• Title/Summary/Keyword: 전기임피던스

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Electrochemical Impedance Spectroscopy Analysis on the Dye-sensitized Solar Cell with Different $TiO_2$ thicknesses ($TiO_2$ 두께에 따른 염료감응형 태양전지의 전기화학적 임피던스 분석)

  • Kim, Hee-Je;Lee, Jeong-Gee;Seo, Hyun-Woong;Son, Min-Kyu;Kim, Jin-Kyoung;Prabalkar, K.;Shin, In-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.12
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    • pp.2425-2430
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    • 2009
  • Dye-sensitized solar cell(DSC) is composed of a dye-adsorbed nanoporous $TiO_2$ layer on fluorine-doped tin oxide(FTO) glass substrate, electrolyte, and platinium doped counter electrode. Among these, a dye-absorbed nanoporous $TiO_2$ layer plays an important role in the performance of the DSC because the injected electrons from excited dye molecules move through this layer. And the condition of $TiO_2$ layer such as the morphology and thickness affects on the electron movement. Therefore, the performances and the efficiency of DSC change as the thickness of $TiO_2$ layer is different. Electrochemical Impedance Spectroscopy(EIS) is the powerful analysis method to study the kinetics of electrochemical and photoelectrochemical processes occurring in the DSC especially the injected electron movements. So we analyzed the DSCs with different $TiO_2$ thicknesses by using EIS to understand the influence of the $TiO_2$ thickness to the performance of the DSC clearly. Finally, we got the EIS analysis on the DSC with different $TiO_2$ thickness from the internal resistance of the DSC, the electron life time and the amount of dye molecules.

Effective Installation Methods of Down Conductors in Lightning Protection Systems (뇌보호시스템에서 인하도선의 효과적인 설치기법)

  • 이복희;엄주홍;이승칠;강성만
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.4
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    • pp.8-14
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    • 2002
  • A modern lightning protection system is required to eliminate the risks such as electrical shocks and damages of structures, electrical and electronic equipments due to lightning. However, the conventional lightning protection systems play and important role in protecting persons and structures only. Thus an effective lightning protection system is indispensable today in computer, information and communication facilities and etc. The mafor objective of this paper is to develop the technology to protect electronics and computerized facilities against lightning-caused overvoltages. The study is oriented on the control of the potential rise of down conductors with the type and installation method of down conductors. As a result, to reduce side flashes and hazards caused by the potential rise of down conductor due to lightning current, the coaxial cable with a low characteristic impedance and high insulation level is suitable for a down conductor. In particular it is extremely effective to bond down conductors to the steel supporter, metal raceways and steel frame of structures.

Electrochemical Characteristics of Porous Silicon/Carbon Composite Anode Using Spherical Nano Silica (구형 나노 실리카를 사용한 다공성 실리콘/탄소 음극소재의 전기화학적 특성)

  • Lee, Ho Yong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.459-464
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    • 2016
  • In this study, the electrochemical characteristics of porous silicon/carbon composite anode were investigated to improve the cycle stability and rate performance in lithium ion batteries. In this study, the effect of TEOS and $NH_3$ concentration, mixing speed and temperature on particle size of nano silica was investigated using $St{\ddot{o}}ber$ method. Nano porous Si/C composites were prepared by the fabrication processes including the synthesis of nano $SiO_2$, magnesiothermic reduction of nano $SiO_2$ to obtain nano porous Si by HCl etching, and carbonization of phenolic resin. Also the electrochemical performances of nano porous Si/C composites as the anode were performed by constant current charge/discharge test, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1vol%). It is found that the coin cell using nano porous Si/C composite has the capacity of 2,006 mAh/g and the capacity retention ratio was 55.4% after 40 cycle.

