-carbon eco-friendly concrete and microwave heat curing technology are expected to contribute to the economic construction of a near-surface transit system, and reduce carbon dioxide emissions and environmental impact.

Effects of iso-Butanol on Photosynthetic Electron Transport Activity in Isolated Spinach Chloroplasts (시금치(Spinacia oleracea L.) 엽록체의 광합성 전자전달 활성에 미치는 iso-Butanol의 영향)

  • 박강은
    • Journal of Plant Biology
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    • v.35 no.3
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    • pp.247-252
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    • 1992
  • The effect of iso-butanol on the electron transport rate of PS I and PS II was investigated in isolated spinach chloroplasts. In photosystem I, the rate of electron transport increased in the presence of 1 to 4% of isobutanol but decreased in 5 to 9% of iso-butanol. But in photosystem II, the rate of electron transport decreased when treated with 0.2 to 1% of iso-butanol. The inhibitory effect of isomers of butanol on PS II electron transport rate increased in the order of 2-butanol, tert-butanol, iso-butanol and I-butanol. This means that PS II activity was affected according to the arrangement of carbon atoms in butanol. The inhibitory effect of iso-butanol reduced when DPC was added in the solution. This means that iso-butanol affects PS II reduction side of thylakoid membrane primarily. The inhibitory effect of iso-butanol was reduced when $Mn^{2+},\;C^{2+}$ or BSA were added in the solution. PS II activity was restored when 1% iso-butanol treated chloroplast solution was diluted to twentyfold or when $Mn^{2+},\;C^{2+}$ or BSA was added to the diluted solution. However, the SDS-PAGE banding pattern of thylakoid membrane proteins was similar even in 2% iso-butanol treated chloroplasts and the control ones. Only in 5% iso-butanol treated chloroplasts these bands were very weak. These observations suggest that low concentrations of iso-butanol releases manganese and calcium ions from chloroplasts and inhibits the electron transport system. This inhibitory effect can be reversible in low concenterations but in high concentrations the inhibitory effect of iso-butanol become irreversible.rsible.

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A Study on the Characteristics of the Landslide in Hyuseok-dong(II) -Geological and Hydrological Characteristics- (휴석동(休石洞) 땅밀림형(型) 산사태(山沙汰)의 발생특성(發生特性)에 관한 연구(硏究)(II) -지질(地質) 및 수문특성(水文特性)-)

  • Woo, Bo-Myeong;Park, Jae-Hyeon;Choi, Hyung-Tae;Jeon, Gi-Seong;Kim, Kyung-Hoon
    • Journal of Korean Society of Forest Science
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    • v.85 no.4
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    • pp.571-576
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    • 1996
  • The geological and hydrological survey was carried out in Hyuseok-dong landslide area(10 ha), Youngchoon-myeon, Danyang-gun, Choongcheongbuk-do. The results showed that the bed rocks in this area consisted of shale, sandstone and limestone, and the piles of stones debris were also scattered around the hill above the study area. Soil texture was sandy loam, and bulk density of the soil in the lower part of the area was higher than that of the upper part, but void ratio of the soil in the lower part was lower than that of the upper part. Subsurface water was springing out to the surface in many places in this area. In this area, the storms over 70mm/day were frequent during the summer period from June through September. It was concluded that the occurrence of landslide had a close relationship with the geological characteristics, hydrological conditions and the rainfall distribution.

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Separator Properties of Silk-Woven Fabrics Coated with PVdF-HFP and Silica and the Charge-Discharge Characteristics of Lithium-ion Batteries Adopting Them (PVdF-HFP와 실리카가 코팅된 실크 견직물의 분리막 특성과 이를 채용한 리튬이온전지의 충방전 특성)

  • Oh, Seem Geon;Lee, Young-Gi;Kim, Kwang Man;Lee, Yong Min;Kim, Sang Hern;Kim, Yong Joo;Ko, Jang Myoun
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.330-334
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    • 2013
  • Mixtures of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) and silica nanoparticles are coated on the surface of a silk fabrics separator. The coated separators are finally prepared by injecting an electrolyte solution and then characterized for use of lithium-ion battery separator/electrolyte. In the preparation, various contents of dibutylphthalate (DBP) as a plasticizer are used to enhance the formation of micropores within the coated membrane. The coated silk fabrics separators are characterized in terms of ionic conductivity, drenching rate, and electrochemical stability, and the charge-discharge profiles of lithium-ion batteries adopting the coated separators are also examined. As a result, the coated silk fabrics separator prepared using DBP 40~50 wt% and silica shows the superior separator properties and high-rate capability. This is due to (i) high sustainability of silk fabrics, (ii) the formation of micropores with the coated layer membrane by DBP, (iii) increase in drenching rate by silica nanoparticles to involve great enhancements in specific surface area and ionic conductivity.

Permeation Effect of NaCl into Shell Egg with Concentration of NaCl Solution, Salting Time and Salting Pressure (염지액농도, 염지시간 및 염지압력에 따른 계란의 염 침투효과)

  • 전기홍;유익종;장윤희;강통삼
    • Korean Journal of Poultry Science
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    • v.20 no.3
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    • pp.125-131
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    • 1993
  • This study was performed to find the desirable conditions for processing salted hard-boiled egg without cracking egg shell in NaCl solution under pressure. Among the many factors affecting saltiness of the shell egg, concentration of NaCl solution(0~40%), different salting time(0~45h) and salting pressure (0~4.5kg/$\textrm{cm}^2$) were employed to identify the permeability of NaCl into shell egg at ambient temperature. The saltiness of the shell egg was proportionally risen as concentration of NaCl solution, salting time and pressure increased. The most desirable saltiness was observed at the 0.70~1.00% of NaCl in albumen and 0.40~0.45% in yolk, Besides the saltiness, sensory evaluation of the shell egg were carried out to evaluate the quality of the salted shell egg. The effect of various concentration of NaCl solution, salting time and pressure on sensory scores of hard-boiled salted eggs showed that 20~40% of NaCl solution, 12~20 h of salting time, 3~4.5 kg/$\textrm{cm}^2$ of salting pressure were proper conditions for processing the product. These results indicate that the desirable condition to get salted hard-boiled shell egg were ; 30% of NaCl solution, 16h of salting time and 4.0kg/$\textrm{cm}^2$ of salting pressure.

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