The Electrochemical Characterization of $LiMn_{2-y}M_{y}O_{4}$ Cathode Material. III. The Effect of Temperature on the Charge-discharge Property and AC Impedance of $LiMn_{2-y}M_{y}O_{4}$ ($LiMn_{2-y}M_{y}O_{4}$ 정극 활물질의 전기화학적 특성. III. $LiMn_{2-y}M_{y}O_{4}$의 충방전 특성과 AC 임피던스의 온도 의존성)

  • 정인성;구할본;김종욱;손명모;이헌수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.663-669
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    • 2001
  • Spinel LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ power was synthesized with solid-state method by calcining the mixture of LiOH.$H_2O$, Mn $O_2$ and MgO at 80$0^{\circ}C$ for 36 h in an air atmosphere. To investigate the effect of temperature on he cycle performance of cathode material during cycling, charge-discharge experiments and ac impedance measurement were performed. Initial discharge capacity was gradually increased with the increase of charge-discharge temperature. Discharge capacity at high temperature was suddenly decreased during cycling. On the other hand, discharge capacity at low temperature was almost constant during cycling. It confirmed that Mn dissolution is serious at high temperature than at low temperature. LiM $n_2$ $O_4$ and LiM $n_{1.9}$M $g_{0.1}$ $O_4$ showed the best capacity and stability at room temperature.ure.ure.

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Study on the High-Frequency Circuit Modeling of the Conducted-Emission from the Motor Drive System of an Electric Vehicle (전기자동차 모터 구동 시스템의 전도 방출에 관한 고주파 모델링 연구)

  • Jung, Kibum;Lee, Jongkyung;Chung, Yeon-Choon;Choi, Jaehoon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.24 no.1
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    • pp.82-90
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    • 2013
  • In this paper, conducted emission from the MDS(Motor Drive System) of a HEV/EV was analyzed using high- frequency circuit modeling in system-level approach. The conducted emission by PWM process can cause RFI(radio- frequency interference) problems in the AM/FM frequency range. In order to mitigate this conducted emission, a high-frequency equivalent circuit model is proposed by analyzing the fundamental circuits, parasitic components in their parts and connections and non-linear characteristics of IGBTs, high-power capacitors, inverters, motors, high-power cables, and bus bars which are composed of the MDS. It is confirmed that the simulated result by the proposed model is well agreed with measured results in spite of a large-scaled analysis in system level. We are looking forward that this approach can be effectively used in the EMC design of HEV/EV.

Characteristics Analysis for Voltage, Current & Capacity of Condenser at Voltage Unbalance (전압 불평형시 콘덴서 전압, 전류, 용량 특성 해석)

  • Kim, Jong-Gyeum;Park, Young-Jeen
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.5
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    • pp.145-151
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    • 2010
  • Voltage unbalance is regarded as a power quality problem of significant at the user application. Although the voltages are quite well balanced at the transmission system, the voltage level of utilization can be unbalanced due to the unequal system impedances and the unequal distribution of single phase loads. Capacitor is generally used for power-factor compensation and reducing harmonics of non linear load with reactor. If voltage unbalance exists, current unbalance is generated and it will be reflected in the capacity variance. When the reactor and condenser are used at the same location, generally its trouble rate is high. And it is very important checking out that how the variance of voltage, current and capacity of condenser is proceeded by the voltage unbalance. In this paper, we calculated that voltage, current and capacity of condenser are within the tolerance limit of official regulations in the event of voltage unbalance with/without reactor.

Development and Verification of a Hand-held Typed Monitoring System for Cardiac Output Measurement using Electrical Impedance Technique (전기적 임피던스 방법을 통한 hand-held 타입의 심박출량 모니터링 시스템 개발 및 검증)

  • Seo, Kwang-Seok;Sim, Myeong-Heon;Kim, Min-Yong;Yoon, Chan-Sol;Chung, Joo-Hong;Park, Sung-Bin;Yoon, Hyung-Ro
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.12
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    • pp.1932-1938
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    • 2012
  • The impedance cardiogram has been proposed as a non-invasive, continuous, operator independent, and cost-effective method for cardiac output monitoring. However, it can not be completely considered as non-restrictive method because of attached spot and band type electrodes. Therefore, we developed a improved convenient hand-held typed measurement system for cardiac output by electrical impedance technique. 80 subjects from Yonsei University and the surrounding areas, participated. All subjects measured stroke volume and cardiac output through Physioflow and developed system. To verify the developed system, statistical methods such as correlation, Wilcoxon signed ranks test, and the Bland-Altman analysis were used. The proposed system showed significant correlation in both male and female stroke volume(r=0.715, r=0.704) and cardiac output(r=0.826; r=0.804). From these results, it can be concluded that stroke volume and cardiac output could be improved convenient measurement using the both hands without the help of a specialist.

A Non-Linear Characteristics Modeling of High Frequency FL Lamp by Experimental Values (실험식을 이용한 고주파 형광램프의 비선형특성 모델링)

  • 함중걸;백수현
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.2
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    • pp.51-55
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    • 1997
  • The high frequency fluorescnet lighting systems are widely used because of their high luminous efficacy. However, the performance of the fluorescnet lamp at high frequency reveals significant changes depending upon operating frequency, lamp shape, lamp voltage and current while adapting either an electronic or an magnetic ballast. Therefore the matching between the fluorescent lamp and the ballast is the major concern in designing a lighting system. In this paper, high frequency characteristics of the FHF32W lamp is measured in a range of frequencies from 12kHz to 50kHz. And we presented a model of a fluorescnet lamp with non-linear impedance depending on the lamp current. Finally, after identifying the operating condition under negative imped¬ance behavior as lamp current changing, we proposed a method of choosing the optimal parameter of a high frequency fluorescnet lamp and the result is analyzed.

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The Effect of Sintering Time in the Microstructure and Electric Conductivity of $(Gd_2O_3)_{0.05}(Y_2O_3)_{0.05}(ZrO_2)_{0.9}$ System ($(Gd_2O_3)_{0.05}(Y_2O_3)_{0.05}(ZrO_2)_{0.9}$계의 소결시간에 따른 미세구조와 전기전도도)

  • 임용무;장복기;신동선;김동근;김종빈;윤성도
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1099-1107
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    • 1998
  • In this study, the microstructure and electric conductivity of 5mol% $Gd_2O_3$-5mol% $Y_2O_3-ZrO_2$ system(5G5YZ) with a variation of sintering time at $1600^{\circ}C$ were investigated. By the result of TEM analysis of 5G5YZ sintered for 12h, a microcrack was observed near grain boundary. The change of the sintering time did not affect the lattice conductivity, but the grain boundary contribution was varied with the sintering time. The grain boundary conductivity of the sample sintered for 1h showed the highest value. Furthermore, the activation energy of the total conductivity was independent upon the sintering time and showed approximately 1.01eV. The highest conductivity measured at $1000^{\circ}C$ was 0.0197S/cm with the sample sintered for 1h. Comparing to 0h’s, the thickness ration of grain boundary as a function of sintering time were 0.88, 1.11 and 1.29 for 1h, 5h and 12h, respectively. In case of the sample sintered for 1h, the thickness of the grain boundary showed the lowest value. The increase of the sintering time over 1h made the decrease of the electric conductivity as well as the increase of the grain growth and the thickness of the grain boundary. As a result, it seemed that the proper sintering time for 5G5YZ composition was 1h.

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Electrochemical Characteristics of Artificial Graphite Anode Coated with Petroleum Pitch treated by Solvent (용매 처리 석유계 피치로 코팅된 인조 흑연 음극소재의 전기화학적 특성)

  • Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.5-10
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    • 2019
  • In this study, electrochemical characteristics of artificial graphite coated with petroleum pitch using solvent method as anode material of lithium ion battery were investigated. As the solvent, n-hexane, toluene, tetrahydrofuran and quinoline were used. The surface of the prepared anode material was analyzed by SEM and TEM. Also the electrochemical performances of the prepared anode materials were performed by constant current first charge/discharge, cycle, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DEC=1:1 vol%). The coating thickness of the prepared graphite was about 100-500 nm and the graphite coated with THF solvent had a smoother surface than that using other solvents. It was found that pitch-coated graphite (THF) show the low initial irreversible capacity (51 mAh/g), the high discharge capacity (360 mAh/g) and coulombic efficiency (99%).